Details of the Researcher

PHOTO

Yoshinao Nakagawa
Section
Graduate School of Engineering
Job title
Associate Professor
Degree
  • 博士(工学)(東京大学)

  • 修士(工学)(東京大学)

Education 2

  • The University of Tokyo Graduate School, Division of Engineering Department of Applied Chemistry

    - 2005/03

  • The University of Tokyo Faculty of Engineering 応用化学科

    - 2000/03

Professional Memberships 3

  • 石油学会

  • 触媒学会

  • 日本化学会

Research Interests 2

  • Redox

  • Catalysis

Research Areas 2

  • Nanotechnology/Materials / Green/sustainable/environmental chemistry /

  • Nanotechnology/Materials / Functional solid-state chemistry /

Awards 3

  1. 第18回グリーン・サステイナブル ケミストリー賞奨励賞

    2019/06 公益社団法人新化学技術推進協会 未利用バイオマス資源を原料とするバイオ増炭+触媒脱酸素によるC4化成品合成

  2. 石油学会奨励賞

    2016/05/22 公益社団法人石油学会 バイオマス由来フラン化合物の水素化用複合金属触媒に関する研究

  3. 触媒学会奨励賞

    2014/03/26 一般社団法人触媒学会 C-O結合直接水素化分解用Re修飾Ir触媒の開発

Papers 248

  1. Selective hydrogenation of guaiacol to 2-methoxycyclohexanone over supported Pd catalysts Peer-reviewed

    Yota Taniwaki, Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    Green Chemistry 26 (20) 10486-10499 2024/09

    DOI: 10.1039/D4GC03793F  

  2. Acid–Base Bifunctional Catalysis of the Lewis Acidic Isolated Co(OH)2 and Basic N Anion Generated from CeO2 and 2-Cyanopyridine

    Masazumi Tamura, Miyu Haga, Anchalee Junkaew, Daiki Asada, Rise Ichikawa, Ryo Toyoshima, Akira Nakayama, Hiroshi Kondoh, Yoshinao Nakagawa, Keiichi Tomishige

    ACS Catalysis 2024/08/15

    DOI: 10.1021/acscatal.4c02378  

  3. Promoting role of Ru species on Ir-Fe/BN catalyst in 1,2-diols hydrogenolysis to secondary alcohols Peer-reviewed

    Ben Liu, Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    Chinese Journal of Catalysis 65 (10) 89-102 2024/08

    DOI: 10.1016/S1872-2067(24)60110-5  

  4. Recent progress on bimetallic catalysts for the production of fuels and chemicals from biomass and plastics by hydrodeoxygenation Invited Peer-reviewed

    Lujie Liu, Ben Liu, Yoshinao Nakagawa, Sibao Liu, Liang Wang, Mizuho Yabushita, Keiichi Tomishige

    Chinese Journal of Catalysis 62 (7) 1-31 2024/06

    DOI: 10.1016/S1872-2067(24)60054-9  

  5. Non-noble metal heterogeneous catalysts for hydrogen-driven deoxydehydration of vicinal diol compounds Invited Peer-reviewed

    Jianxing Gan, Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    Green Chemistry 26 (14) 8267-8281 2024/06

    DOI: 10.1039/D4GC02006E  

  6. Recent progress on catalyst development for ring-opening C-O hydrogenolysis of cyclic ethers in the production of biomass-derived chemicals Invited Peer-reviewed

    Keiichi Tomishige, Masayoshi Honda, Hiroshi Sugimoto, Lujie Liu, Mizuho Yabushita, Yoshinao Nakagawa

    Carbon Neutrality 3 17 2024/06

    DOI: 10.1007/s43979-024-00090-y  

  7. Hydrolysis of amide bonds in dipeptides and nylon 6 over ZrO2 catalyst Invited Peer-reviewed

    Satoshi Tomita, Mizuho Yabushita, Yoshinao Nakagawa, Keiichi Tomishige

    Catalysis Science & Technology 14 (14) 3898-3908 2024/05

    DOI: 10.1039/D4CY00533C  

  8. Highly Efficient Iridium-Iron-Molybdenum Catalysts Condensed on Boron Nitride for Biomass-Derived Diols’ Hydrogenolysis to Secondary Monoalcohols

    Ben Liu, Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    Journal of the American Chemical Society 146 (14) 9984-10000 2024/04/10

    DOI: 10.1021/jacs.4c00661  

    ISSN: 0002-7863

    eISSN: 1520-5126

  9. Direct Esterification of Alkylcarbamic Acids with Alcohols over CeO<inf>2</inf> Catalyst

    Shogen Mihara, Mizuho Yabushita, Yoshinao Nakagawa, Keiichi Tomishige

    ChemSusChem 17 (4) 2024/02/22

    DOI: 10.1002/cssc.202301436  

    ISSN: 1864-5631

    eISSN: 1864-564X

  10. Kinetic Modeling of Erythritol Deoxydehydration and Consecutive Hydrogenation over the ReOx-Pd/CeO2 Catalyst Peer-reviewed

    Ji Cao, Savitri Larasati, Mizuho Yabushita, Yoshinao Nakagawa, Johan Wärnå, Dmirtry Yu. Murzin, Daiki Asada, Akira Nakayama, Keiichi Tomishige

    ACS Catalysis 14 (3) 1663-1677 2024/01

    DOI: 10.1021/acscatal.3c04785  

  11. Overview of intentional formation of paired heteroatom sites in zeolite frameworks

    Mizuho Yabushita, Ryota Osuga, Yoshinao Nakagawa, Satoshi Suganuma, Kiyotaka Nakajima, Keiichi Tomishige

    CrystEngComm 2024

    Publisher: Royal Society of Chemistry (RSC)

    DOI: 10.1039/d4ce00505h  

    eISSN: 1466-8033

    More details Close

    Intentional placement of two heteroatoms in close proximity in zeolite frameworks is an important task for developing fine-tuned catalysts and ion exchangers and has been achieved via three different strategies.

  12. Formation of paired Ga sites in CHA-type zeolite frameworks via a transcription-induced method

    Takumi Kaneko, Mizuho Yabushita, Ryota Osuga, Yugo Sawada, Kei Sato, Ben Liu, Yoshinao Nakagawa, Kiyotaka Nakajima, Keiichi Tomishige

    Chemical Communications 2024

    Publisher: Royal Society of Chemistry (RSC)

    DOI: 10.1039/d4cc00186a  

    ISSN: 1359-7345

    eISSN: 1364-548X

    More details Close

    Paired Ga sites were firstly and intentionally constructed in CHA-type zeolite frameworks via the transcription of pre-formed paired species in Ga-rich amorphous silica–gallia.

  13. Oxidative Cleavage of C-C Bonds in Non-aromatic Oxygenates with Molecular Oxygen for Synthesis of Carboxylic Acids Invited Peer-reviewed

    Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    Asian Journal of Organic Chemistry Just accepted (11) e202300409 2023/09

    DOI: 10.1002/ajoc.202300409  

    ISSN: 2193-5807

  14. Synthesis of dimethyl carbonate from CO2 and methanol over CeO2 catalysts prepared by soft-template precipitation and hydrothermal method Invited Peer-reviewed

    Waleeporn Donphai, Orrakanya Phichairatanaphong, Ryotaro Fujii, Peilang Li, Tao Chang, Mizuho Yabushita, Yoshinao Nakagawa, Keiichi Tomishige

    Materials Today Sustainability Just accepted 2023/09

    DOI: 10.1016/j.mtsust.2023.100549  

    eISSN: 2589-2347

  15. Comparative Study between 2-Furonitrile and 2-Cyanopyridine as Dehydrants in Direct Synthesis of Dialkyl Carbonates from CO2 and Alcohols over Cerium Oxide Catalyst Peer-reviewed

    Wen Sun, Peilang Li, Mizuho Yabushita, Yoshinao Nakagawa, Yuqi Wang, Akira Nakayama, Keiichi Tomishige

    ChemSusChem 16 (24) e202300768 2023/08

    DOI: 10.1002/cssc.202300768  

    ISSN: 1864-5631

    eISSN: 1864-564X

  16. Selective synthesis of 1,3-butadiene by vapor-phase dehydration of 1,4-butanediol over cerium oxide catalyst Peer-reviewed

    Kairi Onodera, Yosuke Nakaji, Mizuho Yabushita, Yoshinao Nakagawa, Keiichi Tomishige

    Applied Catalysis A: General 663 119321 2023/08

    DOI: 10.1016/j.apcata.2023.119321  

    ISSN: 0926-860X

  17. Improvement of Stability of CeO2–Based Catalysts by Mn-Doping for the Synthesis of 2-Imidazolidinone from Ethylenediamine Carbamate Peer-reviewed

    R. Fujii, M. Yabushita, Y. Li, Y. Nakagawa, K. Tomishige

    ACS Catalysis 13 (16) 11041-11056 2023/07

    DOI: 10.1021/acscatal.3c02476  

  18. Mechanistic insights into CeO2-catalyzed direct synthesis of diethyl carbonate from CO2 and ethanol assisted by zeolite and 2,2-diethoxypropane Peer-reviewed

    Tao Chang, Mizuho Yabushita, Yoshinao Nakagawa, Norihisa Fukaya, Jun-Chul Choi, Takayoshi Mishima, Seiji Matsumoto, Satoshi Hamura, Keiichi Tomishige

    Catalysis Science & Technology Just accepted (17) 5084-5093 2023/07

    DOI: 10.1039/D3CY00661A  

    ISSN: 2044-4753

    eISSN: 2044-4761

  19. Oxygen-Saturated Strong Metal-Support Interactions Triggered by Water on Titania Supported Catalysts Peer-reviewed

    Hai Wang, Xue Dong, Yu Hui, Yiming Niu, Bingsen Zhang, Lujie Liu, Ji Cao, Mizuho Yabushita, Yoshinao Nakagawa, Keiichi Tomishige, Yucai Qin, Lijuan Song, Jianping Xiao, Liang Wang, Feng-Shou Xiao

    Advanced Functional Materials 2304303 (42) 2023/06

    DOI: 10.1002/adfm.202304303  

    ISSN: 1616-301X

    eISSN: 1616-3028

  20. Boron Nitride- and Carbon-Supported Iridium-Iron Catalysts for Synthesizing Mono-Alcohols from Biomass-Derived Vicinal Diols Peer-reviewed

    Ben Liu, Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    ACS Catalysis 13 (13) 8485-8502 2023/06

    DOI: 10.1021/acscatal.3c01440  

    eISSN: 2155-5435

  21. Perspective on catalytic production of olefinic compounds from biomass Invited Peer-reviewed

    Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    RSC Sustainability Just accepted (4) 814-837 2023/05

    DOI: 10.1039/D3SU00033H  

    eISSN: 2753-8125

  22. 2-Hydroxyadipic Acid Production by Oxidation of 2-Hydroxycyclohexanone with Molecular Oxygen Peer-reviewed

    Koki Hashimoto, Kosuke Hatakeyama, Mizuho Yabushita, Keiichi Tomishige, Yoshinao Nakagawa

    ChemCatChem Just accepted (10) 2023/03

    DOI: 10.1002/cctc.202300212  

    ISSN: 1867-3880

    eISSN: 1867-3899

  23. Continuous Flow Synthesis of 2-Imidazolidinone from Ethylenediamine Carbamate in Ethylenediamine Solvent over the CeO2 Catalyst: Insights into Catalysis and Deactivation

    Ryotaro Fujii, Mizuho Yabushita, Daiki Asada, Masazumi Tamura, Yoshinao Nakagawa, Atsushi Takahashi, Akira Nakayama, Keiichi Tomishige

    ACS Catalysis 13 (3) 1562-1573 2023/01/11

    Publisher: American Chemical Society (ACS)

    DOI: 10.1021/acscatal.2c05721  

    ISSN: 2155-5435

    eISSN: 2155-5435

  24. Density Functional Theory Study of Deoxydehydration Reaction by TiO2-Supported Monomeric and Dimeric Molybdenum Oxide Catalysts

    Daiki Asada, Tatsushi Ikeda, Koki Muraoka, Yoshinao Nakagawa, Keiichi Tomishige, Akira Nakayama

    The Journal of Physical Chemistry C 126 (48) 20375-20387 2022/12/08

    DOI: 10.1021/acs.jpcc.2c06018  

    ISSN: 1932-7447

    eISSN: 1932-7455

  25. Selective C–O Hydrogenolysis of Terminal C–OH Bond in 1,2-Diols over Rutile-Titania-Supported Iridium-Iron Catalysts Peer-reviewed

    Ben Liu, Yoshinao Nakagawa, Congcong Li, Mizuho Yabushita, Keiichi Tomishige

    ACS Catalysis 12 (24) 15431-15450 2022/12

    DOI: 10.1021/acscatal.2c04499  

    eISSN: 2155-5435

  26. Structure-activity relationship in hydrogenolysis of polyolefins over Ru/support catalysts

    Masazumi Tamura, Shuhei Miyaoka, Yosuke Nakaji, Mifumi Tanji, Shogo Kumagai, Yoshinao Nakagawa, Toshiaki Yoshioka, Keiichi Tomishige

    Applied Catalysis B: Environmental 318 121870-121870 2022/12

    Publisher: Elsevier BV

    DOI: 10.1016/j.apcatb.2022.121870  

    ISSN: 0926-3373

  27. Utilization of Ni as a Non-Noble-Metal Co-catalyst for Ceria-Supported Rhenium Oxide in Combination of Deoxydehydration and Hydrogenation of Vicinal Diols Peer-reviewed

    Kosuke Yamaguchi, Yoshinao Nakagawa, Congcong Li, Mizuho Yabushita, Keiichi Tomishige

    ACS Catalysis 12 (20) 12582-12595 2022/10

    DOI: 10.1021/acscatal.2c03042  

  28. CeO<inf>2</inf>-catalyzed transformation of various amine carbamates into organic urea derivatives in corresponding amine solvent

    Jie Peng, Mizuho Yabushita, Yingai Li, Ryotaro Fujii, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    Applied Catalysis A: General 643 2022/08/05

    DOI: 10.1016/j.apcata.2022.118747  

    ISSN: 0926-860X

  29. Reaction Mechanism of Deoxydehydration by Ceria-Supported Monomeric Rhenium Catalysts: A Computational Study

    Ryu Hosaka, Daiki Asada, Ji Cao, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige, Jun Ya Hasegawa, Akira Nakayama

    Journal of Physical Chemistry C 126 (28) 11566-11573 2022/07/21

    DOI: 10.1021/acs.jpcc.2c02944  

    ISSN: 1932-7447

    eISSN: 1932-7455

  30. Deoxydehydration of Biomass-Derived Polyols Over Silver-Modified Ceria-Supported Rhenium Catalyst with Molecular Hydrogen

    Kosuke Yamaguchi, Ji Cao, Mii Betchaku, Yoshinao Nakagawa, Masazumi Tamura, Akira Nakayama, Mizuho Yabushita, Keiichi Tomishige

    ChemSusChem 15 (10) 2022/05/20

    DOI: 10.1002/cssc.202102663  

    ISSN: 1864-5631

    eISSN: 1864-564X

  31. Dehydration of Amides to Nitriles over Heterogeneous Silica-Supported Molybdenum Oxide Catalyst

    Yo hei Nagasaki, Masazumi Tamura, Mizuho Yabushita, Yoshinao Nakagawa, Keiichi Tomishige

    ChemCatChem 14 (9) 2022/05/06

    DOI: 10.1002/cctc.202101846  

    ISSN: 1867-3880

    eISSN: 1867-3899

  32. One-pot production of dioctyl ether from 1,2-octanediol over rutile-titania-supported palladium-tungsten catalyst

    Yoshinao Nakagawa, Hiroki Hayasaka, Takehiro Asano, Masazumi Tamura, Kazu Okumura, Keiichi Tomishige

    Molecular Catalysis 523 2022/05

    DOI: 10.1016/j.mcat.2020.111208  

    ISSN: 2468-8231

  33. Titania-supported molybdenum oxide combined with Au nanoparticles as a hydrogen-driven deoxydehydration catalyst of diol compounds

    Schanth Hacatrjan, Lujie Liu, Jianxing Gan, Yoshinao Nakagawa, Ji Cao, Mizuho Yabushita, Masazumi Tamura, Keiichi Tomishige

    Catalysis Science and Technology 12 (7) 2146-2161 2022/02/14

    DOI: 10.1039/d1cy02144c  

    ISSN: 2044-4753

    eISSN: 2044-4761

  34. Heterogeneous Enantioselective Hydrogenation of Ketones by 2-Amino-2′-hydroxy-1,1′-binaphthyl-Modified CeO<inf>2</inf>-Supported Ir Nanoclusters

    Masazumi Tamura, Nao Hayashigami, Akira Nakayama, Yoshinao Nakagawa, Keiichi Tomishige

    ACS Catalysis 12 (2) 868-876 2022/01/21

    DOI: 10.1021/acscatal.1c04427  

    eISSN: 2155-5435

  35. Synthesis of Secondary Monoalcohols from Terminal Vicinal Alcohols over Silica-Supported Rhenium-Modified Ruthenium Catalyst

    Ben Liu, Naoyuki Sekine, Yoshinao Nakagawa, Masazumi Tamura, Mizuho Yabushita, Keiichi Tomishige

    ACS Sustainable Chemistry & Engineering 10 (3) 1220-1231 2022/01/11

    Publisher: American Chemical Society (ACS)

    DOI: 10.1021/acssuschemeng.1c07023  

    ISSN: 2168-0485

    eISSN: 2168-0485

  36. Combination of hydrotalcite-like-compound-derived Ni-Fe/Mg/Al and ceria-supported Rh catalysts for fuel reforming in exhaust gas recirculation system of gasoline engine

    Mii Betchaku, Yoshinao Nakagawa, Masazumi Tamura, Mizuho Yabushita, Yasutomo Miura, Shinya Iida, Keiichi Tomishige

    Fuel Processing Technology 225 2022/01

    DOI: 10.1016/j.fuproc.2021.107061  

    ISSN: 0378-3820

  37. Effect of flue gas impurities in carbon dioxide from power plants in the synthesis of isopropyl N-phenylcarbamate from CO<inf>2</inf>, aniline, and 2-propanol using CeO<inf>2</inf> and 2-cyanopyridine

    Yu Gu, Masazumi Tamura, Yoshinao Nakagawa, Eiji Ando, Keiichi Tomishige

    Catalysis Today 410 19-35 2022

    DOI: 10.1016/j.cattod.2022.03.033  

    ISSN: 0920-5861

  38. Unique catalytic properties of Ni-Ir alloy for the hydrogenation of N-heteroaromatics

    Jia Qi Bai, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    Catalysis Science and Technology 2022

    DOI: 10.1039/d2cy00383j  

    ISSN: 2044-4753

    eISSN: 2044-4761

  39. Hydrogenation of n-octanoic acid over the MoPt alloy of Mo-Pt/SiO<inf>2</inf> catalyst under solvent-free conditions

    Masazumi Tamura, Kohei Yugeta, Yoshinao Nakagawa, Keiichi Tomishige

    Organic and Biomolecular Chemistry 2022

    DOI: 10.1039/d2ob00824f  

    ISSN: 1477-0520

  40. Organic compound modification of CeO<inf>2</inf> and 2-cyanopyridine hybrid catalyst in carbonate synthesis from CO<inf>2</inf> and alcohols

    Masazumi Tamura, Daiki Hiwatashi, Yu Gu, Akira Nakayama, Yoshinao Nakagawa, Keiichi Tomishige

    Journal of CO2 Utilization 54 2021/12

    DOI: 10.1016/j.jcou.2021.101744  

    ISSN: 2212-9820

  41. CeO<inf>2</inf>-Catalyzed Synthesis of 2-Imidazolidinone from Ethylenediamine Carbamate

    Jie Peng, Masazumi Tamura, Mizuho Yabushita, Ryotaro Fujii, Yoshinao Nakagawa, Keiichi Tomishige

    ACS Omega 6 (41) 27527-27535 2021/10/19

    DOI: 10.1021/acsomega.1c04516  

    eISSN: 2470-1343

  42. Guaiacol Hydrodeoxygenation over Iron–Ceria Catalysts with Platinum Single-Atom Alloy Clusters as a Promoter

    Congcong Li, Yoshinao Nakagawa, Mizuho Yabushita, Akira Nakayama, Keiichi Tomishige

    ACS Catalysis 11 (20) 12794-12814 2021/10/06

    Publisher: American Chemical Society (ACS)

    DOI: 10.1021/acscatal.1c03539  

    ISSN: 2155-5435

    eISSN: 2155-5435

  43. Hydrogen Atom Abstraction by Heterogeneous-Homogeneous Hybrid Catalyst of CeO<inf>2</inf>and 2-Cyanopyridine via Redox of CeO<inf>2</inf>for C-H Bond Oxidation with Air

    Masazumi Tamura, Eiji Sagawa, Akira Nakayama, Yoshinao Nakagawa, Keiichi Tomishige

    ACS Catalysis 11 (19) 11867-11872 2021/10/01

    DOI: 10.1021/acscatal.1c03757  

    eISSN: 2155-5435

  44. Structure and performance relationship of silica-supported platinum-tungsten catalysts in selective C-O hydrogenolysis of glycerol and 1,4-anhydroerythritol

    Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Minyan Gu, Congcong Li, Masazumi Tamura, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 292 2021/09

    DOI: 10.1016/j.apcatb.2021.120164  

    ISSN: 0926-3373

    eISSN: 1873-3883

  45. Direct synthesis of polycarbonate diols from atmospheric flow CO2 and diols without using dehydrating agents

    Yu Gu, Masazumi Tamura, Yoshinao Nakagawa, Kenji Nakao, Kimihito Suzuki, Keiichi Tomishige

    GREEN CHEMISTRY 23 (16) 5786-5796 2021/08

    DOI: 10.1039/d1gc01172c  

    ISSN: 1463-9262

    eISSN: 1463-9270

  46. Hydrodeoxygenation of C4-C6 sugar alcohols to diols or mono-alcohols with the retention of the carbon chain over a silica-supported tungsten oxide-modified platinum catalyst

    Lujie Liu, Ji Cao, Yoshinao Nakagawa, Mii Betchaku, Masazumi Tamura, Mizuho Yabushita, Keiichi Tomishige

    GREEN CHEMISTRY 23 (15) 5665-5679 2021/08

    DOI: 10.1039/d1gc01486b  

    ISSN: 1463-9262

    eISSN: 1463-9270

  47. Adsorption of Keggin-Type Polyoxometalates on Rh Metal Particles under Reductive Conditions

    Yoshinao Nakagawa, Ayaka Kuwata, Kosuke Yamaguchi, Masazumi Tamura, Mizuho Yabushita, Keiichi Tomishige

    INORGANIC CHEMISTRY 60 (16) 12413-12424 2021/08

    DOI: 10.1021/acs.inorgchem.1c01644  

    ISSN: 0020-1669

    eISSN: 1520-510X

  48. Catalytic performance of hydrotalcite-like-compound-derived Ni-metal alloy catalyst for toluene reforming with gasoline engine exhaust model gas as reforming agent

    Mii Betchaku, Yoshinao Nakagawa, Masazumi Tamura, Mizuho Yabushita, Yasutomo Miura, Shinya Iida, Keiichi Tomishige

    FUEL PROCESSING TECHNOLOGY 218 2021/07

    DOI: 10.1016/j.fuproc.2021.106837  

    ISSN: 0378-3820

    eISSN: 1873-7188

  49. Effective Heterogeneous MoOx-Modified CeO2 Catalyst for Michael Addition of Dimethyl Malonate to 2-Cyclohexen-1-one

    Masazumi Tamura, Yamato Doi, Yingai Li, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMCATCHEM 13 (19) 4075-4079 2021/06

    DOI: 10.1002/cctc.202100682  

    ISSN: 1867-3880

    eISSN: 1867-3899

  50. Low-temperature catalytic upgrading of waste polyolefinic plastics into liquid fuels and waxes

    Yosuke Nakaji, Masazumi Tamura, Shuhei Miyaoka, Shogo Kumagai, Mifumi Tanji, Yoshinao Nakagawa, Toshiaki Yoshioka, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 285 2021/05

    DOI: 10.1016/j.apcatb.2020.119805  

    ISSN: 0926-3373

    eISSN: 1873-3883

  51. Reductive conversion of biomass-derived furancarboxylic acids with retention of carboxylic acid moiety Invited Peer-reviewed

    Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    Transactions of Tianjin University 27 165-179 2021/03

    DOI: 10.1007/s12209-021-00284-w  

  52. Comprehensive Study on Ni- or Ir-Based Alloy Catalysts in the Hydrogenation of Olefins and Mechanistic Insight

    Jia-qi Bai, Masazumi Tamura, Akira Nakayama, Yoshinao Nakagawa, Keiichi Tomishige

    ACS CATALYSIS 11 (6) 3293-3309 2021/03

    DOI: 10.1021/acscatal.0c04615  

    ISSN: 2155-5435

  53. Detailed Characterization of MoOx-Modified Rh Metal Particles by Ambient-Pressure XPS and DFT Calculations

    Ryo Toyoshima, Jumpei Kawai, Kazuhisa Isegawa, Hiroshi Kondoh, Anchalee Junkaew, Akira Nakayama, Takehiro Asano, Masazumi Tamura, Yoshinao Nakagawa, Mizuho Yabushita, Keiichi Tomishige

    JOURNAL OF PHYSICAL CHEMISTRY C 125 (8) 4540-4549 2021/03

    DOI: 10.1021/acs.jpcc.0c10380  

    ISSN: 1932-7447

    eISSN: 1932-7455

  54. Selective Hydrogenolysis of Erythritol over Ir-ReOx/Rutile-TiO2 Catalyst

    Minyan Gu, Lujie Liu, Yoshinao Nakagawa, Congcong Li, Masazumi Tamura, Zheng Shen, Xuefei Zhou, Yalei Zhang, Keiichi Tomishige

    CHEMSUSCHEM 14 (2) 642-654 2021/01

    DOI: 10.1002/cssc.202002357  

    ISSN: 1864-5631

    eISSN: 1864-564X

  55. Hydrodeoxygenation of Guaiacol to Phenol over Ceria-Supported Iron Catalysts

    Congcong Li, Yoshinao Nakagawa, Masazumi Tamura, Akira Nakayama, Keiichi Tomishige

    ACS CATALYSIS 10 (24) 14624-14639 2020/12

    DOI: 10.1021/acscatal.0c04336  

    ISSN: 2155-5435

  56. Reforming of toluene with simulated automobile exhaust gas over hydrotalcite-like-compound-derived Ni catalyst Peer-reviewed

    Mii Betchaku, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Fuel Processing Technology 209 2020/12/01

    DOI: 10.1016/j.fuproc.2020.106545  

    ISSN: 0378-3820

  57. An effective combination catalyst of CeO2 and zeolite for the direct synthesis of diethyl carbonate from CO2 and ethanol with 2,2-diethoxypropane as a dehydrating agent

    Tao Chang, Masazumi Tamura, Yoshinao Nakagawa, Norihisa Fukaya, Jun-Chul Choi, Takayoshi Mishima, Seiji Matsumoto, Satoshi Hamura, Keiichi Tomishige

    GREEN CHEMISTRY 22 (21) 7321-7327 2020/11

    DOI: 10.1039/d0gc02717k  

    ISSN: 1463-9262

    eISSN: 1463-9270

  58. Mechanistic Study on Deoxydehydration and Hydrogenation of Methyl Glycosides to Dideoxy Sugars over a ReOx-Pd/CeO2 Catalyst

    Ji Cao, Masazumi Tamura, Ryu Hosaka, Akira Nakayama, Jun-ya Hasegawa, Yoshinao Nakagawa, Keiichi Tomishige

    ACS CATALYSIS 10 (20) 12040-12051 2020/10

    DOI: 10.1021/acscatal.0c02309  

    ISSN: 2155-5435

  59. Efficient production of adipic acid from 2-methoxycyclohexanone by aerobic oxidation with a phosphotungstic acid catalyst Peer-reviewed

    Kosuke Hatakeyama, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Green Chemistry 22 (15) 4962-4974 2020/08/07

    DOI: 10.1039/d0gc01277g  

    ISSN: 1463-9262

    eISSN: 1463-9270

  60. Hydrogenolysis of tetrahydrofuran-2-carboxylic acid over tungsten-modified rhodium catalyst Peer-reviewed

    Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Applied Catalysis A: General 602 2020/07/25

    DOI: 10.1016/j.apcata.2020.117723  

    ISSN: 0926-860X

  61. Tungsten-zirconia-supported rhenium catalyst combined with a deoxydehydration catalyst for the one-pot synthesis of 1,4-butanediol from 1,4-anhydroerythritol

    Tianmiao Wang, Yoshinao Nakagawa, Masazumi Tamura, Kazu Okumura, Keiichi Tomishige

    Reaction Chemistry and Engineering 5 (7) 1237-1250 2020/07/01

    Publisher: Royal Society of Chemistry

    DOI: 10.1039/d0re00085j  

    ISSN: 2058-9883

  62. Reduction of sugar derivatives to valuable chemicals: Utilization of asymmetric carbons Peer-reviewed

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Catalysis Science and Technology 10 (12) 3805-3824 2020/06/21

    DOI: 10.1039/d0cy00654h  

    ISSN: 2044-4753

    eISSN: 2044-4761

  63. Taming heterogeneous rhenium catalysis for the production of biomass-derived chemicals Peer-reviewed

    Keiichi Tomishige, Yoshinao Nakagawa, Masazumi Tamura

    Chinese Chemical Letters 31 (5) 1071-1077 2020/05

    DOI: 10.1016/j.cclet.2019.07.014  

    ISSN: 1001-8417

  64. One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst Peer-reviewed

    Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Green Chemistry 22 (8) 2375-2380 2020/04

    DOI: 10.1039/d0gc00244e  

    ISSN: 1463-9262

    eISSN: 1463-9270

  65. Catalytic Transformation of Polyolefines to Valuable Liquid Fuels over Heterogeneous supported Ru Catalyst International-journal

    Masazumi Tamura, Yosuke Nakaji, Shuhei Miyaoka, Yoshinao Nakagawa, Toshiaki Yoshioka, Keiichi Tomishige

    The 6th 3R International Scientific Conference on Material Cycles and Waste Management 2020/03

  66. Synthesis of Hexane-Tetrols and -Triols with Fixed Hydroxyl Group Positions and Stereochemistry from Methyl Glycosides over Supported Metal Catalysts Peer-reviewed

    Siddarth H. Krishna, Ji Cao, Masazumi Tamura, Yoshinao Nakagawa, Mario De Bruyn, Graeme S. Jacobson, Bert M. Weckhuysen, James A. Dumesic, Keiichi Tomishige, George W. Huber

    ACS Sustainable Chemistry and Engineering 8 (2) 800-805 2020/01/21

    DOI: 10.1021/acssuschemeng.9b04634  

    eISSN: 2168-0485

  67. Highly active iridium–rhenium catalyst condensed on silica support for hydrogenolysis of glycerol to 1,3-propanediol Peer-reviewed

    Lujie Liu, Shota Kawakami, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Applied Catalysis B: Environmental 256 2019/11/05

    DOI: 10.1016/j.apcatb.2019.117775  

    ISSN: 0926-3373

  68. Highly Efficient Synthesis of Alkyl N-Arylcarbamates from CO<inf>2</inf>, Anilines, and Branched Alcohols with a Catalyst System of CeO<inf>2</inf> and 2-Cyanopyridine Peer-reviewed

    Yu Gu, Ayaka Miura, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ACS Sustainable Chemistry and Engineering 7 (19) 16795-16802 2019/10/07

    DOI: 10.1021/acssuschemeng.9b04318  

    eISSN: 2168-0485

  69. Preparation of Highly Active Monometallic Rhenium Catalysts for Selective Synthesis of 1,4-Butanediol from 1,4-Anhydroerythritol

    Tianmiao Wang, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ChemSusChem 12 (15) 3615-3626 2019/08/08

    Publisher: Wiley-VCH Verlag

    DOI: 10.1002/cssc.201900900  

    ISSN: 1864-564X 1864-5631

  70. CO<inf>2</inf> Conversion with Alcohols and Amines into Carbonates, Ureas, and Carbamates over CeO<inf>2</inf> Catalyst in the Presence and Absence of 2-Cyanopyridine Peer-reviewed

    Keiichi Tomishige, Masazumi Tamura, Yoshinao Nakagawa

    Chemical Record 19 (7) 1354-1379 2019/07

    DOI: 10.1002/tcr.201800117  

    ISSN: 1527-8999

    eISSN: 1528-0691

  71. Demethoxylation of hydrogenated derivatives of guaiacol without external hydrogen over platinum catalyst Peer-reviewed

    Akari Miyagawa, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Molecular Catalysis 471 60-70 2019/07

    DOI: 10.1016/j.mcat.2019.03.019  

    ISSN: 2468-8231

  72. Structure and Mechanism of Titania-Supported Platinum-Molybdenum Catalyst for Hydrodeoxygenation of 2-Furancarboxylic Acid to Valeric Acid Peer-reviewed

    Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    ACS Sustainable Chemistry and Engineering 7 (10) 9601-9612 2019/05/20

    DOI: 10.1021/acssuschemeng.9b01104  

    ISSN: 2168-0485

    eISSN: 2168-0485

  73. Fabrication of FeO <inf>x</inf> -ZrO <inf>2</inf> nanostructures for automotive three-way catalysts by supercritical hydrothermal synthesis with supercritical CO <inf>2</inf> drying Peer-reviewed

    Gimyeong Seong, Tsutomu Aida, Yoshinao Nakagawa, Tetsuya Nanba, Osamu Okada, Akira Yoko, Takaaki Tomai, Seiichi Takami, Tadafumi Adschiri

    Journal of Supercritical Fluids 147 302-309 2019/05

    DOI: 10.1016/j.supflu.2018.11.015  

    ISSN: 0896-8446

  74. Direct Synthesis of Unsaturated Sugars from Methyl Glycosides Peer-reviewed

    Ji Cao, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ACS Catalysis 9 (4) 3725-3729 2019/04

    DOI: 10.1021/acscatal.9b00589  

    ISSN: 2155-5435

    eISSN: 2155-5435

  75. Direct Synthesis of Alternating Polycarbonates from CO2 and Diols by Using a Catalyst System of CeO2 and 2-Furonitrile Peer-reviewed

    Gu Yu, Matsuda Keitaro, Nakayama Akira, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7 (6) 6304-6315 2019/03/18

    DOI: 10.1021/acssuschemeng.8b06870  

    ISSN: 2168-0485

  76. Mechanism of Formation of Highly Dispersed Metallic Ruthenium Particles on Ceria Support by Heating and Reduction

    Yosuke Nakaji, Daisuke Kobayashi, Yoshinao Nakagawa, Masazumi Tamura, Kazu Okumura, Keiichi Tomishige

    Journal of Physical Chemistry C 123 (34) 20817-20828 2019/01/17

    Publisher: American Chemical Society

    DOI: 10.1021/acs.jpcc.9b00515  

    ISSN: 1932-7455 1932-7447

  77. Aerobic oxidation of alkyl chain in alkylphenols over combination of Pt and Pd catalysts Peer-reviewed

    Nakagawa Yoshinao, Tokuma Kensuke, Nakaji Yosuke, Miyagawa Akari, Tamura Masazumi, Tomishige Keiichi

    APPLIED CATALYSIS A-GENERAL 569 149-156 2019/01/05

    DOI: 10.1016/j.apcata.2018.10.024  

    ISSN: 0926-860X

  78. Selective hydrogenolysis of 2-furancarboxylic acid to 5-hydroxyvaleric acid derivatives over supported platinum catalysts

    Takehiro Asano, Hiroshi Takagi, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Green Chemistry 21 (22) 6133-6145 2019

    Publisher: Royal Society of Chemistry

    DOI: 10.1039/c9gc03315g  

    ISSN: 1463-9270 1463-9262

  79. Selective Hydrogenolysis of Glycerol to 1,3-Propanediol over Rhenium-Oxide-Modified Iridium Nanoparticles Coating Rutile Titania Support

    Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Kazu Okumura, Keiichi Tomishige

    ACS Catalysis 10913-10930 2019

    Publisher: American Chemical Society

    DOI: 10.1021/acscatal.9b03824  

    ISSN: 2155-5435

  80. A nickel-iridium alloy as an efficient heterogeneous catalyst for hydrogenation of olefins

    Jia-qi Bai, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    Chemical Communications 55 (71) 10519-10522 2019

    Publisher: Royal Society of Chemistry

    DOI: 10.1039/c9cc04822g  

    ISSN: 1364-548X 1359-7345

  81. Ring-opening polymerization of trimethylene carbonate to poly(trimethylene carbonate) diol over a heterogeneous high-temperature calcined CeO2 catalyst Peer-reviewed

    Tamura Masazumi, Matsuda Keitaro, Nakagawa Yoshinao, Tomishige Keiichi

    CHEMICAL COMMUNICATIONS 54 (99) 14017-14020 2018/12/25

    DOI: 10.1039/c8cc08405j  

    ISSN: 1359-7345

  82. Direct Catalytic Synthesis of N-Arylcarbamates from CO2, Anilines and Alcohols Peer-reviewed

    Tamura Masazumi, Miura Ayaka, Honda Masayoshi, Gu Yu, Nakagawa Yoshinao, Tomishige Keiichi

    CHEMCATCHEM 10 (21) 4835-4839 2018/11/07

    DOI: 10.1002/cctc.201801443  

    ISSN: 1867-3880

  83. Selective C-C Hydrogenolysis of Alkylbenzenes to Methylbenzenes with Suppression of Ring Hydrogenation Peer-reviewed

    Yanatake Shin, Nakaji Yosuke, Betchaku Mii, Nakagawa Yoshinao, Tamura Masazumi, Tomishige Keiichi

    CHEMCATCHEM 10 (18) 4172-4181 2018/09/20

    DOI: 10.1002/cctc.201801118  

    ISSN: 1867-3880

  84. Selective hydrogenation of amides to alcohols in water solvent over a heterogeneous CeO2-supported Ru catalyst Peer-reviewed

    Tamura Masazumi, Ishikawa Susumu, Betchaku Mii, Nakagawa Yoshinao, Tomishige Keiichi

    CHEMICAL COMMUNICATIONS 54 (54) 7503-7506 2018/07/11

    DOI: 10.1039/c8cc02697a  

    ISSN: 1359-7345

  85. Transformation of Sugars into Chiral Polyols over a Heterogeneous Catalyst. International-journal Peer-reviewed

    Masazumi Tamura, Naoto Yuasa, Ji Cao, Yoshinao Nakagawa, Keiichi Tomishige

    Angewandte Chemie (International ed. in English) 57 (27) 8058-8062 2018/07/02

    DOI: 10.1002/anie.201803043  

    ISSN: 1433-7851

  86. Perspective on catalyst development for glycerol reduction to C3 chemicals with molecular hydrogen Peer-reviewed

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Research on Chemical Intermediates 44 (7) 3879-3903 2018/07/01

    DOI: 10.1007/s11164-018-3481-2  

    ISSN: 1568-5675 0922-6168

  87. Regioselective hydrogenolysis of alga-derived squalane over silica-supported ruthenium‑vanadium catalyst Peer-reviewed

    Yosuke Nakaji, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Fuel Processing Technology 176 249-257 2018/07/01

    DOI: 10.1016/j.fuproc.2018.03.038  

    ISSN: 0378-3820

  88. Hydrogenolysis of glycerol with in-situ produced H2 by aqueous-phase reforming of glycerol using Pt-modified Ir-ReOx/SiO2 catalyst Peer-reviewed

    Shiyang Liu, Masazumi Tamura, Zheng Shen, Yalei Zhang, Yoshinao Nakagawa, Keiichi Tomishige

    Catalysis Today 303 106-116 2018/04/01

    DOI: 10.1016/j.cattod.2017.07.025  

    ISSN: 0920-5861

  89. Catalytic transformations of furfural and its derived compounds into pentanediols

    Sibao Liu, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    Furfural: An Entry Point of Lignocellulose in Biorefineries to Produce Renewable Chemicals, Polymers, and Biofuels 91-109 2018/01/01

    Publisher: World Scientific Publishing Co.

    DOI: 10.1142/9781786344878_0005  

  90. Mechanistic Study of Hydrogen-Driven Deoxydehydration over Ceria-Supported Rhenium Catalyst Promoted by Au Nanoparticles Peer-reviewed

    Nakagawa, Y., Tazawa, S., Wang, T., Tamura, M., Hiyoshi, N., Okumura, K., Tomishige, K.

    ACS Catalysis 8 (1) 584-595 2018

    DOI: 10.1021/acscatal.7b02879  

    ISSN: 2155-5435

  91. One-pot catalytic selective synthesis of 1,4-butanediol from 1,4-anhydroerythritol and hydrogen Peer-reviewed

    Wang, T., Liu, S., Tamura, M., Nakagawa, Y., Hiyoshi, N., Tomishige, K.

    Green Chemistry 20 (11) 2547-2557 2018

    DOI: 10.1039/c8gc00574e  

    ISSN: 1463-9262

  92. Nickel-iron alloy catalysts for reforming of hydrocarbons: preparation, structure, and catalytic properties Peer-reviewed

    Keiichi Tomishige, Dalin Li, Masazumi Tamura, Yoshinao Nakagawa

    CATALYSIS SCIENCE & TECHNOLOGY 7 (18) 3952-3979 2017/09

    DOI: 10.1039/c7cy01300k  

    ISSN: 2044-4753

    eISSN: 2044-4761

  93. Transformation of Diols to Ketones via Intramolecular Borrowing Hydrogen Mechanism Peer-reviewed

    Masazumi Tamura, Takahiro Arai, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMISTRY LETTERS 46 (9) 1333-1336 2017/09

    DOI: 10.1246/cl.170498  

    ISSN: 0366-7022

    eISSN: 1348-0715

  94. Oxidative C-C Cleavage of Ketols over Vanadium-Carbon Catalysts Peer-reviewed

    Yoshinao Nakagawa, Dai Sekine, Naoyuki Obara, Masazumi Tamura, Keiichi Tomishige

    CHEMCATCHEM 9 (17) 3412-3419 2017/09

    DOI: 10.1002/cctc.201700566  

    ISSN: 1867-3880

    eISSN: 1867-3899

  95. In Situ Formed Fe Cation Modified Ir/MgO Catalyst for Selective Hydrogenation of Unsaturated Carbonyl Compounds Peer-reviewed

    Masazumi Tamura, Dai Yonezawa, Teruhisa Oshino, Yoshinao Nakagawa, Keiichi Tomishige

    ACS CATALYSIS 7 (8) 5103-5111 2017/08

    DOI: 10.1021/acscatal.7b01055  

    ISSN: 2155-5435

  96. Formation of a New, Strongly Basic Nitrogen Anion by Metal Oxide Modification Peer-reviewed

    Masazumi Tamura, Ryota Kishi, Akira Nakayama, Yoshinao Nakagawa, Jun-ya Hasegawa, Keiichi Tomishige

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139 (34) 11857-11867 2017/08

    DOI: 10.1021/jacs.7b05227  

    ISSN: 0002-7863

  97. Selective N-Methylation of Aniline to N-Methylaniline with CO2 and H-2 by CeO2-supported Cu Sub-nanoparticle Catalyst Peer-reviewed

    Masazumi Tamura, Ayaka Miura, Yu Gu, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMISTRY LETTERS 46 (8) 1243-1246 2017/08

    DOI: 10.1246/cl.170419  

    ISSN: 0366-7022

    eISSN: 1348-0715

  98. Production of Gasoline Fuel from Alga-Derived Botryococcene by Hydrogenolysis over Ceria-Supported Ruthenium Catalyst Peer-reviewed

    Yosuke Nakaji, Shin-ichi Oya, Hideo Watanabe, Makoto M. Watanabe, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    CHEMCATCHEM 9 (14) 2701-2708 2017/07

    DOI: 10.1002/cctc.201700200  

    ISSN: 1867-3880

    eISSN: 1867-3899

  99. Self-Assembled Materials for Catalysis Peer-reviewed

    M. Tamura, Y. Nakagawa, K. Tomishige

    Comprehensive Supramolecular Chemistry II 9 329-349 2017/06/22

    Publisher: Elsevier Inc.

    DOI: 10.1016/B978-0-12-409547-2.12652-6  

  100. Effective NbOx-Modified Ir/SiO2 Catalyst for Selective Gas-Phase Hydrogenation of Crotonaldehyde to Crotyl Alcohol Peer-reviewed

    Masazumi Tamura, Kensuke Tokonami, Yoshinao Nakagawa, Keiichi Tomishige

    ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5 (5) 3685-3697 2017/05

    DOI: 10.1021/acssuschemeng.6b03060  

    ISSN: 2168-0485

  101. Selective hydrogenation of nitroarenes to aminoarenes using a MoOx-modified Ru/SiO2 catalyst under mild conditions Peer-reviewed

    Masazumi Tamura, Naoto Yuasa, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMICAL COMMUNICATIONS 53 (23) 3377-3380 2017/03

    DOI: 10.1039/c7cc00653e  

    ISSN: 1359-7345

    eISSN: 1364-548X

  102. Outstanding Reviewers for Green Chemistry in 2016 Peer-reviewed

    Mark A. Harmer, Toshiyuki Itoh, Rafael Luque, Yoshinao Nakagawa, Jinliang Song

    Green Chemistry 19 (7) 1600 2017

    Publisher: Royal Society of Chemistry

    DOI: 10.1039/c7gc90029e  

    ISSN: 1463-9270 1463-9262

  103. Outstanding Reviewers for Catalysis Science &amp; Technology in 2016 Peer-reviewed

    Pieter C. A. Bruijnincx, Jiri Cejka, Wei-Lin Dai, Burtron H. Davis, Haijun Jiao, Arjan Willem Kleij, Yoshinao Nakagawa, Wenjie Shen, X. Yi-Jun, Ning Yan

    Catalysis Science and Technology 7 (6) 1278 2017

    Publisher: Royal Society of Chemistry

    DOI: 10.1039/c7cy90027a  

    ISSN: 2044-4761 2044-4753

  104. Regioselectivity and Reaction Mechanism of Ru-Catalyzed Hydrogenolysis of Squalane and Model Alkanes Peer-reviewed

    Yoshinao Nakagawa, Shin-ichi Oya, Daisuke Kanno, Yosuke Nakaji, Masazumi Tamura, Keiichi Tomishige

    CHEMSUSCHEM 10 (1) 189-198 2017/01

    DOI: 10.1002/cssc.201601204  

    ISSN: 1864-5631

    eISSN: 1864-564X

  105. Selective Hydrodeoxygenation of 2-Furancarboxylic Acid to Valeric Acid over Molybdenum-Oxide-Modified Platinum Catalyst Peer-reviewed

    Takehiro Asano, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4 (12) 6253-6257 2016/12

    DOI: 10.1021/acssuschemeng.6b01640  

    ISSN: 2168-0485

  106. CeO2-catalyzed direct synthesis of dialkylureas from CO2 and amines Peer-reviewed

    Masazumi Tamura, Kazuki Ito, Yoshinao Nakagawa, Keiichi Tomishige

    JOURNAL OF CATALYSIS 343 (SI) 75-85 2016/11

    DOI: 10.1016/j.jcat.2015.11.015  

    ISSN: 0021-9517

    eISSN: 1090-2694

  107. Deoxydehydration with Molecular Hydrogen over Ceria-Supported Rhenium Catalyst with Gold Promoter Peer-reviewed

    Shuhei Tazawa, Nobuhiko Ota, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    ACS CATALYSIS 6 (10) 6393-6397 2016/10

    DOI: 10.1021/acscatal.6b01864  

    ISSN: 2155-5435

  108. Production of Cellulose-derived Olefins and Applicability to Gasoline Peer-reviewed

    Yasuyo Okuyama, Mitsuru Koike, Shinya Sasaki, Sibao Liu, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige

    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE 59 (5) 228-234 2016/09

    DOI: 10.1627/jpi.59.228  

    ISSN: 1346-8804

  109. Characterization and catalytic performance of hydrotalcite-derived Ni-Cu alloy nanoparticles catalysts for steam reforming of 1-methylnaphthalene Peer-reviewed

    Dalin Li, Miaomiao Lu, Kosuke Aragaki, Mitsuru Koike, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 192 171-181 2016/09

    DOI: 10.1016/j.apcatb.2016.03.052  

    ISSN: 0926-3373

    eISSN: 1873-3883

  110. Catalytic conversion of sorbitol to gasoline-ranged products without external hydrogen over Pt-modified Ir-ReOx/SiO2 Peer-reviewed

    Sibao Liu, Yasuyo Okuyama, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige

    CATALYSIS TODAY 269 122-131 2016/07

    DOI: 10.1016/j.cattod.2015.10.023  

    ISSN: 0920-5861

    eISSN: 1873-4308

  111. Synthesis of 2-Butanol by Selective Hydrogenolysis of 1,4-Anhydroerythritol over Molybdenum Oxide-Modified Rhodium-Supported Silica Peer-reviewed

    Takahiro Arai, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMSUSCHEM 9 (13) 1680-1688 2016/07

    DOI: 10.1002/cssc.201600295  

    ISSN: 1864-5631

    eISSN: 1864-564X

  112. Selective Hydrogenation of Crotonaldehyde to Crotyl Alcohol over Metal Oxide Modified Ir Catalysts and Mechanistic Insight Peer-reviewed

    Masazumi Tamura, Kensuke Tokonami, Yoshinao Nakagawa, Keiichi Tomishige

    ACS CATALYSIS 6 (6) 3600-3609 2016/06

    DOI: 10.1021/acscatal.6b00400  

    ISSN: 2155-5435

  113. Performance, Structure, and Mechanism of ReOx-Pd/CeO2 Catalyst for Simultaneous Removal of Vicinal OH Groups with H-2 Peer-reviewed

    Nobuhiko Ota, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    ACS CATALYSIS 6 (5) 3213-3226 2016/05

    DOI: 10.1021/acscatal.6b00491  

    ISSN: 2155-5435

  114. Oxidative Cleavage of Vicinal Diols with the Combination of Platinum and Vanadium Catalysts and Molecular Oxygen Peer-reviewed

    Naoyuki Obara, Shota Hirasawa, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMCATCHEM 8 (9) 1732-1738 2016/05

    DOI: 10.1002/cctc.201600153  

    ISSN: 1867-3880

    eISSN: 1867-3899

  115. Direct Copolymerization of CO2 and Diols Peer-reviewed

    Masazumi Tamura, Kazuki Ito, Masayoshi Honda, Yoshinao Nakagawa, Hiroshi Sugimoto, Keiichi Tomishige

    SCIENTIFIC REPORTS 6 24038 2016/04

    DOI: 10.1038/srep24038  

    ISSN: 2045-2322

  116. Demethoxylation of guaiacol and methoxybenzenes over carbon-supported Ru-Mn catalyst Peer-reviewed

    Momoko Ishikawa, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 182 193-203 2016/03

    DOI: 10.1016/j.apcatb.2015.09.021  

    ISSN: 0926-3373

    eISSN: 1873-3883

  117. Development of metal oxide-modified noble metal catalysts for selective hydrogenation of unsaturated carbonyl compounds

    Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016 13-13 2016

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2016.0_13  

    More details Close

    Unsaturated alcohols can be synthesized by selective hydrogenation of unsaturated carbonyl compounds, and they are used as important intermediates for perfumes and medicines. However, since selective hydrogenation of the carbonyl group in unsaturated carbonyl compounds is thermodynamically and kinetically unfavorable, development of effective heterogeneous catalysts for the reaction is desirable. In this study, hydrogenation of unsaturated carbonyl compounds (unsaturated aldehydes and unsaturated ketones) to the corresponding unsaturated alcohols was investigated using metal oxide modified noble metal catalysts, showing that Ir-FeOx/MgO catalyst is effective for the reaction.

  118. Multi-metallic catalysts for hydrogenation of biomass-derived furanic compounds

    Nakagawa Yoshinao

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016 43-43 2016

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2016.0_43  

  119. CeO2 catalyzed ring-opening polymerization of trimethylene carbonate

    Matsuda Keitaro, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016 144-144 2016

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2016f.0_144  

  120. Simultaneous removal of vicinal OH groups of methyl glycosides over ReOx-Pd/CeO2 catalyst.

    Yuasa Naoto, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016 125-125 2016

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2016f.0_125  

  121. Hydrogenolysis of alga-derived heavy hydrocarbon over ruthenium based catalyst

    Nakaji Yosuke, Watanabe Hideo, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016 86-86 2016

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2016f.0_86  

  122. An approach to biomass-derived hexanols production by making the most use of in situ hydrogen

    Koike Mitsuru, Okuyama Yasuyo, Liu Sibao, Tamura Masazumi, Nakagawa Yoshinao, Imai Akio, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016 75-75 2016

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2016f.0_75  

  123. Selective transformation of hemicellulose (xylan) into n-pentane, pentanols or xylitol over a rhenium-modified iridium catalyst combined with acids Peer-reviewed

    Sibao Liu, Yasuyo Okuyama, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige

    GREEN CHEMISTRY 18 (1) 165-175 2016

    DOI: 10.1039/c5gc02183a  

    ISSN: 1463-9262

    eISSN: 1463-9270

  124. Hydrogenation of dicarboxylic acids to diols over Re-Pd catalysts Peer-reviewed

    Yasuyuki Takeda, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    CATALYSIS SCIENCE & TECHNOLOGY 6 (14) 5668-5683 2016

    DOI: 10.1039/c6cy00335d  

    ISSN: 2044-4753

    eISSN: 2044-4761

  125. Cu Sub-Nanoparticles on Cu/CeO2 as an Effective Catalyst for Methanol Synthesis from Organic Carbonate by Hydrogenation Peer-reviewed

    Masazumi Tamura, Takahisa Kitanaka, Yoshinao Nakagawa, Keiichi Tomishige

    ACS CATALYSIS 6 (1) 376-380 2016/01

    DOI: 10.1021/acscatal.5b02258  

    ISSN: 2155-5435

  126. Promoting effect of trace Pd on hydrotalcite-derived Ni/Mg/Al catalyst in oxidative steam reforming of biomass tar Peer-reviewed

    Jinhai Chen, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 179 412-421 2015/12

    DOI: 10.1016/j.apcatb.2015.05.042  

    ISSN: 0926-3373

    eISSN: 1873-3883

  127. Characterization of Re-Pd/SiO2 Catalysts for Hydrogenation of Stearic Acid Peer-reviewed

    Yasuyuki Takeda, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    ACS CATALYSIS 5 (11) 7034-7047 2015/11

    DOI: 10.1021/acscatal.5b01054  

    ISSN: 2155-5435

  128. Self-assembled hybrid metal oxide base catalysts prepared by simply mixing with organic modifiers Peer-reviewed

    Masazumi Tamura, Ryota Kishi, Yoshinao Nakagawa, Keiichi Tomishige

    NATURE COMMUNICATIONS 6 8580 2015/10

    DOI: 10.1038/ncomms9580  

    ISSN: 2041-1723

  129. Comparative study on steam reforming of model aromatic compounds of biomass tar over Ni and Ni-Fe alloy nanoparticles Peer-reviewed

    Mitsuru Koike, Dalin Li, Hideo Watanabe, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 506 151-162 2015/10

    DOI: 10.1016/j.apcata.2015.09.007  

    ISSN: 0926-860X

    eISSN: 1873-3875

  130. New reaction schemes for the production of biomass-based chemicals created by selective catalytic hydrogenolysis: Catalysts with noble metal and tungsten Peer-reviewed

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion I: Cellulose Structure, Depolymerization and Conversion by Heterogeneous Catalysts 203-225 2015/09/25

    Publisher: Springer Singapore

    DOI: 10.1007/978-981-287-688-1_8  

  131. Catalytic gasification of oil-extracted residue biomass of Botryococcus braunii Peer-reviewed

    Hideo Watanabe, Dalin Li, Yoshinao Nakagawa, Keiichi Tomishige, Makoto M. Watanabe

    BIORESOURCE TECHNOLOGY 191 452-459 2015/09

    DOI: 10.1016/j.biortech.2015.03.034  

    ISSN: 0960-8524

    eISSN: 1873-2976

  132. Selective Hydrogenation of Lactic Acid to 1,2-Propanediol over Highly Active Ruthenium-Molybdenum Oxide Catalysts Peer-reviewed

    Yasuyuki Takeda, Tomohiro Shoji, Hideo Watanabe, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    CHEMSUSCHEM 8 (7) 1170-1178 2015/04

    DOI: 10.1002/cssc.201403011  

    ISSN: 1864-5631

    eISSN: 1864-564X

  133. Combination of supported bimetallic rhodium-molybdenum catalyst and cerium oxide for hydrogenation of amide Peer-reviewed

    Yoshinao Nakagawa, Riku Tamura, Masazumi Tamura, Keiichi Tomishige

    SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS 16 (1) 014901 2015/02

    DOI: 10.1088/1468-6996/16/1/014901  

    ISSN: 1468-6996

    eISSN: 1878-5514

  134. Production of Renewable Hexanols from Mechanocatalytically Depolymerized Cellulose by Using Ir-ReOx/SiO2 catalyst Peer-reviewed

    Sibao Liu, Yasuyo Okuyama, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige

    CHEMSUSCHEM 8 (4) 628-635 2015/02

    DOI: 10.1002/cssc.201403010  

    ISSN: 1864-5631

    eISSN: 1864-564X

  135. Hydrodeoxygenation of Vicinal OH Groups over Heterogeneous Rhenium Catalyst Promoted by Palladium and Ceria Support Peer-reviewed

    Nobuhiko Ota, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54 (6) 1897-1900 2015/02

    DOI: 10.1002/anie.201410352  

    ISSN: 1433-7851

    eISSN: 1521-3773

  136. Insight into the Mechanism of Hydrogenation of Amino Acids to Amino Alcohols Catalyzed by a Heterogeneous MoOx-Modified Rh Catalyst Peer-reviewed

    Masazumi Tamura, Riku Tamura, Yasuyuki Takeda, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMISTRY-A EUROPEAN JOURNAL 21 (7) 3097-3107 2015/02

    DOI: 10.1002/chem.201405769  

    ISSN: 0947-6539

    eISSN: 1521-3765

  137. Selective hydrogenation of unsaturated ketones over Ir-FeOx/MgO catalyst and clarification of the catalyst structure

    Yonezawa Dai, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2015 154-154 2015

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2015f.0_154  

    More details Close

    Selective hydrogenation of the carbonyl group of unsaturated ketones over heterogeneous catalysts is an useful reaction for the synthesis of unsaturated alcohols. Selective hydrogenation of unsaturated ketones to unsaturated alcohols was investigated using benzylideneacetone as a model substrate. MgO supported Ir-FeOx catalyst(Ir-FeOx/MgO catalyst Fe/Ir molar ratio=0.5) showed high activity and selectivity for the reaction. The Ir-FeOx/MgO catalyst was characterized by various techniques such as XPS and FT-IR.

  138. Simultaneous removal of vicinal OH groups over ReOx-Pd/CeO2 catalyst and characterization of the catalyst.

    Ota Nobuhiko, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2015 79-79 2015

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2015f.0_79  

  139. Oxidative C-C bond cleavage of compounds having oxygen-containing functional groups with molecular oxygen

    Obara Naoyuki, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2015 197-197 2015

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2015f.0_197  

  140. Production of cellulose-derived olefins and their applicability to gasoline

    Okuyama Yasuyo, Koike Mitsuru, Sasaki Shinya, Imai Akio, Liu Sibao, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2015 59-59 2015

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2015f.0_59  

  141. One-pot conversion of furfural to 1,5-pentanediol over noble metal-iridium-rhenium catalysts

    Nakagawa Yoshinao, Liu Sibao, Amada Yasushi, Tamura Masazumi, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2015 11-11 2015

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2015.0_11  

  142. Catalytic Production of Branched Small Alkanes from Biohydrocarbons Peer-reviewed

    Shin-ichi Oya, Daisuke Kanno, Hideo Watanabe, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMSUSCHEM 8 (15) 2472-2475 2015

    DOI: 10.1002/cssc.201500375  

    ISSN: 1864-5631

    eISSN: 1864-564X

  143. Role of Re Species and Acid Cocatalyst on Ir-ReOx/SiO2 in the C-O Hydrogenolysis of Biomass-Derived Substrates Peer-reviewed

    Keiichi Tomishige, Masazumi Tamura, Yoshinao Nakagawa

    CHEMICAL RECORD 14 (6) 1041-1054 2014/12

    DOI: 10.1002/tcr.201402026  

    ISSN: 1527-8999

    eISSN: 1528-0691

  144. Catalytic performance and characterization of Co-Fe bcc alloy nanoparticles prepared from hydrotalcite-like precursors in the steam gasification of biomass-derived tar Peer-reviewed

    Lei Wang, Jinhai Chen, Hideo Watanabe, Ya Xu, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 160 701-715 2014/11

    DOI: 10.1016/j.apcatb.2014.06.021  

    ISSN: 0926-3373

    eISSN: 1873-3883

  145. Characterization of oil-extracted residue biomass of Botryococcus braunii as a biofuel feedstock and its pyrolytic behavior Peer-reviewed

    Hideo Watanabe, Dalin Li, Yoshinao Nakagawa, Keiichi Tomishige, Kunimitsu Kaya, Makoto M. Watanabe

    APPLIED ENERGY 132 475-484 2014/11

    DOI: 10.1016/j.apenergy.2014.07.037  

    ISSN: 0306-2619

    eISSN: 1872-9118

  146. Organic carbonate synthesis from CO2 and alcohol over CeO2 with 2-cyanopyridine: Scope and mechanistic studies Peer-reviewed

    Masayoshi Honda, Masazumi Tamura, Yoshinao Nakagawa, Kenji Nakao, Kimihito Suzuki, Keiichi Tomishige

    JOURNAL OF CATALYSIS 318 95-107 2014/10

    DOI: 10.1016/j.jcat.2014.07.022  

    ISSN: 0021-9517

    eISSN: 1090-2694

  147. Hydrogeonolysis of squalane over novel metal catalysts Peer-reviewed

    Shin-Ichi Oya, Daisuke Kanno, Hideo Watanabe, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 248 2014/08

    ISSN: 0065-7727

  148. Hydrogenation of lactic acid to propylene glycol over Mo modified Ru/C catalyst Peer-reviewed

    Yasuyuki Takeda, Tomohiro Shoji, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 248 2014/08

    ISSN: 0065-7727

  149. Selective Hydrodeoxygenation of Cyclic Vicinal Diols to Cyclic Alcohols over Tungsten Oxide-Palladium Catalysts Peer-reviewed

    Yasushi Amada, Nobuhiko Ota, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMSUSCHEM 7 (8) 2185-2192 2014/08

    DOI: 10.1002/cssc.201402188  

    ISSN: 1864-5631

    eISSN: 1864-564X

  150. Total Hydrogenation of Furfural and 5-Hydroxymethylfurfural over Supported Pd-Ir Alloy Catalyst Peer-reviewed

    Yoshinao Nakagawa, Kana Takada, Masazumi Tamura, Keiichi Tomishige

    ACS CATALYSIS 4 (8) 2718-2726 2014/08

    DOI: 10.1021/cs500620b  

    ISSN: 2155-5435

  151. One-Pot Conversion of Cellulose into n-Hexane over the Ir-ReOx/SiO2 Catalyst Combined with HZSM-5 Peer-reviewed

    Sibao Liu, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ACS SUSTAINABLE CHEMISTRY & ENGINEERING 2 (7) 1819-1827 2014/07

    DOI: 10.1021/sc5001463  

    ISSN: 2168-0485

  152. Promoting effect of Ru on Ir-ReOx/SiO2 catalyst in hydrogenolysis of glycerol Peer-reviewed

    Masazumi Tamura, Yasushi Amada, Sibao Liu, Zhenle Yuan, Yoshinao Nakagawa, Keiichi Tomishige

    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 388 (SI) 177-187 2014/07

    DOI: 10.1016/j.molcata.2013.09.015  

    ISSN: 1381-1169

    eISSN: 1873-314X

  153. Preparation of Ni-Cu/Mg/Al catalysts from hydrotalcite-like compounds for hydrogen production by steam reforming of biomass tar Peer-reviewed

    Dalin Li, Mitsuru Koike, Jinhai Chen, Yoshinao Nakagawa, Keiichi Tomishige

    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 39 (21) 10959-10970 2014/07

    DOI: 10.1016/j.ijhydene.2014.05.062  

    ISSN: 0360-3199

    eISSN: 1879-3487

  154. Direct Cyclic Carbonate Synthesis from CO2 and Diol over Carboxylation/Hydration Cascade Catalyst of CeO2 with 2-Cyanopyridine Peer-reviewed

    Masayoshi Honda, Masazumi Tamura, Kenji Nakao, Kimihito Suzuki, Yoshinao Nakagawa, Keiichi Tomishige

    ACS CATALYSIS 4 (6) 1893-1896 2014/06

    DOI: 10.1021/cs500301d  

    ISSN: 2155-5435

  155. Amination of Alcohols with Ammonia in Water over Rh In Catalyst Peer-reviewed

    Tsukasa Takanashi, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMISTRY LETTERS 43 (6) 822-824 2014/06

    DOI: 10.1246/cl.140051  

    ISSN: 0366-7022

    eISSN: 1348-0715

  156. Catalytic performance and characterization of Co/Mg/Al catalysts prepared from hydrotalcite-like precursors for the steam gasification of biomass Peer-reviewed

    Lei Wang, Dalin Li, Hideo Watanabe, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 150 82-92 2014/05

    DOI: 10.1016/j.apcatb.2013.12.002  

    ISSN: 0926-3373

    eISSN: 1873-3883

  157. Direct Synthesis of Organic Carbonates from CO&lt;inf&gt;2&lt;/inf&gt; and Alcohols Using Heterogeneous Oxide Catalysts Invited

    Yoshinao Nakagawa, Masayoshi Honda, Keiichi Tomishige

    Green Carbon Dioxide: Advances in CO&lt;inf&gt;2&lt;/inf&gt; Utilization 119-148 2014/03/10

    Publisher: Wiley Blackwell

    DOI: 10.1002/9781118831922.ch5  

  158. Heterogeneous CeO2-catalyzed selective synthesis of cyclic carbamates from CO2 and aminoalcohols inacetonitrile solvent Peer-reviewed

    Masayoshi Honda, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 247 2014/03

    DOI: 10.1016/j.jcat.2013.05.013  

    ISSN: 0065-7727

  159. One-pot conversion of furfural into 1,5-pentanediol over Ir-ReOx/SiO2 catalysts modified by noble metals Peer-reviewed

    Sibao Liu, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 247 2014/03

    ISSN: 0065-7727

  160. Synthesis of alpha-Hydroxy Ketones from Vicinal Diols by Selective Dehydrogenation over Ir-ReOx/SiO2 Catalyst Peer-reviewed

    Hiraku Sato, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMISTRY LETTERS 43 (3) 334-336 2014/03

    DOI: 10.1246/cl.130983  

    ISSN: 0366-7022

    eISSN: 1348-0715

  161. Regenerability of Hydrotalcite-Derived Nickel-Iron Alloy Nanoparticles for Syngas Production from Biomass Tar Peer-reviewed

    Dalin Li, Mitsuru Koike, Lei Wang, Yoshinao Nakagawa, Ya Xu, Keiichi Tomishige

    CHEMSUSCHEM 7 (2) 510-522 2014/02

    DOI: 10.1002/cssc.201300855  

    ISSN: 1864-5631

    eISSN: 1864-564X

  162. One-pot selective conversion of furfural into 1,5-pentanediol over a Pd-added Ir-ReOx/SiO2 bifunctional catalyst Peer-reviewed

    Sibao Liu, Yasushi Amada, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    GREEN CHEMISTRY 16 (2) 617-626 2014/02

    DOI: 10.1039/c3gc41335g  

    ISSN: 1463-9262

    eISSN: 1463-9270

  163. Selective Hydrogenolysis of C-O Bonds Using the Interaction of the Catalyst Surface and OH Groups Peer-reviewed

    Keiichi Tomishige, Yoshinao Nakagawa, Masazumi Tamura

    SELECTIVE CATALYSIS FOR RENEWABLE FEEDSTOCKS AND CHEMICALS 353 127-162 2014

    DOI: 10.1007/128_2014_538  

    ISSN: 0340-1022

  164. Performance and characterization of rhenium-modified Rh-Ir alloy catalyst for one-pot conversion of furfural into 1,5-pentanediol Peer-reviewed

    Sibao Liu, Yasushi Amada, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS SCIENCE & TECHNOLOGY 4 (8) 2535-2549 2014

    DOI: 10.1039/c4cy00161c  

    ISSN: 2044-4753

    eISSN: 2044-4761

  165. Structure of catalytically active Rh-In bimetallic phase for amination of alcohols Peer-reviewed

    Tsukasa Takanashi, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    RSC ADVANCES 4 (54) 28664-28672 2014

    DOI: 10.1039/c4ra03984j  

    ISSN: 2046-2069

  166. Catalytic hydrogenation of amino acids to amino alcohols with complete retention of configuration Peer-reviewed

    Masazumi Tamura, Riku Tamura, Yasuyuki Takeda, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMICAL COMMUNICATIONS 50 (50) 6656-6659 2014

    DOI: 10.1039/c4cc02675f  

    ISSN: 1359-7345

    eISSN: 1364-548X

  167. Selective production of cyclohexanol and methanol from guaiacol over Ru catalyst combined with MgO Peer-reviewed

    Yoshinao Nakagawa, Momoko Ishikawa, Masazumi Tamura, Keiichi Tomishige

    GREEN CHEMISTRY 16 (4) 2197-2203 2014

    DOI: 10.1039/c3gc42322k  

    ISSN: 1463-9262

    eISSN: 1463-9270

  168. Hydrogenolysis of C-O bond over Re-modified Ir catalyst in alkane solvent Peer-reviewed

    Yoshinao Nakagawa, Kazuma Mori, Kaiyou Chen, Yasushi Amada, Masazumi Tamura, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 468 418-425 2013/11

    DOI: 10.1016/j.apcata.2013.09.021  

    ISSN: 0926-860X

    eISSN: 1873-3875

  169. Preparation of Rh/CeO2 Using Supercritical CO2 and Its Catalytic Application for Automotive Exhaust Peer-reviewed

    Taichi Shimizu, Masaki Ota, Yoshiyuki Sato, Hiroshi Inomata, Yoshinao Nakagawa, Tetsuya Nanba

    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE 56 (5) 312-316 2013/09

    DOI: 10.1627/jpi.56.312  

    ISSN: 1346-8804

  170. Rapid synthesis of unsaturated alcohols under mild conditions by highly selective hydrogenation Peer-reviewed

    Masazumi Tamura, Kensuke Tokonami, Yoshinao Nakagawa, Keiichi Tomishige

    Chemical Communications 49 (63) 7034-7036 2013/08/14

    DOI: 10.1039/c3cc41526k  

    ISSN: 1359-7345 1364-548X

  171. High catalytic activity of Co-Fe/α-Al2O3 in the steam reforming of toluene in the presence of hydrogen Peer-reviewed

    Mitsuru Koike, Yuji Hisada, Lei Wang, Dalin Li, Hideo Watanabe, Yoshinao Nakagawa, Keiichi Tomishige

    Applied Catalysis B: Environmental 140-141 652-662 2013/08

    DOI: 10.1016/j.apcatb.2013.04.065  

    ISSN: 0926-3373

  172. One-Pot Conversion of Sugar and Sugar Polyols to n-Alkanes without C-C Dissociation over the Ir-ReOx/SiO2 Catalyst Combined with H-ZSM-5 Peer-reviewed

    Kaiyou Chen, Masazumi Tamura, Zhenle Yuan, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMSUSCHEM 6 (4) 613-621 2013/04

    DOI: 10.1002/cssc.201200940  

    ISSN: 1864-5631

  173. Performance, structure and mechanism of Pd-Ag alloy catalyst for selective oxidation of glycerol to dihydroxyacetone Peer-reviewed

    Shota Hirasawa, Hideo Watanabe, Tokushi Kizuka, Yoshinao Nakagawa, Keiichi Tomishige

    Journal of Catalysis 300 205-216 2013/04

    DOI: 10.1016/j.jcat.2013.01.014  

    ISSN: 0021-9517 1090-2694

  174. One-Pot Conversion of Sugar and Sugar Polyols to n-Alkanes without C-C Dissociation over the Ir-ReOx/SiO2 Catalyst Combined with H-ZSM-5 Peer-reviewed

    Yoshinao Nakagawa, Masazumi Tamura, Zhenle Yuan, Keiichi Tomishige, Kaiyou Chen

    CHEMSUSCHEM 6 (4) 548-548 2013/04

    DOI: 10.1002/cssc.201300231  

    ISSN: 1864-5631

  175. Production of renewable hydrogen by steam reforming of tar from biomass pyrolysis over supported Co catalysts Peer-reviewed

    Dalin Li, Chiaki Ishikawa, Mitsuru Koike, Lei Wang, Yoshinao Nakagawa, Keiichi Tomishige

    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 38 (9) 3572-3581 2013/03

    DOI: 10.1016/j.ijhydene.2013.01.057  

    ISSN: 0360-3199

  176. Alkane synthesis from sugars and sugar alcohols by hydrogenolysis over Re-modified Ir catalyst

    Nakagawa Yoshinao, Chen Kaiyou, Yuan Zhenle, Tamura Masazumi, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2013 22-22 2013

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2013.0_22  

  177. Highly efficient synthesis of cyclic ureas from CO2 and diamines by a pure CeO2 catalyst using a 2-propanol solvent Peer-reviewed

    Masazumi Tamura, Kensuke Noro, Masayoshi Honda, Yoshinao Nakagawa, Keiichi Tomishige

    GREEN CHEMISTRY 15 (6) 1567-1577 2013

    DOI: 10.1039/c3gc40495a  

    ISSN: 1463-9262

  178. Ceria-catalyzed conversion of carbon dioxide into dimethyl carbonate with 2-cyanopyridine Peer-reviewed

    Masayoshi Honda, Masazumi Tamura, Yoshinao Nakagawa, Satoru Sonehara, Kimihito Suzuki, Ken-Ichiro Fujimoto, Keiichi Tomishige

    ChemSusChem 6 (8) 1341-1344 2013

    DOI: 10.1002/cssc.201300229  

    ISSN: 1864-564X 1864-5631

  179. Heterogeneous CeO2-catalyzed selective synthesis of cyclic carbamates from CO2 and aminoalcohols in acetonitrile solvent Peer-reviewed

    Masazumi Tamura, Masayoshi Honda, Kensuke Noro, Yoshinao Nakagawa, Keiichi Tomishige

    Journal of Catalysis 305 191-203 2013

    DOI: 10.1016/j.jcat.2013.05.013  

    ISSN: 0021-9517 1090-2694

  180. Catalytic performance and characterization of Ni-Co catalysts for the steam reforming of biomass tar to synthesis gas Peer-reviewed

    Lei Wang, Dalin Li, Mitsuru Koike, Hideo Watanabe, Ya Xu, Yoshinao Nakagawa, Keiichi Tomishige

    Fuel 112 654-661 2013

    DOI: 10.1016/j.fuel.2012.01.073  

    ISSN: 0016-2361

  181. Catalytic performance of manganese-promoted nickel catalysts for the steam reforming of tar from biomass pyrolysis to synthesis gas Peer-reviewed

    Mitsuru Koike, Chiaki Ishikawa, Dalin Li, Lei Wang, Yoshinao Nakagawa, Keiichi Tomishige

    FUEL 103 (SI) 122-129 2013/01

    DOI: 10.1016/j.fuel.2011.04.009  

    ISSN: 0016-2361

    eISSN: 1873-7153

  182. Structure of ReOx Clusters Attached on the Ir Metal Surface in Ir-ReOx/SiO2 for the Hydrogenolysis Reaction Peer-reviewed

    Yasushi Amada, Hideo Watanabe, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige

    JOURNAL OF PHYSICAL CHEMISTRY C 116 (44) 23503-23514 2012/11

    DOI: 10.1021/jp308527f  

    ISSN: 1932-7447

  183. Total Hydrogenation of Furfural over a Silica-Supported Nickel Catalyst Prepared by the Reduction of a Nickel Nitrate Precursor Peer-reviewed

    Yoshinao Nakagawa, Hiroya Nakazawa, Hideo Watanabe, Keiichi Tomishige

    CHEMCATCHEM 4 (11) 1791-1797 2012/11

    DOI: 10.1002/cctc.201200218  

    ISSN: 1867-3880

    eISSN: 1867-3899

  184. Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReOx-Pd/SiO2 catalyst Peer-reviewed

    Yasuyuki Takeda, Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS SCIENCE & TECHNOLOGY 2 (11) 2221-2223 2012/11

    DOI: 10.1039/c2cy20302b  

    ISSN: 2044-4753

  185. C-O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts Peer-reviewed

    Kaiyou Chen, Kazuma Mori, Hideo Watanabe, Yoshinao Nakagawa, Keiichi Tomishige

    JOURNAL OF CATALYSIS 294 171-183 2012/10

    DOI: 10.1016/j.jcat.2012.07.015  

    ISSN: 0021-9517

    eISSN: 1090-2694

  186. Solid acid co-catalyst for the hydrogenolysis of glycerol to 1,3-propanediol over Ir-ReOx/SiO2 Peer-reviewed

    Yoshinao Nakagawa, Xuanhe Ning, Yasushi Amada, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 433 128-134 2012/08

    DOI: 10.1016/j.apcata.2012.05.009  

    ISSN: 0926-860X

  187. Catalyst property of Co-Fe alloy particles in the steam reforming of biomass tar and toluene Peer-reviewed

    Lei Wang, Yuji Hisada, Mitsuru Koike, Dalin Li, Hideo Watanabe, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 121 95-104 2012/06

    DOI: 10.1016/j.apcatb.2012.03.025  

    ISSN: 0926-3373

  188. Stable Low-Valence ReOx Cluster Attached on Rh Metal Particles Formed by Hydrogen Reduction and Its Formation Mechanism Peer-reviewed

    Shuichi Koso, Hideo Watanabe, Kazu Okumura, Yoshinao Nakagawa, Keiichi Tomishige

    JOURNAL OF PHYSICAL CHEMISTRY C 116 (4) 3079-3090 2012/02

    DOI: 10.1021/jp2114225  

    ISSN: 1932-7447

  189. Catalytic partial oxidation of methane at elevated pressure using ceramic foam catalyst

    Kado Shigeru, Kiryu Asako, Imagawa Ken-ichi, Kawai Hironori, Kawazuishi Ken-ichi, Yagi Fuyuki, Nakagawa Yoshinao, Tomishige Keiichi, Suehiro Yoshifumi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2012 27-27 2012

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2012.0_27  

  190. High-yield synthesis of cyclic carbamates from carbon dioxide and aminoalcohols catalyzed by ceria

    Noro Kensuke, Honda Masayoshi, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2012 161-161 2012

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2012f.0_161  

    More details Close

    Cyclic carbamates, which is useful in the pharmaceutical and agrochemical intermediates, were synthesized from carbon dioxide and aminoalcohols using ceria catalyst. Acetonitrile has high solubility of carbon dioxide and is the most effective solvent. In optimized reaction conditions, 2-oxazolidinone is obtained from 2-aminoethanol with 97% yield. When this catalyst system was applied to aminoalcohols which have &ndash;OH and &ndash;NHR groups at 1 and 2-positions or 1 and 3-positions, five- and six-membered-ring carbamates can be selectively synthesized in high yield.

  191. Reaction mechanism of saturated fatty acid hydrogenation over ReOx-Pd/SiO2

    Takeda Yasuyuki, Tamura Masazumi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2012 49-49 2012

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2012f.0_49  

  192. Performance and mechanism of Pd-Ag alloy catalyst for selective oxidation of glycerol to dihydroxyacetone

    Hirasawa Shota, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2012 48-48 2012

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2012f.0_48  

  193. Promoting effect of Cu addition to Ni/Mg/Al catalysts in the steam reforming of biomass-derived tar

    Aragaki Kosuke, Koike Mitsuru, Li Dalin, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2012 54-54 2012

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2012f.0_54  

    More details Close

    The Ni/Mg/Al catalysts were prepared from the calcination and reduction of hydrotalcite-like compounds. The Ni/Mg/Al catalysts have a nanocomposite structure of Ni metal particles and Mg(Ni, Al)O particles. The Ni/Mg/Al catalysts showed high catalytic performance in the steam reforming of biomass-derived tar. In the present study, we also prepared Ni-Cu/Mg/Al catalysts from the calcination and reduction of hydrotalcite-like compounds. The performance of the Ni-Cu/Mg/Al catalysts was investigated in terms of catalytic activity, suppression of coke deposition in the steam reforming of biomass-derived tar.

  194. Hydrogenolysis of cyclic ethers over ReOx-modified Ir catalyst

    Tamura Masazumi, Chen Kaiyou, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2012 44-44 2012

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2012f.0.44.0  

  195. A Highly Active and Coke-Resistant Steam Reforming Catalyst Comprising Uniform Nickel-Iron Alloy Nanoparticles Peer-reviewed

    Mitsuru Koike, Dalin Li, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMSUSCHEM 5 (12) 2312-2314 2012

    DOI: 10.1002/cssc.201200507  

    ISSN: 1864-5631

  196. Production of Biobutanediols by the Hydrogenolysis of Erythritol Peer-reviewed

    Yasushi Amada, Hideo Watanabe, Yuichirou Hirai, Yasuteru Kajikawa, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMSUSCHEM 5 (10) 1991-1999 2012

    DOI: 10.1002/cssc.201200121  

    ISSN: 1864-5631

  197. Comparative study of Rh-MoOx and Rh-ReOx supported on SiO2 for the hydrogenolysis of ethers and polyols Peer-reviewed

    Shuichi Koso, Hideo Watanabe, Kazu Okumura, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 111 27-37 2012/01

    DOI: 10.1016/j.apcatb.2011.09.015  

    ISSN: 0926-3373

    eISSN: 1873-3883

  198. Selective oxidation of glycerol to dihydroxyacetone over a Pd-Ag catalyst Peer-reviewed

    Shota Hirasawa, Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS SCIENCE & TECHNOLOGY 2 (6) 1150-1152 2012

    DOI: 10.1039/c2cy20062g  

    ISSN: 2044-4753

  199. FTIR study of CO adsorption on Rh/MgO modified with Co, Ni, Fe, or CeO2 for the catalytic partial oxidation of methane Peer-reviewed

    Dalin Li, Shigemasa Sakai, Yoshinao Nakagawa, Keiichi Tomishige

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS 14 (25) 9204-9213 2012

    DOI: 10.1039/c2cp41050h  

    ISSN: 1463-9076

  200. Reaction mechanism of the glycerol hydrogenolysis to 1,3-propanediol over Ir-ReOx/SiO2 catalyst Peer-reviewed

    Yasushi Amada, Yasunori Shinmi, Shuichi Koso, Takeshi Kubota, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 105 (1-2) 117-127 2011/06

    DOI: 10.1016/j.apcatb.2011.04.001  

    ISSN: 0926-3373

  201. Mechanism of the hydrogenolysis of ethers over silica-supported rhodium catalyst modified with rhenium oxide Peer-reviewed

    Shuichi Koso, Yoshinao Nakagawa, Keiichi Tomishige

    JOURNAL OF CATALYSIS 280 (2) 221-229 2011/06

    DOI: 10.1016/j.jcat.2011.03.018  

    ISSN: 0021-9517

  202. Tandem Carboxylation-Hydration Reaction System from Methanol, CO2 and Benzonitrile to Dimethyl Carbonate and Benzamide Catalyzed by CeO2 Peer-reviewed

    Masayoshi Honda, Shintaro Kuno, Satoru Sonehara, Ken-ichiro Fujimoto, Kimihito Suzuki, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMCATCHEM 3 (2) 365-370 2011/02

    DOI: 10.1002/cctc.201000339  

    ISSN: 1867-3880

  203. Steam reforming of tar from pyrolysis of biomass over Ni/Mg/Al catalysts prepared from hydrotalcite-like precursors Peer-reviewed

    Dalin Li, Lei Wang, Mitsuru Koike, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 102 (3-4) 528-538 2011/02

    DOI: 10.1016/j.apcatb.2010.12.035  

    ISSN: 0926-3373

  204. Hydrogenation of the stearic acid over Rh-ReOx/SiO2 catalyst

    Takeda Yasuyuki, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2011 65-65 2011

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2011f.0.65.0  

  205. Mechanism of the hydrogenolysis of ethers with CH2OH group over Rh-ReOx/SiO2 catalyst

    Aragaki Kosuke, Koso Shuichi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2011 66-66 2011

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2011f.0.66.0  

  206. Catalyst structure and reaction mechanism of the glycerol hydrogenolysis over Ir-ReOx/SiO2

    Amada Yasushi, Nei Genkaku, Chen Kaiyou, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2011 67-67 2011

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2011f.0.67.0  

  207. Syngas production by steam reforming of tar from pyrolysis of biomass over Ni/Mg/Al catalyst

    Koike Mitsuru, Wang Lei, Li Dalin, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2011 55-55 2011

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2011f.0.55.0  

  208. Preparation of Rh/mesoporous silica catalyst using supercritical fluid method and application to hydrogenolysis reaction

    Shimizu Taichi, Ota Masaki, Sato Yoshiyuki, Inomata Hiroshi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2011 146-146 2011

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2011f.0.146.0  

  209. One pod synthsis of dimethyl carbonate and benzamide from methanol, CO2, benzonitrile

    Sonehara Satoru, Noro Kensuke, Honda Masayoshi, Suzuki Kimihito, Fujimoto Kenichiro, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2011 190-190 2011

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2011f.0.190.0  

  210. Modification of iridium catalyst with rhenium oxide for the hydrogenolysis of glycerol to 1,3-propanediol Peer-reviewed

    Yasushi Amada, Shuichi Koso, Yoshinao Nakagawa, Keiichi Tomishige

    Materials Research Society Symposium Proceedings 1326 34-40 2011

    DOI: 10.1557/opl.2011.973  

    ISSN: 0272-9172

  211. Promoting effect of the alloy formation over Ni-Fe/Al 2O 3 catalysts for the steam reforming of biomass tar to synthesis gas Peer-reviewed

    Lei Wang, Dalin Li, Mitsuru Koike, Yoshinao Nakagawa, Keiichi Tomishige

    Materials Research Society Symposium Proceedings 1326 73-79 2011

    DOI: 10.1557/opl.2011.1044  

    ISSN: 0272-9172

  212. Heterogeneous CeO2 catalyst for the one-pot synthesis of organic carbamates from amines, CO2 and alcohols Peer-reviewed

    Masayoshi Honda, Satoru Sonehara, Hiroshi Yasuda, Yoshinao Nakagawa, Keiichi Tomishige

    GREEN CHEMISTRY 13 (12) 3406-3413 2011

    DOI: 10.1039/c1gc15646b  

    ISSN: 1463-9262

  213. Catalytic performance and characterization of Ni-Fe catalysts for the steam reforming of tar from biomass pyrolysis to synthesis gas Peer-reviewed

    Lei Wang, Dalin Li, Mitsuru Koike, Shuichi Koso, Yoshinao Nakagawa, Ya Xu, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 392 (1-2) 248-255 2011/01

    DOI: 10.1016/j.apcata.2010.11.013  

    ISSN: 0926-860X

  214. Scope and reaction mechanism of an aerobic oxidative alkyne homocoupling catalyzed by a di-copper-substituted silicotungstate Peer-reviewed

    Noritaka Mizuno, Keigo Kamata, Yoshinao Nakagawa, Takamichi Oishi, Kazuya Yamaguchi

    CATALYSIS TODAY 157 (1-4) 359-363 2010/11

    DOI: 10.1016/j.cattod.2010.02.073  

    ISSN: 0920-5861

  215. Total hydrogenation of furan derivatives over silica-supported Ni-Pd alloy catalyst Peer-reviewed

    Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS COMMUNICATIONS 12 (3) 154-156 2010/11

    DOI: 10.1016/j.catcom.2010.09.003  

    ISSN: 1566-7367

    eISSN: 1873-3905

  216. Catalytic synthesis of dialkyl carbonate from low pressure CO2 and alcohols combined with acetonitrile hydration catalyzed by CeO2 Peer-reviewed

    Masayoshi Honda, Shintaro Kuno, Noorjahan Begum, Ken-ichiro Fujimoto, Kimihito Suzuki, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 384 (1-2) 165-170 2010/08

    DOI: 10.1016/j.apcata.2010.06.033  

    ISSN: 0926-860X

  217. Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate Peer-reviewed

    Keigo Kamata, Kazuhiro Yonehara, Yoshinao Nakagawa, Kazuhiro Uehara, Noritaka Mizuno

    NATURE CHEMISTRY 2 (6) 478-483 2010/06

    DOI: 10.1038/NCHEM.648  

    ISSN: 1755-4330

  218. Direct hydrogenolysis of glycerol into 1,3-propanediol over rhenium-modified iridium catalyst Peer-reviewed

    Yoshinao Nakagawa, Yasunori Shinmi, Shuichi Koso, Keiichi Tomishige

    JOURNAL OF CATALYSIS 272 (2) 191-194 2010/06

    DOI: 10.1016/j.jcat.2010.04.009  

    ISSN: 0021-9517

  219. Conversion of Glycerol to Ethylene Glycol over Pt-modified Ni Catalyst Peer-reviewed

    Naoyuki Ueda, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMISTRY LETTERS 39 (5) 506-507 2010/05

    DOI: 10.1246/cl.2010.506  

    ISSN: 0366-7022

    eISSN: 1348-0715

  220. Chemoselective Hydrogenolysis of Tetrahydropyran-2-methanol to 1,6-Hexanediol over Rhenium-Modified Carbon-Supported Rhodium Catalysts Peer-reviewed

    Kaiyou Chen, Shuichi Koso, Takeshi Kubota, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMCATCHEM 2 (5) 547-555 2010/05

    DOI: 10.1002/cctc.201000018  

    ISSN: 1867-3880

  221. Comparative study of Rh/MgO modified with Fe, Co or Ni for the catalytic partial oxidation of methane at short contact time. Part I: Characterization of catalysts Peer-reviewed

    Hisanori Tanaka, Rie Kaino, Kazu Okumura, Tokushi Kizuka, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 378 (2) 175-186 2010/04

    DOI: 10.1016/j.apcata.2010.02.017  

    ISSN: 0926-860X

  222. Comparative study of Rh/MgO modified with Fe, Co or Ni for the catalytic partial oxidation of methane at short contact time. Part II: Catalytic performance and bed temperature profile Peer-reviewed

    Hisanori Tanaka, Rie Kaino, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 378 (2) 187-194 2010/04

    DOI: 10.1016/j.apcata.2010.02.018  

    ISSN: 0926-860X

  223. Preferential CO Oxidation in a H-2-Rich Stream on Pt-ReOx/SiO2: Catalyst Structure and Reaction Mechanism Peer-reviewed

    Tatsuya Ebashi, Yoichi Ishida, Yoshinao Nakagawa, Shin-ichi Ito, Takeshi Kubota, Keiichi Tomishige

    JOURNAL OF PHYSICAL CHEMISTRY C 114 (14) 6518-6526 2010/04

    DOI: 10.1021/jp911908c  

    ISSN: 1932-7447

  224. Modification of Rh/SiO2 catalyst for the hydrogenolysis of glycerol in water Peer-reviewed

    Yasunori Shinmi, Shuichi Koso, Takeshi Kubota, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS B-ENVIRONMENTAL 94 (3-4) 318-326 2010/02

    DOI: 10.1016/j.apcatb.2009.11.021  

    ISSN: 0926-3373

  225. Hydrogenolysis of glycerol over ReOx-modified noble metal catalyst

    Nakagawa Yoshinao, Shinmi Yasunori, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2010 48-48 2010

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2010.0.48.0  

  226. Comparative study of Rh/MgO modified with Fe, Co or Ni for the catalytic partial oxidation of methane at short contact time

    Sakai Shigemasa, Tanaka Hisanori, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2010 26-26 2010

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2010f.0.26.0  

  227. Catalytic performance and characterization of Ni-Fe catalysts for the steam reforming of tar from biomass pyrolysis

    Wang Lei, Koike Mitsuru, Koso Shuichi, Li Dalin, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2010 120-120 2010

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2010f.0.120.0  

  228. Catalyst development for hydrogenolysis of biomass-derived chemicals: Selective synthesis of 1,6-hexanediol from tetrahydropyran-2-methanol

    Chen Kaiyou, Koso Shuichi, Nakagawa Yoshinao, Tomishige Keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2010 117-117 2010

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2010f.0.117.0  

  229. Organic carbonate synthsis from alchol and CO2 in combination with benzonitrile hydration

    Sonehara Satoru, Kuno Shintaro, Honda Masayoshi, Suzuki Kimihito, Fujimoto Kenichiro, Nakagawa Yoshinao, Tomishige keiichi

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2010 19-19 2010

    Publisher: The Japan Petroleum Institute

    DOI: 10.11523/sekiyu.2010f.0.19.0  

  230. Hydrogenolysis of 1,2-Propanediol for the Production of Biopropanols from Glycerol Peer-reviewed

    Yasushi Amada, Shuichi Koso, Yoshinao Nakagawa, Keiichi Tomishige

    CHEMSUSCHEM 3 (6) 728-736 2010

    DOI: 10.1002/cssc.201000040  

    ISSN: 1864-5631

  231. Inorganic Cryptand: Size-Selective Strong Metallic Cation Encapsulation by a Disilicoicosatungstate (Si2W20) Polyoxometalate Peer-reviewed

    Akihiro Yoshida, Yoshinao Nakagawa, Kazuhiro Uehara, Shiro Hikichi, Noritaka Mizuno

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 48 (38) 7055-7058 2009

    DOI: 10.1002/anie.200903275  

    ISSN: 1433-7851

  232. 1,3-Dipolar Cycloaddition of Organic Azides to Alkynes by a Dicopper-Substituted Silicotungstate Peer-reviewed

    Keigo Kamata, Yoshinao Nakagawa, Kazuya Yamaguchi, Noritaka Mizuno

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 (46) 15304-15310 2008/11

    DOI: 10.1021/ja806249n  

    ISSN: 0002-7863

  233. Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives Peer-reviewed

    Yuji Kikukawa, Syuhei Yamaguchi, Yoshinao Nakagawa, Kazuhiro Uehara, Sayaka Uchida, Kazuya Yamaguchi, Noritaka Mizuno

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 (47) 15872-15878 2008/11

    DOI: 10.1021/ja8014154  

    ISSN: 0002-7863

  234. Highly selective sorption of small unsaturated hydrocarbons by nonporous flexible framework with silver ion Peer-reviewed

    Sayaka Uchida, Ryosuke Kawamoto, Hanae Tagami, Yoshinao Nakagawa, Noritaka Mizuno

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 (37) 12370-12376 2008/09

    DOI: 10.1021/ja801453c  

    ISSN: 0002-7863

  235. Synthesis and catalysis of di- and tetranuclear metal sandwich-type silicotungstates [(gamma-SiW(10)O(36))(2)M(2)(mu-OH)(2)](10-) and [(gamma-SiW(10)O(36))(2)M(4)(mu(4)-O)(mu-OH)(6)](8-) (M = Zr or Hf) Peer-reviewed

    Yuji Kikukawa, Syuhei Yamaguchi, Kazutaka Tsuchida, Yoshinao Nakagawa, Kazuhiro Uehara, Kazuya Yamaguchi, Noritaka Mizuno

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 (16) 5472-5478 2008/04

    DOI: 10.1021/ja078313i  

    ISSN: 0002-7863

  236. Activation of Hydrogen Peroxide by Polyoxometalates Peer-reviewed

    Noritaka Mizuno, Kazuya Yamaguchi, Keigo Kamata, Yoshinao Nakagawa

    Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis 155 2008

    Publisher: Elsevier

    DOI: 10.1016/b978-0-444-53188-9.00004-3  

  237. Synthesis and structural characterization of a gamma-Keggin-type dimeric silicotungstate with a bis(mu-hydroxo) dizirconium core [(gamma-SiW10O36)(2)Zr-2(mu-OH)(2)](10-) Peer-reviewed

    Syuhei Yamaguchi, Yuji Kikukawa, Kazutaka Tsuchida, Yoshinao Nakagawa, Kazuhiro Uehara, Kazuya Yamaguchi, Noritaka Mizuno

    INORGANIC CHEMISTRY 46 (21) 8502-8504 2007/10

    DOI: 10.1021/ic701488s  

    ISSN: 0020-1669

  238. Preparation of monodispersed nanoparticles by electrostatic assembly of keggin-type polyoxometalates and 1,4,7-triazacyclononane-based transition-metal complexes Peer-reviewed

    Sayaka Uchida, Shiro Hikichi, Takeo Akatsuka, Toshiyuki Tanaka, Ryosuke Kawamoto, Aides Lesbani, Yoshinao Nakagawa, Kazuhirc Uehara, Noritaka Mizuno

    CHEMISTRY OF MATERIALS 19 (19) 4694-4701 2007/09

    DOI: 10.1021/cm071565y  

    ISSN: 0897-4756

    eISSN: 1520-5002

  239. Mechanism of [gamma-H2SiV2W10O40](4-)-catalyzed epoxidation of alkenes with hydrogen peroxide Peer-reviewed

    Yoshinao Nakagawa, Noritaka Mizuno

    INORGANIC CHEMISTRY 46 (5) 1727-1736 2007/03

    DOI: 10.1021/ic0623258  

    ISSN: 0020-1669

  240. Molecular design of selective oxidation catalyst with polyoxometalate Peer-reviewed

    Noritaka Mizuno, Shiro Hikichi, Kazuya Yamaguchia, Sayaka Uchida, Yoshinao Nakagawa, Kazuhiro Uehara, Keigo Kamata

    CATALYSIS TODAY 117 (1-3) 32-36 2006/09

    DOI: 10.1016/j.cattod.2006.05.002  

    ISSN: 0920-5861

  241. Bis(mu-hydroxo) bridged di-vanadium-catalyzed selective epoxidation of alkenes with H2O2 Peer-reviewed

    N Mizuno, Y Nakagawa, K Yamaguchi

    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 251 (1-2) 286-290 2006/05

    DOI: 10.1016/j.molcata.2006.02.012  

    ISSN: 1381-1169

  242. [gamma-1,2-H2SiV2W10O40] immobilized on surface-modified SiO2 as a heterogeneous catalyst for liquid-phase oxidation with H2O2 Peer-reviewed

    Jun Kasai, Yoshinao Nakagawa, Sayaka Uchida, Kazuya Yamaguchi, Noritaka Mizuno

    CHEMISTRY-A EUROPEAN JOURNAL 12 (15) 4176-4184 2006/05

    DOI: 10.1002/chem.200501414  

    ISSN: 0947-6539

  243. Reactivity of bis(mu-hydroxo) divanadium site in gamma-H2SiV2W10O404- with hydroxo compounds

    Y Nakagawa, K Uehara, N Mizuno

    INORGANIC CHEMISTRY 44 (24) 9068-9075 2005/11

    DOI: 10.1021/ic051163x  

    ISSN: 0020-1669

  244. Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide

    Y Nakagawa, K Kamata, M Kotani, K Yamaguchi, N Mizuno

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 44 (32) 5136-5141 2005

    DOI: 10.1002/anie.200500491  

    ISSN: 1433-7851

  245. Sterically controlled esterification on bis(mu-hydroxo) dioxovanadium site in gamma-H2SiV2W10O404-

    Y Nakagawa, K Uehara, N Mizuno

    INORGANIC CHEMISTRY 44 (1) 14-16 2005/01

    DOI: 10.1021/ic0483388  

    ISSN: 0020-1669

  246. Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [gamma-SiW10O34(H2O)2](4-)

    K Kamata, Y Nakagawa, K Yamaguchi, N Mizuno

    JOURNAL OF CATALYSIS 224 (1) 224-228 2004/05

    DOI: 10.1016/j.jcat.2004.02.027  

    ISSN: 0021-9517

  247. High turnover numbers for the catalytic selective epoxidation of alkenes with 1 atm of molecular oxygen

    Y Nishiyama, Y Nakagawa, N Mizuno

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 40 (19) 3639-+ 2001

    DOI: 10.1002/1521-3773(20011001)40:19<3639::AID-ANIE3639>3.0.CO;2-0  

    ISSN: 1433-7851

  248. A theoretical study of catalytic hydration reactions of ethylene

    Y Nakagawa, N Tajima, K Hirao

    JOURNAL OF COMPUTATIONAL CHEMISTRY 21 (14) 1292-1304 2000/11

    DOI: 10.1002/1096-987X(20001115)21:14<1292::AID-JCC8>3.0.CO;2-5  

    ISSN: 0192-8651

Show all ︎Show first 5

Misc. 48

  1. Thermodynamic and Catalytic Insights into Non-Reductive Transformation of CO<inf>2</inf> with Amines into Organic Urea Derivatives

    Mizuho Yabushita, Ryotaro Fujii, Yoshinao Nakagawa, Keiichi Tomishige

    ChemCatChem 16 (6) 2024/03/22

    DOI: 10.1002/cctc.202301342  

    ISSN: 1867-3880

    eISSN: 1867-3899

  2. Hydrodeoxygenation of potential platform chemicals derived from biomass to fuels and chemicals

    Keiichi Tomishige, Mizuho Yabushita, Ji Cao, Yoshinao Nakagawa

    Green Chemistry 2022

    DOI: 10.1039/d2gc01289h  

    ISSN: 1463-9262

    eISSN: 1463-9270

  3. In situ investigation of a Rh/Re model catalyst during activation process

    河井淳平, 豊島遼, 小澤広聖, 間瀬一彦, 中山哲, 田村正純, 中川善直, 冨重圭一, 近藤寛

    量子ビームサイエンスフェスタ(Web) 2020 2021

  4. In situ investigation of Ir/Re model catalyst during activation process

    小澤広聖, 豊島遼, 河井淳平, 間瀬一彦, 中山哲, 田村正純, 中川善直, 冨重圭一, 近藤寛

    量子ビームサイエンスフェスタ(Web) 2020 2021

  5. Catalytic function of CeO<inf>2</inf> in non-reductive conversion of CO<inf>2</inf> with alcohols

    K. Tomishige, Y. Gu, T. Chang, M. Tamura, Y. Nakagawa

    Materials Today Sustainability 9 2020/09

    DOI: 10.1016/j.mtsust.2020.100035  

    eISSN: 2589-2347

  6. Reaction of CO<inf>2</inf> With Alcohols to Linear-, Cyclic-, and Poly-Carbonates Using CeO<inf>2</inf>-Based Catalysts

    Keiichi Tomishige, Yu Gu, Yoshinao Nakagawa, Masazumi Tamura

    Frontiers in Energy Research 8 2020/06/23

    DOI: 10.3389/fenrg.2020.00117  

    eISSN: 2296-598X

  7. Design of supported metal catalysts modified with metal oxides for hydrodeoxygenation of biomass-related molecules

    Keiichi Tomishige, Yoshinao Nakagawa, Masazumi Tamura

    Current Opinion in Green and Sustainable Chemistry 22 13-21 2020/04

    DOI: 10.1016/j.cogsc.2019.11.003  

    ISSN: 2452-2236

  8. Recent Developments of Heterogeneous Catalysts for Hydrogenation of Carboxylic Acids to their Corresponding Alcohols

    Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    Asian Journal of Organic Chemistry 9 (2) 126-143 2020/02/01

    DOI: 10.1002/ajoc.201900667  

    ISSN: 2193-5807

  9. Erythritol: Another C4 Platform Chemical in Biomass Refinery

    Yoshinao Nakagawa, Takafumi Kasumi, Jun Ogihara, Masazumi Tamura, Takashi Arai, Keiichi Tomishige

    ACS Omega 2020

    DOI: 10.1021/acsomega.9b04046  

    eISSN: 2470-1343

  10. Recent development of production technology of diesel- and jet-fuel-range hydrocarbons from inedible biomass

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    Fuel Processing Technology 193 404-422 2019/10

    DOI: 10.1016/j.fuproc.2019.05.028  

    ISSN: 0378-3820

  11. Recent developments of heterogeneous catalysts for selective hydrogenation of unsaturated carbonyl compounds to unsaturated alcohols

    Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    Journal of the Japan Petroleum Institute 62 (3) 106-119 2019

    Publisher: Japan Petroleum Institute

    DOI: 10.1627/jpi.62.106  

    ISSN: 1349-273X 1346-8804

  12. Selective hydrogenolysis and hydrogenation using metal catalysts directly modified with metal oxide species

    Keiichi Tomishige, Yoshinao Nakagawa, Masazumi Tamura

    GREEN CHEMISTRY 19 (13) 2876-2924 2017/07

    DOI: 10.1039/c7gc00620a  

    ISSN: 1463-9262

    eISSN: 1463-9270

  13. CO₂とジオールからの触媒的プラスチック合成 (特集 新しいものづくりへの挑戦)

    田村 正純, 中川 善直, 杉本 裕, 冨重 圭一

    プラスチックスエージ = Plastics age 63 (1) 76-81 2017/01

    Publisher: プラスチックス・エージ

    ISSN: 0551-0503

  14. Supported Metal Catalysts for Total Hydrogenation of Furfural and 5-Hydroxymethylfurfural

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE 60 (1) 1-9 2017/01

    DOI: 10.1627/jpi.60.1  

    ISSN: 1346-8804

  15. CO₂とジオールからポリカーボネートを直接合成! : 安全かつ環境にやさしい夢の合成法

    田村 正純, 中川 善直, 杉本 裕, 冨重 圭一

    化学 = Chemistry 71 (9) 19-24 2016/09

    Publisher: 化学同人

    ISSN: 0451-1964

  16. Production of Lighter Compounds from Algal Oils using Metal Catalysis

    33 (7) 35-40 2016/07

    Publisher: シーエムシー出版

    ISSN: 0910-6545

  17. Catalytic Conversions of Furfural to Pentanediols

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    CATALYSIS SURVEYS FROM ASIA 19 (4) 249-256 2015/12

    DOI: 10.1007/s10563-015-9194-2  

    ISSN: 1571-1013

    eISSN: 1574-9266

  18. Synthesis of Useful Chemicals by Oxidation of Biomass-derived Polyols

    44 (9) 21-26 2015/09

    Publisher: シーエムシー出版

    ISSN: 0913-6150

  19. Catalytic Total Hydrodeoxygenation of Biomass-Derived Polyfunctionalized Substrates to Alkanes

    Yoshinao Nakagawa, Sibao Liu, Masazumi Tamura, Keiichi Tomishige

    CHEMSUSCHEM 8 (7) 1114-1132 2015/04

    DOI: 10.1002/cssc.201403330  

    ISSN: 1864-5631

    eISSN: 1864-564X

  20. Metal catalysts for steam reforming of tar derived from the gasification of lignocellulosic biomass

    Dalin Li, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    BIORESOURCE TECHNOLOGY 178 53-64 2015/02

    DOI: 10.1016/j.biortech.2014.10.010  

    ISSN: 0960-8524

    eISSN: 1873-2976

  21. 有機カーボネート製造のための固体触媒反応システム

    冨重 圭一, 田村 正純, 中川 善直

    化学経済 2014 (8) 32-38 2014/08/01

    Publisher: 化学工業日報

    ISSN: 0453-0683

  22. Catalytic CO2 conversion to organic carbonates with alcohols in combination with dehydration system

    Masayoshi Honda, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS SCIENCE & TECHNOLOGY 4 (9) 2830-2845 2014

    DOI: 10.1039/c4cy00557k  

    ISSN: 2044-4753

    eISSN: 2044-4761

  23. Direct conversion of CO2 with diols, aminoalcohols and diamines to cyclic carbonates, cyclic carbamates and cyclic ureas using heterogeneous catalysts

    Masazumi Tamura, Masayoshi Honda, Yoshinao Nakagawa, Keiichi Tomishige

    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY 89 (1) 19-33 2014/01

    DOI: 10.1002/jctb.4209  

    ISSN: 0268-2575

    eISSN: 1097-4660

  24. Catalytic materials for the hydrogenolysis of glycerol to 1,3-propanediol

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    JOURNAL OF MATERIALS CHEMISTRY A 2 (19) 6688-6702 2014

    DOI: 10.1039/c3ta15384c  

    ISSN: 2050-7488

    eISSN: 2050-7496

  25. Catalytic reduction of biomass-derived furanic compounds with hydrogen

    Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

    ACS Catalysis 3 (12) 2655-2668 2013/12/06

    Publisher: AMER CHEMICAL SOC

    DOI: 10.1021/cs400616p  

    ISSN: 2155-5435

  26. グリセリンの水素化分解による 1, 3─プロパンジオール合成触媒

    中川善直, 田村正純, 冨重圭一

    触媒 54 (7) 439-443 2012/12

  27. Production of 1,5-pentanediol from biomass via furfural and tetrahydrofurfuryl alcohol

    Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS TODAY 195 (1) 136-143 2012/11

    DOI: 10.1016/j.cattod.2012.04.048  

    ISSN: 0920-5861

  28. バイオマス由来ジオール合成のための触媒開発

    田村正純, 中川善直, 冨重圭一

    ペトロテック 35 (10) 712-717 2012/10

    Publisher: 石油学会 ; 1978-

    ISSN: 0386-2763

  29. バイオマスからの化学原料合成のための触媒開発

    田村正純, 中川善直, 冨重圭一

    Chemistry&Chemical Industry 65 (8) 619-621 2012/08/01

    Publisher: Chemical Society of Japan

    ISSN: 0022-7684

  30. Development of Ni-Based Catalysts for Steam Reforming of Tar Derived from Biomass Pyrolysis

    Dalin Li, Yoshinao Nakagawa, Keiichi Tomishige

    CHINESE JOURNAL OF CATALYSIS 33 (4) 583-594 2012/04

    DOI: 10.1016/S1872-2067(11)60359-8  

    ISSN: 0253-9837

  31. Direct synthesis of dimethyl carbonate from methanol and CO_2 in combination with nitrile hydration

    HONDA Masayoshi, NAKAGAWA Yoshinao, TOMISHIGE Keiichi

    54 (2) 126-128 2012/03/10

    Publisher: 触媒学会

    ISSN: 0559-8958

  32. 酸化セリウムを触媒とする二酸化炭素からのカーボネート・カーバメート合成 (特集 二酸化炭素の再利用と将来展望)

    冨重 圭一, 中川 善直

    ケミカルエンジニヤリング 57 (3) 181-185 2012/03

    Publisher: 化学工業社

    ISSN: 0387-1037

  33. バイオマス由来ジオール合成のための触媒開発

    田村正純, 中川善直, 冨重圭一

    PETROTECH 35 (10) 712-717 2012

    Publisher: Jaoan Petroleum Institute

  34. グリセリンの水素化分解による1, 3─プロパンジオール合成触媒

    中川善直, 田村正純, 冨重圭一

    Catalysts and Catalysis 54 (7) 439-443 2012

    Publisher: Catalysis Society of Japan

  35. Methane reforming to synthesis gas over Ni catalysts modified with noble metals

    Dalin Li, Yoshinao Nakagawa, Keiichi Tomishige

    APPLIED CATALYSIS A-GENERAL 408 (1-2) 1-24 2011/11

    DOI: 10.1016/j.apcata.2011.09.018  

    ISSN: 0926-860X

  36. Catalytically Active Interface between Noble Metal and Low-valence Transition Metal for C-O Hydrogenolysis

    Nakagawa, Yoshinao Tomishige, Keiichi

    Journal of The Surface Science Society of Japan 32 (7) 439-444 2011/07/16

    Publisher: The Surface Science Society of Japan

    DOI: 10.1380/jsssj.32.439  

    ISSN: 0388-5321

  37. Catalyst Development for the Production of Biomass-derived Diols

    Function & materials 31 (6) 12-18 2011/06

    Publisher: シーエムシー出版

    ISSN: 0286-4835

  38. Catalyst Development for the Hydrogenolysis of Biomass-Derived Chemicals to Value-Added Ones

    Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS SURVEYS FROM ASIA 15 (2) 111-116 2011/06

    DOI: 10.1007/s10563-011-9114-z  

    ISSN: 1571-1013

  39. Heterogeneous catalysis of the glycerol hydrogenolysis

    Yoshinao Nakagawa, Keiichi Tomishige

    CATALYSIS SCIENCE & TECHNOLOGY 1 (2) 179-190 2011

    DOI: 10.1039/c0cy00054j  

    ISSN: 2044-4753

  40. Biorefinary Building Blocks and Related Catalysis

    NAKAGAWA Yoshinao

    52 (8) 594-594 2010/12/10

    ISSN: 0559-8958

  41. Regioselective hydrogenolysis of polyalcohols over Re-modified Ir catalyst

    NAKAGAWA Yoshinao, SHINMI Yasunori, KOSO Shuichi, TOMISHIGE Keiichi

    52 (6) 417-419 2010/09/04

    Publisher: 触媒学会

    ISSN: 0559-8958

  42. Regioselective hydroxylation of alkanes catalyzed by a novel di-vanadium-substituted phosphotungstate

    KAMATA Keigo, YONEHARA Kazuhiro, NAKAGAWA Yoshinao, UEHARA Kazuhiro, MIZUNO Noritaka

    52 (6) 381-383 2010/09/04

    Publisher: 触媒学会

    ISSN: 0559-8958

  43. 1, 3-Dipolar cycloaddition of organic azides to alkynes by a dicopper-substituted polyoxometalate

    KAMATA Keigo, NAKAGAWA Yoshinao, YAMAGUCHI Kazuya, MIZUNO Noritaka

    51 (2) 159-161 2009/03/10

    Publisher: 触媒学会

    ISSN: 0559-8958

  44. 1,3-Dipolar Cycloaddition of Organic Azides to Alkynes by a Dicopper-Substituted Silicotungstate

    鎌田慶吾, 中川善直, 山口和也, 水野哲孝

    日本化学会講演予稿集 89th (1) 2009

    ISSN: 0285-7626

  45. High turnover numbers for the catalytic selective epoxidation of Alkenes with 1 atm of molecular oxygen (vol 40, pg 3639, 2001)

    Y. Nishiyama, Y. Nakagawa, N. Mizuno

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 46 (22) 4006-4006 2007

    ISSN: 1433-7851

  46. Divanadium-substituted Silicotungstate Immobilized on Surface Modified SiO_2 as a Heterogeneous Catalyst for Liquid-phase Oxidation with H_2O_2

    KASAI Jun, NAKAGAWA Yoshinao, UCHIDA Sayaka, YAMAGUCHI Kazuya, MIZUNO Noritaka

    48 (6) 424-426 2006/09/10

    Publisher: 触媒学会

    ISSN: 0559-8958

  47. Epoxidation of olefins with hydrogen peroxide catalyzed by γ-Keggin type divanadium-substituted polyoxotungstate

    中川善直, 鎌田慶吾, 小谷美友紀, 山口和也, 水野哲孝

    日本化学会講演予稿集 86th (1) 2006

    ISSN: 0285-7626

  48. Alkene Epoxidation with Hydrogen Peroxide Catalyzed by Vanadium-substituted Polyoxotungstates.

    中川善直, 鎌田慶吾, 住田康隆, 和田正大, 水野哲孝

    日本化学会講演予稿集 81st (1) 2002

    ISSN: 0285-7626

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Presentations 30

  1. ReOx/CeO2とReOx/Cの混合触媒による1,4-アンヒド ロエリスリトールから1,4-ブタンジオールのワンポット合成

    中川善直, 王天淼, 田村正純, 冨重圭一

    第125回触媒討論会 2020/03/27

  2. Demethoxylation of hydrogenated guaiacol in the absence of external hydrogen

    Yoshinao Nakagawa, Akari Miyagawa, Masazumi Tamura, Keiichi Tomishige

    5th International Congress on Catalysis for Biorefineries 2019 (CatBior V) 2019/09/25

  3. Pt-Pd触媒によるアルキルフェノールの側鎖酸化

    中川 善直, 徳間 健輔, 田村 正純, 冨重 圭一

    第51回酸化反応討論会 2018/11/01

  4. ReOx-Au/CeO2 触媒による脱酸素脱水反応

    中川 善直, 田沢 周平, 王 天淼, 田村 正純, 冨重 圭一

    第121回触媒討論会 2018/03/23

  5. 白金-バナジウム-炭素触媒によるジオールおよびケトールの酸素酸化

    関根 大, 小原 直之, 田村 正純, 冨重 圭一

    第50回酸化反応討論会 2017/11/11

  6. Oxidative C-C Cleavage Between Functionalized C Atoms with Pt-V-Activated Carbon Catalyst International-presentation

    Naoyuki Obara, Shota Hirasawa, Masazumi Tamura, Keiichi Tomishige

    25th North American Catalysis Society Meeting 2017/06/04

  7. Heterogeneous ceria-supported Re catalysts modified with noble metal for reduction of vicinal diols International-presentation

    Shuhei Tazawa, Nobuhiko Ota, Masazumi Tamura, Keiichi Tomishige

    APCAT-7 2017/01/17

  8. Conversion of cellulose to n-hexane or hexanols over Ir-ReOx/SiO2 catalyst in water-alkane solvents International-presentation

    Sibao Liu, Masazumi Tamura, Keiichi Tomishige

    International Congress on Catalysis 2016 2016/07/03

  9. Demethoxylation of lignin-model aromatics over carbon-supported rutheniumu-manganese catalyst International-presentation

    M.Ishikawa, M.Tamura, K.Tomishige

    Pacifichem 2015 2015/12/15

  10. 微量貴金属転化Ni/Mg/Al触媒によるバイオマスタールの酸化的水蒸気改質

    陳 金海, 田村 正純, 冨重 圭一

    第116回触媒討論会 2015/09/16

  11. 貴金属-イリジウム-レニウム触媒によるフルフラールから1,5-ペンタンジオールへのワンポット変換

    劉 斯宝, 天田靖史, 田村正純, 冨重圭一

    石油学会 第64回研究発表会 2015/05/27

  12. Partial hydrogenolysis of vicinal cis-diols over Pd-added W catalyst

    天田靖史, 太田伸彦, 田村正純, 冨重圭一

    日本化学会第95回春季年会 2015/03/26

  13. Production of Cyclohexanol from Methoxyphenols Over Ruthenium Catalyst Combined with Base International-presentation

    石川桃子, 田村正純, 冨重圭一

    Frontiers in Biorefining 2014 2014/10/21

  14. C-O結合直接水素化分解用Re修飾Ir触媒の開発

    第114回触媒討論会 2014/09/25

  15. Catalyst Materials for Glycerol Hydrogenolysis: Production of 1,3-Propanediol over Bimetallic Catalysts Composed of Noble Metal and Reducible Metal Oxide International-presentation

    The Eighth International Conference on the Science and Technology for Advanced Ceramics (STAC8) 2014/06/25

  16. Pd-W触媒による環状ジオールからモノオールへの選択的水素化分解反応

    天田靖史, 田村正純, 冨重圭一

    石油学会第63回研究発表会 2014/05/28

  17. Selective oxidation of glycerol to dihydroxyacetone over Pd-Ag alloy catalyst International-presentation

    Yoshinao Nakagawa, Shota Hirasawa, Keiichi Tomishige

    10th Congress on Catalysis Applied to Fine Chemicals 2013/06/16

  18. Re修飾Ir触媒を用いた糖および糖アルコールの水素化分解によるアルカン合成

    中川善直, 陳凱幼, 袁振楽, 田村正純, 冨重圭一

    石油学会第56回年会 2013/05/29

  19. 水素化分解反応によるバイオマス原料の有用化成品への変換

    日本エネルギー学会天然ガス部会科学分科会講演会 2012/12/07

  20. ニトリル類を脱水剤に用いたセリア触媒による二酸化炭素とメタノールからの炭酸ジメチル合成

    本田正義, 田村正純, 曽根原悟, 冨重圭一

    第110回触媒討論会 2012/09/24

  21. バイオマス由来有機分子の水素化分解反応による有用化成品合成

    平成24年度化学系学協会東北大会 2012/09/15

  22. Catalytic selective hydrogenolysis of glycerol to 1,3-propanediol International-presentation

    田村正純, 冨重圭一

    7th International Conference on Environmental Catalysis 2012/09/02

  23. Hydrogenolysis of glycerol into 1,3-propanediol over iridium-rhenium catalyst International-presentation

    Yasushi Adama, Keiichi Tomishige

    15th International Congress on Catalysis 2012 2012/07/01

  24. Catalytically active interface between iridium metal particles and rhenium oxide clusters for hydrogenolysis International-presentation

    Yasushi Amada, Keiichi Tomishige

    Internatioal Association of Colloid and Interface Scientists, 2012 Conference 2012/05/13

  25. C-O水素化分解用RhおよびIr触媒への第2金属添加作用

    高祖修一, 天田靖史, 陳凱幼, 冨重圭一

    第108回触媒討論会 2011/09/20

  26. 担持Ni-Pd合金触媒によるフラン類の完全水素化反応

    冨重圭一

    第107回触媒討論会 2011/03/29

    More details Close

    震災の影響により開催中止、ただし発表は有効。

  27. Direct hydrogenolysis of glycerol into 1,3-propanediol catalyzed by silica-supported rhenium-modified iridium nanoparticles International-presentation

    Yasunori Shinmi, Shuichi Koso, Keiichi Tomishige

    Pacifichem2010 2010/12/15

  28. Re添加Ir触媒による多価アルコールの位置選択的水素化分解反応

    新見泰規, 高祖修一, 冨重圭一

    第106回触媒討論会 2010/09/15

  29. Hydrogenolysis of Glycerol into 1,3-Propanediol over Rhenium-modified Iridium Catalyst International-presentation

    Yasunori Shinmi, Shuichi Koso, Keiichi Tomishige

    TOCAT6/APCAT5 2010/07/18

  30. Re酸化物修飾貴金属触媒によるグリセリンの水素化分解反応

    新見泰規, 冨重圭一

    石油学会第59回研究発表会 2010/05/20

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Industrial Property Rights 8

  1. テトラヒドロフラン化合物の製造方法、並びに水素化触媒及びその製造方法

    冨重圭一, 中川善直

    Property Type: Patent

  2. プロパンジオールの製造方法

    冨重圭一, 中川善直, 松田洋和, 内田敬之

    Property Type: Patent

  3. 1,4-アンヒドロエリスリトールの水素化分解物の製造方法

    冨重圭一, 中川善直, 梶川泰照, 平井雄一郎

    Property Type: Patent

  4. エリスリトールの水素化分解物の製造方法

    冨重圭一, 中川善直, 梶川泰照

    Property Type: Patent

  5. ポリオールの水素化分解物の製造方法

    冨重圭一, 中川善直, 梶川泰照, 松田洋和, 内田敬之, 平井雄一郎

    Property Type: Patent

  6. エリスリトールの水素化分解物の製造方法

    冨重圭一, 中川善直, 梶川泰照, 松田洋和, 内田敬之, 平井雄一郎

    Property Type: Patent

  7. カーバメートの製造方法

    安田浩, 冨重圭一, 中川善直

    Property Type: Patent

  8. 炭酸エステルの製造方法

    鈴木公仁, 中尾憲治, 藤本健一郎, 冨重圭一, 中川善直

    Property Type: Patent

Show all Show first 5

Research Projects 9

  1. ヒドリド還元を水素還元剤で実現する固体金属触媒の開発

    中川 善直

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業

    Category: 基盤研究(B)

    Institution: 東北大学

    2024/02/28 - 2026/03/31

  2. Synthesis of all C4 and C5 monools and diols

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: Tohoku University

    2020/04/01 - 2023/03/31

  3. リグノセルロースからのC6ジカルボン酸製造

    中川善直

    Offer Organization: 国立研究開発法人新エネルギー・産業技術総合開発機構

    System: 官民による若手研究者発掘支援事業・マッチングサポートフェーズ

    Institution: 東北大学

    2021/01 - 2023/01

  4. Establishing the methods for transformation of substituents of aromatics for total utilization of lignocellulose

    Nakagawa Yoshinao

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)

    Category: Grant-in-Aid for Scientific Research (C)

    Institution: Tohoku University

    2015/04/01 - 2018/03/31

    More details Close

    The purpose of this study is to develop transformation reactions of lignin fraction in lignocellulose, which is the most abundant renewable carbon resource. I used guaiacol and cresol as model substrates of mixture of decomposition products of lignin. I found several catalytic reactions, such as Ru + base catalysts for removal of methoxy group, vanadium catalysts for oxidation of hydrogenated derivatives of guaiacol into adipic acid, Pt catalysts for dehydrogenation-demethoxylation of the hydrogenated derivatives of guaiacol, and Pt-Pd catalysts for oxidation of the methyl substituent in cresol.

  5. Development of solid catalysts for selective transformation of peptide chains by reductive cleavage

    TAMURA Masazumi, TOMISHIGE Keiichi, NAKAGAWA Yoshinao

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Challenging Exploratory Research

    Institution: Tohoku University

    2015/04/01 - 2017/03/31

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    Protein(peptide) can be regarded as one of biomass-derived key materials, and can be obtained from green biomass. Therefore, development of transformation methods of protein is required. Dissociation of the amide bonds is one strategy for that, however, the methods that use stoichiometric amount of acids or bases are used as main ones, and alternative environmentally-benign methods are required. In this study, we investigated heterogeneous catalysts that enables direct cleavage of C-N bond in amide by hydrogenation, and found that N2-treated Ru/CeO2 catalyst showed high activity and selectivity for the reaction and that the small Ru particles over Ru/CeO2 are responsible active species for the high performance.

  6. Production of biomass-derived chemicals using intramolecular hydrogen transfer hydrogenolysis

    TOMISHIGE KEIICHI, NAKAGAWA YOSHINAO, TAMURA MASAZUMI

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Scientific Research (A)

    Institution: Tohoku University

    2014/04/01 - 2017/03/31

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    Organic chemicals including resins and polymers have been produced mainly from petrolium. In order to conduct a sustainable society, one of important subjects is the development of environment-bengin method for the production of chemicals. One of the remarkably efficient methods is the production of various chemicals from biomass is to recude the oxygen content in the biomass-derived substrate. Usually, high pressure hydrogen is used for the reduction. In this research, the purpose is to develop the catalysts for C-O hydrogenolysis using the intramolecular hydrogen transfer, and it is found that MoOx-modified Rh metal catalysts was very effective to this reaction system.

  7. Development of hydrodeoxygenation catalysts for conversion of biomass lignin

    NAKAGAWA Yoshinao

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Young Scientists (B)

    Category: Grant-in-Aid for Young Scientists (B)

    Institution: Tohoku University

    2011 - 2012

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    Hydrodeoxygenation of biomass-lignin-derived compounds has been investigated using guaiacol as a model substrate. Both multi-step process and single-step process were developed. The multi-step process involves steps using Rh catalyst, Ru catalyst, and Ir-ReOx catalyst. Cyclohexanol was obtained in good yield. The single-step process uses Ru catalyst and base co-catalyst, giving high yield of cyclohexanol.

  8. Development of selective oxidation catalysts with multi-core active center using a theoretical approach

    NAKAGAWA Yoshinao

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Young Scientists (B)

    Category: Grant-in-Aid for Young Scientists (B)

    2009 - 2010

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    Catalyses of polyoxometalate catalysts with di-vanadium core were investigated. The catalyst with phosphorous as a central atom showed high performance for both epoxidation of alkenes and hydroxylation of alkanes. Catalysts for selective oxidation of aqueous poly-ols were also investigated. The combination of silver and noble metal showed high performance.

  9. 酸化物クラスターの特長を生かした環境調和型の選択酸化反応系開発

    中川 善直

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 特別研究員奨励費

    Category: 特別研究員奨励費

    Institution: 東京大学

    2003 - 2004

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    工業的・有機合成的に重要なエポキシドを、アルケンと等量の過酸化水素を用いて高収率、高選択的に得るエポキシ化反応系の開発が求められている。バナジウム2置換ポリオキソメタレート[γ-H_2SiV_2W_<10>O_<40>]^<4->を触媒に用い過酸化水素を酸化剤としたアルケンのエポキシ化反応系について反応条件の最適化を行った。その結果、アセトニトリルとt-ブチルアルコールを混合した溶媒を用いた場合に、過酸化水素と基質を等量用いて1-オクテンなど反応性の低い末端アルケンのエポキシ化が選択率99%以上、収率90%以上で進行した。さらに、本反応系はジアステレオ選択的エポキシ化やジエンの位置選択的エポキシ化といった立体選択的反応においてきわめて大きな立体効果を示すことを見いだした((R)-(+)-リモネン基質で末端8,9-位への位置選択性:99%、3-メチルシクロヘキセン基質でのanti-エポキシドへのジアステレオ選択性:95%)。この立体効果は触媒の活性点であるV-(OH)_2-Vサイトを囲むポリオキソタングステート骨格に由来すると考えられる。さらに、速度論やNMR等を用いて反応機構を解析し、触媒のV-(OH)_2-Vサイトが過酸化水素と反応してヒドロペルオキソ種V-(OH)(OOH)-Vが生成し、次いでこのヒドロペルオキソ種を前駆体として活性種が生成しエポキシ化反応が進行する機構を推定した。

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Social Activities 2

  1. 東北大学サイエンスキャンパス運営

    東北大学サイエンスキャンパス

    2018/04/14 - 2020/01/18

  2. 第3回藻類バイオマス市民フォーラム

    2015/08/01 -

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    筑波大学・仙台市との共同プロジェクトである藻類バイオマスプロジェクトの内容と成果を市民に公開する。

Other 1

  1. 微生物変換と触媒技術を融合した基幹化合物の原料転換

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    これまで石油を原料として製造されている化成品を、未利用の廃グリセリンから製造する技術開発を行う。グリセリンをまずバイオ技術によって、汎用的な中間原料であるエリスリトールへと変換し、続いてさまざまな高価な原料を作り分けることができる触媒反応によって、ジオールなどの工業原料を生産する。担当項目は触媒反応の部分である。