Details of the Researcher

PHOTO

Eiji Akiyama
Section
Institute for Materials Research
Job title
Professor
Degree
  • 博士(理学)(東北大学)

  • 理学修士(東北大学)

Researcher ID

Research History 6

  • 2016/04 - Present
    Tohoku University Institute for Materials Reseach Professor

  • 2001/04 - 2016/03
    物質・材料研究機構

  • 2002/04 - 2003/03
    Max Planck Institute for Iron Research

  • 1999/06 - 2001/03
    金属材料技術研究所

  • 1997/05 - 1999/05
    The Ohio State University Fontana Corrosion Center Post-doctoral researcher

  • 1991/04 - 1999/03
    Tohoku University Institute for Materials Research

Show all Show first 5

Education 2

  • Tohoku University Graduate School of Science

    1989/04 - 1991/03

  • Tohoku University Faculty of Science Department of Chemistry

    1985/04 - 1989/03

Committee Memberships 33

  • 日本金属学会会誌・欧文誌編集委員会 編集委員

    2024/04 - Present

  • 腐食防食学会 理事

    2024/04 - Present

  • 日本鉄鋼協会「耐水素脆化材料の評価・解析技術の温故知新」フォーラム 幹事

    2024/03 - Present

  • 日本鉄鋼協会東北支部 支部長

    2024/03 - Present

  • 日本ばね学会遅れ破壊試験標準化委員会 委員長

    2024/03 - Present

  • 日本鉄鋼協会「水素侵入と水素捕捉に関する革新的評価技術」研究会 委員

    2023/03 - Present

  • 日本MRS水素科学技術連携研究会 理事

    2022/02 - Present

  • 日本鋼構造協会「OS法(新耐力点法)に係わるJSS規格作成小委員会」 委員

    2021/11 - Present

  • 日本金属学会会誌編集委員会・欧文誌編集委員会 査読委員

    2020/04 - Present

  • 日本鉄鋼協会東北支部 委員

    2020/03 - Present

  • 腐食防食学会 広報・Web委員

    2019/04 - Present

  • CCR研究会 会長

    2018/02 - Present

  • 腐食防食学会 編集委員

    2020/08 - 2024/03

  • 日本鉄鋼協会「実環境の水素脆化過程解明に向けた課題抽出」フォーラム 幹事

    2022/03 - 2024/02

  • 腐食防食学会東北支部 支部長

    2020/04 - 2023/03

  • 日本鉄鋼協会「鋼材腐食水素侵入に関する評価技術の新展開」フォーラム 幹事

    2021/03 - 2023/02

  • 日本鉄鋼協会「水素脆化の基本要因と実用課題」フォーラム 幹事

    2018/03 - 2022/02

  • 日本鉄鋼協会「鉄鋼材料への腐食誘起水素侵入」研究会 幹事

    2018/03 - 2021/02

  • 日本学術振興会第190委員会 第3分科運営幹事

    2016/04 - 2020/03

  • 腐食防食学会 広報委員

    2015/04 - 2018/03

  • 日本鉄鋼協会「大気腐食中の鋼材への水素侵入挙動の解明」フォーラム アドバイザー

    2016/03 - 2018/02

  • 日本鉄鋼協会 「水素脆化の基本要因と特性評価」研究会 幹事

    2015/03 - 2018/02

  • 日本鉄鋼協会 「革新的水素不働態表面構築の原理探求研究会」研究会 アドバイザー

    2013/04 - 2016/02

  • 日本鉄鋼協会 「水素脆化の解析と評価」フォーラム 座長

    2012/04 - 2016/02

  • 日本鉄鋼協会 「水素脆化研究の基盤構築」研究会 幹事

    2009/04 - 2013/03

  • 日本鉄鋼協会 「水素脆化研究の基盤としての材料中の水素の解析」自主フォーラム 座長

    2011/04 - 2012/03

  • 腐食防食学会 庶務理事

    2010/04 - 2012/03

  • 日本鉄鋼協会 「水素の存在状態解析と水素脆化の基礎 」フォーラム 座長

    2009/04 - 2011/03

  • 日本鋼構造協会 「高力ボルトの遅れ破壊特性の評価法開発」小委員会 委員

    2005/04 - 2010/03

  • 腐食防食協会 水素脆化原因調査小委員会 委員

    2008/04 - 2009/03

  • 日本鉄鋼協会 「水素脆化研究の基盤構築」フォーラム 幹事

    2007/04 - 2009/03

  • 日本鉄鋼協会 日本鉄鋼協会「構造材料の強度と破壊」フォーラム 委員

    2004/04 - 2008/03

  • 日本鉄鋼協会 「材料中の水素状態分析標準化の基盤構築」フォーラム 幹事

    2005/04 - 2007/03

Show all ︎Show first 5

Professional Memberships 6

  • The Materials Research Society of Japan

    2022/01 - Present

  • International Society of Electrochemistry

  • 日本電気化学会

  • 腐食防食学会

  • 日本鉄鋼協会

  • 日本金属学会

︎Show all ︎Show first 5

Research Interests 4

  • Electrochemistry

  • Metallic materials

  • Hydrogen embrittlement

  • Corrosion science

Research Areas 1

  • Nanotechnology/Materials / Structural and functional materials / Corrosion Science, Hydrogen embrittlement, Electrochemistry

Awards 10

  1. The 72nd JIM Photo Award for Excellence in Metallography, Optical Microscopy Category

    2022/03 The Japan Institute of Metals and Materials Visualization of Hydrogen Diffusing Preferentially across Grain Boundaries in Ni by Polyaniline

  2. 日本ばね学会論文賞

    2017/11/22 日本ばね学会 「酸性溶液中での腐食摩耗による高強度鋼への水素侵入」

  3. 三島賞(学術貢献賞)

    2016/03/23 日本鉄鋼協会

  4. 澤村論文賞

    2015/03/18 日本鉄鋼協会

  5. 日本鋼構造協会論文賞

    2014/11/13 日本鋼構造協会

  6. 西山記念賞(学術記念賞)

    2009/03/28 日本鉄鋼協会

  7. Hans-Jürgen Engell Prize 2000

    2001/09/03 International Society of Electrochemistry

  8. 原田研究奨励賞

    1997/11/04 金属研究助成会

  9. 日本金属学会奨励賞

    1997/09 日本金属学会

  10. 日本MRS奨励賞

    1993/12/08 日本MRS

Show all ︎Show 5

Papers 309

  1. Stability of electrochemical hydrogen charging in NaCl aqueous solution containing NH<inf>4</inf>SCN: Effect of changes in solution chemistry

    Saya Ajito, Yusuke Kabasawa, Hiroshi Kakinuma, Motomichi Koyama, Eiji Akiyama

    Corrosion Science 249 2025/06

    DOI: 10.1016/j.corsci.2025.112843  

    ISSN: 0010-938X

  2. Semi-quantitative characterisation of coherency-dependent hydrogen diffusion at Σ3 grain boundaries in pure Ni

    Hiroshi Kakinuma, Motomichi Koyama, Rama Srinivas Varanasi, Saya Ajito, Eiji Akiyama

    Materials Research Letters 1-8 2025/01/24

    Publisher: Informa UK Limited

    DOI: 10.1080/21663831.2025.2457369  

    eISSN: 2166-3831

  3. Hydrogen Effects on Hall–Petch Coefficient and Fracture Strength in Pure Ni and Ni-20Cr Alloy: A Macroscopic Insight of the Hydrogen Embrittlement Mechanism

    Motomichi Koyama, Kota Tomatsu, Hiroshi Kakinuma, Saya Ajito, Eiji Akiyama

    Metallurgical and Materials Transactions A 2025/01/23

    Publisher: Springer Science and Business Media LLC

    DOI: 10.1007/s11661-025-07688-6  

    ISSN: 1073-5623

    eISSN: 1543-1940

    More details Close

    Abstract The effects of Cr and H on the yield and fracture strengths in pure Ni and Ni-20Cr alloy were investigated based on the Hall–Petch relationship. The Hall–Petch coefficient, which depends on the dislocation pile-up length and slip transfer resistance at the grain boundaries, drastically increased by 20 pct Cr addition and unchanged by gaseous hydrogen charging at 80 MPa. These results indicate that Cr increased the intergranular stress concentration associated with dislocation pile-up, whereas H did not.

  4. Stress and Plastic Strain Partitioning Behaviors and Those Contributions to Martensitic Transformation of Retained Austenite in Medium Manganese and Transformation-Induced Plasticity-Aided Bainitic Ferrite Steels

    Tomohiko Hojo, Motomichi Koyama, Bakuya Kumai, Yutao Zhou, Yuki Shibayama, Ayumi Shiro, Takahisa Shobu, Hiroyuki Saitoh, Saya Ajito, Eiji Akiyama

    ISIJ International 65 (2) 284-296 2025

    DOI: 10.2355/isijinternational.ISIJINT-2024-268  

    ISSN: 0915-1559

  5. Grain boundary nanochemistry and intergranular corrosion of Fe-0.01wt.%P alloy: Roles of elemental segregations and misorientation

    Saya Ajito, Kazuya Tojima, Hiroshi Kakinuma, Kohei Ikeda, Yongjie Zhang, Tomohiko Hojo, Goro Miyamoto, Motomichi Koyama, Tadashi Furuhara, Eiji Akiyama

    Acta Materialia 120577-120577 2024/11

    Publisher: Elsevier BV

    DOI: 10.1016/j.actamat.2024.120577  

    ISSN: 1359-6454

  6. Stress-controlled hydrogen embrittlement failure in U-bend high-strength steel

    Yuki Shibayama, Tomohiko Hojo, Motomichi Koyama, Eiji Akiyama

    International Journal of Hydrogen Energy 88 1010-1016 2024/10/28

    DOI: 10.1016/j.ijhydene.2024.09.123  

    ISSN: 0360-3199

  7. Novel Fe-Mo intermetallic composite synthesized via diffusional-displacive mixed-mode transformation

    Rama Srinivas Varanasi, Srikakulapu Kiranbabu, Reina Utsumi, Hiroyuki Saitoh, Ronald Schnitzer, Eiji Akiyama, Motomichi Koyama

    Materials Characterization 216 2024/10

    DOI: 10.1016/j.matchar.2024.114287  

    ISSN: 1044-5803

  8. Visualization of Microscopic Hydrogen Diffusion in Polycrystalline Pure Ni Using an Ir Complex

    Saya Ajito, Hiroshi Kakinuma, Motomichi Koyama, Eiji Akiyama

    Zairyo-to-Kankyo 73 (8) 194-199 2024/08/10

    Publisher: Japan Society of Corrosion Engineering

    DOI: 10.3323/jcorr.73.194  

    ISSN: 0917-0480

    eISSN: 1881-9664

  9. ポリアニリンを用いた金属中を拡散する水素の可視化技術

    Hiroshi Kakinuma, Saya Ajito, Motomichi Koyama, Eiji Akiyama

    Materia Japan 63 (6) 381-389 2024/06/01

    Publisher: Japan Institute of Metals

    DOI: 10.2320/materia.63.381  

    ISSN: 1340-2625

    eISSN: 1884-5843

  10. Mechanism of local hydrogen entry into Fe sheets induced by atmospheric corrosion: Significance of potential, pH, and rust layer thickness Peer-reviewed

    Hiroshi Kakinuma, Sachiko Hiromoto, Tomohiko Hojo, Saya Ajito, Motomichi Koyama, Eiji Akiyama

    Corrosion Science 232 112043-112043 2024/05

    Publisher: Elsevier BV

    DOI: 10.1016/j.corsci.2024.112043  

    ISSN: 0010-938X

  11. Effect of Hydrogen on Fatigue Life and Fracture Morphologies of TRIP-Aided Martensitic Steels with Added Nitrogen Peer-reviewed

    Tomohiko Hojo, Akihiko Nagasaka, Junya Kobayashi, Yuki Shibayama, Eiji Akiyama

    Metals 14 (3) 346-346 2024/03/17

    Publisher: MDPI AG

    DOI: 10.3390/met14030346  

    eISSN: 2075-4701

    More details Close

    The effects of hydrogen on the tensile properties, fatigue life, and tensile and fatigue fracture morphologies of nitrogen-added ultrahigh-strength transformation-induced plasticity (TRIP)-aided martensitic (TM) steels were investigated. The total elongation and number of cycles to failure (Nf) of the hydrogen-charged TM steels decreased with the addition of nitrogen; in particular, adding 100 ppm of nitrogen decreased the total elongation and Nf of the TM steels. The quasi-cleavage cracking around the AlN occurred near the sample surface, which is the crack propagation region, although dimples appeared at the center of the fracture surface in the tensile samples. The initial fatigue crack initiated at the AlN precipitate or matrix/AlN interface, located at the notch root. During crack propagation, new cracks were initiated at the AlN precipitates or matrix/AlN interfaces, while quasi-cleavage crack regions were observed around the AlN precipitates. The decrease in the total elongation and Nf of the hydrogen-charged TM steel with 100 ppm of added nitrogen might be attributable to the crack initiation around the AlN precipitates formed by a large amount of hydrogen trapped at the AlN precipitates and matrix/AlN interfaces, and to the dense distribution of AlN, which promoted crack linkage.

  12. Microscopic visualization of hydrogen diffusion in UNS S32750 super duplex stainless steel: Roles of crystal structure and grain size Peer-reviewed

    Hiroshi Kakinuma, Saya Ajito, Motomichi Koyama, Eiji Akiyama

    International Journal of Hydrogen Energy 59 866-873 2024/03

    Publisher: Elsevier BV

    DOI: 10.1016/j.ijhydene.2024.02.069  

    ISSN: 0360-3199

  13. Hydrogen Embrittlement Property of a 1.5 GPa Dual-Phase Steel Evaluated Using U-bending Test: A Comparison with Tempered Martensitic Steel with Identical Tensile Strength Peer-reviewed

    Shuya Chiba, Motomichi Koyama, Tomohiko Hojo, Saya Ajito, Yuki Shibayama, Rama Srinivas Varanasi, Eiji Akiyama

    ISIJ International 64 (4) 706-713 2024/02/28

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2023-287  

    ISSN: 0915-1559

    eISSN: 1347-5460

  14. Effect of Stretch-forming on Hydrogen Diffusion Behavior in High-strength Steel Sheet Peer-reviewed

    Hayato Nishimura, Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Ken-ichi Fujita, Yuki Shibayama, Hiroshi Kakinuma, Eiji Akiyama

    ISIJ International 64 (4) 637-644 2024/02/28

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2023-149  

    ISSN: 0915-1559

    eISSN: 1347-5460

  15. Effect of Hydrogen on Tensile Shear Strength of Spot-Welded Ultrahigh-Strength TRIP-Aided Martensitic Steel Sheet Peer-reviewed

    Tomohiko Hojo, Akihiko Nagasaka, Ryusei Wakabayashi, Chihaya Tabata, Yota Kondo, Kazuma Ogasawara, Yuki Shibayama, Eiji Akiyama

    Tetsu-to-Hagane 110 (3) 171-183 2024/02/15

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2023-077  

    ISSN: 0021-1575

    eISSN: 1883-2954

  16. Quantitative Evaluation of the Relationship between Strain and Color Change in Opal Photonic Crystal Films and Application into Complex Specimen Geometries Peer-reviewed

    Yutao Zhou, Zhipeng Yang, Motomichi Koyama, Saya Ajito, Tomohiko Hojo, Hiroshi Fudouzi, Eiji Akiyama

    Tetsu-to-Hagane 110 (3) 311-320 2024/02/15

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2023-020  

    ISSN: 0021-1575

    eISSN: 1883-2954

  17. Stress and Plastic Strain Partitioning Behaviors and Those Contributions to Martensitic Transformation of Retained Austenite in Medium Manganese and Transformation-Induced Plasticity-Aided Bainitic Ferrite Steels Peer-reviewed

    Tomohiko Hojo, Motomichi Koyama, Bakuya Kumai, Yutao Zhou, Yuki Shibayama, Ayumi Shiro, Takahisa Shobu, Hiroyuki Saitoh, Saya Ajito, Eiji Akiyama

    Tetsu-to-Hagane 110 (3) 227-240 2024/02/15

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2023-062  

    ISSN: 0021-1575

    eISSN: 1883-2954

  18. Plasticity-induced Hydrogen Desorptions Associated with Hydrogen-assisted Martensitic Transformation and Deformation Twinning in Austenitic Stainless Steels Peer-reviewed

    Yifei Wen, Motomichi Koyama, Tomohiko Hojo, Saya Ajito, Eiji Akiyama

    ISIJ International 64 (2) 474-481 2024/01/30

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2023-130  

    ISSN: 0915-1559

    eISSN: 1347-5460

  19. Grain Refinement Effect on Resistance to Hydrogen-assisted Crack Growth in Equiatomic CoCrFeNi High-entropy Alloy with Different H Charging Conditions

    Taein Kong, Haoyu Wang, Taekyung Lee, Motomichi Koyama, Eiji Akiyama

    ISIJ International 64 (4) 688-695 2024

    DOI: 10.2355/ISIJINTERNATIONAL.ISIJINT-2023-218  

    ISSN: 0915-1559

  20. Visualization of Microscopic Hydrogen Diffusion in Polycrystalline Pure Ni Using an Ir Complex

    Saya Ajito, Hiroshi Kakinuma, Motomichi Koyama, Eiji Akiyama

    MATERIALS TRANSACTIONS 2024

    Publisher: Japan Institute of Metals

    DOI: 10.2320/matertrans.mt-c2024008  

    ISSN: 1345-9678

    eISSN: 1347-5320

  21. 超高強度QP-TRIP鋼板の温間V曲げおよび水素脆化特性

    Tomohiko Hojo, Akihiko Nagasaka, Chihaya Tabata, Yuki Shibayama, Junya Kobayashi, Eiji Akiyama

    Tetsu-to-Hagane 2024

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2023-073  

    ISSN: 0021-1575

    eISSN: 1883-2954

  22. Critical role of initial multi-phase microstructure on the phase transformations during hydrogenation in Fe–Mo alloy system Peer-reviewed

    Rama Srinivas Varanasi, Motomichi Koyama, Reina Utsumi, Hiroyuki Saitoh, Toyoto Sato, Shin-ichi Orimo, Eiji Akiyama

    International Journal of Hydrogen Energy 50 1418-1434 2024/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.ijhydene.2023.09.268  

    ISSN: 0360-3199

  23. In situ visualization of misorientation-dependent hydrogen diffusion at grain boundaries of pure polycrystalline Ni using a hydrogen video imaging system Peer-reviewed

    Hiroshi Kakinuma, Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Eiji Akiyama

    Acta Materialia 263 119536-119536 2024/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.actamat.2023.119536  

    ISSN: 1359-6454

  24. Temperature dependence of hydrogen-assisted damage evolution and fracture behavior in TRIP-aided bainitic ferrite steel Peer-reviewed

    Yutao Zhou, Tomohiko Hojo, Motomichi Koyama, Saya Ajito, Eiji Akiyama

    Materials Science and Engineering: A 886 145663 2023/10/17

    DOI: 10.1016/j.msea.2023.145663  

    ISSN: 0921-5093

  25. Mesoscale quantification of grain boundary character and local plasticity in hydrogen-assisted intergranular and intergranular-like cracking paths in tempered martensitic steel Peer-reviewed

    Tingshu Chen, Motomichi Koyama, Takahiro Chiba, Eiji Akiyama, Kenichi Takai

    Materials Science and Engineering: A 145718-145718 2023/09

    Publisher: Elsevier BV

    DOI: 10.1016/j.msea.2023.145718  

    ISSN: 0921-5093

  26. Environment-assisted cracking of AZ31 magnesium alloy in a borate buffer solution containing ammonium thiocyanate under various potentials Peer-reviewed

    Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Sachiko Hiromoto, Eiji Akiyama

    Corrosion Science 218 111195 2023/07/01

    DOI: 10.1016/j.corsci.2023.111195  

    ISSN: 0010-938X

  27. Hydrogen-Induced Delayed Fracture in a 1.5 GPa Dual-Phase Steel via Coalescence of Surface and Sub-surface Cracks Peer-reviewed

    Rama Srinivas Varanasi, Motomichi Koyama, Yuki Shibayama, Shuya Chiba, Saya Ajito, Tomohiko Hojo, Eiji Akiyama

    Metallurgical and Materials Transactions A 54 (8) 2989-2989 2023/05/31

    Publisher: Springer Science and Business Media LLC

    DOI: 10.1007/s11661-023-07096-8  

    ISSN: 1073-5623

    eISSN: 1543-1940

  28. Al-10%Zn-2.5%Mg-1.6%Cu合金の引張特性に及ぼすひずみ速度と内在水素の影響

    Tomohiko Hojo, Mamoru Kikuchi, Hiroyuki Waki, Eiji Akiyama

    Journal of Japan Institute of Light Metals 73 (5) 218-222 2023/05/15

    Publisher: Japan Institute of Light Metals

    DOI: 10.2464/jilm.73.218  

    ISSN: 0451-5994

    eISSN: 1880-8018

  29. Effects of strain rate and internal hydrogen on tensile properties of Al-10%Mg alloys Peer-reviewed

    Tomohiko Hojo, Mamoru Kikuchi, Eiji Akiyama

    Journal of Japan Institute of Light Metals 73 (5) 223-229 2023/05/15

    Publisher: Japan Institute of Light Metals

    DOI: 10.2464/jilm.73.223  

    ISSN: 0451-5994

    eISSN: 1880-8018

  30. Martensite Boundary Characteristics on Cycle- and Time-Dependent Fatigue Crack Growth Paths of Tempered Lath Martensitic Steels in a 90 MPa Gaseous Hydrogen Atmosphere Peer-reviewed

    Tingshu Chen, Motomichi Koyama, Yuhei Ogawa, Hisao Matsunaga, Eiji Akiyama

    Metallurgical and Materials Transactions A 54 (7) 2512-2518 2023/04

    DOI: 10.1007/s11661-023-07041-9  

    ISSN: 1073-5623

  31. Influence of post-oxidizing treatment on passivation performance on the spin-coated titanium oxide films on crystalline silicon Peer-reviewed

    Hao Luo, Van Hoang Nguyen, Kazuhiro Gotoh, Saya Ajito, Tomohiko Hojo, Yasuyoshi Kurokawa, Eiji Akiyama, Noritaka Usami

    Thin Solid Films 764 139597-139597 2023/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.tsf.2022.139597  

    ISSN: 0040-6090

  32. Transformation-Induced Microcracks and Their Arrest with Different Deformation Temperatures in a Medium Mn Steel Peer-reviewed

    Yutao Zhou, Motomichi Koyama, Tomohiko Hojo, Saya Ajito, Eiji Akiyama

    Metallurgical and Materials Transactions A 54 (1) 153-166 2023/01

    DOI: 10.1007/s11661-022-06855-3  

    ISSN: 1073-5623

    eISSN: 1543-1940

  33. Cr Effects on the Local Plasticity Evolution and Fracture Behaviors of Ni–Cr Alloys Tensile-Tested under Hydrogen Charging Peer-reviewed

    Naohiro Kobayashi, Motomichi Koyama, Misaho Yamamura, Tomohiko Hojo, Eiji Akiyama

    MATERIALS TRANSACTIONS 64 (1) 212-219 2023/01/01

    Publisher: Japan Institute of Metals

    DOI: 10.2320/matertrans.mt-m2022140  

    ISSN: 1345-9678

    eISSN: 1347-5320

  34. Phase transformations and microstructure evolutions during depressurization of hydrogenated Fe–Mn–Si–Cr alloy Peer-reviewed

    Rama Srinivas Varanasi, Motomichi Koyama, Hiroyuki Saitoh, Reina Utsumi, Toyoto Sato, Shin-ichi Orimo, Eiji Akiyama

    International Journal of Hydrogen Energy 48 (27) 10081-10088 2022/12

    Publisher: Elsevier BV

    DOI: 10.1016/j.ijhydene.2022.11.274  

    ISSN: 0360-3199

  35. Mechanical loading effect on the hydrogen uptake of tempered martensite steel: Elastic strain effect vs. plastic strain effect Peer-reviewed

    Yota Masuda, Motomichi Koyama, Hiroshi Kakinuma, Eiji Akiyama

    Materials Science and Engineering: A 862 144486-144486 2022/12

    Publisher: Elsevier BV

    DOI: 10.1016/j.msea.2022.144486  

    ISSN: 0921-5093

  36. Mixed type brittle fracture in 1.5 GPa dual-phase steel via {100} ferrite cleavage cracking Peer-reviewed

    Rama Srinivas Varanasi, Motomichi Koyama, Yuki Shibayama, Eiji Akiyama

    Materials Science and Engineering: A 857 144021 2022/11/01

    DOI: 10.1016/j.msea.2022.144021  

    ISSN: 0921-5093

  37. Quantitative Evaluation of the Relationship between Strain and Color Change in Opal Photonic Crystal Films and Application into Complex Specimen Geometries Peer-reviewed

    Yutao Zhou, Zhipeng Yang, Motomichi Koyama, Saya Ajito, Tomohiko Hojo, Hiroshi Fudouzi, Eiji Akiyama

    ISIJ International 62 (10) 2061-2068 2022/10

    DOI: 10.2355/isijinternational.isijint-2022-054  

    ISSN: 0915-1559

    eISSN: 1347-5460

  38. In situ 2D mapping of hydrogen entry into an Fe sheet under a droplet of NaCl solution using a hydrogenochromic sensor Peer-reviewed

    Hiroshi Kakinuma, Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Sachiko Hiromoto, Eiji Akiyama

    International Journal of Hydrogen Energy 47 (90) 38468-38476 2022/09

    Publisher: Elsevier BV

    DOI: 10.1016/j.ijhydene.2022.09.006  

    ISSN: 0360-3199

  39. Simultaneous observations of the corrosion behavior of an Fe sheet and the associated hydrogen distribution therein employing a hydrogenochromic sensor Peer-reviewed

    Hiroshi Kakinuma, Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Sachiko Hiromoto, Eiji Akiyama

    Corrosion Science 206 110534-110534 2022/09

    Publisher: Elsevier BV

    DOI: 10.1016/j.corsci.2022.110534  

    ISSN: 0010-938X

  40. Hydrogen-accelerated fatigue crack growth of equiatomic Fe–Cr–Ni–Mn–Co high-entropy alloy evaluated by compact tension testing Peer-reviewed

    Motomichi Koyama, Shunsuke Mizumachi, Eiji Akiyama, Kaneaki Tsuzaki

    Materials Science and Engineering A 848 2022/07/19

    DOI: 10.1016/j.msea.2022.143394  

    ISSN: 0921-5093

  41. Factors Distinguishing Hydrogen-Assisted Intergranular and Intergranular-Like Fractures in a Tempered Lath Martensitic Steel Peer-reviewed

    Tingshu Chen, Takahiro Chiba, Motomichi Koyama, Eiji Akiyama, Kenichi Takai

    Metallurgical and Materials Transactions A 53 (5) 1645-1658 2022/05

    Publisher: Springer Science and Business Media LLC

    DOI: 10.1007/s11661-022-06608-2  

    ISSN: 1073-5623

    eISSN: 1543-1940

  42. Synergistic effects of hydrogen and deformation temperature on mechanical properties of TRIP-aided bainitic ferrite steel Peer-reviewed

    Yutao Zhou, Tomohiko Hojo, Motomichi Koyama, Saya Ajito, Eiji Akiyama

    Materials Science and Engineering: A 842 143070-143070 2022/05

    DOI: 10.1016/j.msea.2022.143070  

    ISSN: 0921-5093

    eISSN: 1873-4936

  43. Corrosion Monitoring of Carbon Steel in Non-Irradiated, Humidity-Controlled Environments Simulating Gamma-Ray Irradiation Peer-reviewed

    Atsushi Omori, Saya Ajito, Hiroshi Abe, Kuniki Hata, Tomonori Sato, Yoshiyuki Kaji, Hiroyuki Inoue, Mitsumasa Taguchi, Hajime Seito, Eiji Tada, Shunichi Suzuki, Eiji Akiyama

    MATERIALS TRANSACTIONS 63 (4) 555-561 2022/04/01

    Publisher: Japan Institute of Metals

    DOI: 10.2320/matertrans.mt-c2021006  

    ISSN: 1345-9678

    eISSN: 1347-5320

  44. Comparative study of stress and strain partitioning behaviors in medium manganese and transformation-induced plasticity-aided bainitic ferrite steels Peer-reviewed

    Tomohiko Hojo, Motomichi Koyama, Bakuya Kumai, Yuki Shibayama, Ayumi Shiro, Takahisa Shobu, Hiroyuki Saitoh, Saya Ajito, Eiji Akiyama

    Scripta Materialia 210 114463-114463 2022/03

    Publisher: Elsevier BV

    DOI: 10.1016/j.scriptamat.2021.114463  

    ISSN: 1359-6462

  45. Austenite stabilization kinetics in early stages of austempering treatment in TRIP-aided steel using in-situ neutron diffraction technique Peer-reviewed

    Yutao Zhou, Tomohiko Hojo, Amane Kitahara, Yusuke Onuki, Shigeo Sato, Motomichi Koyama, Eiji Akiyama

    Materialia 21 101317-101317 2022/03

    DOI: 10.1016/j.mtla.2022.101317  

    ISSN: 2589-1529

    eISSN: 2589-1529

  46. Hydrogen Embrittlement Behavior of Pure Ni and Ni–20Cr Alloy with Different Grain Sizes Peer-reviewed

    Naohiro Kobayashi, Motomichi Koyama, Kenji Kobayashi, Tomohiko Hojo, Eiji Akiyama

    MATERIALS TRANSACTIONS 63 (2) 247-256 2022/02/01

    Publisher: Japan Institute of Metals

    DOI: 10.2320/matertrans.mt-m2021170  

    ISSN: 1345-9678

    eISSN: 1347-5320

  47. Effects of Thermomechanical Processing on Hydrogen Embrittlement Properties of UltraHigh-Strength TRIP-Aided Bainitic Ferrite Steels Peer-reviewed

    Tomohiko Hojo, Yutao Zhou, Junya Kobayashi, Koh-ichi Sugimoto, Yoshito Takemoto, Akihiko Nagasaka, Motomichi Koyama, Saya Ajito, Eiji Akiyama

    Metals 12 (2) 269-269 2022/01/31

    Publisher: MDPI AG

    DOI: 10.3390/met12020269  

    eISSN: 2075-4701

    More details Close

    The effects of thermomechanical processing on the microstructure and hydrogen embrittlement properties of ultrahigh-strength, low-alloy, transformation-induced plasticity (TRIP)-aided bainitic ferrite (TBF) steels were investigated to apply to automobile forging parts such as engine and drivetrain parts. The hydrogen embrittlement properties were evaluated by conducting conventional tensile tests after hydrogen charging and constant load four-point bending tests with hydrogen charging. The 0.4 mass%C-TBF steel achieved refinement of the microstructure, improved retained austenite characteristics, and strengthening, owing to thermomechanical processing. This might be attributed to dynamic and static recrystallizations during thermomechanical processing in TBF steels. Moreover, the hydrogen embrittlement resistances were improved by the thermomechanical processing in TBF steels. This might be caused by the refinement of the microstructure, an increase in the stability of the retained austenite, and low hydrogen absorption of the thermomechanically processed TBF steels.

  48. Real‐Time Visualization of Hydrogen Distribution in Metals Using Polyaniline: An Ultrasensitive Hydrogenochromic Sensor Peer-reviewed

    Hiroshi Kakinuma, Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Eiji Akiyama

    Advanced Materials Interfaces 9 (18) 2101984-2101984 2022/01/29

    Publisher: Wiley

    DOI: 10.1002/admi.202101984  

    ISSN: 2196-7350

    eISSN: 2196-7350

  49. V-Bendability of Ultrahigh-Strength Low Alloy TRIP-Aided Steel Sheets with Bainitic Ferrite Matrix Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Yuki Shibayama, Masaya Fujita, Takumi Ohashi, Mako Miyasaka, Eiji Akiyama

    ISIJ International 62 (1) 247-256 2022/01/15

    DOI: 10.2355/isijinternational.isijint-2021-092  

    ISSN: 0915-1559

    eISSN: 1347-5460

  50. Effects of Ammonium Thiocyanate and pH of Aqueous Solutions on Hydrogen Absorption into Iron under Cathodic Polarization Peer-reviewed

    Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Eiji Akiyama

    Tetsu-to-Hagane 108 (11) 857-863 2022

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2022-043  

    ISSN: 0021-1575

    eISSN: 1883-2954

  51. Multi-Probe Characterization of Plasticity Heterogeneity: Requirement of Alloy Design Considering Dislocation Planarity for Developing Crack-Resistant Ni–Cr Alloys Peer-reviewed

    Taein Kong, Motomichi Koyama, Misaho Yamamura, Eiji Akiyama

    MATERIALS TRANSACTIONS 63 (1) 88-91 2022/01/01

    Publisher: Japan Institute of Metals

    DOI: 10.2320/matertrans.mt-m2021191  

    ISSN: 1345-9678

    eISSN: 1347-5320

  52. Effect of Stretch-forming on Hydrogen Diffusion Behavior in High-strength Steel Sheet Peer-reviewed

    Hayato Nishimura, Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Ken-ichi Fujita, Yuki Shibayama, Hiroshi Kakinuma, Eiji Akiyama

    Tetsu-to-Hagane 108 (5) 316-324 2022

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2021-096  

    ISSN: 0021-1575

    eISSN: 1883-2954

  53. Cr Effects on the Local Plasticity Evolution and Fracture Behaviors of Ni-Cr Alloys Tensile-Tested under Hydrogen Charging Peer-reviewed

    Naohiro Kobayashi, Motomichi Koyama, Misaho Yamamura, Tomohiko Hojo, Eiji Akiyama

    Journal of the Japan Institute of Metals and Materials 86 (5) 77-84 2022

    Publisher: Japan Institute of Metals

    DOI: 10.2320/jinstmet.j2021054  

    ISSN: 0021-4876

    eISSN: 1880-6880 2433-7501

  54. Cracking Process in Delayed Fracture of High-Strength Steel after Long Atmospheric Exposure Peer-reviewed

    Tomoka Homma, Takahiro Chiba, Kenichi Takai, Eiji Akiyama, Wataru Oshikawa, Michihiko Nagumo

    ISIJ International 2022

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2021-238  

    ISSN: 0915-1559

    eISSN: 1347-5460

  55. Mechanisms of hydrogen embrittlement in high-strength aluminum alloys containing coherent or incoherent dispersoids Peer-reviewed

    Mahdieh Safyari, Masoud Moshtaghi, Tomohiko Hojo, Eiji Akiyama

    Corrosion Science 194 109895-109895 2022/01

    DOI: 10.1016/j.corsci.2021.109895  

    ISSN: 0010-938X

    eISSN: 1879-0496

  56. Pre-straining alters hydrogen-assisted cracking site and local hydrogen diffusivity in a nitrogen-doped duplex steel Peer-reviewed

    Milene Yumi Maeda, Motomichi Koyama, Hayato Nishimura, Osvaldo Mitsuyuki Cintho, Eiji Akiyama

    Scripta Materialia 207 114272-114272 2022/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.scriptamat.2021.114272  

    ISSN: 1359-6462

  57. Hydrogenation treatment under several gigapascals assists diffusionless transformation in a face-centered cubic steel Peer-reviewed

    Motomichi Koyama, Hiroyuki Saitoh, Toyoto Sato, Shin-ichi Orimo, Eiji Akiyama

    Scientific Reports 11 (1) 2021/12

    DOI: 10.1038/s41598-021-98938-1  

    ISSN: 2045-2322

    eISSN: 2045-2322

  58. Corrosion Monitoring of Carbon Steel in Non-Irradiated, Humidity-Controlled Environments Simulating Gamma-Ray Irradiation Peer-reviewed

    Atsushi Omori, Saya Ajito, Hiroshi Abe, Kuniki Hata, Tomonori Sato, Yoshiyuki Kaji, Hiroyuki Inoue, Mitsumasa Taguchi, Hajime Seito, Eiji Tada, Shunichi Suzuki, Eiji Akiyama

    Zairyo-to-Kankyo 70 (11) 358-364 2021/11/10

    Publisher: Japan Society of Corrosion Engineering

    DOI: 10.3323/jcorr.70.358  

    ISSN: 0917-0480

    eISSN: 1881-9664

  59. Effect of Hydrogen on Spot-Welded Tensile Properties in Automotive Ultrahigh-Strength TRIP-Aided Martensitic Steel Sheet Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Katsuya Aoki, Hirofumi Koyama, Akihiro Shimizu, Zulhafiz Bin Zolkepeli, Yuki Shibayama, Eiji Akiyama

    ISIJ International 61 (10) 2644-2653 2021/10/15

    DOI: 10.2355/isijinternational.isijint-2021-210  

    ISSN: 0915-1559

    eISSN: 1347-5460

  60. Hierarchical Characteristics of Hydrogen-Assisted Crack Growth and Microstructural Strain Evolution in Tempered Martensitic Steels: Case of Quasi-cleavage Fracture Peer-reviewed

    Tingshu Chen, Takahiro Chiba, Motomichi Koyama, Akinobu Shibata, Eiji Akiyama, Kenichi Takai

    Metallurgical and Materials Transactions A 52 (10) 4703-4713 2021/10

    Publisher: Springer Science and Business Media LLC

    DOI: 10.1007/s11661-021-06423-1  

    ISSN: 1073-5623

    eISSN: 1543-1940

  61. Depressurization-induced diffusionless transformation in pure iron hydrogenated under several gigapascals

    Motomichi Koyama, Hiroyuki Saitoh, Toyoto Sato, Shin-ichi Orimo, Eiji Akiyama

    Materials Letters: X 11 100078-100078 2021/09

    DOI: 10.1016/j.mlblux.2021.100078  

    ISSN: 2590-1508

  62. Hydrogen embrittlement and associated surface crack growth in fine-grained equiatomic CoCrFeMnNi high-entropy alloys with different annealing temperatures evaluated by tensile testing under in situ hydrogen charging Peer-reviewed

    Haoyu Wang, Motomichi Koyama, Tomohiko Hojo, Eiji Akiyama

    International Journal of Hydrogen Energy 46 (65) 33028-33038 2021/09

    Publisher: Elsevier BV

    DOI: 10.1016/j.ijhydene.2021.07.136  

    ISSN: 0360-3199

  63. Strain rate sensitivity of hydrogen-assisted ε-martensitic transformation and associated hydrogen embrittlement in high-Mn steel Peer-reviewed

    Chunxi Hao, Motomichi Koyama, Saya Ajito, Eiji Akiyama

    International Journal of Hydrogen Energy 46 (53) 27221-27233 2021/08

    Publisher: Elsevier BV

    DOI: 10.1016/j.ijhydene.2021.05.162  

    ISSN: 0360-3199

  64. Effect of austempering treatment on the microstructure and mechanical properties of 0.4C–1.5Si-1.5Mn TRIP-aided bainitic ferrite steel Peer-reviewed

    Yutao Zhou, Tomohiko Hojo, Motomichi Koyama, Eiji Akiyama

    Materials Science and Engineering: A 819 141479-141479 2021/07

    Publisher: Elsevier BV

    DOI: 10.1016/j.msea.2021.141479  

    ISSN: 0921-5093

  65. Effects of Silicon and Manganese Contents on V-Bending in High-Strength TRIP-Aided Dual-Phase Steel Sheets with Polygonal Ferrite Matrix Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Masaya Fujita, Takumi Ohashi, Mako Miyasaka, Yuki Shibayama, Eiji Akiyama

    ISIJ International 61 (6) 1980-1989 2021/06/15

    DOI: 10.2355/isijinternational.isijint-2020_719  

    ISSN: 0915-1559

    eISSN: 1347-5460

  66. An Evaluation Method for Hydrogen Embrittlement of High Strength Steel Sheets Using U-bend Specimens Peer-reviewed

    Yuki Shibayama, Tomohiko Hojo, Eiji Akiyama

    ISIJ International 61 (4) 1104-1111 2021/04/15

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2020-260  

    ISSN: 0915-1559

    eISSN: 1347-5460

  67. Effect of hydrogen charging time on hydrogen blister and hydrogen-induced cracking of pure iron Peer-reviewed

    Xinfeng Li, Weihong Huang, Xubin Wu, Jin Zhang, Yao Wang, Eiji Akiyama, Dewen Hou

    Corrosion Science 181 109200 2021/04

    DOI: 10.1016/j.corsci.2020.109200  

    ISSN: 0010-938X

  68. Effects of matrix structure and nitrogen content on fatigue properties of ultrahigh-strength low alloy trip-aided steels Peer-reviewed

    Tomohiko Hojo, Junya Kobayashi, Koh Ichi Sugimoto, Yoshito Takemoto, Akihiko Nagasaka, Motomichi Koyama, Eiji Akiyama

    ISIJ International 61 (2) 591-598 2021/02/15

    DOI: 10.2355/isijinternational.ISIJINT-2020-392  

    ISSN: 0915-1559

  69. Effect of carbon content on v-bending in high-strength tripaided dual-phase steel sheets with polygonal ferrite matrix Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Masaya Fujita, Takumi Ohashi, Mako Miyasaka, Yuki Shibayama, Eiji Akiyama

    ISIJ International 61 (2) 608-616 2021/02/15

    DOI: 10.2355/isijinternational.ISIJINT-2020-558  

    ISSN: 0915-1559

  70. Hydrogen Embrittlement Behavior of Pure Ni and Ni-20Cr Alloy with Different Grain Sizes Peer-reviewed

    Naohiro Kobayashi, Motomichi Koyama, Kenji Kobayashi, Tomohiko Hojo, Eiji Akiyama

    Journal of the Japan Institute of Metals and Materials 85 (2) 49-58 2021/02/01

    Publisher: Japan Institute of Metals

    DOI: 10.2320/jinstmet.j2020036  

    ISSN: 0021-4876

    eISSN: 1880-6880 2433-7501

  71. Effect of Hydrogen on Spot Welded Tensile Properties in Automotive Ultrahigh Strength TRIP-aided Martensitic Steel Sheet Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Katsuya Aoki, Hirofumi Koyama, Akihiro Shimizu, Zulhafiz Bin Zolkepeli, Yuki Shibayama, Eiji Akiyama

    Tetsu-to-Hagane 107 (2) 175-184 2021/02

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2020-069  

    ISSN: 0021-1575

    eISSN: 1883-2954

  72. Effects of Si and Mn contents on V-bending in high strength TRIP-aided dual-phase steel sheets with polygonal ferrite matrix Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Masaya Fujita, Takumi Ohashi, Mako Miyasaka, Yuki Shibayama, Eiji Akiyama

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 107 (2) 154-164 2021/02/01

    DOI: 10.2355/tetsutohagane.TETSU-2020-031  

    ISSN: 0021-1575

  73. V-bendability of ultrahigh strength low alloy trip-aided steel sheets with bainitic ferrite matrix Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Yuki Shibayama, Masaya Fujita, Takumi Ohashi, Mako Miyasaka, Eiji Akiyama

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 107 (2) 165-174 2021/02/01

    DOI: 10.2355/tetsutohagane.TETSU-2020-043  

    ISSN: 0021-1575

  74. Hydrogen-assisted damage evolution in nitrogen-doped duplex stainless steel Peer-reviewed

    Milene Yumi Maeda, Motomichi Koyama, Hayato Nishimura, Osvaldo Mitsuyuki Cintho, Eiji Akiyama

    International Journal of Hydrogen Energy 46 (2) 2716-2728 2021/01/06

    DOI: 10.1016/j.ijhydene.2020.10.152  

    ISSN: 0360-3199

  75. Availability of Opal Photonic Crystal Films for Visualizing Heterogeneous Strain Evolution in Steels: Example of Lüders Deformation Peer-reviewed

    Zhipeng Yang, Motomichi Koyama, Hiroshi Fudouzi, Tomohiko Hojo, Eiji Akiyama

    Tetsu-to-Hagane 107 (8) 681-686 2021

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2021-028  

    ISSN: 0021-1575

    eISSN: 1883-2954

  76. Effects of Residual Stress on Hydrogen Embrittlement of a Stretch-Formed Tempered Martensitic Steel Sheet Peer-reviewed

    Hayato Nishimura, Tomohiko Hojo, Saya Ajito, Yuki Shibayama, Motomichi Koyama, Hiroyuki Saitoh, Ayumi Shiro, Ryo Yasuda, Takahisa Shobu, Eiji Akiyama

    Tetsu-to-Hagane 107 (9) 760-768 2021

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2021-055  

    ISSN: 0021-1575

    eISSN: 1883-2954

  77. Effects of Matrix Structure and Nitrogen Content on Fatigue Properties of Ultrahigh-Strength Low Alloy TRIP-Aided Steels

    Tomohiko Hojo, Junya Kobayashi, Koh-ichi Sugimoto, Yoshito Takemoto, Akihiko Nagasaka, Motomichi Koyama, Eiji Akiyama

    Tetsu-to-Hagane 107 (8) 672-680 2021

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/tetsutohagane.tetsu-2021-015  

    ISSN: 0021-1575

    eISSN: 1883-2954

  78. Effects of Stress and Plastic Strain on Hydrogen Embrittlement Fracture of a U-bent Martensitic Steel Sheet Peer-reviewed

    Yuki Shibayama, Tomohiko Hojo, Motomichi Koyama, Hiroyuki Saitoh, Ayumi Shiro, Ryo Yasuda, Takahisa Shobu, Takashi Matsuno, Eiji Akiyama

    ISIJ International 61 (4) 1322-1329 2021

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2020-569  

    ISSN: 0915-1559

    eISSN: 1347-5460

  79. Effects of Ammonium Thiocyanate and pH of Aqueous Solutions on Hydrogen Absorption into Iron under Cathodic Polarization Peer-reviewed

    Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Eiji Akiyama

    ISIJ International 61 (4) 1209-1214 2021

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2020-551  

    ISSN: 0915-1559

    eISSN: 1347-5460

  80. Effects of Residual Stress on Hydrogen Embrittlement of a Stretch-Formed Tempered Martensitic Steel Sheet Peer-reviewed

    Hayato Nishimura, Tomohiko Hojo, Saya Ajito, Yuki Shibayama, Motomichi Koyama, Hiroyuki Saitoh, Ayumi Shiro, Ryo Yasuda, Takahisa Shobu, Eiji Akiyama

    ISIJ International 61 (4) 1170-1178 2021

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2020-492  

    ISSN: 0915-1559

    eISSN: 1347-5460

  81. Roles of hydrogen content and pre-strain on damage evolution of TRIP-aided bainitic ferrite steel Peer-reviewed

    Virendra Kumar Verma, Motomichi Koyama, Bakuya Kumai, Tomohiko Hojo, Eiji Akiyama

    ISIJ International 61 (4) 1309-1314 2021

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.ISIJINT-2020-514  

    ISSN: 0915-1559

    eISSN: 1347-5460

  82. Potential Effects of Short-Range Order on Hydrogen Embrittlement of Stable Austenitic Steels—A Review Invited Peer-reviewed

    Motomichi Koyama, Burak Bal, Dermican Canadinc, Kishan Habib, Toshihiro Tsuchiyama, Kaneaki Tsuzaki, Eiji Akiyama

    Advanced Structured Materials 143 1-18 2021

    DOI: 10.1007/978-3-030-66948-5_1  

    ISSN: 1869-8433

    eISSN: 1869-8441

  83. Activation energy of hydrogen desorption from high-performance titanium oxide carrier-selective contacts with silicon oxide interlayers Peer-reviewed

    Kazuhiro Gotoh, Takeya Mochizuki, Tomohiko Hojo, Yuki Shibayama, Yasuyoshi Kurokawa, Eiji Akiyama, Noritaka Usami

    Current Applied Physics 21 36-42 2021/01

    DOI: 10.1016/j.cap.2020.10.002  

    ISSN: 1567-1739

  84. Effects of residual stress and plastic strain on hydrogen embrittlement of a stretch-formed TRIP-aided martensitic steel sheet Peer-reviewed

    Tomohiko Hojo, Eiji Akiyama, Hiroyuki Saitoh, Ayumi Shiro, Ryo Yasuda, Takahisa Shobu, Junichiro Kinugasa, Fumio Yuse

    Corrosion Science 177 108957-108957 2020/12

    Publisher: Elsevier BV

    DOI: 10.1016/j.corsci.2020.108957  

    ISSN: 0010-938X

  85. Role of mill scale on corrosion behavior of steel rebars in mortar Peer-reviewed

    Kotaro Doi, Sachiko Hiromoto, Tadashi Shinohara, Koichi Tsuchiya, Hideki Katayama, Eiji Akiyama

    Corrosion Science 177 108995 2020/12

    DOI: 10.1016/j.corsci.2020.108995  

    ISSN: 0010-938X

  86. Quantitative Evaluation of Hydrogen Effects on Evolutions of Deformation-Induced ε-Martensite and Damage in a High-Mn Steel Peer-reviewed

    Chunxi Hao, Motomichi Koyama, Eiji Akiyama

    Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science 51 (12) 6184-6194 2020/12

    Publisher: Springer Science and Business Media LLC

    DOI: 10.1007/s11661-020-06021-7  

    ISSN: 1073-5623

    eISSN: 1543-1940

  87. Availability of Opal Photonic Crystal Films for Visualizing Heterogeneous Strain Evolution in Steels: Example of Lüders Deformation Peer-reviewed

    Zhipeng Yang, Motomichi Koyama, Hiroshi Fudouzi, Tomohiko Hojo, Eiji Akiyama

    ISIJ International 60 (11) 2604-2608 2020/11/15

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.ISIJINT-2020-223  

    ISSN: 0915-1559

    eISSN: 1347-5460

  88. Effects of Mn Content and Grain Size on Hydrogen Embrittlement Susceptibility of Face-Centered Cubic High-Entropy Alloys Peer-reviewed

    Motomichi Koyama, Haoyu Wang, Virendra Kumar Verma, Kaneaki Tsuzaki, Eiji Akiyama

    Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science 51 (11) 5612-5616 2020/11/01

    DOI: 10.1007/s11661-020-05966-z  

    ISSN: 1073-5623

  89. Pre-strain effects on critical stress and hydrogen content for hydrogen-induced quasi-cleavage fracture in a TRIP-aided bainitic ferrite steel: Martensitic transformation, matrix damage, and strain aging Peer-reviewed

    Bakuya Kumai, Tomohiko Hojo, Motomichi Koyama, Eiji Akiyama, Hiroyuki Waki, Akihiko Nagasaka

    International Journal of Hydrogen Energy 45 (51) 27920-27928 2020/10/16

    DOI: 10.1016/j.ijhydene.2020.07.036  

    ISSN: 0360-3199

  90. Application of an iridium complex for detecting hydrogen permeation through pure iron Peer-reviewed

    Saya Ajito, Tomohiko Hojo, Motomichi Koyama, Ken ichi Fujita, Eiji Akiyama

    International Journal of Hydrogen Energy 45 (46) 25580-25586 2020/09/21

    Publisher: Elsevier BV

    DOI: 10.1016/j.ijhydene.2020.06.113  

    ISSN: 0360-3199

  91. Hydrogen Enhances Shape Memory Effect of a Ferrous Face-Centered Cubic Alloy Peer-reviewed

    Motomichi Koyama, Chunxi Hao, Eiji Akiyama, Kaneaki Tsuzaki

    Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science 51 (9) 4439-4441 2020/09/01

    DOI: 10.1007/s11661-020-05886-y  

    ISSN: 1073-5623

  92. Hydrogen embrittlement resistance of pre-strained ultra-high-strength low alloy TRIP-aided steel Peer-reviewed

    Tomohiko Hojo, Bakuya Kumai, Motomichi Koyama, Eiji Akiyama, Hiroyuki Waki, Hiroyuki Saitoh, Ayumi Shiro, Ryo Yasuda, Takahisa Shobu, Akihiko Nagasaka

    International Journal of Fracture 224 (2) 253-260 2020/08/01

    DOI: 10.1007/s10704-020-00451-5  

    ISSN: 0376-9429

    eISSN: 1573-2673

  93. Effects of hydrogen content that alters damage evolution mechanisms in SUH 660 precipitation-strengthened Fe–Cr–Ni steel Peer-reviewed

    Virendra Kumar Verma, Motomichi Koyama, Shigeru Hamada, Eiji Akiyama

    Materials Science and Engineering A 791 2020/07/22

    DOI: 10.1016/j.msea.2020.139750  

    ISSN: 0921-5093

  94. Corrosion Monitoring in Humidity-Controlled Environment Simulating Gamma Ray Irradiation Peer-reviewed

    Atsushi Omori, Eiji Akiyama, Hiroshi Abe, Kuniki Hata, Tomonori Sato, Yoshiyuki Kaji, Hiroyuki Inoue, Mitsumasa Taguchi, Hajime Seito, Eiji Tada, Shunichi Suzuki

    Zairyo-to-Kankyo 69 (4) 107-111 2020/04/10

    Publisher: Japan Society of Corrosion Engineering

    DOI: 10.3323/jcorr.69.107  

    ISSN: 0917-0480

    eISSN: 1881-9664

  95. Multiple damage mechanisms facilitated by planar dislocation glide in a commercial-grade precipitation-strengthened Fe–Ni–Cr-based steel Peer-reviewed

    Virendra Kumar Verma, Motomichi Koyama, Shigeru Hamada, Eiji Akiyama

    Materials Science and Engineering A 782 139250 2020/04

    DOI: 10.1016/j.msea.2020.139250  

    ISSN: 0921-5093

  96. Effect of carbon content on v-bending in high-strength TRIP-aided dual-phase steel sheets with polygonal ferrite matrix Peer-reviewed

    Akihiko Nagasaka, Tomohiko Hojo, Masaya Fujita, Takumi Ohashi, Mako Miyasaka, Yuki Shibayama, Eiji Akiyama

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 106 (12) 934-943 2020

    DOI: 10.2355/TETSUTOHAGANE.TETSU-2020-012  

    ISSN: 0021-1575

  97. Strain rate and hydrogen effects on crack growth from a notch in a Fe-high-Mn steel containing 1.1 wt% solute carbon Peer-reviewed

    Hina Najam, Motomichi Koyama, Burak Bal, Eiji Akiyama, Kaneaki Tsuzaki

    International Journal of Hydrogen Energy 45 (1) 1125-1139 2020/01/01

    DOI: 10.1016/j.ijhydene.2019.10.227  

    ISSN: 0360-3199

  98. Effects of alloying elements addition on delayed fracture properties of ultra high-strength trip-aided martensitic steels Peer-reviewed

    Tomohiko Hojo, Junya Kobayashi, Koh Ichi Sugimoto, Akihiko Nagasaka, Eiji Akiyama

    Metals 10 (1) 10.3390/met10010006 2020/01

    DOI: 10.3390/met10010006  

    eISSN: 2075-4701

  99. Transformation-assisted hydrogen desorption during deformation in steels: Examples of α′- and ε-Martensite Peer-reviewed

    Tomohiko Hojo, Motomichi Koyama, Natsuki Terao, Kaneaki Tsuzaki, Eiji Akiyama

    International Journal of Hydrogen Energy 44 (57) 30472-30477 2019/11/15

    DOI: 10.1016/j.ijhydene.2019.09.171  

    ISSN: 0360-3199

  100. Detection of hydrogen effusion before, during, and after martensitic transformation: Example of multiphase transformation-induced plasticity steel Peer-reviewed

    Motomichi Koyama, Daisuke Yamasaki, Arisa Ikeda, Tomohiko Hojo, Eiji Akiyama, Kenichi Takai, Kaneaki Tsuzaki

    International Journal of Hydrogen Energy 44 (47) 26028-26035 2019/10/04

    DOI: 10.1016/j.ijhydene.2019.07.254  

    ISSN: 0360-3199

  101. Corrosion Behavior of Reinforcing Steel with Mill Scale in Concrete

    Kotaro Doi, Sachiko Hiromoto, Tadashi Shinohara, Koichi Tsuchiya, Eiji Akiyama

    ECS Meeting Abstracts {MA}2019-02 (10) 824-824 2019/09/01

    Publisher: The Electrochemical Society

    DOI: 10.1149/MA2019-02/10/824  

  102. Effect of strain rate on the hydrogen embrittlement property of ultra high-strength low-alloy trip-aided steel Peer-reviewed

    Tomohiko Hojo, Riko Kikuchi, Hiroyuki Waki, Fumihito Nishimura, Yuko Ukai, Eiji Akiyama

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 105 (4) 33-41 2019/04

    DOI: 10.2355/tetsutohagane.TETSU-2018-087  

    ISSN: 0021-1575

  103. Hydrogen embrittlement behavior of Inconel 718 alloy at room temperature Peer-reviewed

    Xinfeng Li, Jin Zhang, Eiji Akiyama, Qinqin Fu, Qizhen Li

    Journal of Materials Science and Technology 35 (4) 499-502 2019/04

    DOI: 10.1016/j.jmst.2018.10.002  

    ISSN: 1005-0302

  104. Lowering Strain Rate Simultaneously Enhances Carbon- and Hydrogen-Induced Mechanical Degradation in an Fe-33Mn-1.1C Steel Peer-reviewed

    Ibrahim Burkay Tuğluca, Motomichi Koyama, Yusaku Shimomura, Burak Bal, Demircan Canadinc, Eiji Akiyama, Kaneaki Tsuzaki

    Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science 50 (3) 1137-1141 2019/03/15

    DOI: 10.1007/s11661-018-5080-7  

    ISSN: 1073-5623

  105. Hydrogen embrittlement of high strength steam turbine last stage blade steels: Comparison between PH17-4 steel and PH13-8Mo steel Peer-reviewed

    Xinfeng Li, Jin Zhang, Qinqin Fu, Eiji Akiyama, Xiaolong Song, Sicong Shen, Qizhen Li

    Materials Science and Engineering A 742 353-363 2019/01/10

    DOI: 10.1016/j.msea.2018.10.086  

    ISSN: 0921-5093

  106. An evaluation method for hydrogen embrittlement of high strength steel sheets using u-bend specimens Peer-reviewed

    Yuki Shibayama, Tomohiko Hojo, Eiji Akiyama

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 105 (9) 73-80 2019

    DOI: 10.2355/tetsutohagane.TETSU-2019-036  

    ISSN: 0021-1575

  107. Tensile mechanical properties and fracture behaviors of nickel-based superalloy 718 in the presence of hydrogen Peer-reviewed

    Xinfeng Li, Jin Zhang, Qinqin Fu, Eiji Akiyama, Xiaolong Song, Yanfei Wang, Qizhen Li, Ning Zou

    International Journal of Hydrogen Energy 43 (43) 20118-20132 2018/10/25

    DOI: 10.1016/j.ijhydene.2018.08.179  

    ISSN: 0360-3199

  108. Microstructural and crystallographic study of hydrogen-assisted cracking in high strength PSB1080 steel Peer-reviewed

    Xinfeng Li, Jin Zhang, Eiji Akiyama, Yanfei Wang, Qizhen Li

    International Journal of Hydrogen Energy 43 (37) 17898-17911 2018/09/13

    DOI: 10.1016/j.ijhydene.2018.07.158  

    ISSN: 0360-3199

  109. High-concentration carbon assists plasticity-driven hydrogen embrittlement in a Fe-high Mn steel with a relatively high stacking fault energy Peer-reviewed

    Ibrahim Burkay Tuğluca, Motomichi Koyama, Burak Bal, Demircan Canadinc, Eiji Akiyama, Kaneaki Tsuzaki

    Materials Science and Engineering A 717 78-84 2018/02/21

    DOI: 10.1016/j.msea.2018.01.087  

    ISSN: 0921-5093

  110. Cooling and deformation-induced hydrogen desorption in metastable austenitic steels detected by mass spectroscopy. Peer-reviewed

    Motomichi Koyama, N. Terao, T. Hojo, E.Akiyama, Kaneaki Tsuzaki

    Conference proceedings J03 2018

  111. Interstitial carbon enhanced corrosion resistance of Fe-33Mn-xC austenitic steels: Inhibition of anodic dissolution Peer-reviewed

    Aya Chiba, Motomichi Koyama, Eiji Akiyama, Toshiyasu Nishimura

    Journal of the Electrochemical Society 165 (2) C19-C26 2018

    DOI: 10.1149/2.0661802jes  

    ISSN: 0013-4651

    eISSN: 1945-7111

  112. Effects of oxygen pressure and chloride ion concentration on corrosion of iron in mortar exposed to pressurized humid oxygen gas Peer-reviewed

    Kotaro Doi, Sachiko Hiromoto, Hideki Katayama, Eiji Akiyama

    Journal of the Electrochemical Society 165 (9) C582-C589 2018

    Publisher: The Electrochemical Society

    DOI: 10.1149/2.1421809jes  

    ISSN: 0013-4651

    eISSN: 1945-7111

  113. Hyperbaric-oxygen accelerated corrosion test for iron in cement paste and mortar Peer-reviewed

    Kotaro Doi, Sachiko Hiromoto, Eiji Akiyama

    Materials Transactions 59 (6) 927-934 2018

    DOI: 10.2320/matertrans.M2018029  

    ISSN: 1345-9678

  114. Effect of strain rate on the hydrogen embrittlement property of ultra high-strength low alloy TRIP-aided steel Peer-reviewed

    Tomohiko Hojo, Riko Kikuchi, Hiroyuki Waki, Fumihito Nishimura, Yuko Ukai, Eiji Akiyama

    ISIJ International 58 (4) 751-759 2018

    DOI: 10.2355/isijinternational.ISIJINT-2017-576  

    ISSN: 0915-1559

  115. Size and distribution of micropores and voids in 5052 aluminum alloys during tensile deformation Peer-reviewed

    Tomohiko Hojo, Mamoru Kikuchi, Kazuyuki Shimizu, Hiroyuki Toda, Akihisa Takeuchi, Eiji Akiyama

    Keikinzoku/Journal of Japan Institute of Light Metals 68 (11) 630-634 2018

    DOI: 10.2464/jilm.68.630  

    ISSN: 0451-5994

  116. Hyperbaric-oxygen accelerated corrosion test of iron in cement paste and mortar Peer-reviewed

    Kotaro Doi, Sachiko Hiromoto, Eiji Akiyama

    Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals 82 (1) 1-7 2018

    DOI: 10.2320/jinstmet.J2017030  

    ISSN: 0021-4876

  117. Hydrogen embrittlement properties of nitrogen added ultra-high-strength TRIP-aided martensitic steels evaluated by using conventional strain rate technique Peer-reviewed

    Tomohiko Hojo, Kiattada Chanvichitkul, Hiroyuki Waki, Fumihito Nishimura, Eiji Akiyama

    Procedia Manufacturing 15 1581-1587 2018

    DOI: 10.1016/j.promfg.2018.07.309  

    eISSN: 2351-9789

  118. Room-temperature blue brittleness of Fe-Mn-C austenitic steels Peer-reviewed

    Motomichi Koyama, Yusaku Shimomura, Aya Chiba, Eiji Akiyama, Kaneaki Tsuzaki

    Scripta Materialia 141 20-23 2017/12

    DOI: 10.1016/j.scriptamat.2017.07.017  

    ISSN: 1359-6462

  119. モルタル埋設鉄の腐食発生と進展の促進

    土井 康太郎, 廣本 祥子, 秋山英二

    第64回材料と環境討論会講演集 115-116 2017/11/01

    More details Close

    我々の研究グループでは、モルタルに埋設した鉄試料に高圧酸素を供給することで腐食を促進させる高酸素腐食促進試験を開発した。この方法は、腐食の過程を発生と進展に分類すると腐食の進展の促進を行う方法である。本研究では、モルタル埋設鉄の腐食発生を促進する方法を検討し、高酸素腐食促進試験と組み合わせることでさらなる腐食促進を達成した。

  120. Effect of heat treatment on hydrogen-assisted fracture behavior of PH13-8Mo steel Peer-reviewed

    Xinfeng Li, Jin Zhang, Eiji Akiyama, Qizhen Li, Yanfei Wang

    Corrosion Science 128 198-212 2017/11

    DOI: 10.1016/j.corsci.2017.09.018  

    ISSN: 0010-938X

    eISSN: 1879-0496

  121. Recent progress in microstructural hydrogen mapping in steels: quantification, kinetic analysis, and multi-scale characterisation Peer-reviewed

    Motomichi Koyama, Michael Rohwerder, Cemal Cem Tasan, Asif Bashir, Eiji Akiyama, Kenichi Takai, Dierk Raabe, Kaneaki Tsuzaki

    Materials Science and Technology (United Kingdom) 33 (13) 1481-1496 2017/09/02

    DOI: 10.1080/02670836.2017.1299276  

    ISSN: 0267-0836

    eISSN: 1743-2847

  122. Acceleration of Fe Corrosion in Cement Paste and Mortar By Enhancing Oxygen Supply

    Kotaro Doi, Sachiko Hiromoto, Eiji Akiyama

    ECS Meeting Abstracts 2017/09/01

    Publisher: The Electrochemical Society

    DOI: 10.1149/MA2017-02/13/798  

  123. Warm tempforming effect on the hydrogen embrittlement of 1.8-GPa-class ultra-high-strength low-alloy steel Peer-reviewed

    Yuuji Kimura, Tadanobu Inoue, Eiji Akiyama

    Materials Science and Engineering A 703 (8) 503-512 2017/08/04

    DOI: 10.1016/j.msea.2017.07.091  

    ISSN: 0921-5093

    eISSN: 1873-4936

  124. Overview of hydrogen embrittlement in high-Mn steels Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Young Kook Lee, Dierk Raabe, Kaneaki Tsuzaki

    International Journal of Hydrogen Energy 42 (17) 12706-12723 2017/04

    DOI: 10.1016/j.ijhydene.2017.02.214  

    ISSN: 0360-3199

    eISSN: 1879-3487

  125. Interfacial hydrogen localization in austenite/martensite dual-phase steel visualized through optimized silver decoration and scanning Kelvin probe force microscopy Peer-reviewed

    T. Nagashima, M. Koyama, A. Bashir, M. Rohwerder, C. C. Tasan, E. Akiyama, D. Raabe, K. Tsuzaki

    Materials and Corrosion 68 (3) 306-310 2017/03/01

    DOI: 10.1002/maco.201609104  

    ISSN: 0947-5117

    eISSN: 1521-4176

  126. Hydrogen Entry into a High Strength Steel with Tribocorrosion in Acidic Solution Peer-reviewed

    DOI Kotaro, AKIYAMA Eiji

    Transactions of Japan Society of Spring Engineers 2017 (62) 9-14 2017

    Publisher: Japan Society of Spring Engineers

    DOI: 10.5346/trbane.2017.9  

    ISSN: 0385-6917

    More details Close

    <p>Hydrogen entry into a high strength steel with tribocorrosion in acidic solutions was studied in the present study and it was compared with that in a neutral solution. The samples of SCM 435 high strength steel were subjected to tribocorrosion using a pin-on-disk type wear equipment and to static corrosion in neutral and acidic solutions containing Cl-. The hydrogen content entered into the steel was measured using hydrogen thermal desorption analysis. In a neutral solution, the hydrogen content in the tribocorroded sample was larger than that in the corroded sample without wear. In the acidic solution of pH 2.7, the hydrogen content in the tribocorroded sample was also larger than that in the corroded sample without wear in the case of 6 and 12 h duration time. On the other hand, the hydrogen content in the corroded sample without wear became larger than that in the tribocorroded sample after 18 h duration time. In the measurement of pH changes of the solution for the duration of 48 h tribocorrosion test and static corrosion test, it is revealed that the pH of acidic solution during tribocorrosion increased from about 2.7 to 6.0, though the pH of the acidic solution during static corrosion test revealed little variation. Because H+ consumption by hydrogen generation in cathodic reaction was enhanced with tribocorrosion in acidic solution. The concentration of H+ decreased gradually and pH became higher. As a result, corrosion of the steel and hydrogen generation were suppressed and hydrogen entry into the sample was diminished.</p>

  127. Electrochemical hydrogen permeation test under controlled temperature and humidity after outdoor exposure at Beijing, Chongqing and Okinawa Peer-reviewed

    Eiji Akiyama, Songjie Li, Hideki Katayama, Boping Zhang, Kai Zhao, Wataru Oshikawa

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 103 (2) 93-100 2017

    DOI: 10.2355/tetsutohagane.TETSU-2016-096  

    ISSN: 0021-1575

    eISSN: 1883-2954

  128. Effects of Hydrogen on Tensile Properties at Slow Strain Rate of Ultra High-Strength TRIP-aided Bainitic Ferrite Steels Peer-reviewed

    Tomohiko Hojo, Yuko Ukai, Eiji Akiyama

    Procedia Engineering 207 1868-1873 2017

    Publisher: Elsevier Ltd

    DOI: 10.1016/j.proeng.2017.10.953  

    ISSN: 1877-7058

    eISSN: 1877-7058

  129. 酸素加圧下におけるコンクリート中鉄筋の腐食挙動

    土井 康太郎, 廣本 祥子, 秋山 英二

    第63回材料と環境討論会講演集 303-304 2016/10/01

    More details Close

    コンクリート中の鉄筋は表面に保護性の酸化皮膜である不働態を形成するため良好な耐食性を有しているが、コンクリート中への塩化物イオンや二酸化炭素の侵入により不働態は破壊され鉄筋が腐食しコンクリートの劣化につながる。自然界では数十年から数百年かかるといわれている鉄筋の腐食を実験室レベルで再現するために、短期間でコンクリート中の鉄筋を腐食させる加速試験法を考案した。現在、コンクリート中と比較して約20倍の加速に成功しており、生成した鉄さびの組成も自然界で生成されるものと同等である。

  130. Martensitic transformation-induced hydrogen desorption characterized by utilizing cryogenic thermal desorption spectroscopy during cooling Peer-reviewed

    Motomichi Koyama, Yuji Abe, Kei Saito, Eiji Akiyama, Kenichi Takai, Kaneaki Tsuzaki

    Scripta Materialia 122 50-53 2016/09/01

    DOI: 10.1016/j.scriptamat.2016.05.012  

    ISSN: 1359-6462

  131. Electrochemical hydrogen permeation tests under galvanostatic hydrogen charging conditions conventionally used for hydrogen embrittlement study Peer-reviewed

    Eiji Akiyama, Songjie Li

    Corrosion Reviews 34 (1-2) 103-112 2016/03/01

    DOI: 10.1515/corrrev-2015-0049  

    ISSN: 0334-6005

    eISSN: 2191-0316

  132. Hydrogen-assisted damage in austenite/martensite dual-phase steel Peer-reviewed

    Motomichi Koyama, Cemal Cem Tasan, Tatsuya Nagashima, Eiji Akiyama, Dierk Raabe, Kaneaki Tsuzaki

    Philosophical Magazine Letters 96 (1) 9-18 2016/01/02

    DOI: 10.1080/09500839.2015.1130275  

    ISSN: 0950-0839

    eISSN: 1362-3036

  133. Electrochemical hydrogen permeation test under controlled temperature and humidity after outdoor exposure at Beijing, Chongqing and Okinawa Peer-reviewed

    Eiji Akiyama, Songjie Li, Hideki Katayama, Boping Zhang, Kai Zhao, Wataru Oshikawa

    ISIJ International 56 (3) 436-443 2016

    DOI: 10.2355/isijinternational.ISIJINT-2015-275  

    ISSN: 0915-1559

    eISSN: 1347-5460

  134. Comparison of constant load, SSRT and CSRT methods for hydrogen embrittlement evaluation using round bar specimens of high strength steels Peer-reviewed

    Tetsushi Chida, Yukito Hagihara, Eiji Akiyama, Kengo Iwanaga, Shusaku Takagi, Masao Hayakawa, Hiroyuki Ohishi, Daisuke Hirakami, Toshimi Tarui

    ISIJ International 56 (7) 1268-1275 2016

    DOI: 10.2355/isijinternational.ISIJINT-2015-565  

    ISSN: 0915-1559

    eISSN: 1347-5460

  135. Hydrogen entry into an AISI 4135 high strength steel in tribocorrosion environment Peer-reviewed

    K. Doi, E. Akiyama, M. Hayakawa

    ECS Transactions 75 (29) 33-41 2016

    DOI: 10.1149/07529.0033ecst  

    ISSN: 1938-6737

    eISSN: 1938-5862

  136. Electrochemical hydrogen permeation tests under conventional potentiostatic hydrogen charging conditions for hydrogen embrittlement study Peer-reviewed

    E. Akiyama, S. Li

    ECS Transactions 75 (29) 23-31 2016

    Publisher: Electrochemical Society Inc.

    DOI: 10.1149/07529.0023ecst  

    ISSN: 1938-6737

    eISSN: 1938-5862

  137. Hydrogen visualization in steels using Ag decoration method Peer-reviewed

    Eiji Akiyama, Saburo Matsuoka

    Materials Transactions 56 (6) 793-797 2015

    DOI: 10.2320/matertrans.M2014431  

    ISSN: 1345-9678

    eISSN: 1347-5320

  138. Spatially and kinetically resolved mapping of hydrogen in a twinning-induced plasticity steel by use of Scanning Kelvin Probe Force Microscopy Peer-reviewed

    Motomichi Koyama, Asif Bashir, Michael Rohwerder, Sergiy V. Merzlikin, Eiji Akiyama, Kaneaki Tsuzaki, Dierk Raabe

    Journal of the Electrochemical Society 162 (12) C638-C647 2015

    DOI: 10.1149/2.0131512jes  

    ISSN: 0013-4651

    eISSN: 1945-7111

  139. Hydrogen-assisted decohesion and localized plasticity in dual-phase steel Peer-reviewed

    Motomichi Koyama, Cemal Cem Tasan, Eiji Akiyama, Kaneaki Tsuzaki, Dierk Raabe

    Acta Materialia 70 174-187 2014/05/15

    DOI: 10.1016/j.actamat.2014.01.048  

    ISSN: 1359-6454

    eISSN: 1873-2453

  140. Hydrogen embrittlement associated with strain localization in a precipitation-hardened Fe-Mn-Al-C light weight austenitic steel Peer-reviewed

    Motomichi Koyama, Hauke Springer, Sergiy V. Merzlikin, Kaneaki Tsuzaki, Eiji Akiyama, Dierk Raabe

    International Journal of Hydrogen Energy 39 (9) 4634-4646 2014/03/18

    DOI: 10.1016/j.ijhydene.2013.12.171  

    ISSN: 0360-3199

    eISSN: 1879-3487

  141. Factors affecting hydrogen embrittlement susceptibility of twinning-induced plasticity steels. Peer-reviewed

    Motomichi Koyama, E. Akiyama, D. Raabe, Kaneaki Tsuzaki

    Proc. 2nd HMnS 2014

  142. Fe-Mn-C-Al TWIP鋼の水素脆化における静的および動的ひずみ時効の影響 Peer-reviewed

    小山元道, 秋山英二, 津﨑兼彰

    鉄と鋼 100 1132-1139 2014

  143. 水素チャージ下引張試験におけるAl添加型TWIP鋼の水素脆化 Peer-reviewed

    小山元道, 秋山英二, 津﨑兼彰

    鉄と鋼 100 662-667 2014

  144. Effects of static and dynamic strain aging on hydrogen embrittlement in twip steels containing Al Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 100 (9) 1132-1139 2014

    DOI: 10.2355/tetsutohagane.100.1132  

    ISSN: 0021-1575

    eISSN: 1883-2954

  145. Hydrogen embrittlement in Al-added twinning-induced plasticity steels evaluated by tensile tests during hydrogen charging Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 100 (5) 662-667 2014

    DOI: 10.2355/tetsutohagane.100.662  

    ISSN: 0021-1575

    eISSN: 1883-2954

  146. Factors affecting static strain aging under stress at room temperature in a Fe-Mn-C twinning-induced plasticity steel Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 100 (9) 1123-1131 2014

    DOI: 10.2355/tetsutohagane.100.1123  

    ISSN: 0021-1575

    eISSN: 1883-2954

  147. Comparison of constant load, SSRT and CSRT methods for hydrogen embrittlement evaluation using round bar specimens of high strength steels Peer-reviewed

    Tetsushi Chida, Yukito Hagihara, Eiji Akiyama, Kengo Iwanaga, Shusaku Takagi, Hiroyuki Ohishi, Masao Hayakawa, Daisuke Hirakami, Toshimi Tarui

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 100 (10) 1298-1305 2014

    DOI: 10.2355/tetsutohagane.100.1298  

    ISSN: 0021-1575

    eISSN: 1883-2954

  148. Hydrogen visualization in steels using ag decoration method Peer-reviewed

    Eiji Akiyama, Saburo Matsuoka

    Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals 77 (12) 622-626 2013/12

    DOI: 10.2320/jinstmet.JC201311  

    ISSN: 0021-4876

    eISSN: 1880-6880

  149. Hydrogen-assisted quasi-cleavage fracture in a single crystalline type 316 austenitic stainless steel Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Takahiro Sawaguchi, Kazuyuki Ogawa, Irina V. Kireeva, Yury I. Chumlyakov, Kaneaki Tsuzaki

    Corrosion Science 75 345-353 2013/10

    DOI: 10.1016/j.corsci.2013.06.018  

    ISSN: 0010-938X

    eISSN: 1879-0496

  150. Hydrogen-assisted failure in a twinning-induced plasticity steel studied under in situ hydrogen charging by electron channeling contrast imaging Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki, Dierk Raabe

    Acta Materialia 61 (12) 4607-4618 2013/07

    DOI: 10.1016/j.actamat.2013.04.030  

    ISSN: 1359-6454

  151. Fretting fatigue behaviour of Ni-free high-nitrogen stainless steel in a simulated body fluid Peer-reviewed

    Norio Maruyama, Sachiko Hiromoto, Eiji Akiyama, Morihiko Nakamura

    Science and Technology of Advanced Materials 14 (2) 025002 2013/04

    DOI: 10.1088/1468-6996/14/2/025002  

    ISSN: 1468-6996

  152. Studies of evaluation of hydrogen embrittlement property of high-strength steels with consideration of the effect of atmospheric corrosion Peer-reviewed

    Eiji Akiyama, Maoqiu Wang, Songjie Li, Zuogui Zhang, Yuuji Kimura, Nobuyoshi Uno, Kaneaki Tsuzaki

    Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science 44 (3) 1290-1300 2013/03

    DOI: 10.1007/s11661-012-1403-2  

    ISSN: 1073-5623

    eISSN: 1543-1940

  153. Stochastic Evaluation of Hydrogen Uptake Affecting the Delayed Fracture of High Strength Bolts Peer-reviewed

    MATSUOKA Kazumi, UNO Nobuyoshi, AKIYAMA Eiji, HAGIHARA Yukito, MATSUYAMA Shinsaku, HARADA Hiroaki

    Kou kouzou rombunshuu 20 (79) 79_29-79_40 2013

    Publisher: Japanese Society of Steel Construction

    DOI: 10.11273/jssc.20.79_29  

    ISSN: 1880-9928

    More details Close

    The local concentration of hydrogen absorbed from the environment in the section of high strength steels, where the hydrostatic stress is the highest under loading and where the initiation of delayed fracture takes place, was investigated stochastically. For the investigation, the results of statistical analysis of critical hydrogen concentration for delayed fracture obtained by using conventional strain rate tests and the ratio of fracture of exposed high strength bolts were used. The probability distribution of the local hydrogen was successfully evaluated and the correspondent environmental pH was estimated. The pH value simulating the maximum hydrogen entry caused by atmospheric corrosion in Okinawa was slightly lower than 2.

  154. Hydrogen entry behavior into iron and steels under atmospheric corrosion Peer-reviewed

    Songjie Li, Eiji Akiyama, Tadashi Shinohara, Kazumi Matsuoka, Wataru Oshikawa

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 99 (11) 651-658 2013

    DOI: 10.2355/tetsutohagane.99.651  

    ISSN: 0021-1575

    eISSN: 1883-2954

  155. Effects of static and dynamic strain aging on hydrogen embrittlement in twip steels containing al Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    ISIJ International 53 (7) 1268-1274 2013

    DOI: 10.2355/isijinternational.53.1268  

    ISSN: 0915-1559

  156. Factors affecting static strain aging under stress at room temperature in a Fe-Mn-C twinning-induced plasticity steel Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    ISIJ International 53 (6) 1089-1096 2013

    DOI: 10.2355/isijinternational.53.1089  

    ISSN: 0915-1559

  157. Hydrogen entry behavior into iron and steel under atmospheric corrosion Peer-reviewed

    Songjie Li, Eiji Akiyama, Tadashi Shinohara, Kazumi Matsuoka, Wataru Oshikawa

    ISIJ International 53 (6) 1062-1069 2013

    DOI: 10.2355/isijinternational.53.1062  

    ISSN: 0915-1559

    eISSN: 1347-5460

  158. The use of renewable energy in the form of methane via electrolytic hydrogen generation Peer-reviewed

    K. Hashimoto, N. Kumagai, K. Izumiya, H. Takano, P. R. Zabiński, A. A. El-Moneim, M. Yamasaki, Z. Kato, E. Akiyama, H. Habazaki

    Archives of Metallurgy and Materials 58 (1) 231-239 2013

    DOI: 10.2478/v10172-012-0179-0  

    ISSN: 1733-3490

  159. Effect of hydrogen content on the embrittlement in a Fe-Mn-C twinning-induced plasticity steel Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    Corrosion Science 59 277-281 2012/06

    DOI: 10.1016/j.corsci.2012.03.009  

    ISSN: 0010-938X

  160. Hydrogen-induced delayed fracture of a Fe-22Mn-0.6C steel pre-strained at different strain rates Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    Scripta Materialia 66 (11) 947-950 2012/06

    DOI: 10.1016/j.scriptamat.2012.02.040  

    ISSN: 1359-6462

  161. Hydrogen embrittlement of a 1500-MPa tensile strength level steel with an ultrafine elongated grain structure Peer-reviewed

    Yihong Nie, Yuuji Kimura, Tadanobu Inoue, Fuxing Yin, Eiji Akiyama, Kaneaki Tsuzaki

    Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science 43 (5) 1670-1687 2012/05

    DOI: 10.1007/s11661-011-0974-7  

    ISSN: 1073-5623

  162. Hydrogen-induced cracking at grain and twin boundaries in an Fe-Mn-C austenitic steel Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Takahiro Sawaguchi, Dierk Raabe, Kaneaki Tsuzaki

    Scripta Materialia 66 (7) 459-462 2012/04

    DOI: 10.1016/j.scriptamat.2011.12.015  

    ISSN: 1359-6462

  163. Evaluation of delayed fracture property of high strength bolt steels Peer-reviewed

    Eiji Akiyama

    ISIJ International 52 (2) 307-315 2012

    DOI: 10.2355/isijinternational.52.307  

    ISSN: 0915-1559

    eISSN: 1347-5460

  164. Hydrogen embrittlement in Al-added twinning-induced plasticity steels evaluated by tensile tests during hydrogen charging Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    ISIJ International 52 (12) 2283-2287 2012

    DOI: 10.2355/isijinternational.52.2283  

    ISSN: 0915-1559

    eISSN: 1347-5460

  165. Hydrogen embrittlement in a Fe-Mn-C ternary twinning-induced plasticity steel Peer-reviewed

    Motomichi Koyama, Eiji Akiyama, Kaneaki Tsuzaki

    Corrosion Science 54 (1) 1-4 2012/01

    DOI: 10.1016/j.corsci.2011.09.022  

    ISSN: 0010-938X

  166. Corrosion behaviour of sputter-deposited Mg-Zr alloys in a borate buffer solution Peer-reviewed

    A. A. El-Moneim, E. Akiyama, K. M. Ismail, K. Hashimoto

    Corrosion Science 53 (9) 2988-2993 2011/09

    DOI: 10.1016/j.corsci.2011.05.043  

    ISSN: 0010-938X

  167. Constant-load delayed fracture test of atmospherically corroded high strength steels Peer-reviewed

    Eiji Akiyama, Katsuhiro Matsukado, Songjie Li, Kaneaki Tsuzaki

    Applied Surface Science 257 (19) 8275-8281 2011/07/15

    DOI: 10.1016/j.apsusc.2011.03.037  

    ISSN: 0169-4332

    eISSN: 1873-5584

  168. Hydrogen entry into Fe and high strength steels under simulated atmospheric corrosion Peer-reviewed

    Eiji Akiyama, Songjie Li, Tadashi Shinohara, Zuogui Zhang, Kaneaki Tsuzaki

    Electrochimica Acta 56 (4) 1799-1805 2011/01/15

    DOI: 10.1016/j.electacta.2010.09.043  

    ISSN: 0013-4686

    eISSN: 1873-3859

  169. Evaluation of delayed fracture property of outdoor-exposed high strength AISI 4135 steels Peer-reviewed

    Songjie Li, Eiji Akiyama, Nobuyoshi Uno, Keiji Hirai, Kaneaki Tsuzaki, Boping Zhang

    Corrosion Science 52 (10) 3198-3204 2010/10

    DOI: 10.1016/j.corsci.2010.05.038  

    ISSN: 0010-938X

    eISSN: 1879-0496

  170. Evaluation of hydrogen entry into high strength steel under atmospheric corrosion Peer-reviewed

    Eiji Akiyama, Katsuhiro Matsukado, Maoqiu Wang, Kaneaki Tsuzaki

    Corrosion Science 52 (9) 2758-2765 2010/09

    DOI: 10.1016/j.corsci.2009.11.046  

    ISSN: 0010-938X

    eISSN: 1879-0496

  171. Evaluation of susceptibility of high strength steels to delayed fracture by using cyclic corrosion test and slow strain rate test Peer-reviewed

    Songjie Li, Zuogui Zhang, Eiji Akiyama, Kaneaki Tsuzaki, Boping Zhang

    Corrosion Science 52 (5) 1660-1667 2010/05

    DOI: 10.1016/j.corsci.2010.02.005  

    ISSN: 0010-938X

    eISSN: 1879-0496

  172. Hydrogen embrittlement property of a 1700-MPa-class ultrahigh-strength tempered martensitic steel Peer-reviewed

    Songjie Li, Eiji Akiyama, Kimura Yuuji, Kaneaki Tsuzaki, Nobuyoshi Uno, Boping Zhang

    Science and Technology of Advanced Materials 11 (2) 025005 2010

    DOI: 10.1088/1468-6996/11/2/025005  

    ISSN: 1468-6996

    eISSN: 1878-5514

  173. Effects of severe plastic deformation on the corrosion behavior of aluminum alloys Peer-reviewed

    Eiji Akiyama, Zuogui Zhang, Yoshimi Watanabe, Kaneaki Tsuzaki

    Journal of Solid State Electrochemistry 13 (2) 277-282 2009/02

    DOI: 10.1007/s10008-007-0496-9  

    ISSN: 1432-8488

  174. Hydrogen embrittlement of high strength steels and environmental hydrogen entry Peer-reviewed

    Eiji Akiyama, Songjie Li, Zuogui Zhang, Maoqiu Wang, Katsuhiro Matsukado, Kaneaki Tsuzaki, Boping Zhang

    Proceedings of the 2008 International Hydrogen Conference - Effects of Hydrogen on Materials 54-61 2009

  175. Evaluation of delayed fracture characteristics of high strength steel based on CSRT method Peer-reviewed

    Yukito Hagihara, Chikahito Ito, Noriyuki Hisamori, Hiroshi Suzuki, Kenichi Takai, Eiji Akiyama

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 94 (6) 215-221 2008

    DOI: 10.2355/tetsutohagane.94.215  

    ISSN: 0021-1575

    eISSN: 1883-2954

  176. Effect of hydrogen on the fracture behavior of high strength steel during slow strain rate test Peer-reviewed

    Maoqiu Wang, Eiji Akiyama, Kaneaki Tsuzaki

    Corrosion Science 49 (11) 4081-4097 2007/11

    DOI: 10.1016/j.corsci.2007.03.038  

    ISSN: 0010-938X

  177. Effect of α-Al/Al<inf>3</inf>Ni microstructure on the corrosion behaviour of Al-5.4 wt% Ni alloy fabricated by equal-channel angular pressing Peer-reviewed

    Zuogui Zhang, Eiji Akiyama, Yoshimi Watanabe, Yasuyuki Katada, Kaneaki Tsuzaki

    Corrosion Science 49 (7) 2962-2972 2007/07

    DOI: 10.1016/j.corsci.2007.02.007  

    ISSN: 0010-938X

  178. Corrosion behavior of Al-7wt% Sl-1.5wt% Cu severely deformed by equal-channel angular pressing Peer-reviewed

    Zuogui Zhang, Eiji Akiyama, Yoshimi Watanabe, Yasuyuki Katada, Kaneaki Tsuzaki

    Materials Science Forum 539-543 (PART 3) 2892-2897 2007

    DOI: 10.4028/0-87849-428-6.2892  

    ISSN: 0255-5476

    eISSN: 1662-9752

  179. The role of corrosion-resistant alloying elements in passivity Peer-reviewed

    K. Hashimoto, K. Asami, A. Kawashima, H. Habazaki, E. Akiyama

    Corrosion Science 49 (1) 42-52 2007/01

    DOI: 10.1016/j.corsci.2006.05.003  

    ISSN: 0010-938X

  180. Discrete electrochemical transients of aluminium alloys generated by slurry jet impingement Peer-reviewed

    Eiji Akiyama, Martin Stratmann, Achim Walter Hassel

    Journal of Physics D: Applied Physics 39 (15) 3157-3164 2006/08/07

    DOI: 10.1088/0022-3727/39/15/S05  

    ISSN: 0022-3727

    eISSN: 1361-6463

  181. Determination of the critical hydrogen concentration for delayed fracture of high strength steel by constant load test and numerical calculation Peer-reviewed

    Maoqiu Wang, Eiji Akiyama, Kaneaki Tsuzaki

    Corrosion Science 48 (8) 2189-2202 2006/08

    DOI: 10.1016/j.corsci.2005.07.010  

    ISSN: 0010-938X

  182. Effect of hydrogen on notch tensile strength of high strength steel Peer-reviewed

    Mao Qiu Wang, Han Dong, Wei Jun Hui, Jie Shi, Eiji Akiyama, Kaneaki Tsuzaki

    Cailiao Rechuli Xuebao/Transactions of Materials and Heat Treatment 27 (4) 57-60 2006/08

    ISSN: 1009-6264

  183. Fracture criterion for hydrogen embrittlement of high strength steel Peer-reviewed

    M. Q. Wang, E. Akiyama, K. Tsuzaki

    Materials Science and Technology 22 (2) 167-172 2006/02

    DOI: 10.1179/174328406X86191  

    ISSN: 0267-0836

  184. Acetate and chloride effects on hydrogen production across crevices Peer-reviewed

    T. Sundararajan, E. Akiyama, K. Tsuzaki

    Materials Science Forum 512 97-102 2006

    DOI: 10.4028/0-87849-996-2.97  

    ISSN: 0255-5476

    eISSN: 1662-9752

  185. Effect of hydrogen on the fracture behavior of high-strength Cr-Mo steel Peer-reviewed

    Maoqiu Wang, Eiji Akiyama, Kaneaki Tsuzaki

    Materials Science Forum 512 55-60 2006

    DOI: 10.4028/0-87849-996-2.55  

    ISSN: 0255-5476

    eISSN: 1662-9752

  186. Influence of microstructure on electrochemical properties of severely deformed AI-5 wt% Cu alloy by ECAP Peer-reviewed

    Zuogui Zhang, Eiji Akiyama, Yoshimi Watanabe, Yasuyuki Katada, Kaneaki Tsuzaki

    Materials Science Forum 519-521 (PART 1) 705-710 2006

    DOI: 10.4028/0-87849-408-1.705  

    ISSN: 0255-5476

    eISSN: 1662-9752

  187. Hydrogen entry in crevice region: Evaluation by hydrogen permeation technique Peer-reviewed

    Thiyagarajan Sundararajan, Eiji Akiyama, Yasuyuki Katada, Kaneaki Tsuzaki

    ISIJ International 46 (7) 1081-1085 2006

    DOI: 10.2355/isijinternational.46.1081  

    ISSN: 0915-1559

  188. Hydrogen mapping across a crevice: Effect of applied potential Peer-reviewed

    T. Sundararajan, E. Akiyama, K. Tsuzaki

    Scripta Materialia 53 (11) 1219-1223 2005/12

    DOI: 10.1016/j.scriptamat.2005.08.016  

    ISSN: 1359-6462

  189. Crosshead speed dependence of the notch tensile strength of a high strength steel in the presence of hydrogen Peer-reviewed

    Maoqiu Wang, Eiji Akiyama, Kaneaki Tsuzaki

    Scripta Materialia 53 (6) 713-718 2005/09

    DOI: 10.1016/j.scriptamat.2005.05.014  

    ISSN: 1359-6462

  190. Effect of hydrogen and stress concentration on the notch tensile strength of AISI 4135 steel Peer-reviewed

    Maoqiu Wang, Eiji Akiyama, Kaneaki Tsuzaki

    Materials Science and Engineering A 398 (1-2) 37-46 2005/05/25

    DOI: 10.1016/j.msea.2005.03.008  

    ISSN: 0921-5093

  191. Hydrogen degradation of a boron-bearing steel with 1050 and 1300MPa strength levels Peer-reviewed

    Maoqiu Wang, Eiji Akiyama, Kaneaki Tsuzaki

    Scripta Materialia 52 (5) 403-408 2005/03

    DOI: 10.1016/j.scriptamat.2004.10.023  

    ISSN: 1359-6462

  192. Depassivation and repassivation of titanium under particle impingements Peer-reviewed

    E. Akiyama, K. Tsuzaki

    ECS Transactions 1 (4) 437-446 2005

    DOI: 10.1149/1.2215527  

    ISSN: 1938-5862

    eISSN: 1938-6737

  193. Hydrogen mapping across crevices Peer-reviewed

    T. Sundararajan, E. Akiyama, K. Tsuzaki

    Electrochemical and Solid-State Letters 8 (9) B30-B33 2005

    DOI: 10.1149/1.1979367  

    ISSN: 1099-0062

  194. Storage and release of soluble hexavalent chromium from chromate conversion coatings on Al alloys Peer-reviewed

    E. Akiyama, A. J. Markworth, J. K. McCoy, G. S. Frankel, L. Xia, R. L. McCreery

    Journal of the Electrochemical Society 150 (2) B83-B91 2003/02

    DOI: 10.1149/1.1537755  

    ISSN: 0013-4651

  195. Distribution of hydrogen occluded in bolts tightened beyond the yield strength and exposed at a seashore site Peer-reviewed

    Shinji Sakashita, Eiji Akiyama, Kaneaki Tsuzaki, Shinsaku Matsuyama

    Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 88 (12) 849-856 2002/12

    DOI: 10.2355/tetsutohagane1955.88.12_849  

    ISSN: 0021-1575

    eISSN: 1883-2954

  196. Materials for global carbon dioxide recycling Peer-reviewed

    K. Hashimoto, M. Yamasaki, S. Meguro, T. Sasaki, H. Katagiri, K. Izumiya, N. Kumagai, H. Habazaki, E. Akiyama, K. Asami

    Corrosion Science 44 (2) 371-386 2002/02

    DOI: 10.1016/S0010-938X(01)00067-1  

    ISSN: 0010-938X

  197. Advanced materials for global carbon dioxide recycling Peer-reviewed

    K. Hashimoto, H. Habazaki, M. Yamasaki, S. Meguro, T. Sasaki, H. Katagiri, T. Matsui, K. Fujimura, K. Izumiya, N. Kumagai, E. Akiyama

    Materials Science and Engineering A 304-306 (1-2) 88-96 2001/05/31

    DOI: 10.1016/S0921-5093(00)01457-X  

    ISSN: 0921-5093

  198. Enhancement of corrosion resistance of amorphous aluminum alloys by alloying additions Peer-reviewed

    E Akiyama, K Asami, H Habazaki, A Kawashima, K Hashimoto

    CORROSION AND CORROSION PROTECTION 2001 (22) 1-8 2001

  199. Angle-resolved XPS for determination of diffusion coefficients and mobilities of cations in thin passive films Peer-reviewed

    Katsuhiko Asami, Eiji Akiyama, Koji Hashimoto

    Surface and Interface Analysis 30 (1) 106-111 2000/08

    DOI: 10.1002/1096-9918(200008)30:1<106::AID-SIA768>3.0.CO;2-3  

    ISSN: 0142-2421

  200. Storage and release of soluble hexavalent chromium from chromate conversion coatings. Equilibrium aspects of CrVI concentration Peer-reviewed

    Lin Xia, Eiji Akiyama, Gerald Frankel, Richard McCreery

    Journal of the Electrochemical Society 147 (7) 2556-2562 2000/07

    DOI: 10.1149/1.1393568  

    ISSN: 0013-4651

  201. Effects of nanocrystalline heterogeneity on the corrosion behavior of sputter-deposited chromium-niobium alloys Peer-reviewed

    M. Mehmood, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 42 (2) 361-382 2000/02/01

    DOI: 10.1016/S0010-938X(99)00077-3  

    ISSN: 0010-938X

  202. Oxidation behavior of amorphous Ni-Zr and Ni-Zr-rare earth element alloys Peer-reviewed

    M Yamasaki, H Habazaki, A Kawashima, K Asami, E Akiyama, K Hashimoto

    HIGH TEMPERATURE CORROSION AND MATERIALS CHEMISTRY 99 (38) 180-191 2000

  203. XPS determination of diffusion coefficients of cations in thin passive films on alloys Peer-reviewed

    Katsuhiko Asami, Eiji Akiyama, Koji Hashimoto

    Solid State Phenomena 72 79-84 2000

    DOI: 10.4028/www.scientific.net/ssp.72.79  

    ISSN: 1012-0394

  204. Influence of dichromate ions on aluminum dissolution kinetics in artificial crevice electrode cells Peer-reviewed

    E. Akiyama, G. S. Frankel

    Journal of the Electrochemical Society 146 (11) 4095-4100 1999/11

    DOI: 10.1149/1.1392597  

    ISSN: 0013-4651

  205. The corrosion behavior of sputter-deposited amorphous Fe-Cr-Ni-Ta alloys in 12 M HCl Peer-reviewed

    X. Y. Li, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 41 (9) 1849-1869 1999/08

    DOI: 10.1016/S0010-938X(99)00019-0  

    ISSN: 0010-938X

  206. The degradation of the corrosion resistance of sputter-deposited chromium-titanium alloys by nanoscale heterogeneity Peer-reviewed

    M. Mehmood, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 41 (9) 1871-1890 1999/08

    DOI: 10.1016/S0010-938X(99)00020-7  

    ISSN: 0010-938X

  207. The sulfidation and oxidation behavior of sputter-deposited Al-Nb-Mo alloys Peer-reviewed

    K. Hon-Yashiki, H. Habazaki, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto, S. Mrowec

    Materials Science and Engineering A 267 (2) 277-284 1999/07/31

    DOI: 10.1016/S0921-5093(99)00103-3  

    ISSN: 0921-5093

  208. Corrosion-resistant Mn-Zr-Cr alloys in chloride-containing media Peer-reviewed

    A. A. El-Moneim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science and Engineering A 267 (2) 285-293 1999/07/31

    DOI: 10.1016/S0921-5093(99)00104-5  

    ISSN: 0921-5093

  209. CO<inf>2</inf> methanation catalysts prepared from amorphous Ni-Zr-Sm and Ni-Zr-misch metal alloy precursors Peer-reviewed

    Michiaki Yamasaki, Mitsuru Komori, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Materials Science and Engineering A 267 (2) 220-226 1999/07/31

    DOI: 10.1016/S0921-5093(99)00095-7  

    ISSN: 0921-5093

  210. Oxygen evolution on manganese-molybdenum oxide anodes in seawater electrolysis Peer-reviewed

    K. Fujimura, T. Matsui, K. Izumiya, N. Kumagai, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science and Engineering A 267 (2) 254-259 1999/07/31

    DOI: 10.1016/S0921-5093(99)00100-8  

    ISSN: 0921-5093

  211. Global CO<inf>2</inf> recycling - Novel materials and prospect for prevention of global warming and abundant energy supply Peer-reviewed

    K. Hashimoto, M. Yamasaki, K. Fujimura, T. Matsui, K. Izumiya, M. Komori, A. A. El-Moneim, E. Akiyama, H. Habazaki, N. Kumagai, A. Kawashima, K. Asami

    Materials Science and Engineering A 267 (2) 200-206 1999/07/31

    DOI: 10.1016/S0921-5093(99)00092-1  

    ISSN: 0921-5093

  212. Electrochemical and XPS studies of the corrosion behavior of sputter-deposited amorphous Fe-Cr-Ni-Nb alloys in 6 M HCl Peer-reviewed

    X. Y. Li, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 41 (6) 1095-1118 1999/06/01

    DOI: 10.1016/S0010-938X(98)00174-7  

    ISSN: 0010-938X

  213. Release of chromate ions from chromate conversion coatings on Al alloys Peer-reviewed

    E Akiyama, L Xia, R McCreery, A Markworth, GS Frankel

    PASSIVITY AND LOCALIZED CORROSION 99 (27) 300-309 1999

  214. The critical size and nature of nanocrystalline heterogeneity for pitting corrosion Peer-reviewed

    K Hashimoto, M Mehmood, XY Li, E Akiyama, H Habazaki, A Kawashima, K Asami

    PROCEEDINGS OF THE SYMPOSIUM ON CRITICAL FACTORS IN LOCALIZED CORROSION III 98 (17) 245-255 1999

  215. Anodically deposited manganese-molybdenum oxide anodes with high selectivity for evolving oxygen in electrolysis of seawater Peer-reviewed

    K. Fujimura, K. Izumiya, A. Kawashima, E. Akiyama, H. Habazaki, N. Kumagai, K. Hashimoto

    Journal of Applied Electrochemistry 29 (6) 765-771 1999

    DOI: 10.1023/A:1003492009263  

    ISSN: 0021-891X

  216. The influence of concentration of hydrochloric acid solutions on the passivation behavior of sputter-deposited tungsten rich W-Nb alloys Peer-reviewed

    J. Bhattarai, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (11) 1897-1914 1998/11/01

    DOI: 10.1016/S0010-938X(98)00088-2  

    ISSN: 0010-938X

  217. Hydrogen evolution characteristics of sputter-deposited Co-Mo, Co-Al and Co-Mo-Al alloy electrodes in NaOH solution Peer-reviewed

    Toshio Aihara, Asahi Kawashima, Eiji Akiyama, Hiroki Habazaki, Katsuhiko Asami, Koji Hashimoto

    Materials Transactions, JIM 39 (10) 1017-1023 1998/10

    DOI: 10.2320/matertrans1989.39.1017  

    ISSN: 0916-1821

  218. The effect of alloying elements on the corrosion behaviour of sputter-deposited amorphous Mn-Ta-Cr alloys in 1 M H<inf>2</inf>SO<inf>4</inf> Peer-reviewed

    A. A. El-Moneim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (9) 1491-1512 1998/09/01

    DOI: 10.1016/S0010-938X(98)00061-4  

    ISSN: 0010-938X

  219. XPS and electrochemical studies on the corrosion behaviour of sputter-deposited amorphous Mn-Nb alloys in a neutral chloride solution Peer-reviewed

    A. A. El-Moneim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (9) 1513-1531 1998/09/01

    DOI: 10.1016/S0010-938X(98)00064-X  

    ISSN: 0010-938X

  220. Electrochemical and XPS studies of the passivation behavior of sputter-deposited Cr-Ta alloys in 12 M HCl Peer-reviewed

    X. Y. Li, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (9) 1587-1604 1998/09/01

    DOI: 10.1016/S0010-938X(98)00070-5  

    ISSN: 0010-938X

  221. Electrochemical and XPS studies of the passivation behavior of sputter-deposited Cr-Ta alloys in 12 M HCl Peer-reviewed

    XY Li, E Akiyama, H Habazaki, A Kawashima, K Asami, K Hashimoto

    CORROSION SCIENCE 40 (9) 1587-1604 1998/09

    DOI: 10.1016/S0010-938X(97)00106-6  

    ISSN: 0010-938X

  222. Anodically deposited manganese oxide and manganese-tungsten oxide electrodes for oxygen evolution from seawater Peer-reviewed

    K. Izumiya, E. Akiyama, H. Habazaki, N. Kumagai, A. Kawashima, K. Hashimoto

    Electrochimica Acta 43 (21-22) 3303-3312 1998/07/01

    DOI: 10.1016/S0013-4686(98)00075-9  

    ISSN: 0013-4686

  223. An XPS study of passive films on sputter-deposited Cr-Nb alloys in 12 M HCl solution Peer-reviewed

    X. Y. Li, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (4-5) 821-838 1998/04

    DOI: 10.1016/S0010-938X(98)00003-1  

    ISSN: 0010-938X

  224. The passivation behavior of sputter-deposited W-Ta alloys in 12M HCl Peer-reviewed

    J. Bhattarai, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (4-5) 757-779 1998/04

    DOI: 10.1016/S0010-938X(97)00177-7  

    ISSN: 0010-938X

  225. The effect of heat treatment on the corrosion behavior of sputter-deposited aluminum-chromium alloys Peer-reviewed

    M. Mehmood, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 41 (3) 477-499 1998/03/01

    DOI: 10.1016/S0010-938X(98)00130-9  

    ISSN: 0010-938X

  226. Electrochemical and XPS studies on the passivation behavior of sputter-deposited W-Cr alloys in 12M HCl solution Peer-reviewed

    J. Bhattarai, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (2-3) 155-175 1998/02

    DOI: 10.1016/S0010-938X(97)00106-6  

    ISSN: 0010-938X

  227. Mn-W oxide anodes prepared by thermal decomposition for oxygen evolution in seawater electrolysis Peer-reviewed

    K. Izumiya, E. Akiyama, H. Habazaki, N. Kumagai, A. Kawashima, K. Hashimoto

    Materials Transactions, JIM 39 (2) 308-313 1998/02

    DOI: 10.2320/matertrans1989.39.308  

    ISSN: 0916-1821

  228. Passivity and its breakdown on sputter-deposited amorphous Mn-Zr alloys in neutral chloride solutions Peer-reviewed

    A. A. El-Moneim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (2-3) 235-250 1998/02

    DOI: 10.1016/S0010-938X(97)00123-6  

    ISSN: 0010-938X

  229. Electrochemistry and corrosion engineering of global CO2 recycling Peer-reviewed

    K Hashimoto, K Izumiya, K Fujimura, M Yamasaki, E Akiyama, H Habazaki, A Kawashima, M Komori, K Shimamura, N Kumagai

    PROCEEDINGS OF CORROSION 98 - RESEARCH TOPICAL SYMPOSIUM ON CORROSION IN ADVANCED MATERIALS AND SYSTEMS 1-14 1998

  230. XPS study of transformation of air-formed film to passive film on sputter-deposited Mo-Nb alloys in 12 M HCl

    D Huerta, PY Park, E Akiyama, H Habazaki, A Kawashima, K Asami, K Hashimoto

    PROCEEDINGS OF THE SYMPOSIUM ON PASSIVITY AND ITS BREAKDOWN 97 (26) 770-780 1998

  231. Spontaneously passivated sputter-deposited alloys with richer corrosion resistance than alloy components Peer-reviewed

    K Hashimoto, J Bhattarai, XY Li, PY Park, JH Kim, E Akiyama, H Habazaki, A Kawashima, K Asami, K Shimamura

    PROCEEDINGS OF THE SYMPOSIUM ON PASSIVITY AND ITS BREAKDOWN 97 (26) 369-383 1998

  232. Change in pitting susceptibility with alloy heterogeneity induced by crystallization of amorphous alloys Peer-reviewed

    M. Mehmood, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science Forum 289-292 (PART 2) 629-640 1998

    DOI: 10.4028/www.scientific.net/msf.289-292.629  

    ISSN: 0255-5476

    eISSN: 1662-9752

  233. Characterization of CO<inf>2</inf> methanation catalysts prepared from amorphous Ni-Zr and Ni-Zr-rare earth element alloys Peer-reviewed

    M. Yamasaki, H. Habazaki, T. Yoshida, M. Komori, K. Shimamura, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Studies in Surface Science and Catalysis 114 451-454 1998

    DOI: 10.1016/s0167-2991(98)80793-3  

    ISSN: 0167-2991

  234. Methanation of carbon dioxide on catalysts derived from amorphous Ni-Zr-rare earth element alloys Peer-reviewed

    H. Habazaki, T. Yoshida, M. Yamasaki, M. Komori, K. Shimamura, E. Akiyama, A. Kawashima, K. Hashimoto

    Studies in Surface Science and Catalysis 114 261-266 1998

    DOI: 10.1016/s0167-2991(98)80754-4  

    ISSN: 0167-2991

  235. Experimental evidence for the critical size of heterogeneity areas for pitting corrosion of Cr-Zr alloys in 6 M HCl Peer-reviewed

    M. Mehmood, B. P. Zhang, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (1) 1-17 1998/01

    DOI: 10.1016/S0010-938X(97)00107-8  

    ISSN: 0010-938X

  236. Electrochemical and XPS studies of the corrosion behavior of sputter-deposited W-Nb alloys in concentrated hydrochloric acid solutions Peer-reviewed

    J. Bhattarai, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 40 (1) 19-42 1998/01

    DOI: 10.1016/S0010-938X(97)00108-X  

    ISSN: 0010-938X

  237. Compositional dependence of the CO<inf>2</inf> methanation activity of Ni/ZrO<inf>2</inf> catalysts prepared from amorphous Ni-Zr alloy precursors Peer-reviewed

    Michiaki Yamasaki, Hiroki Habazaki, Takeshi Yoshida, Eiji Akiyama, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto, Mitsuru Komori, Kazuo Shimamura

    Applied Catalysis A: General 163 (1-2) 187-197 1997/12/05

    DOI: 10.1016/S0926-860X(97)00142-7  

    ISSN: 0926-860X

  238. Effects of additional elements on electrocatalytic properties of thermally decomposed manganese Oxide electrodes for oxygen evolution from seawater Peer-reviewed

    K. Izumiya, E. Akiyama, H. Habazaki, N. Kumagai, A. Kawashima, K. Hashimoto

    Materials Transactions, JIM 38 (10) 899-905 1997/10

    DOI: 10.2320/matertrans1989.38.899  

    ISSN: 0916-1821

  239. An angle-resolved XPS study of the in-depth structure of passivated amorphous aluminum alloys Peer-reviewed

    E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (8) 1351-1364 1997/08

    DOI: 10.1016/S0010-938X(97)00034-6  

    ISSN: 0010-938X

  240. An XPS study of passive films on corrosion-resistant Cr-Zr alloys prepared by sputter deposition Peer-reviewed

    X. Y. Li, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (8) 1365-1380 1997/08

    DOI: 10.1016/S0010-938X(97)00035-8  

    ISSN: 0010-938X

  241. Application of sputter deposition technique to the preparation of amorphous alloy-derived catalysts for NO decomposition Peer-reviewed

    Kota Funayama, Hiroki Habazaki, Eiji Akiyama, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto, Mitsuru Komori

    Materials Transactions, JIM 38 (7) 643-649 1997/07

    DOI: 10.2320/matertrans1989.38.643  

    ISSN: 0916-1821

  242. Characterization of sputter-deposited Ni-Mo and Ni-W alloy electrocatalysts for hydrogen evolution in alkaline solution Peer-reviewed

    Asahi Kawashima, Eiji Akiyama, Hiroki Habazaki, Koji Hashimoto

    Materials Science and Engineering A 226-228 905-909 1997/06/15

    DOI: 10.1016/s0921-5093(97)80095-0  

    ISSN: 0921-5093

  243. Corrosion-resistant amorphous aluminum alloys and structure of passive films Peer-reviewed

    E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science and Engineering A 226-228 920-924 1997/06/15

    DOI: 10.1016/s0921-5093(96)10819-4  

    ISSN: 0921-5093

  244. The sulfidation and oxidation behavior of sputter-deposited Cr-refractory metal alloys at high temperatures Peer-reviewed

    K. Ito, H. Habazaki, H. Mitsui, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto, S. Mrowec

    Materials Science and Engineering A 226-228 910-914 1997/06/15

    DOI: 10.1016/s0921-5093(96)10817-0  

    ISSN: 0921-5093

  245. Spontaneously passivated films on sputter-deposited Cr-Ti alloys in 6M HCl solution Peer-reviewed

    X. Y. Li, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (5) 935-948 1997/05

    DOI: 10.1016/S0010-938X(97)81159-6  

    ISSN: 0010-938X

  246. No decomposition catalysts prepared from amorphous Ni-Ta-Pd alloys Peer-reviewed

    M. Komori, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Applied Catalysis B: Environmental 11 (3-4) 243-255 1997/03/21

    DOI: 10.1016/S0926-3373(97)00049-0  

    ISSN: 0926-3373

  247. Energy balance of global CO<inf>2</inf> recycling and amounts of reduction of CO<inf>2</inf> emission Peer-reviewed

    K. Hashimoto, E. Akiyama, H. Habazaki, A. Kawashima, M. Komori, K. Shimamura, N. Kumagai

    Science Reports of the Rerearch Institutes Tohoku University Series A-Physics 43 (2) 153-160 1997/03

    ISSN: 0040-8808

  248. The effect of molybdenum on the stability of passive films formed on amorphous Fe-Cr-Mo-P-C alloys by potentiostatic polarization in deaerated 1 M HCl Peer-reviewed

    M. W. Tan, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (3) 589-603 1997/03

    DOI: 10.1016/S0010-938X(96)00148-5  

    ISSN: 0010-938X

  249. The role of phosphorus in enhancing corrosion resistance of amorphous alloys Peer-reviewed

    K. Hashimoto, B. P. Zhang, B. M. Im, H. J. Lee, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami

    Science Reports of the Rerearch Institutes Tohoku University Series A-Physics 43 (2) 145-151 1997/03

    ISSN: 0040-8808

  250. The corrosion behaviour of sputter-deposited amorphous Mn-Ti alloys in 0.5 M NaCl solutions Peer-reviewed

    A. A. El-Moneim, B. P. Zhang, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (2) 305-320 1997/02

    DOI: 10.1016/S0010-938X(96)00128-X  

    ISSN: 0010-938X

  251. Electrochemical and XPS studies of the corrosion behavior of sputter-deposited amorphous W-Zr alloys in 6 and 12 M HCl solutions Peer-reviewed

    J. Bhattarai, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (2) 355-375 1997/02

    DOI: 10.1016/S0010-938X(97)83351-3  

    ISSN: 0010-938X

  252. The roles of tantalum and phosphorus in the corrosion behavior of Ni-Ta-P alloys in 12 M HCl Peer-reviewed

    H. J. Lee, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (2) 321-332 1997/02

    DOI: 10.1016/S0010-938X(96)00129-1  

    ISSN: 0010-938X

  253. The microcomposite structure of catalysts prepared by oxidation of amorphous Ni-Ta-Pd alloys Peer-reviewed

    Bo Ping Zhang, Kota Funayama, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Materials Transactions, JIM 38 (2) 123-132 1997/02

    DOI: 10.2320/matertrans1989.38.123  

    ISSN: 0916-1821

  254. The corrosion behavior of Ni-Cr-Mo ternary alloys in hot concentrated sulfuric acids with active carbon (part 2) Peer-reviewed

    Katsuo Sugahara, Yoshio Takizawa, Eiji Akiyama, Koji Hashimoto

    Zairyo to Kankyo/ Corrosion Engineering 46 (11) 702-708 1997

    Publisher: Japan Society of Corrosion Engineering

    DOI: 10.3323/jcorr1991.46.702  

    ISSN: 0917-0480

  255. The Corrosion Behavior of Ni-Cr-Mo Ternary Alloys in Hot Concentrated Sulfuric Acids with Active Carbon (Part 1) Peer-reviewed

    Katsuo Sugahara, Yoshio Takizawa, Eiji Akiyama, Koji Hashimoto

    Zairyo to Kankyo/ Corrosion Engineering 46 (10) 643-650 1997

    Publisher: Japan Society of Corrosion Engineering

    DOI: 10.3323/jcorr1991.46.643  

    ISSN: 0917-0480

  256. Surface activation of manganese oxide electrode for oxygen evolution from seawater Peer-reviewed

    K. Izumiya, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto, N. Kumagai

    Journal of Applied Electrochemistry 27 (12) 1362-1368 1997

    DOI: 10.1023/A:1018421028624  

    ISSN: 0021-891X

  257. The corrosion behaviour of sputter-deposited amorphous Mn-Ta alloys in 0.5 M NaCl solution Peer-reviewed

    A. A. El-Moneim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 39 (10-11) 1965-1979 1997

    DOI: 10.1016/S0010-938X(97)00089-9  

    ISSN: 0010-938X

  258. The role of chromium and molybdenum in passivation of amorphous Fe-Cr-Mo-P-C alloys in de-aerated 1 M HCl Peer-reviewed

    M. W. Tan, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (12) 2137-2151 1996/12

    DOI: 10.1016/S0010-938X(96)00071-6  

    ISSN: 0010-938X

  259. The corrosion behavior of sputter-deposited Mo-Ti alloys in concentrated hydrochloric acid Peer-reviewed

    P. Y. Park, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (10) 1649-1667 1996/10

    DOI: 10.1016/S0010-938X(96)00041-8  

    ISSN: 0010-938X

  260. The corrosion behavior of sputter-deposited Mo-Nb alloys in 12 M HCl solution Peer-reviewed

    P. Y. Park, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (10) 1731-1750 1996/10

    DOI: 10.1016/S0010-938X(96)00070-4  

    ISSN: 0010-938X

  261. Decomposition of nitrogen monoxide over NiTa<inf>2</inf>O<inf>6</inf>-supported palladium catalysts prepared from amorphous alloy precursors Peer-reviewed

    Mitsuru Komori, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Applied Catalysis B: Environmental 9 (1-4) 93-106 1996/09/02

    DOI: 10.1016/0926-3373(96)90075-2  

    ISSN: 0926-3373

  262. The influence of pre-immersion on the potentiostatic polarization behavior of amorphous Fe-Cr-Mo-P-C alloys in DE-aerated 1 M HCl Peer-reviewed

    M. W. Tan, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (9) 1495-1511 1996/09

    DOI: 10.1016/0010-938X(96)00040-6  

    ISSN: 0010-938X

  263. The effects of alloying elements on the passivity of sputter-deposited amorphous Al-Cr-Mo alloys in 1 M HCl Peer-reviewed

    E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (8) 1281-1294 1996/08

    DOI: 10.1016/0010-938X(96)00017-0  

    ISSN: 0010-938X

  264. The corrosion behavior of amorphous and crystalline Ni-10Ta-20P alloys in 12M HCl Peer-reviewed

    H. J. Lee, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (8) 1269-1279 1996/08

    DOI: 10.1016/0010-938X(96)00016-9  

    ISSN: 0010-938X

  265. A study of the structure of a passive film using angle-resolved x-ray photo-electron spectroscopy Peer-reviewed

    E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (7) 1127-1140 1996/07

    DOI: 10.1016/0010-938X(96)81813-0  

    ISSN: 0010-938X

  266. The corrosion behavior of sputter-deposited Mo-Ta alloys in 12 M HCl solution Peer-reviewed

    P. Y. Park, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (3) 397-411 1996/03

    DOI: 10.1016/0010-938X(96)00134-5  

    ISSN: 0010-938X

  267. The effect of phosphorus addition on the corrosion behavior of arc-melted Ni-10Ta-P alloys in 12 M HCl Peer-reviewed

    H. J. Lee, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (3) 469-485 1996/03

    DOI: 10.1016/0010-938X(96)00144-8  

    ISSN: 0010-938X

  268. Recent progress in corrosion-resistant new alloys prepared by sputter deposition Peer-reviewed

    K. Hashimoto, H. Habazaki, E. Akiyama, H. Yoshioka, J. H. Kim, P. Y. Park, A. Kawashima, K. Asami

    Science Reports of the Rerearch Institutes Tohoku University Series A-Physics 42 (1) 99-105 1996/03

    ISSN: 0040-8808

  269. The corrosion behavior of sputter-deposited amorphous Al-Cr-Mo alloys in 1 M HCl Peer-reviewed

    E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (2) 279-292 1996/02

    DOI: 10.1016/0010-938X(96)00119-9  

    ISSN: 0010-938X

  270. The influences of Mo addition and air exposure on the corrosion behavior of amorphous Fe-8Cr-13P-7C alloy in de-aerated 1 M HCl Peer-reviewed

    M. W. Tan, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 38 (2) 349-365 1996/02

    DOI: 10.1016/0010-938X(96)00133-3  

    ISSN: 0010-938X

  271. Global CO<inf>2</inf> recycling

    Koji Hashimto, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Kazuo Shimamura, Mitsuru Komori, Xaokazu Kumagai

    Zairyo to Kankyo/ Corrosion Engineering 45 (10) 614-620 1996

    DOI: 10.3323/jcorr1991.45.614  

    ISSN: 0917-0480

  272. Total Synthesis and Absolute Configuration of (-)-Sedacryptine Peer-reviewed

    Eiji Akiyama, Masahiro Hirama

    Synlett 1996 (1) 100-102 1996

    DOI: 10.1055/s-1996-5335  

    ISSN: 0936-5214

  273. XPS study of Ni-Mo-B amorphous ultra-fine particles prepared by chemical reduction Peer-reviewed

    Junji Saida, Eiji Akiyama, Koji Hashimoto, Akihisa Inoue, Tsuyoshi Masumoto

    Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals 60 (1) 79-83 1996

    DOI: 10.2320/jinstmet1952.60.1_79  

    ISSN: 0021-4876

    eISSN: 1880-6880

  274. High temperature sulfidation and oxidation behavior of sputter-deposited al-refractory metal alloys Peer-reviewed

    H. Mitsui, H. Habazaki, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto, S. Mrowec

    Materials Transactions, JIM 37 (3) 379-382 1996

    DOI: 10.2320/matertrans1989.37.379  

    ISSN: 0916-1821

  275. The corrosion behavior of Ni-Ta-5P alloys in concentrated hydrochloric acid Peer-reviewed

    Ho Jin Lee, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Materials Transactions, JIM 37 (3) 383-388 1996

    DOI: 10.2320/matertrans1989.37.383  

    ISSN: 0916-1821

  276. The corrosion behavior of sputter-deposited amorphous WTi alloys in 6 M HCl solution Peer-reviewed

    J. Bhattarai, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (12) 2071-2086 1995/12

    DOI: 10.1016/0010-938X(95)00120-9  

    ISSN: 0010-938X

  277. The corrosion behavior of sputter-deposited Cr-Mo alloys in 12 M HCl solution Peer-reviewed

    P. Y. Park, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (11) 1843-1860 1995/11

    DOI: 10.1016/0010-938X(95)00090-7  

    ISSN: 0010-938X

  278. Effect of cathodic reduction on catalytic activity of amorphous alloy electrodes for electrooxidation of sulfite Peer-reviewed

    T. Mori, A. Kawashima, E. Akiyama, H. Habazaki, K. Asami, K. Hashimoto

    Journal of Applied Electrochemistry 25 (10) 953-961 1995/10

    DOI: 10.1007/BF00241590  

    ISSN: 0021-891X

    eISSN: 1572-8838

  279. The effect of microcrystallites in the amorphous matrix on the corrosion behavior of amorphous Fe-8Cr-P alloys Peer-reviewed

    B. M. Im, M. Komori, B. T. Lee, E. Aoyagi, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hiraga, K. Hashimoto

    Corrosion Science 37 (9) 1411-1422 1995/09

    DOI: 10.1016/0010-938X(95)00048-O  

    ISSN: 0010-938X

  280. The effect of air exposure on the corrosion behavior of amorphous Fe-8Cr-Mo-13P-7C alloys in 1 M HCl Peer-reviewed

    M. W. Tan, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (8) 1289-1301 1995/08

    DOI: 10.1016/0010-938X(95)00035-I  

    ISSN: 0010-938X

  281. The effect of phosphorus on the passivation behavior of Ni-10Ta-P alloys in 12 M HCl Peer-reviewed

    H. J. Lee, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (8) 1313-1324 1995/08

    DOI: 10.1016/0010-938X(95)00049-P  

    ISSN: 0010-938X

  282. Recent progress in corrosion-resistant metastable alloys Peer-reviewed

    Koji Hashimoto, Pyeong Yeol Park, Jin Han Kim, Hideaki Yoshioka, Hiroyuki Mitsui, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Zbigniew Grzesik, Stanislaw Mrowec

    Materials Science and Engineering A 198 (1-2) 1-10 1995/07/15

    DOI: 10.1016/0921-5093(95)80052-V  

    ISSN: 0921-5093

  283. The effect of phosphorus addition on the corrosion behavior of amorphous Fe-8Cr-P alloys in 9M H<inf>2</inf>SO<inf>4</inf> Peer-reviewed

    B. M. Im, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (5) 709-722 1995/05

    DOI: 10.1016/0010-938X(95)80004-2  

    ISSN: 0010-938X

  284. AMORPHOUS ALLOY ELECTRODES FOR ELECTROOXIDATION OF PROPANE

    H KISHIMOTO, A KAWASHIMA, E AKIYAMA, K ASAMI, K HASHIMOTO

    SCIENCE REPORTS OF THE RESEARCH INSTITUTES TOHOKU UNIVERSITY SERIES A-PHYSICS CHEMISTRY AND METALLURGY 41 (1) 83-88 1995/03

    ISSN: 0040-8808

  285. Change in the surface composition of amorphous FeCrMoPC alloys during air exposure Peer-reviewed

    M. W. Tan, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (2) 331-341 1995/02

    DOI: 10.1016/0010-938X(94)00141-R  

    ISSN: 0010-938X

  286. The corrosion behavior of sputter-deposited amorphous Mo-Zr alloys in 12 M HCl Peer-reviewed

    P. Y. Park, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (2) 307-320 1995/02

    DOI: 10.1016/0010-938X(94)00139-W  

    ISSN: 0010-938X

  287. The effect of phosphorus addition on the corrosion behavior of amorphous Ni-30Ta-P alloys in 12 M HCl Peer-reviewed

    H. J. Lee, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 37 (2) 321-330 1995/02

    DOI: 10.1016/0010-938X(94)00140-2  

    ISSN: 0010-938X

  288. Corrosion behavior of sputter-deposited amorphous Al-Cr-Ti alloys in 1 M HCl Peer-reviewed

    E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science Forum 185-188 809-818 1995

    DOI: 10.4028/www.scientific.net/msf.185-188.809  

    ISSN: 0255-5476

  289. In-door atmospheric corrosion behavior of rapidly quenched amorphous Zr-Cu alloys Peer-reviewed

    K. Asami, E. Akiyama, Y. Murakami, H. M. Kimura, M. Kikuchi, K. Hashimoto

    Materials Science Forum 185-188 789-798 1995

    DOI: 10.4028/www.scientific.net/msf.185-188.789  

    ISSN: 0255-5476

  290. Similarity and difference in roles of chromium and molybdenum in passivating amorphous alloys in concentrated acids Peer-reviewed

    K. Hashimoto, P. Y. Park, J. H. Kim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami

    Materials Science Forum 185-188 779-788 1995

    DOI: 10.4028/www.scientific.net/msf.185-188.779  

    ISSN: 0255-5476

  291. The corrosion behavior of amorphous Fe-8Cr-13P-7C and Fe-8Cr-20P alloys in concentrated sulfuric acid Peer-reviewed

    B. M. Im, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 36 (9) 1537-& 1994/09

    DOI: 10.1016/0010-938X(94)90051-5  

    ISSN: 0010-938X

  292. The corrosion behavior of sputter-deposited amorphous Cr-Ni-Mo alloys in 12 M HCl Peer-reviewed

    P. Y. Park, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 36 (8) 1395-1410 1994/08

    DOI: 10.1016/0010-938X(94)90188-0  

    ISSN: 0010-938X

  293. The corrosion behaviour of sputter-deposited amorphous NiTi alloys in 1 M HCl Peer-reviewed

    Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Materials Science and Engineering A 181-182 (C) 1128-1132 1994/05/15

    DOI: 10.1016/0921-5093(94)90816-8  

    ISSN: 0921-5093

    eISSN: 1873-4936

  294. Amorphous alloy catalysts for decomposition of CCl<inf>2</inf>F<inf>2</inf> by hydrolysis Peer-reviewed

    K. Ebidzuka, H. Habazaki, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science and Engineering A 181-182 (C) 1091-1094 1994/05/15

    DOI: 10.1016/0921-5093(94)90808-7  

    ISSN: 0921-5093

    eISSN: 1873-4936

  295. Amorphous alloy electrodes for anodic oxidation of sulfite Peer-reviewed

    Toshiyuki Mori, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Materials Science and Engineering A 181-182 (C) 1081-1084 1994/05/15

    DOI: 10.1016/0921-5093(94)90806-0  

    ISSN: 0921-5093

    eISSN: 1873-4936

  296. Effect of phosphorus on the passivation behavior of amorphous Fe8Cr13P7C alloy in 9M H<inf>2</inf>SO<inf>4</inf> solution Peer-reviewed

    Byung Mo Im, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Materials Science and Engineering A 181-182 (C) 1119-1122 1994/05/15

    DOI: 10.1016/0921-5093(94)90814-1  

    ISSN: 0921-5093

    eISSN: 1873-4936

  297. Amorphous Fe-valve metal-Pt group metal alloy catalysts for methanation of CO<inf>2</inf> Peer-reviewed

    Toyoaki Tada, Hiroki Habazaki, Eiji Akiyama, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Materials Science and Engineering A 181-182 (C) 1133-1136 1994/05/15

    DOI: 10.1016/0921-5093(94)90817-6  

    ISSN: 0921-5093

    eISSN: 1873-4936

  298. Nitrogen monoxide decomposition catalysts prepared from amorphous Ni-valve metal-Pd alloys Peer-reviewed

    M. Komori, H. Habazaki, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science and Engineering A 181-182 (C) 1123-1127 1994/05/15

    DOI: 10.1016/0921-5093(94)90815-X  

    ISSN: 0921-5093

    eISSN: 1873-4936

  299. Highly corrosion-resistant amorphous CrNiP alloys Peer-reviewed

    B. P. Zhang, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Materials Science and Engineering A 181-182 (C) 1114-1118 1994/05/15

    DOI: 10.1016/0921-5093(94)90813-3  

    ISSN: 0921-5093

    eISSN: 1873-4936

  300. An XPS study of the corrosion behavior of sputter-deposited amorphous Cr-Nb and Cr-Ta alloys in 12 M HCl solution Peer-reviewed

    J. H. Kim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 36 (3) 511-523 1994/03

    DOI: 10.1016/0010-938X(94)90040-X  

    ISSN: 0010-938X

  301. Preparation of Protective Multilayer SiO<inf>2</inf> and Al<inf>2</inf>O<inf>3</inf> Coatings on Austenitic Stainless Steel by Sol-Gel Method Peer-reviewed

    Asahi Kawashima, Ying Wang, Eiji Akiyama, Hiroki Habazaki, Katsuhiko Asami, Koji Hashimoto

    Zairyo-to-Kankyo 43 (11) 654-659 1994

    DOI: 10.3323/jcorr1991.43.654  

    ISSN: 0917-0480

    eISSN: 1881-9664

  302. The corrosion behavior of sputter-deposited amorphous CrNb and CrTa alloys in 12 M HCl solution Peer-reviewed

    J. H. Kim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 34 (12) 1947-1955 1993/12

    DOI: 10.1016/0010-938X(93)90052-I  

    ISSN: 0010-938X

  303. The corrosion behavior of sputter-deposited amorphous chromium-zirconium alloys in 6 M HCl solution Peer-reviewed

    J. H. Kim, E. Akiyama, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 34 (11) 1817-1827 1993/11

    DOI: 10.1016/0010-938X(93)90019-D  

    ISSN: 0010-938X

  304. Electrochemical and XPS studies of the effects of alloying elements on the corrosion behavior of amorphous FeCrMetalloid alloys in 9 M H<inf>2</inf>SO<inf>4</inf> Peer-reviewed

    Byung Mo Im, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Corrosion Science 34 (11) 1829-1839 1993/11

    DOI: 10.1016/0010-938X(93)90020-H  

    ISSN: 0010-938X

  305. The corrosion behavior of sputter-deposited amorphous titanium-chromium alloys in 1 M and 6 M HCl solutions Peer-reviewed

    J. H. Kim, E. Akiyama, H. Yoshioka, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 34 (6) 975-987 1993/06

    DOI: 10.1016/0010-938X(93)90074-Q  

    ISSN: 0010-938X

  306. Decomposition of Nitrogen Monoxide over Amorphous Co&ndash;65Zr Alloys Containing Platinum Group Elements Peer-reviewed

    M. Komori, H. Habazaki, E. Akiyama, A. Kawashima, K. Asami, K. Hashimoto

    Materials Transactions, JIM 34 (8) 725-731 1993

    DOI: 10.2320/matertrans1989.34.725  

    ISSN: 0916-1821

    eISSN: 2432-471X

  307. The effect of magnesium on the corrosion behavior of sputter-deposited amorphous AlMgTi ternary alloys in a neutral chloride solution Peer-reviewed

    E. Akiyama, H. Yoshioka, J. H. Kim, H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto

    Corrosion Science 34 (1) 27-40 1993/01

    DOI: 10.1016/0010-938X(93)90256-G  

    ISSN: 0010-938X

  308. Corrosion-resistant amorphous surface alloys Peer-reviewed

    K. Hashimoto, N. Kumagai, H. Yoshioka, J. H. Kim, E. Akiyama, H. Habazaki, S. Mrowec, A. Kawashima, K. Asami

    Corrosion Science 35 (1-4) 363-370 1993

    DOI: 10.1016/0010-938X(93)90168-G  

    ISSN: 0010-938X

  309. Preparation of Protective Alumina Coating on Austenitic Stainless Steel by Sol-Gel Method Peer-reviewed

    Ying Wang, Eiji Akiyama, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami, Koji Hashimoto

    Zairyo-to-Kankyo 42 (3) 158-165 1993

    DOI: 10.3323/jcorr1991.42.158  

    ISSN: 0917-0480

    eISSN: 1881-9664

Show all ︎Show first 5

Misc. 58

  1. The Importance of Learning the Rule of Sumb of Metals Invited Peer-reviewed

    Eiji Akiyama

    Zairyo-to-Kankyo 71 (12) 340-345 2022/12

  2. Fundamental Technologies for Hydrogen Embrittlement Assessment of Steel Materials Invited Peer-reviewed

    Eiji Akiyama

    47 (4) 257-267 2022/04

  3. Evaluation and Analytical Method for Hydrogen Embrittlement Invited Peer-reviewed

    Eiji AKIYAMA

    Journal of the Society of Materials Science, Japan 71 (3) 327-334 2022/03/15

    Publisher: Society of Materials Science, Japan

    DOI: 10.2472/jsms.71.327  

    ISSN: 0514-5163

    eISSN: 1880-7488

  4. Carbon Dioxide Recycling by Methanation: For Global Sustainable Development by Renewable Energy. Invited Peer-reviewed

    橋本功二, 熊谷直和, 泉屋宏一, 高野裕之, 四宮博之, 幅崎浩樹, 秋山英二

    触媒 64 (3) 140-147 2022

    ISSN: 0559-8958

  5. Corrosion Monitoring of Carbon Steels under Humid Air Environment with Ozone Simulating Irradiation Invited Peer-reviewed

    Eiji Akiyama, Atsushi Omori, Saya Ajito, Tomohiko Hojo, Motomichi Koyama

    Zairyo-to-Kankyo 70 (12) 448-456 2021/12

  6. Database for corrosion under irradiation conditions (Contract research) Peer-reviewed

    Sato, Tomonori, Hata, Kuniki, Kaji, Yoshiyuki, Ueno, Fumiyoshi, Inoue, Hiroyuki, Taguchi, Mitsumasa, Seito, Hajime, Tada, Eiji, Abe, Hiroshi, Akiyama, Eiji, Suzuki, Shunichi

    JAEA-Review 2021-001 2021/06

    DOI: 10.11484/jaea-review-2021-001  

  7. A Novel Hydrogen Visualization Technique with a Metal Complex Invited Peer-reviewed

    Saya Ajito, Kenichi Fujita, Eiji Akiyama

    CERAMICS JAPAN 56 84-87 2021/02

  8. Review of Hydrogen Embrittlement in Metals: Hydrogen Diffusion, Hydrogen Characterization, Hydrogen Embrittlement Mechanism and Prevention Peer-reviewed

    Xinfeng Li, Xianfeng Ma, Jin Zhang, Eiji Akiyama, Yanfei Wang, Xiaolong Song

    Acta Metallurgica Sinica (English Letters) 33 (6) 759-773 2020/06/01

    Publisher: Springer Science and Business Media LLC

    DOI: 10.1007/s40195-020-01039-7  

    ISSN: 1006-7191

    eISSN: 2194-1289

  9. Prospective Research of Fundamental Factors and Characteristic Evaluations of Hydrogen Embrittlement Invited Peer-reviewed

    Kenichi Takai, Takehide Senuma, Eiji Akiyama

    Bull. Iron Steel Inst. Jpn 25 (3) 162-169 2020/03

  10. U曲げ加工した自動車用高強度鋼板の遅れ破壊挙動

    北條智彦, 西村文仁, 衣笠潤一郎, 湯瀬文雄, 秋山英二

    日本機械学会東北支部総会・講演会講演論文集(Web) 54th 2019

    ISSN: 2424-2713

  11. Corrosion Acceleration of Iron in Mortar by Combination of Electrochemical Passive Film Breakdown and Pressurized Oxygen Gas Supply

    18 1-6 2018/10

    Publisher: 日本材料学会

    ISSN: 2434-7396

  12. Erratum: EFfect of strain rate on the hydrogen embrittlement property of ultra high-strength low alloy trip-aided steel (ISIJ International (2018) 58:4 (751-759) DOI: 10.2355/isijinternational.ISIJINT-2017-576)

    Tomohiko Hojo, Riko Kikuchi, Hiroyuki Waki, Fumihito Nishimura, Yuko Ukai, Eiji Akiyama

    ISIJ International 58 (9) 1748-1749 2018/09/15

    DOI: 10.2355/isijinternational.58.1748  

    ISSN: 0915-1559

  13. 高酸素腐食促進試験における供給酸素圧とモルタル埋設鉄の腐食の関係

    土井康太郎, 廣本祥子, 秋山英二

    日本金属学会講演概要(CD-ROM) 161st ROMBUNNO.84 2017/08/23

    ISSN: 1342-5730

  14. 高酸素腐食促進試験によるモルタル中鉄さびの加速生成

    土井康太郎, 廣本祥子, 秋山英二

    日本金属学会講演概要(CD-ROM) 160th ROMBUNNO.402 2017/03/01

    ISSN: 1342-5730

  15. Hydrogen Embrittlement of Metallic Materials and Recent Subjects

    Eiji Akiyama

    Materia Japan 56 (3) 230-233 2017/03

    Publisher: 日本金属学会

    DOI: 10.2320/materia.56.230  

    ISSN: 1340-2625

  16. 超微細繊維状結晶粒組織を有する1800MPa級超高強度鋼の遅れ破壊特性

    木村勇次, 井上忠信, 秋山英二

    日本熱処理技術協会講演大会講演概要集 84th 2017

  17. Observation of hydrogen distribution in materials Peer-reviewed

    Eiji Akiyama

    Bulletin of The Iron and Steel Institute of Japan 21 (11) 630-638 2016/11/01

    Publisher: 日本鉄鋼協会

    ISSN: 1341-688X

  18. 腐食摩耗環境における高強度鋼への水素侵入挙動

    土井康太郎, 秋山英二, 秋山英二, 早川正夫

    日本ばね学会ばね及び復元力応用講演会講演論文集 2016 5‐6-6 2016/06/01

    More details Close

    自動車のサスペンション等の構造材料に用いられる高強度鋼は高強度ゆえに水素脆化に対する感受性が高い。本研究では、より水素が発生する環境として、磨耗腐食が生じる水溶液中の摺動環境を考え、この環境における高強度鋼への水素侵入を検討した。回転式磨耗試験機により溶液中で摩擦を加えた試料と、溶液に浸漬させただけの試料に侵入した水素量をTDS(昇温脱離分析)で計測し、その差を検討した結果、磨耗試験を行った試料には浸漬試験を行った試料よりも多量の水素が入ること、水素の侵入量は磨耗速度および磨耗時間の増加により増加することが明らかとなった。

  19. 塩化物水溶液中摺動環境における高強度鋼への水素侵入挙動

    土井康太郎, 秋山英二, 早川正夫

    日本金属学会講演概要(CD-ROM) 157th ROMBUNNO.192 2015/09/02

    ISSN: 1342-5730

  20. 温間テンプフォームで作製した超微細繊維状結晶粒鋼の遅れ破壊特性

    木村勇次, 井上忠信, 秋山英二, 津崎兼彰, 津崎兼彰

    日本熱処理技術協会講演大会講演概要集 77th 2014

  21. Fretting corrosion fatigue of biomaterials Peer-reviewed

    Eiji Akiyama, Norio Maruyama

    Zairyo to Kankyo/ Corrosion Engineering 63 (6) 378-382 2014

    Publisher: Japan Society of Corrosion Engineering

    DOI: 10.3323/jcorr.63.378  

    ISSN: 0917-0480

    eISSN: 1881-9664

  22. Fretting corrosion fatigue of biomaterials

    Eiji Akiyama, Norio Maruyama

    Corrosion Engineering 63 (6) 303-309 2014

    Publisher: Japan Society of Corrosion Engineering

    DOI: 10.3323/jcorr.63.378  

    ISSN: 1881-9664 0917-0480

  23. Hydrogen thermal desorption analysis for the studies of hydrogen embrittlement of high strength steels Peer-reviewed

    Eiji Akiyama

    Journal of the Vacuum Society of Japan 57 (6) 207-213 2014

    Publisher: Vacuum Society of Japan

    DOI: 10.3131/jvsj2.57.207  

    ISSN: 1882-2398

    eISSN: 1882-4749

  24. OS2102 Role of deformation twin on hydrogen embrittlement of TWIP steels

    Koyama Motomichi, Akiyama Eiji, Tsuzaki Kaneaki

    2013 "OS2102-1"-"OS2102-2" 2013/10/12

    Publisher: The Japan Society of Mechanical Engineers

  25. OS2106 Tensile deformation and crack propagation of Fe-Mn-C high strength austenitic steel under hydrogen charging

    Koyama Motomichi, Akiyama Eiji, Tsuzaki Kaneaki

    2013 "OS2106-1"-"OS2106-2" 2013/10/12

    Publisher: The Japan Society of Mechanical Engineers

  26. 1C3 Hydrogen embrittlement iii a Fe-18Mn-0.6C twinning-induced plasticity steel

    Koyama Motomichi, Akiyama Eiji, Tsuzaki Kaneaki

    2013 69-70 2013/09/28

    Publisher: The Japan Society of Mechanical Engineers

  27. Report of The JSCE Materials and Environments 2013

    FUJIHASHI Katsumi

    Summaries of technical papers of annual meeting 62 (9) 322-323 2013/09/15

    Publisher: Architectural Institute of Japan

    ISSN: 0917-0480

  28. 水素を経て使える燃料の形での再生可能エネルギーの利用

    熊谷直和, 橋本功二, 泉屋宏一, 高野裕之, 加藤善大, 幅崎浩樹, 秋山英二, 山崎倫昭

    Hits技報 74 (1) 33-41 2013/05

    Publisher: 日立造船事業・製品開発センター

    ISSN: 1882-0018

  29. Report of The JSCE Materials and Environments 2012

    62 (3) 95-96 2013/03/15

    ISSN: 0917-0480

  30. 高強度溶接金属の水素低温割れに及ぼす組織因子の影響

    末吉仁, 石川信行, 秋山英二, 木村勇次, 津崎兼彰, 川上和人

    材料とプロセス(CD-ROM) 25 (2) 2012

    ISSN: 1882-8922

  31. Delayed fracture of high strength steels under atmospheric corrosion Peer-reviewed

    Eiji Akiyama

    Corrosion Engineering 60 (4) 148-155 2011/04

    Publisher: Allergen Press, Inc.

    DOI: 10.3103/S0892422811040021  

  32. Delayed fracture of high strength steels under atmospheric corrosion

    Eiji Akiyama

    Zairyo to Kankyo/ Corrosion Engineering 60 (4) 184-189 2011

    DOI: 10.3323/jcorr.60.184  

    ISSN: 0917-0480

  33. 大気腐食環境下の水素侵入と遅れ破壊 Invited Peer-reviewed

    秋山英二

    Rust prevention & control 54 (12) 451-458 2010/12

    Publisher: 日本防錆技術協会

    ISSN: 0520-6340

  34. Future and future of materials science Invited

    Eiji Akiyama

    Zairyo to Kankyo/ Corrosion Engineering 59 (10) 359 2010/10

    DOI: 10.3323/jcorr.59.359  

    ISSN: 0917-0480

  35. 超高力ボルトの創製と機械的特性

    木村勇次, 秋山英二, 津崎兼彰

    鋼構造論文集 14 (54) 2007

    ISSN: 1880-9928

  36. 208th ECS Meeting

    AKIYAMA Eiji

    Zairyo-to-kankyo 55 (10) 441-443 2006/10/15

    Publisher: 腐食防食協会

    ISSN: 0917-0480

  37. The Effect of Relative Humidity on Delayed Fracture Behavior of High Strength Bolt Steels under Atmospheric Corrosion Condition

    MATSUKADO Katsuhiro

    18 (3) 558-558 2005/03/01

    ISSN: 0914-6628

  38. ECS Transactions: Preface

    S. Fujimoto, B. MacDougall, H. Habazaki, E. Akiyama

    ECS Transactions 1 (4) 2005

    ISSN: 1938-5862

    eISSN: 1938-6737

  39. Hydrogen Absorption Behavior of High Strength Bolt Steels under Atmospheric Corrosion

    MATSUKADO Katsuhiro

    CAMP-ISIJ 17 (6) 1349-1349 2004/09/01

    ISSN: 0914-6628

  40. Effect of Hydrogen Content on Fracture Stress for High Strength Steel

    WANG Maoqiu, AKIYAMA Eiji, TSUZAKI Kaneaki

    17 (6) 1354-1354 2004/09/01

    ISSN: 0914-6628

  41. Evaluation of the Hydrogen Absorption Property of High Strength Bolt Steels under Atmospheric Corrosion

    MATSUKADO Katsuhiro

    17 (3) 461-461 2004/03/01

    ISSN: 0914-6628

  42. Evaluation of the Delayed Fracture Property of High Strength Bolts under Atmospheric Corrosion : Establishment of Performance Evaluation Method for High Strength Bolts-1

    MATSUKADO Katsuhiro

    17 (3) 459-459 2004/03/01

    ISSN: 0914-6628

  43. Evaluation of the Absorbed Hydrogen of High Strength Bolts under Atmospheric Corrosion : Establishment of Performance Evaluation Method for High Strength Bolts-2

    MATSUKADO Katsuhiro

    17 (3) 460-460 2004/03/01

    ISSN: 0914-6628

  44. マックスプランク鉄鋼研究所に滞在して

    秋山 英二

    まてりあ : 日本金属学会会報 42 (12) 913-913 2003/12/20

    ISSN: 1340-2625

  45. Examination of Evaluation of Maximum Hydrogen Content in the Environment for High Strength Bolt Steel

    SAKASHITA Shinji

    15 (3) 576-576 2002/03/01

    ISSN: 0914-6628

  46. Evaluation of Absorbed Hydrogen Distribution in the High Strength Bolts Tightened to Various Strength by Exposed Test

    SAKASHITA Shinji

    14 (6) 1302-1302 2001/09/01

    ISSN: 0914-6628

  47. Evaluation of Absorbed Hydrogen Concentration in High Strength Bolt by CCT simulating Atmospheric Corrosion

    SAKASHITA Shinji

    CAMP-ISIJ 14 (6) 1303-1303 2001/09/01

    ISSN: 0914-6628

  48. Visualization of Hydrogen In Stress-Concentrated Region of SUS304 Stainless Steel by Using Ag Decoration Technique

    AKIYAMA Eiji

    14 (6) 1300-1300 2001/09/01

    ISSN: 0914-6628

  49. Tailoring Electrodes and Catalysts for CO_2 Recycling Plant

    HASHIMOTO Koji, MEGURO Shinsaku, SASAKI Teruhito, KATAGIRI Hiroshi, YAMASAKI Michiaki, IZUMIYA Koichi, KUMAGAI Naokazu, HABAZAKI Hiroki, KAWASHIMA Asahi, ASAMI Katsuhiko, AKIYAMA Eiji

    Materia Japan 40 (4) 372-375 2001/04/20

    Publisher: The Japan Institute of Metals and Materials

    DOI: 10.2320/materia.40.372  

    ISSN: 1340-2625

  50. Observation of Hydrogen Distribution in Steels by Means of Ag Decoration Technique/Atomic Force Michroscope

    AKIYAMA Eiji

    14 (3) 642-642 2001/03/01

    ISSN: 0914-6628

  51. Global Carbon Dioxide Recycling

    HASHIMOTO Koji, YAMAZAKI Michiaki, MEGURO Shinsaku, SASAKI Teruhito, KATAGIRI Hiroshi, KUMAGAI Naokazu, IZUMIYA Koichi, HABAZAKI Hiroki, AKIYAMA Eiji, KAWASHIMA Asahi, ASAMI Katsuhiko

    The Journal of the Surface Finishing Society of Japan 52 (2) 195-200 2001/02/01

    Publisher: 表面技術協会

    ISSN: 0915-1869

  52. 太陽エネルギーと海水電解を利用するグローバル二酸化炭素リサイクル

    橋本功二, 山崎倫昭, 泉屋宏一, 目黒眞作, 佐々木昭仁, 片桐洋, 秋山英二, 熊谷直和, 幅崎浩樹, 川嶋朝日, 浅見勝彦

    海洋開発ニュース 28 (6) 3-8 2000/03

  53. グローバル二酸化炭素リサイクル −地球温暖化防止と豊富なエネルギー供給のために−

    橋本功二, 山崎倫昭, 松井徹郎, 泉屋宏一, 目黒眞作, 佐々木昭仁, 片桐洋, 秋山英二, 熊谷直和, 幅崎浩樹, 川嶋朝日, 浅見勝彦

    エレクトロヒート 111 1-9 2000/01

  54. 海水電解とグローバル二酸化炭素リサイクル二酸化炭素リサイクル

    橋本功二, 山崎倫昭, 松井徹郎, 泉屋宏一, 目黒眞作, 佐々木昭仁, 片桐洋, 秋山英二, 幅崎浩樹, 川嶋朝日, 浅見勝彦, 熊谷直和

    水素エネルギーシステム 25 (1) 55-63 2000/01

  55. グローバル二酸化炭素リサイクル

    ソーダと塩素 50 (6) 224-232 1999/06

    Publisher: 日本ソ-ダ工業会

    ISSN: 0371-3768

    More details Close

    橋本功二, 山崎倫昭, 藤村和也, 松井徹郎, 泉屋宏一, 秋山英二, 幅崎浩樹, 川嶋朝日, 浅見勝彦, 熊谷直和

  56. オハイオ州立大学滞在記

    秋山 英二

    材料と環境 : zairyo-to-kankyo 47 (11) 706-707 1998/11/15

    ISSN: 0917-0480

  57. グロ-バルCO2リサイクル

    橋本 功二, 秋山 英二, 幅崎 浩樹

    月刊エコインダストリ- 2 (2) 5-14 1997/02

    Publisher: シ-エムシ-

    ISSN: 1342-3037

  58. Substantiation plant of global CO<inf>2</inf> recycling Peer-reviewed

    Koji Hashimoto, Hiroki Habazaki, Eiji Akiyama

    Zairyo/Journal of the Society of Materials Science, Japan 45 (9) 1067-1068 1996/09

    ISSN: 0514-5163

Show all ︎Show first 5

Books and Other Publications 4

  1. Hydrogenomics: The Science of Fully Utilizing Hydrogen

    2023/07/01

    ISBN: 4320952200

  2. ハイドロジェノミクス : “水素"を使いこなすためのサイエンス

    秋山, 英二, 味戸, 沙耶, 藤田, 健一

    共立出版 2022/01

    ISBN: 9784320044982

  3. 高力ボルトの遅れ破壊評価法ガイドライン JSS IV 10-2014, 日本鋼構造協会標準

    宇野暢芳, 秋山英二, 萩原行人, 原田宏明, 松岡和巳, 松山晋作

    日本鋼構造協会 2014/04

  4. JSSCテクニカルレポートNo.91 高力ボルトの遅れ破壊特性評価ガイドブック

    秋山英二, 宇野暢芳, 高橋稔彦, 萩原行人, 平井敬二, 松岡和巳, 松山晋作, 向井昭義

    日本鋼構造協会 2012/07

Presentations 41

  1. 高強度鋼の水素脆化に及ぼす水素、材料および応力因子の影響 Invited

    秋山英二

    日本鉄鋼協会第250回西山記念技術講座「環境劣化の腐食科学と防食技術の新展開」 2023/11/30

  2. 高強度鋼の水素脆化挙動の評価・解析 Invited

    秋山英二

    第12回エネルギー・マテリアル融合領域シンポジウム 次世代エネルギー材料開発のための先端解析技術 2023/11/13

  3. 高強度鋼の水素脆化に及ぼす水素、材料および応力因子の影響 Invited

    日本鉄鋼協会第249回西山記念技術講座「環境劣化の腐食科学と防食技術の新展開」 2023/11/02

  4. 高強度鋼の水素脆化評価と腐食誘起水素侵入 Invited

    秋山英二

    日本鉄鋼協会自動車用材料共同調査研究会 (特殊鋼 WG)2023年度第 2 回講演会「次世代エネルギー材料開発のための先端解析技術」 2023/10/18

  5. 環境破壊 Invited

    秋山英二

    日本材料学会第9回フラクトグラフィ講習会 2023/10/10

  6. 水素が金属の損傷に及ぼす効果とその評価・解析

    秋山英二

    金研講習会 2023/08/01

  7. 大気腐食による鉄鋼材料への水素侵入と水素脆化 Invited

    秋山英二

    日本金属学会「非鉄金属材料の水素侵入・水素脆化研究グループ」 2023/05/24

  8. Hydrogen embrittlement of high strength steels and corrosion-induced hydrogen entry Invited

    Eiji Akiyama

    2023/03/27

  9. 水素脆化

    秋山英二

    水素科学 GX オープンイノべーションセンター 第 1 回(キックオフ)水素科学ワークショップ 2023/02/10

  10. 金属構造材料中への水素侵入と損傷のプロセスの解明と評価 Invited

    秋山英二

    東北大学材料科学世界トップレベル研究拠点 産学連携フォーラム 2023

  11. Stress and hydrogen distribution analyses for elucidating hydrogen embrittlement

    Eiji Akiyama

    2022/11/21

  12. Elucidation and Evaluation of the Effects of Hydrogen on Strength of Steel Materials Invited

    Eiji Akiyama

    2022/11/14

  13. 鉄鋼材料と水素に関わる新たな研究展開 Invited

    日本MRS水素科学技術連携研究会 6月研究会 2022/06/23

  14. 金属材料中の水素の挙動と水素脆化 Invited

    秋山英二

    第141回金研講演会 2021/12/01

  15. 環境破壊 Invited

    秋山英二

    日本材料学会 第8回フラクトグラフィ講習会 2021/10/12

  16. 高強度鋼の水素脆化の克服に向けた特性の理解 Invited

    秋山英二

    第2回東北大学材料科学ウェビナー 2021/09/06

  17. 高強度鋼張出し試験片の水素脆化挙動と水素拡散 Invited

    秋山英二

    日本鉄鋼協会 「大気暴露中の腐食誘起水素侵入に対する理解に向けてⅢ~最終報告会~」シンポジウム 2021/09/03

  18. 水素脆化評価と水素侵入の解析・水素チャージ法の諸問題 Invited

    秋山英二

    日本鉄鋼協会「鋼材腐食水素侵入に関する評価技術の新展開」フォーラム 2021/08/04

  19. 水素脆化の基礎と評価・解析法および抑制技術への応用 Invited

    秋山英二

    日本テクノセンターオンラインセミナー 2021/03/10

  20. 張出し試験片の水素脆化によるき裂の発生と進展

    秋山英二

    日本鉄鋼協会材料の組織と特性部会 「鉄鋼材料への腐食誘起水素侵入」研究会 第5回研究会 2021/01/08

  21. Ir錯体による金属を透過した水素の可視化 Invited

    秋山英二

    第14 回 物性科学領域横断研究会(領域合同研究会) 2020/12/04

  22. 高強度鋼の水素脆化と評価方法 Invited

    秋山英二

    軽金属学会アルミニウム中の水素と材料物性研究部会第3回研究会 2020/06/04

  23. 水素脆性の基礎と評価・解析および脆化の抑制技術 Invited

    秋山英二

    日本テクノセンターセミナー 2020/03/10

  24. 放射環境下での腐食データベースの構築 (5)湿潤・乾燥環境でのガンマ線照射を模擬した腐食試験

    秋山英二, 大森惇志, 阿部博志, 端邦樹, 佐藤智徳, 加治芳行, 井上博之, 田口光正, 清藤一, 多田英司, 鈴木俊一

    第 66 回材料と環境討論会 2019/10/22

  25. Hydrogen Embrittlement of High Strength Steels Assisted by Corrosive Environment International-presentation Invited

    AKIYAMA Eiji

    International Ocean and Polar Engineering Conference, ISOPE-2019 2019/06/19

  26. 張出し試験片を用いた水素脆化特性評価

    秋山 英二, Patrick Knöchel, 北條 智彦

    日本鉄鋼協会春季大会「大気暴露中の腐食誘起水素侵入に対する理解に向けてII」シンポジウム 2019/03/21

  27. 高強度鋼の水素脆化に関する研究 Invited

    秋山 英二

    腐食防食学会東北支部講演会 2019/03/08

  28. Hydrogen embrittlement property of high strength under atmospheric corrosion environment International-presentation Invited

    AKIYAMA Eiji

    CORCON2018 2018/09/30

  29. 大気腐食環境下でのボルトの遅れ破壊 Invited

    秋山 英二

    材料学会腐食防食部門委員会例会 2018/05/21

  30. Hydrogen Embrittlement Characteristics of High Strength Steels in Atmospheric Corrosion Environment International-presentation Invited

    AKIYAMA Eiji

    International Conference on Materials Science and Engineering, Recent Advances and Challenges, ICMSE-RAC 2018/03/12

  31. Electrochemical hydrogen permeation tests to study hydrogen embrittlement Invited

    AKIYAMA Eiji, LI Songjie

    Joint HYDROGENIUS and I2CNER International Workshop on Hydrogen-Materials Interactions 2018 2018/02/02

  32. 高強度鋼への腐食による水素侵入と水素脆化 Invited

    秋山 英二

    第14回プラント材溶接部腐食合同研究委員会 2017/11/20

  33. 高強度鋼の水素脆化挙動とその評価 Invited

    日本金属学会第1分科 水素エネルギー材料に関する講演会 2017/11/16

  34. 本多記念講演 大気腐食による水素侵入と水素脆化 Invited

    日本金属学会/日本鉄鋼協会九州支部秋季講演会 2017/10/20

  35. 日本金属学会創立80周年記念シンポジウム 金属材料の水素脆化と今日の課題 Invited

    日本金属学会2017年秋期講演大会 2017/09/06

    More details Close

    発表 20170907

  36. 定電流、定電位水素チャージ条件下での水素透過試験

    秋山英二, 李松杰

    日本鉄鋼協会第173回春季講演大会 2017/03/15

    More details Close

    「大気腐食中の鋼材への水素侵入挙動の解明」フォーラム 「腐食中の鋼材への水素侵入3」シンポジウム 「腐食中の鋼材への水素侵入3」シンポジウム資料, p.6-9

  37. Electrochemical hydrogen permeation tests under conventional potentiostatic hydrogen charging conditions for hydrogen embrittlement study International-presentation

    E. Akiyama, S. Li

    PRiME2016 2016/10/02

  38. 高強度鋼の水素脆化プロセスと特性評価 Invited

    大阪大学工業会機械工学系技術交流会講演会 2016/07/29

    More details Close

    大阪大学大学院工学研究科機械工学専攻(吹田キャンパス)

  39. 高強度鋼の水素脆化 -鋼中水素の役割と大気腐食環境の影響- Invited

    学振 材料の微細組織と機能性第133委員会 第233 回研究会 2016/07/23

  40. 高強度鋼の水素脆化 -鋼中水素の役割と大気腐食環境の影響- Invited

    学振 産学協力研究委員会「材料中の水素機能解析技術第190委員会」第4回総会・講演会 2016/01/29

  41. 環境破壊 Invited

    秋山英二

    日本材料学会 第7回フラクトグラフィ講習会 2019/10/15

Show all Show first 5

Industrial Property Rights 15

  1. コンクリート中性化促進試験法およびこれに用いる試験装置

    土井 康太郎, 廣本 祥子, 秋山 英二, 片山 英樹, 土谷 浩一

    特許第6945854号

    Property Type: Patent

  2. 鉄筋腐食促進試験法およびこれに用いる試験装置

    土井 康太郎, 廣本 祥子, 秋山 英二, 片山 英樹, 土谷 浩一

    特許第6744629号

    Property Type: Patent

  3. 水素量測定装置

    各務比出秋, 中村正則, 津﨑兼彰, 秋山英二, 早川正夫, 原徹

    特許第5237644号

    Property Type: Patent

  4. 炭化水素改質ガス用アモルファス合金触媒とその用法

    橋本功二, 幅崎浩樹, 秋山英二, 張波萍, 吉田健, 山崎倫昭, 石井宏治, 河野駿平

    特許第3932494号

    Property Type: Patent

  5. 二酸化炭素のメタン化用アモルファス合金触媒

    橋本功二, 幅崎浩樹, 秋山英二, 吉田健, 小森充, 嶋村和郎

    特許第3819516号

    Property Type: Patent

  6. 二酸化炭素のメタン化用アモルファス合金触媒

    橋本功二, 幅崎浩樹, 秋山英二, 吉田健, 小森充, 嶋村和郎

    特許第3819486号

    Property Type: Patent

  7. 酸素発生用電極とその製造方法

    橋本功二, 泉屋宏一, 秋山英二, 幅崎浩樹, 川嶋朝日, 浅見勝彦

    特許第3724096号

    Property Type: Patent

  8. 酸素発生用電極

    橋本功二, 泉屋宏一, 秋山英二, 幅崎浩樹, 川嶋朝日, 浅見勝彦

    特許第3677856号

    Property Type: Patent

  9. 膜状センサ及び水素検出システム

    柿沼洋, 秋山英二, 味戸沙耶, 小山元道, 北條智彦

    Property Type: Patent

  10. 非ステンレス鋼材料、その製造方法およびその用途

    千葉 亜耶, 小山 元道, 秋山 英二, 西村 俊弥

    Property Type: Patent

  11. Steel for high strength bolts, contains carbon, silicon, manganese, molybdenum and/or tungsten, and iron, and has specified tensile strength

    KONDO Takaaki, YAMADA Yuuichi, MURAKAMI Youichi, KIMURA Yuuji, JP, AKIYAMA Eiji, JP, TSUZAKI Kaneaki

    Property Type: Patent

  12. 酸素発生用電極とその製造方法

    橋本功二, 泉屋宏一, 秋山英二, 川嶋朝日, 熊谷直和

    Property Type: Patent

  13. 塩素イオンを含有する水溶液を電解して酸素と水素を発生する電解方法および電解装置

    橋本功二, 泉屋宏一, 秋山英二, 川嶋朝日, 熊谷直和, 佐俣芳光

    特開平11-256383

    Property Type: Patent

  14. NOx分解用アモルファス合金触媒

    橋本功二, 小森充, 川嶋朝日, 浅見勝彦, 幅崎浩樹, 秋山英二

    Property Type: Patent

  15. 水素発生用陰極材料

    橋本功二, 林桂三, 秋山英二, 川嶋朝日, 浅見勝彦

    Property Type: Patent

Show all Show first 5

Research Projects 18

  1. Effect of stress on hydrogen trapping state and elucidation of hydrogen embrittlement

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)

    Category: Grant-in-Aid for Scientific Research (A)

    Institution: Tohoku University

    2019/04/01 - 2024/03/31

  2. 破壊に強い高強度鋼の先進的設計 - 粒界偏析制御におけるパラダイム転換

    古原 忠, 大谷 博司, 秋山 英二

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 基盤研究(A)

    Category: 基盤研究(A)

    Institution: 東北大学

    2020/04/01 - 2023/03/31

    More details Close

    (1)不純物偏析の粒界性格依存性の評価: 高純度Fe-P二元合金を、フェライト単相域の600℃においてPが平衡偏析に達するように長時間焼鈍した。個々の粒界の回転軸と回転角を電子線後方散乱回折法(EBSD)により測定し、面方位を集束イオンビーム(FIB)加工により作製した断面上のトレースから評価した上で、粒界性格を方位差の傾角成分とねじれ成分で評価した。三次元アトムプローブ(3DAP)の結果から、大角粒界におけるPの偏析量が比較的に高く、ねじれ成分よりも傾角成分のほうが偏析量に大きな影響を与えることがわかった。 (2)粒界を対象とした大規模なモデルを第一原理計算の精度で計算可能にする目的で、第一原理計算を高精度で再現する深層学習ポテンシャルの作成に取り組んだ。作成した深層学習ポテンシャルは第一原理計算結果を誤差0.03 eV/atom以内の精度で再現する結果が得られた。さらに10000原子以上の大規模なモデルにおける計算が可能であることも確認し、粒界中の局所構造の特徴を明らかにする計算手法を整えた。 (3)リンの粒界偏析量がそれぞれ2 at%,4 at%,6 at%であるFe-0.01P (mass%) を用いて浸漬試験を行い,リンの粒界偏析が鉄の腐食に及ぼす影響を調査した.合わせて腐食粒界の結晶方位差を測定することで以下の2つの結論を得た.(1) リンの偏析量が大きいほど腐食の開始確率が高まったが,腐食の進展速度には影響を与えなかった.(2) 小角粒界では腐食が生成しなかった.また,結晶方位差が大きくなるとともに腐食痕の数が増加していた.

  3. 高温・水素雰囲気照射法の開発によるフェライト鋼の中性子照射劣化への水素効果の解明

    外山 健, 秋山 英二, 波多野 雄治

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 基盤研究(B)

    Category: 基盤研究(B)

    Institution: 東北大学

    2020/04/01 - 2023/03/31

    More details Close

    第一に、中性子照射手法の開発を行った。ベルギーBR2を利用して高温・水素雰囲気照射を行うための照射キャプセルを試験するための照射試験チェンバーを作製した。試験チェンバーには電気ヒーター・熱電対・ガスフローシステムなどを設け、試験を精度よく実施可能な構造とした。 第二に、試料を準備した。鉄-クロム2元系合金やF82H等について、微小引張試験片(4×0.25×16 mm3)およびディスク試験片(φ6×0.2 mm3)等を作製した。これら の試料厚さは中性子照射中の水素拡散長よりも十分に小さくした。 第三に、上記試料のミクロ組織観察および昇温脱離分析を行った。ミクロ組織観察は、金研大洗センターに整備されている透過電子顕微鏡(対象:転位組織、クロムリッチ相、粒界偏析/欠乏、炭化物界面)、陽電子消滅測定(対象:空孔、空孔-水素複合体、空孔クラスター、クロムリッチ相)、3次元アトムプロープ(対象:クロムリッチ相、溶質クラスター、粒界偏析/欠乏、炭化物界面)を用いた。さらに、同じく金研大洗センターに整備されている昇温脱離分析装置で、水素蓄積量を定量評価した。その結果をミクロ組織観察の結果と直接比較した。 以上により、【ア】空孔クラスターの形成・成長の促進、【イ】溶質原子拡散の促進または抑制、【ウ】転位組織の形成・発達の促進、【エ】金属水素化物の形成、【オ】炭化物組織の回復の促進等について観察し、電子線照射組織の形成・発達に対する水素効果をそれぞれ調べた。

  4. HYDROGENOMICS: Creation of Innovative Materials, Devices, and Reaction Processes using Higher-Order Hydrogen Functions

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    Institution: Tokyo Institute of Technology

    2018/06/29 - 2023/03/31

  5. Improvement of hydrogen embrittlement resistance by thermomechanical processing in ultrahigh-strength TRIP-aided steels

    Hojo Tomohiko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)

    Category: Grant-in-Aid for Scientific Research (C)

    Institution: Tohoku University

    2018/04/01 - 2021/03/31

    More details Close

    Effects of thermomechanical processing on mechanical properties and hydrogen embrittlement resistance of the TRIP-aided steels were investigated. Mechanical properties and hydrogen embrittlement properties of TRIP-aided steels were improved by the thermomechanical processing. These might be caused by the microstructure refinement and improvement of retained austenite characteristics due to the combination of hot forging and heat treatment. The hot-forged TRIP-aided steels possessed excellent hydrogen embrittlement resistance in comparison with the conventional tempered martensitic steels. The excellent hydrogen embrittlement resistance of TRIP-aided steels was attributed to the refinement of microstructure because of the dynamic recrystallization during hot forging.

  6. Small-angle scattering for characterizing nano-scale heterogeneities of light elements in steels

    OHNUMA Masato, SUZUKI Jun-ichi, TSUZAKI Kaneaki, AKIYAMA Eiji, FURUSAKA Michihiro

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)

    Category: Grant-in-Aid for Scientific Research (A)

    Institution: National Institute for Materials Science

    2009 - 2011

    More details Close

    For suppressing hydrogen embrittlement, small-angle neutron scattering(SANS) measurements system has been optimized to get accurate and keep high reproducibility for relatively small samples for bolts. Furthermore, combined use of SANS and small-angle X-ray scattering(SAXS) has been established for getting compositional information of the embryo or clusters of carbide, oxide, nitride or other hetero-structure with light elements.

  7. Fretting fatigue behaviour of Ni-free high-nitrogen stainless steel in a simulated body fluid

    MARUYAMA Norio, HIROMOTO Sachiko, AKIYAMA Eiji, KATADA Yasuyuki, ITOH Shinji

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: National Institute for Materials Science

    2008 - 2011

    More details Close

    Fretting fatigue behavior was studied in air and in phosphate-buffered saline(PBS(-)) for Ni-free high-nitrogen steel(HNS) and for cold-rolled SUS316L steel(SUS316L(CR)). The plain fatigue limit of HNS was lower than that of SUS316L(CR). The fretting fatigue limit of HNS was much higher than that of SUS316L(CR) in both air and PBS(-). It was revealed that HNS has much better fretting fatigue properties than SUS316L(CR) in both the environments. The influence of fretting on fatigue limit was not solely explained by friction stress of the fretting, but also by wear behavior and/or plastic deformation in the fretting region.

  8. Effect of passive film on tribocorrosion

    AKIYAMA Eiji

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)

    Category: Grant-in-Aid for Scientific Research (C)

    Institution: National Institute for Materials Science

    2008 - 2010

    More details Close

    To clarify the influence of regeneration of passive film on the property of tribocorrosion, quick transient of repassivation current after mechanical breakdown of the surface of titanium was measured. It has been found that the growth of newly generated passive film is controlled by high field. Hydrogen embrittle property of high strength steels has been also investigated using a tensile test of samples corroded atmospherically, and it has been clarified that the evaluation method is simple, easy and appropriate.

  9. PREPARATION AND CHARACTERIZATION OF SURFACE CONTROLLED FUNCTIONAL MATERIALS USING NON-EQUILIBRIUM ALLOYS AS THEIR PRECURSORS

    ASAMI Katsuhiko, HABAZAKI Hiroki, KIKUCHI Michio

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)

    Category: Grant-in-Aid for Scientific Research (C)

    Institution: TOHOKU UNIVERSITY

    1997 - 1999

    More details Close

    1. Ni catalysts supported by zirconia, which have high activity for the reaction for methanation of carbon dioxide with hydrogen, were prepared from amorphous Ni-Zr alloys, and evaluated their activity in relation with alloy composition, reaction temperature. It was found that their activity was highest when they have prepared from Ni-Zr alloys containing Zr from 40 to 50at%Zr. The origin of the alloy composition dependence was explained by the alloy composition dependence of dispersion of metallic Ni on the catalyst surface, turnover number, and the relative concentration of tetragonal zirconia in the support. On the base of the above results, catalysts with higher activity were prepared by addition of a certain amount of Sm which caused stabilization of tetragonal phase of zirconia and increase of Ni dispersion on zirconia. 2. Non-equilibrium Nb-W and Nb-Mn alloys were prepared by sputtering method. They showed amorphous structure within the composition range of 20-50at%W and 26-75at%Mn, respectively. Their corrosion resistance and surface compositions were evaluated by electrochemical measurements and photoelectron spectroscopy. 3. Co-20at%Al alloy prepared by sputtering method was a non-equilibrium metallic compound with CsCl-type structure. When alloy films were prepared by reactive sputtering in NィイD22ィエD2 and OィイD22ィエD2 containing atmosphere, they showed ferromagnetic property with high performance even at high frequency region. It was clarified that they were composed of nano-particles of Co surrounded by insulating AlN and AlィイD22ィエD2OィイD23ィエD2, respectively. 4. Sr-Bi-Ta oxides prepared by sol-gel method followed by annealing at low temperatures showed no ferroelectric properties. But they become ferroelectric substance at high temperature annealing. Their performance was, however, dependent on annealing temperature and atmosphere during annealing. It was made clear that deviation of surface composition from stoichiometry and existence of metallic Bi were harmful to ferroelectric performance.

  10. Tailoring of new amorphous alloy catalysts for conservation of atmosphere

    HASHIMOTO Koji, AKIYAMA Eiji, HABAZAKI Hiroki, KAWASHIMA Asahi, ASAMI Katsuhiko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)

    Category: Grant-in-Aid for Scientific Research (A)

    Institution: TOHOKU UNIVERSITY

    1995 - 1998

    More details Close

    Since non-equilibrium alloys become a single phase supersaturated solid solution by additions of large amounts of various elements, tailoring of catalysts for conservation of environments by combination of elements necessary for high reactivity and selectivity was aimed. 1. Catalysts for decomposition of nitrogen oxides : For direct decomposition of nitrogen oxide to nitrogen and oxygen, Pd/NiTaO_6 catalyst formed from amorphous Ni-Ta-Pd alloys showed the most stable high reactivity in a wide temperature range up to 900゚C.When this was used as a catalyst for reduction of nitrogen monoxide by propane in oxygen containing atmosphere, a high conversion was observed at low temperatures such as 300゚C 2. Catalysts for decomposition of chlorofluorocarbon : Amorphous Ni-Zr alloys possess high reactivity and durability for hydrolytic decomposition of CFC-12 into CO_2, HC1 and HF.The durability increased remarkably by the addition of phosphorus. Active species formed from the alloys were ZrF2, (F,O)_<2,706> and Zr(F,O)_<3.80゚> 3. Catalysts for methanation of carbon dioxide : Amorphous Ni-Zr alloys have the highest activity and 100% selectivity for methane formation by the reaction of CO_2 with H_2 in comparison with conventional Ni-impregnated ZrO_2, crystalline Ni-Zr and precious metal catalysts. Because nickel supported on tetragonal ZrO_2, which is an essentially metastable phase and formed during the reaction, showed a selectively high activity and because the addition of rare earth elements stabilizes the tetragonal ZrO_2 phase, the most active catalysts were obtained from amorphous Ni-Zr-rare earth element alloys. 4. Hydrogen evolution cathodes for seawater electrolysis : Tailoring of highly active electrodes for production of hydrogen necessary for methanation of CO_2 was carried out by preparing amorphous alloys. Modification of the electronic structure of nickel by the addition of molybdenum resulted in the cathodes whose activities are competitive to that of platinum.

  11. 高耐食アルミニウム基アモルファス合金の創製と不働態皮膜の構造・腐食機構の研究

    秋山 英二

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 奨励研究(A)

    Category: 奨励研究(A)

    Institution: 東北大学

    1996 - 1996

    More details Close

    アモルファスAl-Cr-Mo合金、Al-Ti-Mg合金をDCマクネトロンスパッター装置を用いて作製し、これらの合金の腐食挙動および表面皮膜を調べた。Al-Cr合金は1M塩酸中で活性溶解するが,Moの添加によって自己不働態化し,耐食性の改善が見られた.また,Moの添加によって,孔食電位は著しく高く,あるいは,Crの過不働態域まで認められず,耐孔食性も著しく改善された.一方Al-Ti合金への少量のMgの添加は,耐孔食性の向上に有効であった。各合金試料の表面を角度分解光電子分光法を用いて分析した結果,これらの合金上に生成した不働態皮膜には,耐食金属元素であるCrあるいはTiの濃縮が見られ,これらが不働態皮膜の安定性を担うことが明らかとなった。これらの濃縮は,Al-CrおよびAl-Ti2元合金の場合には見られない。角度分解X線光電子分光法試料表面の見かけの組成の光電子取り出し角依存性を求め,深さ方向の組成の変化を,金属イオンの泳動と拡散を考慮した高濃度勾配のモデルを用いて検討し,不働態皮膜の構造を推定した.その結果,Al-Cr-Mo合金上の不働態皮膜の表面側にはCrが濃縮し,内部ではAlが濃縮していることがわかった。耐食性を担うCrの泳動の方がAlのそれより速いことが分かったが,この結果から,不働態皮膜の役割は,拡散障壁としてではなく,それ自身の溶解性の低さ,すなわち安定性によって下地合金を保護する事にあると推定された。一方Al-Ti-Mg合金上の不働態皮膜では,外方に向かってTi濃度は高くなるが,皮膜内部でもTi濃度は合金中の濃度よりも高かった。これはAlと比較してTiの泳動が遅いためと考えられた。さらに,角度分解分光測定結果から,皮膜直下の下地合金の構造の推定を行った。その結果,下地合金表面でCr, Tiが濃縮しており,深さ方向に向かって合金組成に近づく濃度勾配があることが分かった。これらの金属元素の濃縮は,Al-Cr-Mo合金の場合で約1nm,Al-Ti-Mg合金で0.3nm程度の比較的浅い範囲で見られることが明らかとなった。

  12. PRIMARY STUDY OF CREATION OF FINE METALLIC PARTICLES DISPERSED ON METAL OXIDES BY UTILIZING PROPERTIES OF NON-EQUILIBRIUM ALLOYS

    ASAMI Katsuhiro, AKIYAMA Eiji, KIKUCHI Michio, KAWASHIMA Asahi

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)

    Category: Grant-in-Aid for Scientific Research (A)

    Institution: TOHOKU UNIVERSITY

    1994 - 1996

    More details Close

    Oxidation behavior of non-equilibrium Cu-Zr, Cu-Ta and Ni-Zr alloys and catalytic properties of Co-Zr alloys for NO direct decomposition were examined in details. The initial surface ZrO_2 film formed on the rapidly quenched Cu-Zr alloy surface was very thin and protective, but it lost its protectiveness by reaction with moisture in atmosphere, resulting in oxidation of the alloy. The reaction with moisture developed a sandwich-structure of metallic copper layrs and ZrO_2 layrs. Two types of ZrO_2 oxide, tetragonal and monoclinic phases were formed ; the former transformes to the latter phase by reaction with the atmospheric moisture. Cu-Ta alloys prepared by sputter-deposition were colored to various colors by exposure to an air with relative humidities of 70% at 70゚C for 60 hours. The color depends on the alloy composition. The topmost surface of the colored specimens consisted of metallic copper, under which oxide layr containing Ta, and the coloration depends mostly on the protectiveness of the initial oxide film. A morphous Ni-33Zr alloy about 20mum thick showed complete preferential oxidation of Zr in air at high temperature. Nickel was oxidized after the complete Zr oxidation. The formed ZrO_2 was mainly tetragonal on high Ni alloys and monoclinic on low Ni alloys. Treatment of amorphous Co-Zr alloys containing small amount of Pt-group elements in HF solutions followed by oxidation formed fine particles of Pt-group metals dispersed and supported on oxides and showed high activity to the decomposition reaction of NO.On the other hand, binary Co-Zr alloys had no catalytic activity to the above reaction. Among the additive Pt-group metals, palladium was most effective, and Co-Zr-Pd alloys had almost the same high catalytic activity with that of Pd-black because of synergistic action of Co_3O_4, ZrO_2 and metallic Pd for the catalytic reaction. Amorphous Fe-Cr-P-C alloy powder of nanometer-size was also successfully formed.

  13. Tairoring Amorphous Surface Alloys Resistant against High Temperature Corrosion

    HASHIMOTO Koji, KUMAGAI Naokazu, YOSHIOKA Hideaki, HABAZAKI Hiroki, KAWASHIMA Asahi, ASAMI Katsuhiko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Developmental Scientific Research (B)

    Category: Grant-in-Aid for Developmental Scientific Research (B)

    Institution: Institute for Materials Research, Tohoku University

    1993 - 1995

    More details Close

    One of the objectives of this work is to tailor amorphous surface alloys on conventional metals by sputter deposition in order to protect the underlying conventional metals against sulfidation and oxidation at high temperatures. Tailoring active catalysis from amorphous alloy precursors for hydrolytic decomposition of cholorofluorocarbon is another aim of this work. We succeeded to prepare amorphous Al-Mo, Al-Nb and Al-Ta alloys with high resistance against both sulfidation and oxidation. In addition, the above-mentioned alloys with small additions of silicon have been obtained for further enhancement of oxidation resisitance. It is the first time on the history of corrosion science that the alloys with low sulfidation rates which are comparable to the oxidation rates of oxidation-resistant conventional alloys are obtained. Sulfide scales formed on these alloys consist of an outer aluminum sulfide layr and an inner refractory metal sulfide layr, the latter of which has high protectiveness against sulfidation. The amorphous alloys are converted to intermetallics at high temperatures where sulfidation and oxidation take place, but the formation of fine grained intermatallics is responsible for better adhesion of the alloys to the substrate metals. Silicone contained in the alloys form silicides with refractory elements in the alloys at high temperatures, and because the silicides are stable against oxidation, the presence of silicon suppresses oxidation of refractory elements. Amorphous surface alloys have been successfully prepared on 304 stainless steel and show high protectiveness against both sulfidation and oxidation at high temperatures. In the catalytic decomposition of a cholorofluorocarbon CCl_2F_2 by hydrolysis into CO_2, HCl and HF the catalyst should be exposed to very aggressive decomposition products. The active and durable catalysts have been obtained as a result of the catalystic reaction from amorphous Ni-Zr alloy precursors containing small amounts of chromium, molybdenum or tungsten.

  14. 高耐食アルミニウム基アモルファス合金の創製とその特性

    秋山 英二

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 奨励研究(A)

    Category: 奨励研究(A)

    Institution: 東北大学

    1994 - 1994

    More details Close

    当研究室では、スパッター法により作製したアルミニウム-クロムの合金はクロム濃度の増加に伴って腐食速度が低下するが、アルミニウムが優先酸化により皮膜に濃縮するために、クロムの含量が56at%より少ない場合には合金の自然電位はクロムの活性態に位置することを以前報告している。本年度の研究では、これを改善するためにチタンを添加した3元のアモルファスアルミニウム-クロム-チタン合金をスパッター法を用いて作製し、その1M塩酸中での腐食挙動を検討した。 スパッター法で作製したアルミニウム-クロム-チタン合金は広い組成範囲でアモルファス単相合金となった。アルミニウム-クロム合金に10at%以上のチタンを添加した合金の場合、腐食速度はアルミニウム-クロム合金に比べて約1桁低くチタンの添加が耐食性の改善に効果的であることを明らかにした。これらの合金の自然浸漬電位は時間とともに急激に上昇し、クロムの不働態域に至る。このことは、合金の腐食速度が低いという結果とよく一致している。また、光電子分光法によって表面組成の解析を行ったところ、アルミニウムが濃縮した初期の大気酸化被膜に比較して、電位の上昇に対応して皮膜中のクロムの濃度が上昇する事が観察された。アルミニウム-クロム二元合金の場合には、皮膜中にアルミニウムが濃縮するが、チタンを添加した耐食性に優れた合金の表面皮膜中にはアルミニウムの濃縮が抑制されており、これに伴って、皮膜中のクロムの濃度は合金中の濃度、あるいはそれ以上となっていた。クロム-チタン合金の濃塩酸中の分極測定により、チタンはクロムの活性態での溶解を抑制することが明らかとなっているが、このことから、アルミニウム-クロム-チタン合金の場合にもチタンがクロムの活性態での溶解を抑制し、自然電位の上昇を促すことが、耐食性の向上の原因と考えられる。

  15. HOT SULFIDATION-AND OXIDATION-RESISTANT NEW ALLOYS

    HASHIMOTO Koji, J-CZACHOR M., MROWEC S., AKIYAMA Eiji, KAWASHIMA Asahi, ASAMI Katsuhiko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for international Scientific Research

    Category: Grant-in-Aid for international Scientific Research

    Institution: TOHOKU UNIVERSITY

    1993 - 1994

    More details Close

    High temperature corrosion of sputter-deposited amorphous Al- (34-46) Mo and Al-31Mo- (6-16) Si alloys has been studies as a function of temperature in sulfur vapor, as well as in oxygen and air. The sulfidation process follows parabolic kinetics. The alloys showed excellent resistance to sulfide corrosion, their sulfidation rates being comparable with oxidation rates of chromia-forming materials. The oxidation resistance of binary Al-Mo alloys has been found to be satisfactory, but only at temperatures not exceeding 1073K.Above the melting point of MoO_3 (1069K), the scale, consisting mainly of Al_2O_3 with 5% MoO_3, becomes unprotectable because of evaporation of MoO_3. However, ternary Al-Mo-Si alloys show excellent resistance to oxidizing environment up to about 1200K,their oxidation rates being comparable with those of Al_2O_3 formers. This resulted from the fact that during heating of the ternary alloys, Mo_5Si_3 scale was formed instead of AlMo_3 formed. The beneficial effect of alloying with aluminum enhancing the sulfidation resistance of molybdenum has been studied as a function of aluminum content. The reaction rate of Mo-Al alloys with low aluminum contents is lower than that of pure molybdenum and decreases with increasing aluminum content. The lower sulfidation rate is explained in terms of the aluminum doping effect in the MoS_2 scale. Sputter-deposited Al-Nb alloys have excellent sulfidation resistance, their sulfidation rates being lower than that of niobium. Although their initial sulfidation rate is high due to the preferential sulfidation of aluminum, which leads to the enrichment of niobium at metal/scale interface, and consequently, the protective NbS_2 scale formed on the Al-Nb alloys. The resistance of these alloys to high temperature oxidation is higher than that of niobium. The oxide scale is composed of a double aluminum-niobium oxide and alumina, which lead to high oxidation resistance.

  16. IN-SITU CHARACTERIZATION OF SURFACES ON NEW ELECTRODE FOR FUEL CELLS AND ELECTROLYSIS

    HASHIMOTO Koji, AKIYAMA Eiji, HABAZAKI Hiroki, KAWASHIMA Asahi, ASAMI Katsuhiko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for General Scientific Research (A)

    Category: Grant-in-Aid for General Scientific Research (A)

    Institution: INSTITUTE FOR MATERIALS RESEARCH,TOHOKU UNIVERSITY

    1991 - 1994

    More details Close

    X-ray photoelectron spectroscopy is an effective method for nondestructive determination of valence and composition in the specimen surface. In-situ determination of the surface is particularly necessary for a better understanding of chemical species contributing to the reaction on the electrode surface exposed to relatively low oxidizing power. In-situ characterization in XPS is to determine the surface without oxidation of the surface species as a result of exposure to air before being exposed to high vacuum of the X-ray photoelectron spectrometer. In the present work an electrode in an electrolytic cell is rinsed with deaerated distillled water, transferred without air exposure into a globe box and is mounted on an air-tight transfer vessel for X-ray photoelectron spectrometer under nitrogen atmosphere in the globe box. Useful information has been obtained for the electrode surface without the detrimental effect of air oxidation. These include fuel cell electrodes for hydrogen, methane, ethane and propane as fuels, electrodes for evolution of hydrogen, chlorine and oxygen in electrolysis of seawater and electrodes for electrochemical oxidation of sulfite. In the study of amorphous alloy electrodes for fuel cells additions of platinum group elements and tin are effective in enhancing the electrocatalytic activity. The presence of a redox system of Sn^<2+>/Sn^<4+> which accelerates oxidation of fuels is confirmed. When the electrode is exposed to air after electrolysis, even platinum group elements are readily covered with oxides and hence the specification of the effective species for the electrode reactions is difficult. In fact platinum group elements directly act in the metallic state for oxidation of fuels and sulfite. These could not be obtained so far by ex-situ surface characterization.

  17. 耐高温酸化性と耐高温硫化性を兼ね備えたアモルファスアルミニウム合金の耐食機構

    幅崎 浩樹, 秋山 英二

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 一般研究(C)

    Category: 一般研究(C)

    Institution: 東北大学

    1993 - 1993

    More details Close

    耐高温硫化性と耐高温酸化性を兼ね備えた材料を見出すことを目的として,スパッター法によりアモルファスアルミニウム-高融点合金を作製し,その耐高温硫化性を10^3Paの硫黄蒸気中,耐高温酸化性を空気中で調べた。アモルファスAl-Mo合金の硫化は,放物線則に従い,その耐高温硫化性は金属モリブデンよりも高く,これまで知られている金属材料の中でも最も高いことがわかった。生成したスケールは二層からなり,外層はAl_2S_3,内層はMoS_2が主体であった。また,スケールは硫黄の内方拡散により成長することがマーカー試験により明らかになった。このアモルファスAl-Mo合金が高い耐高温硫化性を示す理由は,内層の主体であるMoS_2へのアルミニウムのドーピング効果によると考えられる。実際,モリブデンへ少量のアルミニウムを添加した場合,その添加量に応じて硫化速度が低下することからも,このことは支持された。 Al-Mo合金の高温酸化速度は,1123Kまでは,クロミアスケールを形成する合金に匹敵するが,それ以上の温度では,酸化モリブデンの蒸発のため,重量減少が起こり,耐酸化性は充分ではない。このAl-Mo合金にケイ素を添加すると,耐酸化性は1223Kまで典型的なアルミナスケールを形成する合金に匹敵するほどまで向上した。ただし,過剰のケイ素の添加は耐高温硫化性を低下させた。ケイ素の添加のより耐酸化性が向上するのは,Al-Mo二元合金の場合には,高温でAl_8Mo_3とAlMo_3が生成するのに対し,ケイ素を添加した合金ではモリブデンリッチの金属間化合物に代わって,シリコンリッチで,耐酸化性に優れたMo_5Si_3が生成することが最も大きな要因であり,これによりモリブデンの酸化が抑制されたと考えられる。Al-Nb合金は耐酸化性は低いものの,耐高温硫化性はニオブを上回ることがわかった。

  18. 高耐食アルミニウム-高融点金属系アモルファス合金の作製

    秋山 英二

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 奨励研究(A)

    Category: 奨励研究(A)

    Institution: 東北大学

    1993 - 1993

    More details Close

    アルミニウムと高融点のバルブメタル(タンタル、ニオブ、ジルコニウム、チタン)、およびタングステン、モリブデンとのアモルファス合金が耐食性に優れることを、当研究室で既に報告している。本研究では、さらに第三の元素を添加することによって更に耐食性を向上させることを目的とした。アルミニウム-チタン合金に種々の元素を添加したアモルファス合金をスパッター法を用いて作製し、その腐食挙動について検討した。 1.アモルファスアルミニウム-マグネシウム-チタン合金:活性元素であるマグネシウムを少量アモルファスアルミニウム-チタン合金に添加し、その腐食挙動を塩素イオンを含む中性溶液中で検討した。マグネシウム自身の優先的な溶解と、それに伴うアルミニウムの溶解の促進により皮膜中にチタンが濃縮することをXPS表面分析によって確かめた。また、チタンの濃縮した安定な皮膜の生成によって孔食電位は上昇した。 2.アモルファスアルミニウム-ニッケル-チタン合金:1M塩酸中での腐食挙動を検討した。アルミニウム-チタン合金は、1M塩酸中活性態-不働態遷移を示す。これらより貴な元素であるニッケルを添加すると、自然浸漬電位は著しく上昇し、1M塩酸中においても自己不働態化し、腐食速度は減少した。また、ニッケルの添加によって孔食電位は上昇した。 3.アモルファスアルミニウム-クロム-チタン合金:アモルファスアルミニウム-チタン合金は1M塩酸中アルミニウムと同程度の高い腐食速度を示すが、クロムを添加すると時間と共に自然浸漬電位が著しく上昇し、クロムの不働態に入って、腐食速度は低下した。また電位の上昇によって、皮膜中にクロムが濃縮した耐食性に優れた皮膜が生成することを確かめた。

Show all Show first 5

Media Coverage 22

  1. 助力材料设计更高效: 日本开发新型氢观测可视化技术 (より効率的な材料設計を可能に:日本、水素の新しい可視化技術を開発)

    中国宝武报 中国宝武报 第8903期:第04版

    2024/01/23

    Type: Internet

  2. Tohoku University’s Innovative Approach to Hydrogen Dynamics

    EnergyNews.biz H2 energy news Report

    2024/01/17

    Type: Internet

  3. Tohoku University's Institute for Materials Research develops new video imaging technology to observe the behavior of hydrogen in metals

    Japan Science and Technology Agency (JST) Science Japan Physics & Materials

    2024/01/17

    Type: Internet

  4. Filming the microscopic flow of hydrogen atoms in a metal.

    NewsRX LLC GALE ACADEMIC ONFILE

    2024/01/07

    Type: Internet

  5. Filming the microscopic flow of hydrogen atoms in a metal

    Newethic Publication Newethic Publication

    2024/01/03

    Type: Internet

  6. Visualizing hydrogen diffusion in real time

    John Wiley & Sons Wiley Analytical Science

    2023/12/28

    Type: Internet

  7. Фізики візуалізували рух атомів водню крізь метал (фото+відео) 物理学者が金属中の水素原子の動きを可視化(写真+動画)

    CIKAVOSTI CIKAVOSTI cikavosti.com

    2023/12/23

    Type: Internet

  8. Observing the Minute Movement of Hydrogen Atoms in a Metal through Filming

    Verve times

    2023/12/22

    Type: Internet

  9. 日本东北大学金属材料研究所开发出氢在金属中运动状态的可视化新技术

    国立研究開発法人科学技術振興機構(JST) 客観日本 化学材料

    2023/12/20

    Type: Internet

  10. Filming the microscopic flow of hydrogen atoms in a metal

    SWIFTTELECAST SWIFTTELECAST

    2023/12/20

    Type: Internet

  11. Filming the microscopic flow of hydrogen atoms in a metal

    Phys.org PHYS ORG Chemistry / Analytical Chemistry, Chemistry / Mterials Science

    2023/12/19

    Type: Internet

  12. Filming the Microscopic Flow of Hydrogen Atoms in a Metal.

    Asia Research News Asia Research News

    2023/12/19

    Type: Internet

  13. 金属中の水素原子の流れを可視化し、動画撮影できる新手法を開発

    TechEyesOnline TechEyesOnline 業界ニュース

    2023/12/19

    Type: Internet

  14. Filming the microscopic flow of hydrogen atoms in a metal

    Today Headline Today Headline science news & society

    2023/12/19

    Type: Internet

  15. Filming the microscopic flow of hydrogen atoms in a metal

    ScienceDaily ScienceDaily Science News

    2023/12/19

    Type: Internet

  16. 研究開発の最前線 金属中の水素原子の流れを可視化し、動画撮影できる新手法を開発

    アイティメディア株式会社 MONOist 素材/化学

    2023/12/19

    Type: Internet

  17. 金属中の水素の振る舞い 動画撮影の新技術開発 東北大金研

    科学新聞社 科学新聞

    2023/12/08

    Type: Newspaper, magazine

  18. 金属中の水素原子の振る舞い リアルタイムで広域に可視化 動的挙動・分布観察が可能 機能性材料開発へ応用期待

    化学工業日報 化学工業日報 https://chemicaldaily.com/archives/389917

    2023/12/04

    Type: Newspaper, magazine

  19. 水素の拡散経路可視化 金属にポリアニリン成膜 東北大

    日刊工業新聞社 日刊工業新聞

    2023/11/29

    Type: Newspaper, magazine

  20. 東北大、金属中の水素の流れを動画撮影する技術を開発

    日本経済新聞社 日経電子版 速報 プレスリリース

    2023/11/27

    Type: Internet

  21. 東北大、水素の拡散経路可視化 金属にポリアニリン成膜

    日刊工業新聞社 日刊工業新聞 電子版

    2023/11/19

    Type: Internet

  22. 「水素原子の流れ」を動画として撮影 東北大助教らが技術を世界初開発

    株式会社官庁通信社 文教速報デジタル版

    2003/11

    Type: Internet

Show all Show first 5