Details of the Researcher

PHOTO

Rie Makiura
Section
Graduate School of Engineering
Job title
Professor
Degree

  • DSc (Kyushu University)

e-Rad No.
30457436

Research History 10

  • 2025/11 - Present
    Tohoku University　Department of Applied Chemistry　Professor

  • 2025/11 - Present
    Osaka Metropolitan University　Department of Materials Science　Visiting Professor

  • 2020/07 - Present
    Applied Surface Science, Elsevier　Editor

  • 2022/04 - 2025/10
    Osaka Metropolitan University　Department of Materials Science　Associate Professor

  • 2024/08 - 2025/08
    Stanford University　Department of Chemistry　Visiting Scholar

  • 2015/04 - 2022/03
    Osaka Prefecture University　Department of Materials Science　Associate Professor

  • 2012/10 - 2016/08
    JST　PRESTO researcher

  • 2010/04 - 2015/03
    Osaka Prefecture University　Research Organization for the 21st Century

  • 2007/06 - 2010/03
    Kyushu University　Department of Chemistry　Assistant Professor

  • 2002/04 - 2007/05
    Seiko Epson Corp.

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Education 2

  • University of Tsukuba　MSc

    2000/04 - 2002/03

  • University of Tsukuba　First Cluster of Colleges,College of Natural Sciences　Chemistry

    1996/04 - 2000/03

Professional Memberships 6

  • the American Chemical Society

    2021/10 - Present

  • 日本化学会 コロイドおよび界面化学部会

  • THE MATERIALS RESEARCH SOCIETY OF JAPAN

  • THE SOCIETY OF POLYMER SCIENCE, JAPAN

  • JAPAN SOCIETY OF COORDINATION CHEMISTRY

  • THE CHEMICAL SOCIETY OF JAPAN

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Research Interests 10

  • coordination polymer

  • thin film devices

  • nanoscience

  • nanostructure

  • metal-organic framework (MOF)

  • porous materials

  • air/liquid interfaces

  • nanosheets

  • metal complexes

  • nanomaterials

Research Areas 4

  • Nanotechnology/Materials / Nanomaterials /

  • Nanotechnology/Materials / Nanostructure chemistry /

  • Nanotechnology/Materials / Organic functional materials /

  • Nanotechnology/Materials / Inorganic and coordination chemistry / coordination chemistry

Awards 9

  1. 第62回高分子研究発表会 ヤングサイエンティスト講演賞

    2016/07　高分子学会関西支部　液相界面を利用した結晶性分子ナノシートのボトムアップ創製

  2. 第25回日本MRS年次大会 奨励賞

    2016/01　般社団法人 日本MRS　Bottom Up Assemblies of Highly-oriented Molecular Nanosheets with Regulated Nanopores Specifically Formed at Air/Liquid Interfaces

  3. 第8回資生堂 女性研究者サイエンスグラント受賞

    2015/06　資生堂女性研究者サイエンスグラント　気液界面における高配向性機能分子膜の形成過程の解明 （液体と気体の接する境目に分子を積み重ねる新材料開発）

  4. 文部科学大臣表彰 若手科学者賞

    2014/04　文部科学省　有機―無機複合ナノ構造体の構築と機能創出に関する研究

  5. H25年度日本化学会 女性化学者奨励賞

    2014/03　（社）日本化学会　有機－無機複合ナノ構造体の構築と機能創出

  6. 日本化学会第92春季年会 優秀講演賞（学術）

    2012/04　（社）日本化学会　気液界面を利用した配位高分子ナノシートの作製と結晶ドメインサイズの配位子依存性

  7. 講演奨励賞

    2009/09　（社）応用物理学会　ヨウ化銀ナノ粒子のイオン伝導性と相転移挙動

  8. 優秀講演賞（産業）

    2009/05　（社）日本化学会　ヨウ化銀ナノ粒子のイオン伝導性と相転移挙動

  9. Poster award

    2001/11　International Symposium on Cooperative Phenomena of Assembled Metal Complexes 実行委員会　Electronic state of a Halogen-Bridged Mixed-Valence Binuclear Complex, Ni2(dta)4I

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Papers 49

  1. Macroscopic Structural Transition of Nickel Dithiolate Capsule with Uniaxial Magnetic Anisotropy in Water Peer-reviewed

    Tomoko Fujino, Mafumi Hishida, Masatoshi Ito, Toshikazu Nakamura, Mizue Asada, Naoya Kurahashi, Hisao Kiuchi, Yoshihisa Harada, Koji Harano, Rie Makiura, Kanokwan Jumtee Takeno, So Yokomori, Hiroshi Oike, Hatsumi Mori

    Advanced Science　2025/08

    DOI： 10.1002/advs.202504967 　

  2. Influence of varying the nickel salt aqueous subphase on the formation of Ni3(hexaiminotriphenylene)2 metal–organic framework nanosheets at the air/liquid interface Peer-reviewed

    Kazuaki Tachimoto, Kanokwan Jumtee Takeno, Rie Makiura

    CrystEngComm　2025

    DOI： 10.1039/D5CE00630A 　

  3. (Invited) air/Liquid Interfacial Formation Process of Electrically Conductive Metal-Organic Framework Nanosheets Peer-reviewed

    Rie Makiura

    ECS Meeting Abstracts　2024/11/22

    Publisher: Elsevier {BV}

    DOI： 10.1149/MA2024-02372551mtgabs 　

  4. Self-Assembly of Peptide-Conjugated Forklike Mesogens at Aqueous/Liquid Crystalline Interfaces: Molecular Design for Ordering Transition Induced by Specific Binding of Biomolecules Peer-reviewed

    Junya Uchida, Anna Niwa, Mina Hasome, Rie Makiura, Nicholas L. Abbott, Takashi Kato

    ACS Applied Materials & Interfaces　2023/07/21

    Publisher: American Chemical Society (ACS)

    DOI： 10.1021/acsami.3c04289 　

    ISSN： 1944-8244

    eISSN： 1944-8252

  5. Assembling Triphenylene-Based Metal–Organic Framework Nanosheets at the Air/Liquid Interface: Modification by Tuning the Spread Solution Concentration Peer-reviewed

    Kazuaki Tachimoto, Takashi Ohata, Kanokwan Jumtee Takeno, Akihiro nomoto, Takeshi Watanabe, Ichiro Hirosawa, Rie Makiura

    Langmuir　39　(26)　8952-8962　2023/06/16

    Publisher: American Chemical Society ({ACS})

    DOI： 10.1021/acs.langmuir.2c02685 　

  6. Tunable electrical conductivity in covalent organic frameworks by intercalation of electron acceptor molecules Peer-reviewed

    Shintaro Toda, Kanokwan Jumtee Takeno, Rie Makiura

    Journal of Physics and Chemistry of Solids　181　111512-111512　2023/06/16

    Publisher: Elsevier {BV}

    DOI： 10.1016/j.jpcs.2023.111512 　

  7. Influence of the Solvent on the Assembly of Ni<inf>3</inf>(hexaiminotriphenylene)<inf>2</inf> MetalOrganic Framework Nanosheets at the Air/Liquid Interface Peer-reviewed

    Takashi Ohata, Kazuaki Tachimoto, Kanokwan Jumtee Takeno, Akihiro Nomoto, Takeshi Watanabe, Ichiro Hirosawa, Rie Makiura

    Bulletin of the Chemical Society of Japan　96　(3)　274-282　2023/03

    DOI： 10.1246/bcsj.20220283 　

    ISSN： 0009-2673

    eISSN： 1348-0634

  8. In situ grazing incidence X-ray diffraction measurement system for characterizations of hydrogen-bonded organic framework nanosheets assembled on the liquid surface with bending magnet-based X-ray source Peer-reviewed

    Rie Makiura

    JPS Conference Proceedings　2023

  9. Assembling Triphenylene-based Metal–Organic Framework Nanosheets at the Air/Liquid interface—Modification by Tuning the Spread Solution Concentration

    Kazuaki Tachimoto, Takashi Ohata, Kanokwan, Jumtee Takeno, Akihiro Nomoto, Takeshi Watanabe, Ichiro Hirosawa, Rie Makiura

    Langmuir　2023

  10. Ambipolar Nickel Dithiolene Complex Semiconductors: From One- to Two-Dimensional Electronic Structures Based upon Alkoxy Chain Lengths Peer-reviewed

    Masatoshi Ito, Tomoko Fujino, Lei Zhang, So Yokomori, Toshiki Higashino, Rie Makiura, Kanokwan Jumtee Takeno, Taisuke Ozaki, Hatsumi Mori

    Journal of the American Chemical Society　2022/12/13

    Publisher: American Chemical Society (ACS)

    DOI： 10.1021/jacs.2c08015 　

    ISSN： 0002-7863

    eISSN： 1520-5126

  11. Creation of metal–organic framework nanosheets by the Langmuir-Blodgett technique Peer-reviewed

    Rie Makiura

    Coordination Chemistry Reviews　469　214650-214650　2022/10

    Publisher: Elsevier {BV}

    DOI： 10.1016/j.ccr.2022.214650 　

    ISSN： 0010-8545

  12. Metal-organic Framework and Hydrogen-bonded Organic Framework Nanosheets Assembled at Air/Water Interfaces — Synthesis, Characterizations and Applications Peer-reviewed

    Rie Makiura

    Zeolite　2022/07/15

    DOI： 10.20731/zeoraito.39.3.96 　

    ISSN： 0918-7774

  13. Uniaxially Oriented Electrically Conductive Metal–Organic Framework Nanosheets Assembled at Air/Liquid Interfaces Peer-reviewed

    Takashi Ohata, Akihiro Nomoto, Takeshi Watanabe, Ichiro Hirosawa, Tatsuyuki Makita, Jun Takeya, Rie Makiura

    ACS Applied Materials & Interfaces　13　(45)　54570-54578　2021/11/17

    Publisher: American Chemical Society ({ACS})

    DOI： 10.1021/acsami.1c16180 　

    ISSN： 1944-8252

    eISSN： 1944-8252

  14. Direct causality between film formation and water-retaining effect of surfactant-based film-forming curing compound for concrete Peer-reviewed

    Yoko Ito, Yuya Sakai, Rie Makiura, Seunghyun Na, Taro Toyota

    Journal of Building Engineering　43　102930-102930　2021/11

    Publisher: Elsevier {BV}

    DOI： 10.1016/j.jobe.2021.102930 　

    ISSN： 2352-7102

  15. Air/water interfacial monolayer assembly of peptide-conjugated liquid-crystalline molecules Peer-reviewed

    Makiura, R., Niwa, A., Eimura, H., Uchida, J., Kato, T.

    Bulletin of the Chemical Society of Japan　94　(8)　2060-2067　2021

    Publisher: The Chemical Society of Japan

    DOI： 10.1246/bcsj.20210166 　

    ISSN： 1348-0634 0009-2673

    eISSN： 1348-0634

  16. (Invited) Liquid Phase Interfacial Assemblies of Porous Nanosheets with Controlled Orientation and Thickness

    Rie Makiura

    ECS Meeting Abstracts　2020/11/23

    DOI： 10.1149/MA2020-02301998mtgabs 　

  17. Heteroatom-Doped Carbon Electrocatalysts Derived from Nanoporous Two-Dimensional Covalent Organic Frameworks for Oxygen Reduction and Hydrogen Evolution Peer-reviewed

    Chao Yang, Shanshan Tao, Ning Huang, Xiaobin Zhang, Jingui Duan, Rie Makiura, Shinya Maenosono

    ACS Applied Nano Materials　3　(6)　5481-5488　2020/06/26

    Publisher: American Chemical Society ({ACS})

    DOI： 10.1021/acsanm.0c00786 　

    ISSN： 2574-0970

  18. 界面活性剤系被膜養生剤による水分蒸発抑制効果に関する研究 Water-Retaining Effect of Surfactant-Based Membrane-Forming Curing Compounds Peer-reviewed

    Rie Makiura

    第19回 コンクリート構造物の補修，補強，アップグレードシンポジウム　2019

  19. ブリュースター角顕微鏡による界面活性剤系被膜養生剤の観察 Peer-reviewed

    Rie Makiura

    生産研究　2019/01/01

    DOI： 10.11188/seisankenkyu.71.51 　

    ISSN： 0037-105X 1881-2058

  20. Controlled release of DNA from zinc and magnesium ion-doped hydroxyapatites Peer-reviewed

    Chie Kojima, Kenji Watanabe, Hidenobu Murata, Yuki Nishio, Rie Makiura, Katsuyuki Matsunaga, Atsushi Nakahira

    Research on Chemical Intermediates　45　(1)　23-32　2019/01

    DOI： 10.1007/s11164-018-3626-3 　

    ISSN： 0922-6168

    eISSN： 1568-5675

  21. Influence of solution pH and reaction atmosphere on the morphology of SrTiO3 nanocubes synthesized by thermohydrolysis Peer-reviewed

    Rie Makiura

    Research on Chemical Intermediates　44　(8)　1-8　2018/01/24

    DOI： 10.1007/s11164-018-3283-6 　

    ISSN： 1568-5675 0922-6168

  22. Structural Analysis of Molecular Naonsheets for Separation Membrane Assembled with a Bottom‒Up Approach at Liquid Interfaces Peer-reviewed

    Ohata T, Hirosawa I, Watanabe T, Makiura R

    SPring-8 / SACLA Research Report　6　(1)　137-140　2018

    Publisher: Japan Synchrotron Radiation Research Institute

    DOI： 10.18957/rr.6.1.137 　

  23. Air/Liquid Interfacial Nanoassembly of Molecular Building Blocks into Preferentially Oriented Porous Organic Nanosheet Crystals via Hydrogen Bonding Peer-reviewed

    Rie Makiura, Kohei Tsuchiyama, Ehmke Pohl, Kosmas Prassides, Osami Sakata, Hiroo Tajiri, Oleg Konovalov

    ACS NANO　11　(11)　10875-10882　2017/11

    DOI： 10.1021/acsnano.7b04447 　

    ISSN： 1936-0851

    eISSN： 1936-086X

  24. Solution-based sequential modification of LiCoO2 particle surfaces with iron(II) oxalate nanolayers Peer-reviewed

    Yuki Kishimoto, So Yubuchi, Akitoshi Hayashi, Masahiro Tatsumisago, Rie Makiura

    CRYSTENGCOMM　19　(29)　4175-4181　2017/08

    DOI： 10.1039/c7ce00552k 　

    ISSN： 1466-8033

  25. Optimization of dendrimer structure for sentinel lymph node imaging: Effects of generation and terminal group Peer-reviewed

    Yuichiro Niki, Mikako Ogawa, Rie Makiura, Yasuhiro Magata, Chie Kojima

    NANOMEDICINE-NANOTECHNOLOGY BIOLOGY AND MEDICINE　11　(8)　2119-2127　2015/11

    DOI： 10.1016/j.nano.2015.08.002 　

    ISSN： 1549-9634

    eISSN： 1549-9642

  26. External stimulation-controllable heat-storage ceramics Peer-reviewed

    Hiroko Tokoro, Marie Yoshikiyo, Kenta Imoto, Asuka Namai, Tomomichi Nasu, Kosuke Nakagawa, Noriaki Ozaki, Fumiyoshi Hakoe, Kenji Tanaka, Kouji Chiba, Rie Makiura, Kosmas Prassides, Shin-ichi Ohkoshi

    NATURE COMMUNICATIONS　6　2015/05

    DOI： 10.1038/ncomms8037 　

    ISSN： 2041-1723

  27. Liquid-phase step-by-step growth of an iron cyanide coordination framework on LiCoO2 particle surfaces Peer-reviewed

    Rie Makiura, Shingo Teragawa, Kohei Tsuchiyama, Akitoshi Hayashi, Kiyoharu Tadanaga, Masahiro Tatsumisago

    DALTON TRANSACTIONS　44　(34)　15279-15285　2015

    DOI： 10.1039/c5dt00968e 　

    ISSN： 1477-9226

    eISSN： 1477-9234

  28. Towards Rational Modulation of In-Plane Molecular Arrangements in Metal-Organic Framework Nanosheets Peer-reviewed

    Rie Makiura, Ryo Usui, Yuta Sakai, Akihiro Nomoto, Akiya Ogawa, Osami Sakata, Akihiko Fujiwara

    CHEMPLUSCHEM　79　(9)　1352-1360　2014/09

    DOI： 10.1002/cplu.201402150 　

    ISSN： 2192-6506

  29. Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks Peer-reviewed

    Rie Makiura, Ryo Usui, Ehmke Pohl, Kosmas Prassides

    CHEMISTRY LETTERS　43　(7)　1161-1163　2014/07

    DOI： 10.1246/cl.140275 　

    ISSN： 0366-7022

    eISSN： 1348-0715

  30. Micropattern Formation by Molecular Migration via UV-induced Dehydration of Block Copolymers Peer-reviewed

    Kenji Okada, Yasuaki Tokudome, Rie Makiura, Kristina Konstas, Luca Malfatti, Plinio Innocenzi, Hiroki Ogawa, Toshiji Kanaya, Paolo Falcaro, Masahide Takahashi

    ADVANCED FUNCTIONAL MATERIALS　24　(19)　2801-2809　2014/05

    DOI： 10.1002/adfm.201302812 　

    ISSN： 1616-301X

    eISSN： 1616-3028

  31. Toward step-by-step nuclear growth of surface two-dimensional porphyrin nanonetworks Peer-reviewed

    Rie Makiura, Hiroshi Kitagawa, Yasuyuki Akita, Mamoru Yoshimoto

    JOURNAL OF COLLOID AND INTERFACE SCIENCE　413　71-77　2014/01

    DOI： 10.1016/j.jcis.2013.09.024 　

    ISSN： 0021-9797

    eISSN： 1095-7103

  32. EQCM analysis of redox behavior of Prussian blue in a lithium battery electrolyte Peer-reviewed

    Shunsuke Yagi, Masaaki Fukuda, Rie Makiura, Tetsu Ichitsubo, Eiichiro Matsubara

    JOURNAL OF MATERIALS CHEMISTRY A　2　(21)　8041-8047　2014

    DOI： 10.1039/c4ta00410h 　

    ISSN： 2050-7488

    eISSN： 2050-7496

  33. Bottom-up assembly of ultrathin sub-micron size metal-organic framework sheets Peer-reviewed

    Rie Makiura, Oleg Konovalov

    Dalton Transactions　42　(45)　15931-15936　2013/12/07

    DOI： 10.1039/c3dt51703a 　

    ISSN： 1477-9226 1477-9234

  34. Preparation of hydroxyapatite-decorated poly(lactide-co-glycolide) microspheres for paclitaxel delivery Peer-reviewed

    Chie Kojima, Kenji Watanabe, Takashi Nagayasu, Yuki Nishio, Rie Makiura, Atsushi Nakahira

    Journal of Nanoparticle Research　15　(12)　2013/12

    DOI： 10.1007/s11051-013-2098-z 　

    ISSN： 1388-0764 1572-896X

  35. Interfacial growth of large-area single-layer metal-organic framework nanosheets Peer-reviewed

    Rie Makiura, Oleg Konovalov

    SCIENTIFIC REPORTS　3　2013/08

    DOI： 10.1038/srep02506 　

    ISSN： 2045-2322

  36. Single-Molecule Imaging of Gold-Binding Peptide Adsorbed on Au(111) Peer-reviewed

    Satoshi Kanata, Tomoaki Nishino, Rie Makiura, Sho Saiki, Nobuhiko Hayashi

    ANALYTICAL SCIENCES　29　(4)　405-409　2013/04

    DOI： 10.2116/analsci.29.405 　

    ISSN： 0910-6340

  37. Paclitaxel-loaded hydroxyapatite/collagen hybrid gels as drug delivery systems for metastatic cancer cells Peer-reviewed

    Kenji Watanabe, Yuki Nishio, Rie Makiura, Atsushi Nakahira, Chie Kojima

    International Journal of Pharmaceutics　446　(1-2)　81-86　2013/03/25

    DOI： 10.1016/j.ijpharm.2013.02.002 　

    ISSN： 0378-5173 1873-3476

  38. Designer coordination polymers: dimensional crossover architectures and proton conduction Peer-reviewed

    Teppei Yamada, Kazuya Otsubo, Rie Makiura, Hiroshi Kitagawa

    CHEMICAL SOCIETY REVIEWS　42　(16)　6655-6669　2013

    DOI： 10.1039/c3cs60028a 　

    ISSN： 0306-0012

  39. Nanoscale Effects on the Stability of the lambda-Ti3O5 Polymorph Peer-reviewed

    Rie Makiura, Yasuhiro Takabayashi, Andrew N. Fitch, Hiroko Tokoro, Shin-ichi Ohkoshi, Kosmas Prassides

    CHEMISTRY-AN ASIAN JOURNAL　6　(7)　1886-1890　2011/07

    DOI： 10.1002/asia.201100125 　

    ISSN： 1861-4728

  40. Highly Crystalline Nanofilm by Layering of Porphyrin Metal-Organic Framework Sheets Peer-reviewed

    Soichiro Motoyama, Rie Makiura, Osami Sakata, Hiroshi Kitagawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　133　(15)　5640-5643　2011/04

    DOI： 10.1021/ja110720f 　

    ISSN： 0002-7863

    eISSN： 1520-5126

  41. Highly-ordered porous coordination polymer nanofilms grown by layer-by-layer deposition technique Peer-reviewed

    Rie Makiura, Hiroshi Kitagawa

    Materials Research Society Symposium Proceedings　1312　491-496　2011

    DOI： 10.1557/opl.2011.1 　

    ISSN： 0272-9172

  42. Self-assembly of highly crystalline two-dimensional MOF sheets on liquid surfaces Peer-reviewed

    Rie Makiura, Kohei Tsuchiyama, Osami Sakata

    CRYSTENGCOMM　13　(18)　5538-5541　2011

    DOI： 10.1039/c1ce05684k 　

    ISSN： 1466-8033

  43. Porous Porphyrin Nanoarchitectures on Surfaces Peer-reviewed

    Rie Makiura, Hiroshi Kitagawa

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY　(24)　3715-3724　2010/08

    DOI： 10.1002/ejic.201000730 　

    ISSN： 1434-1948

  44. Surface nano-architecture of a metal-organic framework Peer-reviewed

    Rie Makiura, Soichiro Motoyama, Yasushi Umemura, Hiroaki Yamanaka, Osami Sakata, Hiroshi Kitagawa

    NATURE MATERIALS　9　(7)　565-571　2010/07

    DOI： 10.1038/NMAT2769 　

    ISSN： 1476-1122

    eISSN： 1476-4660

  45. Assembly of a Highly-Ordered Nanofilm Comprised of Molecular Frameworks and Surface/Interface Structural Study Peer-reviewed

    Rie MAKIURA, Hiroshi KITAGAWA

    Nihon Kessho Gakkaishi　52　(6)　295-300　2010

    Publisher: The Crystallographic Society of Japan

    DOI： 10.5940/jcrsj.52.295 　

    ISSN： 1884-5576

    More details Close

    The rational assembly of ultrathin films of metal-organic frameworks (MOFs) —highly ordered microporous materials— with well-controlled growth direction and film thickness is a critical and as yet unrealised issue for enabling the use of MOFs in nanotechnological devices, such as sensors, catalysts, and electrodes for fuel cells. Here we explain our recent success of the facile bottom-up fabrication of such a perfect preferentially-oriented MOF nanofilm on a solid surface (NAFS-1), consisting of metalloporphyrin building units. The assembly of NAFS-1 was achieved by the unconventional integration in a modular fashion of a layer-by-layer (LbL) growth technique coupled with the Langmuir-Blodgett (LB) method. NAFS-1 is endowed with highly crystalline order both in the out-of-plane and in-plane orientations to the substrate, as determined by synchrotron X-ray surface crystallography. We expect that the versatility of the solution-based growth strategy presented here will allow the fabrication of various well-ordered MOF nanofilms, opening the way for their use in a range of important applications.

  46. Size-controlled stabilization of the superionic phase to room temperature in polymer-coated AgI nanoparticles Peer-reviewed

    Rie Makiura, Takayuki Yonemura, Teppei Yamada, Miho Yamauchi, Ryuichi Ikeda, Hiroshi Kitagawa, Kenichi Kato, Masaki Takata

    NATURE MATERIALS　8　(6)　476-480　2009/06

    DOI： 10.1038/NMAT2449 　

    ISSN： 1476-1122

  47. Structural Evaluation of an Iron Oxalate Complex Layer Grown on an Ultra-smooth Sapphire (0001) Surface by a Wet Method Peer-reviewed

    R. Haruki, O. Sakata, T. Yamada, K. Kanaizuka, R. Makiura, Y. Akita, M. Yoshimoto, H. Kitagawa

    TRANSACTIONS OF THE MATERIALS RESEARCH SOCIETY OF JAPAN, VOL 33, NO 3　33　(3)　629-631　2008

  48. Electronic state of a halogen-bridged mixed-valence binuclear complex, Ni-2(dta)(4)I Peer-reviewed

    R Makiura, H Kitagawa, R Ikeda

    MOLECULAR CRYSTALS AND LIQUID CRYSTALS　379　309-314　2002

    DOI： 10.1080/10587250290090651 　

    ISSN： 1058-725X

  49. An unusual six-co-ordinate platinum(II) complex containing a neutral I-2 ligand Peer-reviewed

    R Makiura, Nagasawa, I, N Kimura, S Ishimaru, H Kitagawa, R Ikeda

    CHEMICAL COMMUNICATIONS　17　(17)　1642-1643　2001/09

    DOI： 10.1039/b103648n 　

    ISSN： 1359-7345

Show all ︎Show first 5

Misc. 11

  1. Soft organic paramagnet in water: a supramolecular approach based on amphiphilic nickel dithiolene complex salt

    藤野智子, 菱田真史, 伊藤雅聡, 中村敏和, 浅田瑞枝, 倉橋直也, 木内久雄, 原田慈久, 原野幸治, 牧浦理恵, 武野カノクワン, 横森創, 大池広志, 森初果

    日本化学会春季年会講演予稿集(Web)　105th　2025

  2. Soft organic paramagnet in water: a supramolecular approach based on amphiphilic nickel dithiolene complex salt

    藤野智子, 菱田真史, 伊藤雅聡, 中村敏和, 浅田瑞枝, 倉橋直也, 木内久雄, 原田慈久, 原野幸治, 牧浦理恵, 武野カノクワン, 横森創, 大池広志, 森初果

    日本物理学会講演概要集(CD-ROM)　80　(1)　2025

    ISSN： 2189-079X

  3. 多孔性ナノシート材料の水面合成と機能

    牧浦理恵

    機能材料　43　(2)　51-62　2023/02

  4. Interfacial Bottom-up Assembly of Molecular Building Blocks Into Highly-oriented Crystalline Nanosheets

    67　(4)　237-243　2016

    Publisher: 小峰工業出版

    ISSN： 0451-2014

  5. 規則ナノ細孔を有する分子ナノシートの液相界面ボトムアップ合成

    牧浦 理恵

    C&I Commun.　41　(3)　19-21　2016

    Publisher: 日本化学会コロイドおよび界面化学部会

  6. Surface molecular architecture : Highly-crystalline metal-organic framework nanofilms assembled by Langmuir-Blodgett and Layer-by-Layer method

    R. Makiura, H. Kitagawa

    SPring-8 Research Frontier　94-95　2010

  7. HEADLINE REVIEW "ナノテクによる安全で高性能な新しい電池の開発へ道"

    牧浦 理恵, 北川 宏

    OHM　96　2009/12

  8. トピックス "ナノ粒子のサイズ制御で室温超イオン伝導を実現"

    牧浦 理恵, 北川 宏

    CERAMICS JAPAN　44　646　2009/08

  9. Ionics and Hydrogen in Nanoparticles

    R. Makiura, H. Kobayashi, H. Kitagawa

    Kyushu University Global-COE program, Science for Future Molecular Systems, Journal　3　21-29　2009

  10. AgI nanoplarticles : Size-controlled stabilisation of the superionic phase to room temperature

    R. Makiura, H. Kitagawa, K. Kato

    SPring-8 Research Frontier 2009　100-101　2009

  11. Structural study of an iron oxalate and a copper rubeanate layer on an ultra-smooth sapphire c-face

    Rie Haruki, Osami Sakata, Teppei Yamada, Katsuhiko Kanaizuka, Rie Makiura, Yasuyuki Akita, Mamoru Yoshimoto, Hiroshi Kitagawa

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES　64　C399-C400　2008

    DOI： 10.1107/S0108767308087205 　

    ISSN： 2053-2733

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Books and Other Publications 7

  1. Frontier chemistry of nano-metal complexes

    Rie Makiura

    2022/07/29

    ISBN: 4782708017

  2. ポストグラフェン材料の創製と用途開発最前線 : 二次元ナノシートの物性評価、構造解析、合成、成膜プロセス技術、応用展開

    牧浦理恵

    エヌ・ティー・エス　2020/04

    ISBN: 9784860436575

  3. ＰＣＰ／ＭＯＦおよび各種多孔質材料の 作り方，使い方，評価解析

    牧浦理恵 他

    2019/10

  4. CSJカレントレビューシリーズNo.25 "2次元物質の化学"

    牧浦理恵, 大坪主弥, 北川宏

    化学同人　2017

  5. イオン伝導体の材料技術と測定方法

    牧浦理恵, 北川 宏

    サイエンス＆テクノロジー　2011

  6. 触媒年鑑：触媒技術の動向と展望

    山田 鉄兵, 北川 宏, 牧浦 理恵

    2011

  7. Molecular Technology: Life Innovation

    牧浦 理恵

    Wiley

Show all Show first 5

Industrial Property Rights 46

  1. FINE SOLID SOLUTION ALLOY PARTICLES AND METHOD FOR PRODUCING SAME

    KITAGAWA, Hiroshi, KUSADA, Kohei, MAKIURA, Rie

    Property Type: Patent

  2. 固溶体型合金微粒子

    北川 宏, 草田 康平, 牧浦 理恵

    特許5774756

    Property Type: Patent

  3. Three-dimensional structure and method of producing the same

    R. Makiura, H. Kitagawa

    Property Type: Patent

  4. FINE SOLID SOLUTION ALLOY PARTICLES AND METHOD FOR PRODUCING SAME

    KITAGAWA, Hiroshi, KUSADA, Kohei, MAKIURA, Rie

    Property Type: Patent

  5. Silver iodide fine particle, methods for producing the same, and electrochemical device using the same

    Property Type: Patent

  6. Organometallic complex, three－dimensional structure and production method of these

    Property Type: Patent

  7. 液状材料

    牧浦 理恵, 奥山 智幸, 川瀬 健夫, 納戸 光治, 林田 剛, 後藤 康之

    特許4990264

    Property Type: Patent

  8. Light-emitting element, light-emitting device and electronic apparatus

    Makiura Rie

    Property Type: Patent

  9. Thin film transistor, electronic circuit, display device, and electronic device

    Makiura Rie

    Property Type: Patent

  10. Manufacturing method of light emitting device, light emitting device, and electronic device

    Makiura Rie

    Property Type: Patent

  11. Manufacturing method of transistor, transistor, transistor circuit, electronic device, and electronic instrument

    Property Type: Patent

  12. 有機発光素子の製造方法

    牧浦 理恵, 奥山 智幸, 川瀬 健夫, 納戸 光治, 林田 剛, 後藤 康之

    特許4273132

    Property Type: Patent

  13. Organic-inorganic composite semiconductor material, liquid material, organic light emitting element, method of manufacturing organic light emitting element, light emitting device and electronic apparatus

    R. Makiura, T. Okuyama, T. Kawase, M. Noto, T. Hayashida, Y. Goto

    Property Type: Patent

  14. Organic electroluminescence device, its driving method and electronic equipment

    Property Type: Patent

  15. Organic Light-Emitting , Method Of Manufacturing Light-Emitting Element, Light-Emitting Device, and Electronic Apparatus

    R. Makiura, T. Okuyama, T. Kawase

    Property Type: Patent

  16. Light－emitting element, method for manufacturing same, light－emitting device, and electronic equipment

    Property Type: Patent

  17. Manufacturing method of light－emitting element, and light emitting device and electronic equipment

    Makiura Rie

    特許4479642

    Property Type: Patent

  18. Organic electroluminescence device, electronic device manufacturing method of the organic electroluminescence device, and manufacturing method thereof

    Makiura Rie

    Property Type: Patent

  19. Organic light emitting element, method for manufacturing same, light emitting device and electronic apparatus

    特許4548301

    Property Type: Patent

  20. Wiring board, manufacturing method of wiring board, electro－optical device, and electronic equipment

    Makiura Rie

    Property Type: Patent

  21. METHOD OF MANUFACTURING LIGHT-EMITTING ELEMENT, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE AND ELECTRONIC APPARATUS (Methods of manufacturing light-emitting element including anode buffer layer formation from polysiloxane precursors.)

    Makiura Rie

    Property Type: Patent

  22. Electroluminescence device, an electronic equipment, and methods of manufacturing the same

    Makiura Rie

    Property Type: Patent

  23. Organic el device and method of manufacturing organic el device

    Makiura Rie

    Property Type: Patent

  24. Organic electro luminescent device and method of manufacturing organic electro luminescent device

    Makiura Rie

    Property Type: Patent

  25. Organic el device, driving method thereof, and electronic device

    特許4462081

    Property Type: Patent

  26. Organic electro-luminescence device, driving method thereof and electronic apparatus.

    H. Hara, R. Makiura

    Property Type: Patent

  27. Organic el device, its driving method and electronic apparatus

    Property Type: Patent

  28. Organic electroluminescence device, method for driving thereof, and electronic appliance.

    H. Hara, R. Makiura

    Property Type: Patent

  29. Organic el device and electronic equipment

    Property Type: Patent

  30. Organic el device, and electronic appliance

    Property Type: Patent

  31. Organic el device and electronic apparatus

    Property Type: Patent

  32. Thin-film forming method, thin－film device, and electronic apparatus

    Property Type: Patent

  33. Thin-film forming method, thin－film device and electronic device

    特許4581652

    Property Type: Patent

  34. Organic el device and electronic apparatus

    Makiura Rie

    特許4622357

    Property Type: Patent

  35. Organic el device, its manufacturing method, and electronic equipment

    Property Type: Patent

  36. Method of forming thin film of organometallic compound, thin film of organometallic compound, method of manufacturing organoelectronic device equipped with the same, organoelectronic device, method of manufacturing organic electroluminescence, organic electroluminescence, and electronic apparatus

    T. Takashima, K. Morii, H. Hokari, R. Makiura

    Property Type: Patent

  37. Organic light-emitting device, manufacturing method thereof, and electronic apparatus thereof

    K. Morii, T. Takashima, H. Hokari, R. Makiura

    Property Type: Patent

  38. Organic electroluminescence apparatus, method of manufacturing organic electroluminescence apparatus and electronic apparatus

    Property Type: Patent

  39. Method for forming thin film of organometallic compound, organometallic thin film, method for manufacturing organic electronic device equipped with the same, organic electronic device and method for manufacturing organic electroluminescence, organic electroluminescence, and electronic equipment

    Property Type: Patent

  40. Organic el device, manufacturing method of the same, and electronic apparatus

    Property Type: Patent

  41. Organic electroluminescent device, manufacturing method of organic electroluminescent el device, and electronic equipment.

    Property Type: Patent

  42. Organic electroluminescent device, manufacturing method of organic electroluminescent device, and electronic equipment

    Property Type: Patent

  43. Manufacturing method for organic electroluminescence device, and electronic device therewith

    T. Takashima, S. Takei, K. Morii, H. Hokari, R. Makiura, S. Shuich

    Property Type: Patent

  44. Manufacturing method of organic el device, and electronic equipment

    特許4830254

    Property Type: Patent

  45. 3次元構造体およびその製造方法

    牧浦 理恵, 北川 宏

    特許5531027

    Property Type: Patent

  46. 固溶体型合金微粒子からなる微粒子群の製造方法

    北川 宏, 草田 康平, 牧浦 理恵

    特許5639045

    Property Type: Patent

Show all Show first 5

Research Projects 27

  1. Development of ultrathin nanosheets with regulated nanopores towards realization of ultimate gas separation performance

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: Osaka Metropolitan University

    2024/04/01 - 2028/03/31

  2. Creation of ultrathin films composed of multiply programmed layers by air/liquid interfacial synthesis

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Transformative Research Areas (B)

    Institution: Osaka Metropolitan University

    2025/04 - 2028/03

  3. Coordinating Group for Multiply programmed Layers: Advanced Functionalities in Ultrathin Films through Electronic and Lattice Degree of Freedom Control

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Transformative Research Areas (B)

    Institution: The University of Tokyo

    2025/04 - 2028/03

  4. Metal-organic framework nanosheets: Establishing liquid interfacial synthesis and understanding electronic properties

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Fund for the Promotion of Joint International Research (Fostering Joint International Research)

    Institution: Osaka Metropolitan University

    2024 - 2026

  5. 選択的分子捕捉と信号伝達の両者を担う革新的ナノポア配位高分子シートセンサの創製

    牧浦 理恵

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業

    Category: 挑戦的研究(萌芽)

    Institution: 大阪公立大学

    2023/06 - 2025/03

  6. Design of Molecules and Construction of Molecular Assemblies for the Development of Aquatic Functional Materials

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    Institution: The University of Tokyo

    2019/06 - 2024/03

  7. porous electrically conductive coordination polymer nanosheets for highly selective / sensitive sensing Competitive

    Makiura Rie

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Challenging Exploratory Research

    Institution: Osaka Prefecture University

    2016/04 - 2021/03/31

    More details Close

    Metal-organic frameworks (MOFs) composed of metal ions and organic ligands possess regulated nanopores and their electronic properties can be controlled by varying the combination of the components. Electrically conductive MOFs are expected to show new functionalities generated from interaction of guest molecules into framework electronic properties and application of MOFs in nanosheet states will open further up their use in varied applications including thin film electronic devices. The aim of this work is to create highly-oriented conductive MOF nanosheets and reveal their electronic properties. Air/liquid interfacial synthesis was applied for creating highly-oriented MOF nanosheets composed of triphenylene derivatives with high π electron activity and transition metal ions. The planar electric conductivity of the nanosheets recorded as highest in related MOF nanosheets.

  8. Bottom-up synthesis of molecular nanosheets with size-regulated nanopores: development of interfacial synthetic methodology and separation membrane application Competitive

    Makiura Rie

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Young Scientists (A)

    Institution: Osaka Prefecture University

    2016/04 - 2021/03/31

    More details Close

    The development of separation membranes with high selectivity and high permeability is strongly desired in the environmental, energy, and chemical industries, where separation and purification operations are essential. In this study, we aimed to develop ideal membranes for the ultimate separation performance, i.e., ultra-thin nanosheets with regular nanopores. We succeeded in creating molecular nanosheets with the targeted nanopore structure by assembling organic molecules with rich structural design bottom-up two-dimensionally through interfacial reactions between the air and liquid phases. We systematically varied the conditional factors that affect the nanosheet formation crystallinity.

  9. Hetero-interfacial synthesis of porous molecular nanosheets towards separation membrane

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Scientific Research (B)

    2020/04 - 2024/03/31

  10. ガス分離膜の超高性能化を目指した多孔性分子ナノシートの液相界面合成

    Offer Organization: 一般社団法人増屋記念基礎研究振興財団

    System: 研究助成金

    2019/06 - 2020/03

  11. 水圏機能材料（計画研究、領域立ち上げ）

    Offer Organization: （独）日本学術振興会

    System: 科学研究費補助金 新学術

    2019/07 -

  12. Synthesis of effective photosensitizer accumulating in cancer for photo dynamic therapy

    Nomoto Akihiro

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Scientific Research (B)

    2019/04 - 2023/03/31

    More details Close

    In this study, we focused on photodynamic therapy PDT which has a low-invasive treatment for the children’s or elderly’s body, and we conducted the development of new agents for next-generation PDT treatment. The introduction of sugar chains into the chlorin skeleton of PDT agents may lead to improvement of the uptaking into tumor cells and the generation the singlet oxygen based on the heavy atom effect. We proceeded with dye syntheses for PDT agents and prepared some new agents that have a good tumor cell-killing effect or adsorption ability of light with a longer wavelength. By utilizing the reactivity of heteroatoms for the formation of the molecular skeleton, we have established a synthesis method applicable to a practical synthesis scale, and are expected to be new PDT agents.

  13. 高性能分離膜応用を目指した多孔性分子ナノシートの液相ボトムアップ創製 Competitive

    牧浦 理恵

    Offer Organization: （公益財団）マツダ財団

    System: 第33回（2017年度）マツダ研究助成

    2017/12 -

  14. 全固体リチウムイオン二次電池の性能向上に向けた金属錯体ナノ薄層による電極活物質表面の修飾 Competitive

    牧浦 理恵

    Offer Organization: （一般財団）イオン工学振興財団

    System: 研究助成金

    2015/09 - 2017/03

  15. 電子状態が段階的・可逆的に制御可能な配位高分子ナノシートの創製 Competitive

    牧浦 理恵

    Offer Organization: （公益財団）村田学術振興財団

    System: 研究助成金

    2015/06 - 2016/05

  16. 気液界面における高配向性機能分子膜の形成過程の解明 Competitive

    牧浦 理恵

    Offer Organization: 資生堂 女性研究者 サイエンスグラント

    System: 研究助成金

    2015/06 - 2016/05

  17. 全固体電池チーム Competitive

    Offer Organization: （独）科学技術振興機構

    System: 特別重点技術領域 ALCA

    2012/10 - 2016/03

  18. 液相界面を利用した高配向性機能分子膜の創製 Competitive

    牧浦 理恵

    Offer Organization: （独）科学技術振興機構

    System: 戦略的創造研究推進事業 さきがけ

    2012/10 - 2016/03

  19. 固体界面を制御した全固体二次電池の創製 Competitive

    Offer Organization: （独）科学技術振興機構

    System: 戦略的創造研究推進事業 CREST

    2010/10 - 2016/03

  20. 気液界面を利用した階層的配位高分子ナノ構造の構築と機能開拓 Competitive

    牧浦 理恵

    Offer Organization: （独）日本学術振興会

    System: 科学研究費補助金 新学術領域研究

    Category: 新学術領域研究(研究領域提案型)

    Institution: 大阪府立大学

    2012/04 - 2014/03

    More details Close

    原子・分子スケールの厚みを有する２次元ナノシートは、その次元性に由来した特殊な電子状態など基礎物性研究の観点、および分子デバイスへの適用という応用の面で注目を集めている。一方で、有機分子が金属イオンとの配位結合を介し連結した３次元ネットワーク構造を有する配位高分子は、様々な金属イオンと有機配位子の組み合わせが可能なことから設計性や物質群としての多様性に優れ、多くの新規化合物が合成されている。本件においては、分子１層の厚みを有する大面積の配位高分子２次元ナノシートを得ることを目的に、気液界面におけるナノシートの形成過程を明らかにしシート作製時の種々の条件が分子の配列状態にどのような影響を及ぼすかを詳細に調べた。 トラフ（浅い容器）を硝酸銅水溶液で満たした後、その表面に金属と結合可能なカルボキシル基を有するポルフィリン（MTCPP）の溶液を展開した。表面圧を測定しながら液表面を棒（バリア）で圧縮することによりナノシート（NAFS-13と呼ぶ）を作製した。放射光X線を用いたその場X線回折（XRD）測定により、液面上に形成したNAFS-13ナノシートの面内（in-plane）XRD測定を行った。また、MTCPPを液面に展開後、表面をバリアで圧縮する過程において平均分子占有面積（a）に対する表面圧（π）の変化（π-a isotherms）を調べた。表面圧が0 mN/mの状態においても結晶性に由来する反射ピークが観測されたことから、液面上でMTCPPと金属イオンとの間に配位結合が生じ、表面の圧縮なしに自発的に結晶性のナノシートが形成されていることが示唆された。 上述のナノシート形成過程に関する知見をもとに、シート作製方法を改良することで、よりサイズが大きく均一なナノシートを作製することに成功した。

  21. 金属錯体の三次元配列制御による高効率光電変換ナノ材料の創製 Competitive

    牧浦 理恵

    Offer Organization: （公益財団）稲盛財団

    System: 研究助成金

    2012/04 - 2014/03

  22. 配位化合物を基盤材料とした多孔性ナノ薄膜の細孔構造制御と大面積化 Competitive

    牧浦 理恵

    Offer Organization: （公益財団）花王芸術・科学財団

    System: 研究助成金 科学技術部門

    2012/04 - 2013/03

  23. 金属錯体の三次元配列制御による高効率光電変換ナノ材料の創製 Competitive

    牧浦 理恵

    Offer Organization: （公益財団）国際科学技術財団

    System: 研究助成金 「環境、エネルギー、社会基盤」分野

    2012/01 - 2013/03

  24. Interfacial control and phase transition behavior of superionic nanoparticles Competitive

    MAKIURA Rie

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research

    Category: Grant-in-Aid for Young Scientists (B)

    Institution: Osaka Prefecture University

    2010/04 - 2012/03

    More details Close

    Nanoscale effects on ionic conduction of organic-inorganic hybrid nanoparticles have been examined. As a result, it was found that high ionic conductivity of the nanoparticles remains even low temperatures below 0℃.

  25. 配位高分子を基盤材料とした多孔性ナノ薄膜の構築と機能開拓 Competitive

    牧浦 理恵

    Offer Organization: （独）日本学術振興会

    System: 科学研究費補助金 新学術領域研究

    Category: 新学術領域研究(研究領域提案型)

    Institution: 大阪府立大学

    2010/04 - 2012/03

    More details Close

    本研究の第一の目的は、有機配位子(MBU : molecular building unit)と金属イオンとの間に形成される配位結合を巧みに利用し、配列が制御された多孔性の薄膜をナノスケールで作製する合理的手法を確立することである。また、創製した薄膜の構造や特性を詳細に調べることで、ナノスケールで起こる新しい現象や機能を開拓するとともに、センサなどの素子としての応用の可能性を探る。これまでに、溶液プロセスを基盤とした分子ボトムアップ手法により高い結晶性を有する配位高分子ナノ膜の作製に成功した。液面を利用してLangmuir-Blodgett(LB)法により配位高分子ナノシートを形成し、このシートを固体基板に移しとる工程を繰り返すことで、1層ずつ、すなわちLayer-by-Layerでシートを積層することができ、得られた薄膜は面外、面内共に結晶性であることがわかった。 本年度においては、配位高分子の面内の格子サイズを制御することを目的とし、MBUとして様々な大きさのポルフィリン誘導体を用いてナノシート及びその積層を行い、その結晶構造を調べた。また、液面で放射光XRD測定を行うことで、液面上で構成要素である有機配位子と金属イオンが配位結合を生じ規則配列しながらナノシートが形成する過程を詳細に調べた。 液面において結晶性のナノシートが形成する過程に関して詳細に調べるために、液面上で放射光XRD測定を行った。展開液にMBUであるポルフィリンの溶液、下層液に硝酸銅水溶液を用い、回折計に設置されたトラフ上にナノシートの作製を行った。表面をバリアで圧縮する過程において得られた分子占有面積に対する表面圧の変化(π-a isotherms)を調べた。表面圧の異なるいくつかの点においてin-plane XRD測定を行った結果、表面圧が低い場合においても結晶性に由来する反射ピークが観測されたことから、液面上でMBUと金属イオンとの間に配位結合が生じ、表面の圧縮なしに自発的に結晶性のナノシートが形成されていることが示唆された。

  26. 逐次積層法による金属錯体ナノ薄膜の構築 Competitive

    Offer Organization: （独）科学技術振興機構

    System: 戦略的創造研究推進事業 CREST

    2010/04 - 2012/03

  27. 全固体電池実現に向けた銀系イオン伝導物質の開発 Competitive

    牧浦 理恵

    Offer Organization: （独）科学技術振興機構

    System: 研究成果最適支援事業(A-STEP)

    2010/10 - 2011/03

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