研究者詳細

顔写真

フルカワ　シヨウイチ
古川　翔一
Shohichi Furukawa
所属
高等研究機構材料科学高等研究所　デバイス・システムグループ
職名
特任助教（研究）
学位

  • 博士（人間･環境学）（京都大学）

  • 修士（人間･環境学）（京都大学）

e-Rad 研究者番号
21004293

研究分野 3

  • ナノテク・材料 / 有機機能材料 / 多孔質有機構造材料

  • ナノテク・材料 / 有機合成化学 / 有機金属錯体

  • ナノテク・材料 / 高分子化学 / 高分子ゲル

論文 10

  1. Tailoring Ca2+/Li+ Dual-Cation Gel Polymer Electrolytes via Cross-Linking for Reductive and Oxidative Stability in Ca-Metal Batteries

    Takara Shinohara, Kazuaki Kisu, Shohichi Furukawa, Kenji Zushida, Shin-ichi Orimo

    ACS Applied Energy Materials　2025年3月12日

    出版者・発行元： American Chemical Society (ACS)

    DOI： 10.1021/acsaem.4c03065 　

    ISSN：2574-0962

    eISSN：2574-0962

  2. Photocatalytic decarboxylative deuteration of lauric acid with heavy water for sustainable synthesis of deuterated alkanes

    Haifan Huang, Zihan Lin, Akira Yamamoto, Yagna Bhoi Prakash, Kexin Zou, Shohichi Furukawa, Ken-ichi Fujita, Gunik Lee, Jun Kumagai, Hisao Yoshida

    Catalysis Science & Technology　2025年

    出版者・発行元： Royal Society of Chemistry (RSC)

    DOI： 10.1039/d5cy00316d 　

    ISSN：2044-4753

    eISSN：2044-4761

    詳細を見る 詳細を閉じる

    A green photocatalytic strategy with Au/TiO2 for synthesizing deuterated compounds by using heavy water (D2O) as the deuterium source. Deuterium substitution of the major product predominantly occurs at the second carbon.

  3. Selective N-alkylation catalyzed by polymer gels with crosslinked domains containing iridium complexes

    Shohichi Furukawa, Hiroki Takeshita, Ken-ichi Fujita, Shohei Ida

    Polymer Journal　56　(5)　561-565　2024年1月26日

    出版者・発行元： Springer Science and Business Media LLC

    DOI： 10.1038/s41428-024-00885-x 　

    ISSN：0032-3896

    eISSN：1349-0540

  4. Low‐Temperature N‐Alkylation of Amines with Alcohols in Protic Solvents Catalyzed by Iridium Complexes Bearing N‐Heterocyclic Carbenes

    Shohichi Furukawa, Namino Morishima, Ken‐ichi Fujita

    European Journal of Organic Chemistry　27　(6)　2024年1月16日

    出版者・発行元： Wiley

    DOI： 10.1002/ejoc.202301105 　

    ISSN：1434-193X

    eISSN：1099-0690

    詳細を見る 詳細を閉じる

    Abstract Amines are important compounds found in natural products, pharmaceuticals, and fine chemicals. Therefore, the development of elegant, environmentally friendly, and simple synthetic methods is desirable. Recently, the borrowing‐hydrogen (BH) strategy has received considerable attention for C−N bond formations because of its high atomic efficiency and the absence of toxic waste generation. Researchers have recently reported that the use of N‐heterocyclic carbene (NHC) ligands with strong electron‐donating properties and protic solvents can increase the catalytic activity in the BH strategy. Therefore, herein, we focused on the versatility of the synthetic methods, such as a synthetic system that allows simple synthesis, operates at low reaction temperatures, and involves the use of effective solvent simultaneously. The catalyzed N‐alkylation of alcohols and amines in protic solvents under mild conditions was investigated using simple NHC complexes developed by our group. We achieved the synthesis of various alkylamines under mild conditions, such as 40–60 °C, using iridium complexes comprising NHC ligands with simple structures and protic solvents such as 2,2,2‐trifluoroethanol and 1,1,1,3,3,3‐hexafluoroisopropanol.

  5. Long-Term Hydrogen Production from a Methanol–Water Solution Catalyzed by an Iridium Complex

    Shohichi Furukawa, Kaito Kubota, Han Wang, Haotong Gong, Shumpei Kajita, Ken-ichi Fujita

    Catalysts　13　(6)　1027-1027　2023年6月20日

    出版者・発行元： MDPI AG

    DOI： 10.3390/catal13061027 　

    eISSN：2073-4344

    詳細を見る 詳細を閉じる

    Long-term hydrogen production from a methanol–water solution was achieved by developing a new reaction system employing a homogeneous iridium catalyst bearing a bipyridonate-type functional ligand. By optimizing the methanol:water ratio of the reaction solution, the efficiency of hydrogen production was greatly improved in relation to that reported in our previous studies. Additionally, the effect of the scale of reaction was investigated. It was found that a small-scale reaction led to a longer lifetime of the iridium catalyst, accomplishing long-term continuous hydrogen production at a constant rate for over 500 h. Furthermore, procedures for catalyst reuse were studied. After hydrogen production for 400 h, all volatiles in the reaction system were removed under vacuum. This simple procedure is highly effective for the reactivation and reuse of the catalyst. Finally, hydrogen production (13.7 L, 562 mmol) from methanol (12.3 mL, 303 mmol) and water (5.46 mL, 303 mmol), in a continuous reaction for 800 h, was achieved.

  6. Synthesis of thermoresponsive polymer gels with crosslinked domains containing iridium complexes for ammonia sensing and N-alkylation catalysis

    Shohichi Furukawa, Takahiro Okuno, Takuya Shimbayashi, Hiroki Takeshita, Ken-ichi Fujita, Shohei Ida

    Polymer Journal　55　(9)　945-955　2023年6月7日

    出版者・発行元： Springer Science and Business Media LLC

    DOI： 10.1038/s41428-023-00801-9 　

    ISSN：0032-3896

    eISSN：1349-0540

  7. Synthesis of 2-Methylquinoxaline Derivatives from Glycerol and Diamines Catalyzed by Iridium Complexes Bearing an N-Heterocyclic Carbene Ligand

    Toshiki Tanaka, Akane Enomoto, Shohichi Furukawa, Ken-ichi Fujita

    Catalysts　11　(10)　1200-1200　2021年9月30日

    出版者・発行元： MDPI AG

    DOI： 10.3390/catal11101200 　

    eISSN：2073-4344

    詳細を見る 詳細を閉じる

    2-Methylquinoxaline derivatives are widely used as intermediates in the synthesis of pharmaceuticals, natural products, and dyes; however, their syntheses usually require excess reagents, making them environmentally burdensome. Meanwhile, glycerol can be sustainably obtained in large quantities as a by-product in the production of biodiesel fuel using waste oil as a raw material. Thus, it is worthwhile to develop a new catalytic system that utilizes glycerol as a C3 source. In this study, an efficient catalytic system was developed to obtain 2-methylquinoxaline derivatives from glycerol and 1,2-phenylenediamines. This system is beneficial because it is environmentally friendly and has excellent atom efficiency.

  8. Iridium Complex Catalyzed Hydrogen Production from Glucose and Various Monosaccharides

    Ken-ichi Fujita, Takayoshi Inoue, Toshiki Tanaka, Jaeyoung Jeong, Shohichi Furukawa, Ryohei Yamaguchi

    Catalysts　11　(8)　891-891　2021年7月23日

    出版者・発行元： MDPI AG

    DOI： 10.3390/catal11080891 　

    eISSN：2073-4344

    詳細を見る 詳細を閉じる

    A new catalytic system has been developed for hydrogen production from various monosaccharides, mainly glucose, as a starting material under reflux conditions in water in the presence of a water-soluble dicationic iridium complex bearing a functional bipyridine ligand. For example, the reaction of D-glucose in water under reflux for 20 h in the presence of [Cp*Ir(6,6′-dihydroxy-2,2′-bipyridine)(H2O)][OTf]2 (1.0 mol %) (Cp*: pentamethylcyclopentadienyl, OTf: trifluoromethanesulfonate) resulted in the production of hydrogen gas in 95% yield. In the present catalytic reaction, it was experimentally suggested that dehydrogenation of the alcoholic moiety at 1-position of glucose proceeded.

  9. N‐Alkylation of Aqueous Ammonia with Alcohols Leading to Primary Amines Catalyzed by Water‐Soluble N‐Heterocyclic Carbene Complexes of Iridium

    Ken‐ichi Fujita, Shohichi Furukawa, Namino Morishima, Mineyuki Shimizu, Ryohei Yamaguchi

    ChemCatChem　10　(9)　1993-1997　2018年3月5日

    出版者・発行元： Wiley

    DOI： 10.1002/cctc.201702037 　

    ISSN：1867-3880

    eISSN：1867-3899

    詳細を見る 詳細を閉じる

    Abstract A new catalytic system for the N‐monoalkylation of aqueous ammonia with a variety of alcohols was developed. Water‐soluble dicationic complexes of iridium bearing N‐heterocyclic carbene and diammine ligands exhibited high catalytic activity for this type of reaction on the basis of hydrogen‐transfer processes without generating harmful or wasteful byproducts. Various primary amines were efficiently synthesized by using safe, inexpensive, and easily handled aqueous ammonia as a nitrogen source. For example, the reaction of 1‐(4‐methylphenyl)ethanol with aqueous ammonia in the presence of a water‐soluble N‐heterocyclic carbene complex of iridium at 150 °C for 40 h gave 1‐(4‐methylphenyl)ethylamine in 83 % yield.

  10. 成長する架橋剤—RAFT重合によりビニル基間の鎖長を変化させる架橋剤の合成とそれを用いたゲル化

    72　(7)　440-446　2015年

    出版者・発行元：

    DOI： 10.1295/koron.2014-0098 　

    ISSN：0386-2186

    eISSN：1881-5685

︎全件表示 ︎最初の5件までを表示

書籍等出版物 1

  1. 水中有機合成の開発動向

    監修:小林 修, 北之園 拓, 古川 翔一

    シーエムシー出版　2022年3月

    ISBN: 9784781316635