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Hiroshi Jinnai

Section

Institute of Multidisciplinary Research for Advanced Materials

Job title

Professor

Degree

工学修士（京都大学）
博士（工学）（京都大学）

researchmap

https://researchmap.jp/hjinnai27

J-GLOBAL ID

201801008136376968

Research History 15

2024/10 - Present

Japan Science and Technology Agency　Core Research for Evolutional Science and Technology (CREST)　Principle Researcher
2016/01 - Present

POLYMER (Editor), Elsevier　POLYMER　Editor
2015/04 - Present

Tohoku University　Institute of Multidisciplinary Research for Advanced Materials
2019/10 - 2025/03

Japan Science and Technology Agency　Core Research for Evolutional Science and Technology (CREST)　Principle Researcher
2011/04 - 2015/03

Kyushu University　Institute for Materials Chemistry and Engineering
2011/04 - 2014/03

Kyushu University
2011/04 - 2014/03

科学技術振興機構　高原ソフト界面プロジェクト　技術参事＆グループリーダー
2007/04 - 2014/03

理化学研究所　播磨研究所　客員研究員（兼任）
2009/04 - 2012/03

Tohoku University
2007/04 - 2011/03

Kyoto Institute of Technology
2006/04 - 2007/03

Kyoto Institute of Technology
2002/11 - 2006/03

Kyoto Institute of Technology
1998/08 - 2002/10

Kyoto Institute of Technology
1993/10 - 1998/08

科学技術振興事業団　橋本相分離構造プロジェクト　グループリーダー
1993/04 - 1993/09

日本学術振興会　京都大学工学研究科　特別研究員(PD）

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Education 3

Kyoto University

1990/04 - 1993/03
Kyoto University

1988/04 - 1990/03
Kyoto University　Faculty of Engineering

1984/04 - 1988/03

Committee Memberships 5

The Japanese Society of Microscopy　Presidnt

2025/06 - Present
公益社団法人日本顕微鏡学会　学会連携推進委員長(材料)

2021 - Present
公益社団法人日本顕微鏡学会　ソフトマテリアル分科会責任者

2020 - Present
公益社団法人日本顕微鏡学会　代議員

2017 - Present
公益社団法人高分子学会　東北支部常任幹事

2016 - Present

Professional Memberships 8

THE ROYAL SOCIETY OF CHEMISTRY

2022/05 -
Sigma Xi Scientific Research Honor Society

2021/07 -
アメリカ物理学会

2011 -
ドイツ顕微鏡学会

2007 -
アメリカ化学会

2005 -
THE JAPANESE SOCIETY OF MICROSCOPY

2004 -
THE SOCIETY OF POLYMER SCIENCE, JAPAN

1994 -
THE SOCIETY OF RUBBER SCIENCE AND TECHNOLOGY

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Research Interests 2

Electron Microscopy
Polymer Physics

Research Areas 4

Nanotechnology/Materials / Applied physics - general /
Nanotechnology/Materials / Polymer materials /
Nanotechnology/Materials / Nanostructure physics /
Nanotechnology/Materials / Nanomaterials /

Awards 14

Award for the Scientific Paper (PHYSICAL SCIENCES)

2025/06　The Japanese Society of Microscopy　Electron irradiation damage of amorphous epoxy resin at low electron doses
The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology (Research Category)

2024/04　the Minister of Education, Culture, Sports, Science and Technology
The Arthur K Doolittle Award

2023/09　American Chemical Society　Nanoscale static and dynamic characterization of polymer hierarchical structures for sustainable engineering.
IAAM Fellow

2023/03　International Association of Advanced Materials
FELLOW of THE ROYAL SOCIETY OF CHEMISTRY

2022/05　The Royal Society of Chemistry
The Award of the Society of Polymer Science, Japan (2017)

2017/05　the Society of Polymer Science, Japan　3D observations of interfacial morphologies and their dynamical processes in multicomponent polymer system
The Japanese Society of Microscopy, Setoh Prize

2012/05
Fellow of the American Physical Society

2010/11　American Physical Society　For elucidating the three-dimensional morphology of complex polymer system by transmission electron microtomograpy
The Society of Rubber Industry, Japan. 2010 Bridgestone Soft Materials Frontier Award

2010/05　The Society of Rubber Industry, Japan
Award for Persons of Merit in Industry-Academia-Government Collaboration in FY2008 (Minister of Education, Culture, Sports, Science and Technology Award)

2008/06
Presidential Award of Kyoto Institute of Technology

2007/10　Kyoto Institute of Technology
Ernst-Ruska-Preis 2007

2007/09　the German Society for Electron Microscopy　"Novel and Quantitative Uses of Electron Tomography in the 3D Study of Nanostructured Materials"
Fuel Cells Gordon Research Conference “The Pixar Award”

2007/07　Fuel Cells Gordon Research Conference
SPSJ (The Society of Polymer Science, Japan) Wiley Award (2006)

2006/09　the Society of Polymer Science, Japan

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Papers 322

Nanoscale C-H/C-D mapping of organic materials using electron spectroscopy Peer-reviewed

Ryosuke Senga, Katsumi Hagita, Tomohiro Miyata, Hsiao-Fang Wang, Koichi Mayumi, Hiroshi Jinnai, Kazu Suenaga

NATURE NANOTECHNOLOGY　20　740-746　2025/03/24

DOI： 10.1038/s41565-025-01893-5 　

ISSN： 1748-3387

eISSN： 1748-3395
Orientation distribution and branching mechanism of lamellar crystals inside an isotactic polystyrene spherulite Peer-reviewed

Shusuke Kanomi, Koichi Azuma, Tomohiro Miyata, Akihiko Toda, Hiroshi Jinnai

Polymer　326　128335-128335　2025/03
Publisher: Elsevier BV
DOI： 10.1016/j.polymer.2025.128335 　

ISSN： 0032-3861
Helically deployed Au nanoparticles using block copolymer templates as chiral plasmonic monoliths Peer-reviewed

Hsiu-Wen Tsai, Sheng-Wei Shao, Po-Ting Chiu, Cheng-Yen Chang, Yu-Chuan Sung, Guan-Hong Li, Yi-Ching Chen, Akemi Kumagai, Hiroshi Jinnai, Yu-Chueh Hung, Jing-Cherng Tsai, Rong-Ming Ho

Giant　21　100350-100350　2025/02
Publisher: Elsevier BV
DOI： 10.1016/j.giant.2024.100350 　

ISSN： 2666-5425
Effect of inorganic material surface chemistry on structures and fracture behaviours of epoxy resin Peer-reviewed

Tomohiro Miyata, Yohei K. Sato, Yoshiaki Kawagoe, Keiichi Shirasu, Hsiao-Fang Wang, Akemi Kumagai, Sora Kinoshita, Masashi Mizukami, Kaname Yoshida, Hsin-Hui Huang, Tomonaga Okabe, Katsumi Hagita, Teruyasu Mizoguchi, Hiroshi Jinnai

Nature Communications　15　(1)　2024/03/08
Publisher: Springer Science and Business Media LLC
DOI： 10.1038/s41467-024-46138-6 　

eISSN： 2041-1723

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Abstract The mechanisms underlying the influence of the surface chemistry of inorganic materials on polymer structures and fracture behaviours near adhesive interfaces are not fully understood. This study demonstrates the first clear and direct evidence that molecular surface segregation and cross-linking of epoxy resin are driven by intermolecular forces at the inorganic surfaces alone, which can be linked directly to adhesive failure mechanisms. We prepare adhesive interfaces between epoxy resin and silicon substrates with varying surface chemistries (OH and H terminations) with a smoothness below 1 nm, which have different adhesive strengths by ~13 %. The epoxy resins within sub-nanometre distance from the surfaces with different chemistries exhibit distinct amine-to-epoxy ratios, cross-linked network structures, and adhesion energies. The OH- and H-terminated interfaces exhibit cohesive failure and interfacial delamination, respectively. The substrate surface chemistry impacts the cross-linked structures of the epoxy resins within several nanometres of the interfaces and the adsorption structures of molecules at the interfaces, which result in different fracture behaviours and adhesive strengths.
Model Based on the River Meander Curve for Simulating the Adhesion of Cross-Linked Polymers to Rough Surfaces Peer-reviewed

Katsumi Hagita, Takahiro Murashima, Tomohiro Miyata, Hiroshi Jinnai

Macromolecules　2024/03/07
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.macromol.3c02660 　

ISSN： 0024-9297

eISSN： 1520-5835
Microscopic Chemical Characterization of Epoxy Resin with Scanning Transmission Electron Microscopy – Electron Energy-Loss Spectroscopy Peer-reviewed

Hsin-Hui Huang, Tomohiro Miyata, Yohei K. Sato, Teruyasu Mizoguchi, Hiroshi Jinnai, Kaname Yoshida

Micron　103623-103623　2024/03
Publisher: Elsevier BV
DOI： 10.1016/j.micron.2024.103623 　

ISSN： 0968-4328
高分子材料中における結晶構造のナノスケール可視化

Shusuke Kanomi, Hiroshi Jinnai

Sen'i Gakkaishi　80　(3)　P-94　2024
Publisher: Society of Fiber Science and Technology Japan
DOI： 10.2115/fiber.80.p-94 　

ISSN： 0037-9875

eISSN： 1884-2259
Toughening of a polymer network by the addition of a small amount of large-sized multicyclic chains Peer-reviewed

Hironori Marubayashi, Minami Ebe, Atsushi Imasaki, Kaiyu Fujiwara, Naruhiko Mashita, Katsumi Hagita, Takahiro Murashima, Sunao Mori, Takuya Isono, Toshifumi Satoh, Hiroshi Jinnai

Polymer　292　126607-126607　2024/01
Publisher: Elsevier BV
DOI： 10.1016/j.polymer.2023.126607 　

ISSN： 0032-3861
Formation of Polyion Complex Aggregate Formed from a Cationic Block Copolymer and Anionic Polysaccharide Peer-reviewed

Kazushi Ogata, Mineo Hashizume, Rintaro Takahashi, Tasuku Hamaguchi, Hiroshi Jinnai, Shin-ichi Yusa

Langmuir　39　(46)　16484-16493　2023/11/10
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.langmuir.3c02404 　

ISSN： 0743-7463

eISSN： 1520-5827
Reassessing chain tilt in the lamellar crystals of polyethylene Peer-reviewed

Shusuke Kanomi, Hironori Marubayashi, Tomohiro Miyata, Hiroshi Jinnai

Nature Communications　14　(1)　5531-5531　2023/09/21
Publisher: Springer Science and Business Media LLC
DOI： 10.1038/s41467-023-41138-4 　

eISSN： 2041-1723

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Abstract Semicrystalline polymers are extensively used in various forms, including fibres, films, and bottles. They exhibit remarkable properties, e.g., mechanical and thermal, that are governed by hierarchical structures comprising 10–20-nm-thick lamellar crystals. In 1957, Keller deduced that long polyethylene (PE) chains fold to form thin single lamellar crystals, with the molecular chains perpendicular to the flat faces of the crystals (the chain-folding model). Chains inclining to the perpendicular orientation in single crystals have since been reported, along with their effects on the physical properties of PE. For bulk specimens, the chain tilt angle (φ) has been investigated only for model samples with well-annealed internal structures. However, for briefly annealed specimens, the φ values of lamellae and their origins are controversial owing to the disordered lamellar morphology and orientation. Herein, we report the direct determination of molecular-chain orientations in the lamellar crystals of high-density PE using a state-of-the-art electron-diffraction-based imaging technique with nanometre-scale positional resolution and provide compelling evidence for the existence of lamellar crystals with different inner-chain orientations. Clarifying the nanoscale variation in lamellar crystals in PE can allow precise tuning of properties and expedite resource-saving material design.
In-Situ Shearing Process Observation System for Soft Materials via Transmission Electron Microscopy Peer-reviewed

Tomohiro Miyata, Hsiao-Fang Wang, Daisuke Watanabe, Yoshiaki Kawagoe, Tomonaga Okabe, Hiroshi Jinnai

Microscopy　2023/09/13
Publisher: Oxford University Press (OUP)
DOI： 10.1093/jmicro/dfad045 　

ISSN： 2050-5698

eISSN： 2050-5701

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Abstract We developed an in-situ shear test system suitable for transmission electron microscopy (TEM) observations, which enabled us to examine the shear deformation behaviours inside soft materials at nanoscale resolutions. This study was conducted on a nanoparticle-filled rubber to investigate its nanoscale deformation behaviour under a large shear strain. First, the shear deformation process of a large area in the specimen was accurately examined and proven to exhibit an almost perfect simple shear. At the nanoscale, voids grew along the maximum principal strain during shear deformation. In addition, the nanoscale regions with rubber and silica aggregates exhibited deformation behaviours similar to the global shear deformation of the specimen. Although the silica aggregates exhibited displacement along the shearing directions, rotational motions were also observed owing to the torque generated by the local shear stress. This in-situ shear deformation system for TEM enabled us to understand the nanoscale origins of the mechanical properties of soft materials, particularly polymer composites.
Rotaxane Formation of Multicyclic Polydimethylsiloxane in a Silicone Network: A Step toward Constructing “Macro‐Rotaxanes” from High‐Molecular‐Weight Axle and Wheel Components Peer-reviewed

Minami Ebe, Asuka Soga, Kaiyu Fujiwara, Brian J. Ree, Hironori Marubayashi, Katsumi Hagita, Atsushi Imasaki, Miru Baba, Takuya Yamamoto, Kenji Tajima, Tetsuo Deguchi, Hiroshi Jinnai, Takuya Isono, Toshifumi Satoh

Angewandte Chemie International Edition　62　(35)　2023/07/17
Publisher: Wiley
DOI： 10.1002/anie.202304493 　

ISSN： 1433-7851

eISSN： 1521-3773

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Abstract Rotaxanes consisting of a high‐molecular‐weight axle and wheel components (macro‐rotaxanes) have high structural freedom, and are attractive for soft‐material applications. However, their synthesis remains underexplored. Here, we investigated macro‐rotaxane formation by the topological trapping of multicyclic polydimethylsiloxanes (mc‐PDMSs) in silicone networks. mc‐PDMS with different numbers of cyclic units and ring sizes was synthesized by cyclopolymerization of a α,ω‐norbornenyl‐functionalized PDMS. Silicone networks were prepared in the presence of 10–60 wt % mc‐PDMS, and the trapping efficiency of mc‐PDMS was determined. In contrast to monocyclic PDMS, mc‐PDMSs with more cyclic units and larger ring sizes can be quantitatively trapped in the network as macro‐rotaxanes. The damping performance of a 60 wt % mc‐PDMS‐blended silicone network was evaluated, revealing a higher tan δ value than the bare PDMS network. Thus, macro‐rotaxanes are promising as non‐leaching additives for network polymers.
Molecular Dynamics Simulations on Epoxy/Silica Interfaces Using Stable Atomic Models of Silica Surfaces Peer-reviewed

Katsumi Hagita, Tomohiro Miyata, Hiroshi Jinnai

Langmuir　39　(20)　7063-7078　2023/05/09
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.langmuir.3c00306 　

ISSN： 0743-7463

eISSN： 1520-5827
Kinetic Pathway of the Order–Order Transition from Hexagonally Packed Cylinder to Hexagonally Perforated Layer in Polystyrene-block-Poly(2-vinylpyridine) Using Time-Resolved 3D Transmission Electron Microtomography Peer-reviewed

Hsiao-Fang Wang, Hironori Marubayashi, Hiroshi Jinnai

Macromolecules　56　1503-1513　2023/02/15
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.macromol.2c01849 　

ISSN： 0024-9297

eISSN： 1520-5835
Atomic-scale analysis on a rubber-brass adhesive interface using scanning transmission electron microscopy Peer-reviewed

Tomohiro Miyata, Katsunori Shimizu, Yohei K. Sato, Hiroshi Jinnai

Polymer　265　125602-125602　2023/01
Publisher: Elsevier BV
DOI： 10.1016/j.polymer.2022.125602 　

ISSN： 0032-3861
Electron irradiation damage of amorphous epoxy resin at low electron doses Peer-reviewed

Kaname Yoshida, Hsin-Hui Huang, Tomohiro Miyata, Yohei K Sato, Hiroshi Jinnai

Microscopy　72　(4)　361-367　2022/12/10
Publisher: Oxford University Press (OUP)
DOI： 10.1093/jmicro/dfac068 　

ISSN： 2050-5698

eISSN： 2050-5701

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Abstract The mechanisms of electron irradiation damage to epoxy resin samples were evaluated using their electron diffraction patterns and electron energy-loss (EEL) spectra. Their electron diffraction patterns consisted of three indistinct halo rings. The halo ring, related to an intermolecular distance of ~6.4 Å, degraded rapidly with electron beam irradiation. Such molecular-scale collapse could have been caused by cross-linking between molecular chains. The degree of electron irradiation damage to the samples changed with the accelerating voltage. Tolerance dose limit of epoxy resin estimated from the intensity of the halo ring was found to be improved at higher accelerating voltage. Changes in low-loss EEL spectra indicated that the mass loss of epoxy resin was remarkable in the early stage of electron irradiation.
Nanoscale TEM Imaging of Hydrogel Network Architecture Peer-reviewed

Ryuji Kiyama, Masahiro Yoshida, Takayuki Nonoyama, Tomas Sedlacik, Hiroshi Jinnai, Takayuki Kurokawa, Tasuku Nakajima, Jian Ping Gong

Advanced Materials　35　(1)　2208902-2208902　2022/11/18
Publisher: Wiley
DOI： 10.1002/adma.202208902 　

ISSN： 0935-9648 1521-4095

eISSN： 1521-4095
Characterization of Microplastics by Advanced Analytical Techniques

Tomoko KAJIWARA, Ying Jun AN, Adchara PADERMSHOKE, Akemi KUMAGAI, Hironori MARUBAYAHI, Yuka IKEMOTO, Hiroshi JINNAI, Atsuhiko ISOBE, Atsushi TAKAHARA

BUNSEKI KAGAKU　71　(10.11)　541-547　2022/10/05
Publisher: Japan Society for Analytical Chemistry
DOI： 10.2116/bunsekikagaku.71.541 　

ISSN： 0525-1931
Dislocation-Induced Defect Formation in a Double-Gyroid Network Peer-reviewed

Tomohiro Miyata, Hsiao-Fang Wang, Takafumi Suenaga, Daisuke Watanabe, Hironori Marubayashi, Hiroshi Jinnai

Macromolecules　55　8143-8149　2022/09/12
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.macromol.2c01298 　

ISSN： 0024-9297

eISSN： 1520-5835
Morphologies of polymer chains adsorbed on inorganic nanoparticles in a polymer composite as revealed by atomic-resolution electron microscopy Peer-reviewed

Tomohiro Miyata, Yoshiaki Kawagoe, Tomonaga Okabe, Hiroshi Jinnai

Polymer Journal　54　(11)　1297-1306　2022/08/10
Publisher: Springer Science and Business Media LLC
DOI： 10.1038/s41428-022-00690-4 　

ISSN： 0032-3896

eISSN： 1349-0540
Ring-Filling Effect on Stress–Strain Curves of Randomly End-Linked Tetra-Arm Prepolymers Peer-reviewed

Katsumi Hagita, Takahiro Murashima, Takahiro Ohkuma, Hiroshi Jinnai

Macromolecules　55　(15)　6547-6561　2022/08/09
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.macromol.2c00451 　

ISSN： 0024-9297

eISSN： 1520-5835
Compositional Analysis on Epoxy-resin/inorganic Interfaces using Scanning Transmission Electron Microcopy Peer-reviewed

Tomohiro Miyata, Yohei Sato, Kaname Yoshida, Hsin-Hui Huang, Teruyasu Mizoguchi, Katsumi Hagita, Masashi Mizukami, Hiroshi Jinnai

Microscopy and Microanalysis　28　(S1)　2522-2524　2022/08
Publisher: Cambridge University Press (CUP)
DOI： 10.1017/s1431927622009643 　

ISSN： 1431-9276

eISSN： 1435-8115
Real-time observation of microcrack growth in thin film microtomed from rubber/nanocellulose composite sheets, during tensile deformation Peer-reviewed

Hiroshi Jinnai, Toru Noguchi, Akemi Kumagai, Morinobu Endo, Akira Isogai

Polymer Compos.　43　(9)　6310-6319　2022/07/27

DOI： 10.1002/pc.26939 　
Correlative light and electron microscopy of poly(ʟ-lactic acid) spherulites for fast morphological measurements using a convolutional neural network Peer-reviewed

Yuji Konyuba, Hironori Marubayashi, Tomohiro Haruta, Hiroshi Jinnai

Microscopy　71　(2)　104-110　2022/04
Publisher: Oxford University Press (OUP)
DOI： 10.1093/jmicro/dfab058 　

ISSN： 2050-5698

eISSN： 2050-5701

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Abstract Polarized optical microscopy (POM) and transmission electron microscopy (TEM) are widely used for imaging polymer spherulite structures. TEM provides nanometer resolution to image small spherulites of sub-micrometer in diameter, while POM is more suitable for observing large spherulites. However, high-resolution images with a large field of view are challenging to achieve due to the deformations of ultrathin sectioned samples used for TEM observations. In this study, we demonstrated that correlative light and electron microscopy (CLEM) combining POM and TEM could effectively characterize the spherulite structures in a wide range from nanometer to several hundred micrometers that neither TEM nor POM alone could cover. Furthermore, the deformations of the TEM ultrathin sections were corrected by referencing to the POM images at the same position of the sample, and large-area TEM images without deformations were successfully produced. The spherulite structures of poly(ʟ-lactic acid) were successfully analyzed using CLEM and TEM in a wide range of spatial scales at the same field of view. The large-area TEM image (250 µm × 250 µm), consisting of 702 TEM images stitched together, was subjected to machine learning to extract the essential structural information of spherulites. Analysis using the convolutional neural network, a well-known algorithm You Only Look Once (YOLO), demonstrated that it was practical to accurately obtain the diameter distribution and the space-filling factor (relative crystallinity) of the spherulites. This study presents a new approach for acquiring high-resolution images with a large field of view and processing the images at a fast speed.
Crack propagation behaviors in a nanoparticle‐filled rubber studied by in situ tensile electron microscopy Peer-reviewed

Daisuke Watanabe, Tomohiro Miyata, Tomohiko Nagao, Akemi Kumagai, Hiroshi Jinnai

Journal of Polymer Science　60　(7)　1277-1284　2022/04/01
Publisher: Wiley
DOI： 10.1002/pol.20210269 　

ISSN： 2642-4150

eISSN： 2642-4169
Demonstration of reinforcement in polymer composite with rings penetrating the diamond-lattice network Peer-reviewed

Katsumi Hagita, Takahiro Murashima, Hiroshi Jinnai

Polymer　243　124637-124637　2022/03
Publisher: Elsevier BV
DOI： 10.1016/j.polymer.2022.124637 　

ISSN： 0032-3861
Electron microscopy for polymer structures Invited Peer-reviewed

Hiroshi Jinnai

Microscopy　71　(Supplement_1)　i148-i164　2022/02/18
Publisher: Oxford University Press (OUP)
DOI： 10.1093/jmicro/dfab057 　

ISSN： 2050-5698

eISSN： 2050-5701

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Abstract This paper reviews recent advances and perspectives of electron microscopy and its application to polymer hierarchical structures. Of the various kinds of hierarchical polymer structures, we placed particular emphasis on polymer nanocomposites and polymer crystals based mainly on our recent results. In those nanocomposites, the chemical bonding between the nanometer-size fillers and rubber matrix, a key contributor to the mechanical properties of the material, has been investigated by combining scanning transmission electron microscopy (STEM) with electron energy-loss spectroscopy (EELS). The position-dependent EELS spectrum with high spatial resolution of STEM successfully provided revealed the presence/absence of the chemical bonds across the interface. The mechanical properties and fracture mechanism of nanocomposites have been studied by combining structural observations made using transmission electron microscopy (TEM) with simulations. They have been further investigated using in situ TEM with a newly designed stretching holder, in which morphological changes, including cavity formation, were visualized and analyzed in terms of local strain distribution. The fracture processes of nanocomposite have been observed at nanometer resolution. The fundamental reinforcement mechanisms have been elucidated from morphological studies of nanocomposites under tensile deformation and during the fracture process. Moreover, nano-diffraction imaging, a position-resolved electron diffraction imaging with STEM, has been applied to a polymer crystal to evaluate the orientation of lamellar crystals at nanometer resolution. All these recent successes with radiation-sensitive polymer materials stemmed from developments made in electron optics and super-sensitive cameras used for advanced electron microscopy.
Structural Correlations of the Nonlinear Optical Response in Polydiacetylene Nanotubes Hybridized with Gold Nanoparticles Peer-reviewed

Wakana Ito-Washiyama, Tsunenobu Onodera, Masaki Ageishi, Rodrigo Sato, Boyi Zhang, Satoshi Kato, Akito Masuhara, Hitoshi Kasai, Hiroaki Mamiya, Hiroshi Jinnai, Yoshihiko Takeda, Hidetoshi Oikawa

The Journal of Physical Chemistry C　126　(5)　2763-2771　2022/02/10
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.jpcc.1c08884 　

ISSN： 1932-7447

eISSN： 1932-7455
Efficient Compressed Database of Equilibrated Configurations of Ring-Linear Polymer Blends for MD Simulations Peer-reviewed

K. Hagita, T. Murashima, M. Ogino, M. Omiya, K. Ono, T. Deguchi, H. Jinnai, T. Kawakatsu

Scientific Data　9　40　2022/02/08

DOI： 10.6084/m9.figshare.18742097 　
Direct Visualization of Interfacial Regions between Fillers and Matrix in Rubber Composites Observed by Atomic Force Microscopy-Based Nanomechanics Assisted by Electron Tomography International-journal Peer-reviewed

Makiko Ito, Haonan Liu, Akemi Kumagai, Xiaobin Liang, Ken Nakajima, Hiroshi Jinnai

Langmuir　38　(2)　777-785　2022/01/18
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.langmuir.1c02788 　

ISSN： 0743-7463

eISSN： 1520-5827

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In order to explain or predict the macroscopic mechanical properties of polymer composites with complex nanostructures, atomic force microscopy (AFM)-based nanomechanics is one of the most appropriate tools because the local mechanical properties can be obtained by it. However, automatic force curve analysis based on contact mechanics would mislead us to the wrong conclusion. The purpose of this study is to elucidate this point by applying AFM nanomechanics on a carbon black (CB)-reinforced isoprene rubber (IR). The CB aggregates underneath the rubber surface prevent us from quantitatively evaluating the ratio of CB and interfacial polymer region (IPR), which is an important parameter to determine the macroscopic mechanical properties. In order to overcome this problem, transmission electron microtomography was incorporated to investigate the 3D structure in the same field of view as AFM nanomechanics. As a result, it was found that there are buried structures that do not appear in the AFM topographic image. In addition, we were able to reveal the existence of a force curve with an inflection point, which is characteristic of such "false" IPRs. To put it another way, we evidenced the existence of true IPRs for the first time by combining these state-of-the-art techniques.
Densely Arrayed Cage-Shaped Polymer Topologies Synthesized via Cyclopolymerization of Star-Shaped Macromonomers

Yoshinobu Mato, Maho Sudo, Hironori Marubayashi, Brian J. Ree, Kenji Tajima, Takuya Yamamoto, Hiroshi Jinnai, Takuya Isono, Toshifumi Satoh

Macromolecules　54　(19)　9079-9090　2021/10/12
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.macromol.1c01230 　

ISSN： 0024-9297

eISSN： 1520-5835
Polymer Crystals Studied by Nanodiffraction Imaging

56　(2)　87-90　2021/08/30
Nanodiffraction Imaging of Polymer Crystals Peer-reviewed

Shusuke Kanomi, Hironori Marubayashi, Tomohiro Miyata, Kenji Tsuda, Hiroshi Jinnai

Macromolecules　54　(13)　6028-6037　2021/07/13
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.macromol.1c00683 　

ISSN： 0024-9297

eISSN： 1520-5835
Cellulose nanofiber-reinforced rubber composites prepared by TEMPO-functionalization and elastic kneading Peer-reviewed

Toru Noguchi, Ken-ich Niihara, Ayumi Kurashima, Rie Iwamoto, Takashi Miura, Akira Koyama, Morinobu Endo, Hironori Marubayashi, Akemi Kumagai, Hiroshi Jinnai, Akira Isogai

Composites Science and Technology　210　108815-108815　2021/07
Publisher: Elsevier BV
DOI： 10.1016/j.compscitech.2021.108815 　

ISSN： 0266-3538
Preparation of high‐performance carbon nanotube/polyamide composite materials by elastic high‐shear kneading and improvement of properties by induction heating treatment Peer-reviewed

Toru Noguchi, Ken‐ichi Niihara, Keiichi Kawamoto, Masanori Fukushi, Hiroshi Jinnai, Ken Nakajima, Morinobu Endo

Journal of Applied Polymer Science　138　(22)　e50512-e50512　2021/06/10
Publisher: Wiley
DOI： 10.1002/app.50512 　

ISSN： 0021-8995

eISSN： 1097-4628
Nanoscale Stress Distribution in Silica-Nanoparticle-Filled Rubber as Observed by Transmission Electron Microscopy: Implications for Tire Application Peer-reviewed

Tomohiro Miyata, Tomohiko Nagao, Daisuke Watanabe, Akemi Kumagai, Keizo Akutagawa, Hiroshi Morita, Hiroshi Jinnai

ACS Applied Nano Materials　4　(5)　4452-4461　2021/05/28
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acsanm.1c00009 　

ISSN： 2574-0970

eISSN： 2574-0970
Tribute to Takeji Hashimoto

Hiroshi Jinnai, Mikihito Takenaka, Mitsuhiro Shibayama, Charles C. Han, Stephen Z.D. Cheng

Polymer　222　2021/04/22
Publisher: Elsevier Ltd
DOI： 10.1016/j.polymer.2021.123676 　

ISSN： 0032-3861
Elucidation of oxygen reduction reaction and nanostructure of platinum-loaded graphene mesosponge for polymer electrolyte fuel cell electrocatalyst Peer-reviewed

Atsushi Ohma, Yoshihisa Furuya, Tetsuya Mashio, Masashi Ito, Keita Nomura, Tomohiko Nagao, Hirotomo Nishihara, Hiroshi Jinnai, Takashi Kyotani

Electrochimica Acta　370　137705-137705　2021/02
Publisher: Elsevier BV
DOI： 10.1016/j.electacta.2020.137705 　

ISSN： 0013-4686
Ultra-low dielectric properties of porous polyimide thin films fabricated by using the two kinds of templates with different particle sizes Peer-reviewed

Yumi Kourakata, Tsunenobu Onodera, Hitoshi Kasai, Hiroshi Jinnai, Hidetoshi Oikawa

Polymer　212　123115-123115　2021/01
Publisher: Elsevier BV
DOI： 10.1016/j.polymer.2020.123115 　

ISSN： 0032-3861
Visualization of chemical bonding in a silica-filled rubber nanocomposite using STEM-EELS Peer-reviewed

Yohei K. Sato, Yasufumi Kuwauchi, Wakana Miyoshi, Hiroshi Jinnai

Scientific Reports　10　(1)　21558-21558　2020/12
Publisher: Springer Science and Business Media LLC
DOI： 10.1038/s41598-020-78393-0 　

eISSN： 2045-2322

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<title>Abstract</title>In nanocomposites, the adhesion between nanofillers and the polymeric matrix is key to the mechanical properties. The strength and spatial distribution of the adhesive layer around the nanofillers are important, particularly the presence of chemical bonding between the nanofillers and matrix. In this work, we studied a styrene-butadiene rubber composite filled with silica nanoparticles to visualize the spatial distribution of the adhesive layer. A silane coupling agent (SCA) was added to the nanocomposite for strong adhesion. The reaction involving the SCA on the silica surface was investigated by scanning transmission electron microscopy combined with electron energy-loss spectroscopy. Si-L_2,3 spectra of the silica-filled rubber nanocomposite without the SCA were the same around the nanofillers, whereas in the nanocomposite containing the SCA the spectra were position-dependent. The spectra were fitted with the intensity profiles of the Si-L_2,3 spectra of silica and SCA by multiple linear least-squares fitting. The fitting coefficients of silica and SCA were used to map the spatial distribution of the chemical bonding between silica and rubber chains. Chemical bonding was observed around the silica nanoparticles but not in the SBR matrix region, providing direct evidence of the reinforcing mechanism in the silica-filled rubber nanocomposite.
Networks with controlled chirality via self-assembly of chiral triblock terpolymers International-journal International-coauthorship Peer-reviewed

Hsiao-Fang Wang, Po-Ting Chiu, Chih-Ying Yang, Zhi-Hong Xie, Yu-Chueh Hung, Jing-Yu Lee, Jing-Cherng Tsai, Ishan Prasad, Hiroshi Jinnai, Edwin L. Thomas, Rong-Ming Ho

Science Advances　6　(42)　eabc3644-eabc3644　2020/10

DOI： 10.1126/sciadv.abc3644 　

ISSN： 2375-2548

eISSN： 2375-2548
Atomic-scale Observation of Polymer-chain Conformations Using Scanning Transmission Electron Microscopy

Tomohiro Miyata, Raita Goseki, Takashi Ishizone, Hiroshi Jinnai

Microscopy and Microanalysis　26　(S2)　3016-3017　2020/08
Publisher: Cambridge University Press (CUP)
DOI： 10.1017/s1431927620023545 　

ISSN： 1431-9276

eISSN： 1435-8115
Staining-free observation of polymer blend thin films on transmission extreme ultraviolet microscopy Peer-reviewed

Mitsunori Toyoda, Shunsuke Aizawa, Shiori Gondai, Toshiyuki Kakudate, Masaki Ageishi, Hiroshi Jinnai, Jun Chen

Applied Physics Express　13　(8)　082011-082011　2020/08/01

DOI： 10.35848/1882-0786/aba882 　

ISSN： 1882-0778

eISSN： 1882-0786
Strategy for Finely Aligned Gold Nanorod Arrays Using Polymer Brushes as a Template

Satoshi Nakamura, Hideyuki Mitomo, Yu Sekizawa, Takeshi Higuchi, Yasutaka Matsuo, Hiroshi Jinnai, Kuniharu Ijiro

Langmuir　36　(13)　3590-3599　2020/04/07

DOI： 10.1021/acs.langmuir.9b03835 　

ISSN： 0743-7463

eISSN： 1520-5827
Degradation of a Metal–Polymer Interface Observed by Element-Specific Focused Ion Beam-Scanning Electron Microscopy Peer-reviewed

Takashi Kakubo, Katsunori Shimizu, Akemi Kumagai, Hiroaki Matsumoto, Miki Tsuchiya, Naoya Amino, Hiroshi Jinnai

Langmuir　36　(11)　2816-2822　2020/03/24
Publisher: American Chemical Society (ACS)
DOI： 10.1021/acs.langmuir.0c00034 　

ISSN： 0743-7463

eISSN： 1520-5827
Cellulose nanofiber/elastomer composites with high tensile strength, modulus, toughness, and thermal stability prepared by high-shear kneading Peer-reviewed

Toru Noguchi, Morinobu Endo, Kenichi Niihara, Hiroshi Jinnai, Akira Isogai

Composites Science and Technology　188　108005-108005　2020/03
Publisher: Elsevier BV
DOI： 10.1016/j.compscitech.2020.108005 　

ISSN： 0266-3538
Hierarchical structure of the triclinic a-phase crystal in nylon 6,12 mediated by two-dimensional confinement International-journal International-coauthorship Peer-reviewed

Z. Lai, S. Zhang, N. Zheng, S. Yu, M. Ageishi, H. Jinnai, Y. Cao

J. Appl. Crystallogr.　53　2019/10

DOI： 10.1107/S1600576719014705 　
Visualization of the tensile fracture behaviors at adhesive interfaces between brass and sulfur-containing rubber studied by transmission electron microscopy Peer-reviewed

K. Shimizu, T. Miyata, T. Nagao, A. Kumagai, H. Jinnai

Polymer　181　121789-121789　2019/09

DOI： 10.1016/j.polymer.2019.121789 　
An Inverse Modeling Approach for Predicting Filled Rubber Performance International-journal International-coauthorship Peer-reviewed

M. Shakoor, H. Jinnai, H. Kadowaki, E. Seta, W.-K. Liu

Comput. Methods Appl. Mech. Engrg.　357　112567　2019/08

DOI： 10.1016/j.cma.2019.112567 　
Self-Assembled Morphologies of Lamella-Forming Block Copolymers Confined in Conical Nanopores International-journal International-coauthorship Peer-reviewed

Y. Kim, A. Kumagai, X. Hu, A.-C. Shi, B. Li, H. Jinnai, K. Char

Macromolecules　52　4803-4811　2019/06

DOI： 10.1021/acs.macromol.9b00822 　
Adding Symmetry: Cylindrically Confined Crystallization of Nylon-6 International-journal International-coauthorship Peer-reviewed

S. Yu, Z. Lai, H. Jinnai, X. Zeng, M. Ageishi, B. Lotz, S. Z, D. Cheng, N. Zheng, S. Zhang, X. Feng, Y. Cao

Macromolecules　52　3298-3305　2019/04

DOI： 10.1021/acs.macromol.8b02672 　
Scattering Patterns and Stress‐Strain Relations on Phase‐ separated ABA Block Copolymers under Uniaxial Elongating Simulations Peer-reviewed

K. Hagita, K. Akutagawa, T. Tominaga, H. Jinnai

15　(5)　926-936　2019/02

DOI： 10.1039/C8SM02363H 　
Cascade Self-Organization of Shish Kebabs in Fibers Spun from Polymer Solutions: Crystalline Fibrils Bridging Neighboring Kebabs Discovered by Transmission Electron Microtomography Peer-reviewed

Murase Hiroki, Jinnai Hiroshi, Toriyama Takaaki, Hashimoto Takeji

52　(2)　575-591　2019/01

DOI： 10.1021/acs.macromol.8b02246 　
In situ Three-Dimensional Observation of Rubber Materials under Tensile Deformation

Hiroshi Jinnai

53　(3)　113-117　2018/12

DOI： 10.11410/kenbikyo.53.3_113 　
Super-resolution for asymmetric resolution of FIB-SEM 3D imaging using AI with deep learning Peer-reviewed

Katsumi Hagita, Takeshi Higuchi, Hiroshi Jinnai

Scientific Reports　8　(1)　2018/12/01

DOI： 10.1038/s41598-018-24330-1 　

ISSN： 2045-2322
Development of a three-dimensional tomography holder for in situ tensile deformation for soft materials Peer-reviewed

Higuchi Takeshi, Gondo Takashi, Miyazaki Hiroya, Kumagai Akemi, Akutagawa Keizo, Jinnai Hiroshi

Microscopy　67　(5)　296-300　2018/10

DOI： 10.1093/jmicro/dfy027 　
Interfacial Morphologies and Associated Processes of Multicomponent Polymers Invited Peer-reviewed

Jinnai Hiroshi

50　1121-1138　2018/08

DOI： 10.1038/s41428-018-0103-1 　
Stabilizing the Ordered Bicontinuous Double Diamond Structure of Diblock Copolymer by Configurational Regularity International-journal International-coauthorship Peer-reviewed

Chih-Hsuan Lin, Takeshi Higuchi, Hsin-Lung Chen, Jing-Cherng Tsai, Hiroshi Jinnai, Takeji Hashimoto

Macromolecules　51　(11)　4049-4058　2018/06/12

DOI： 10.1021/acs.macromol.7b02404 　

ISSN： 1520-5835 0024-9297
Enhancement of Oxygen Reduction Reaction Activity of Pd Core-Pt Shell Structured Catalyst on a Potential Cycling Accelerated Durability Test Peer-reviewed

Naoya Aoki, Hideo Inoue, Takashi Okawa, Yuta Ikehata, Akira Shirai, Hideo Daimon, Takayuki Doi, Yuki Orikasa, Yoshiharu Uchimoto, Hiroshi Jinnai, Shin Inamoto, Yuji Otsuka, Minoru Inaba

Electrocatalysis　9　(2)　125-128　2018/03/01

DOI： 10.1007/s12678-017-0399-1 　

ISSN： 1868-5994 1868-2529
Anatomy of triply-periodic network assemblies: Characterizing skeletal and inter-domain surface geometry of block copolymer gyroids International-journal International-coauthorship Peer-reviewed

Ishan Prasad, Hiroshi Jinnai, Rong-Ming Ho, Edwin L. Thomas, Gregory M. Grason

Soft Matter　14　(18)　3612-3623　2018

DOI： 10.1039/c8sm00078f 　

ISSN： 1744-6848 1744-683X
Controlled self-assemblies of polystyrene-block-polydimethylsiloxane micelles in cylindrical confinement through a micelle solution wetting method and Rayleigh-instability-driven transformation International-journal International-coauthorship Peer-reviewed

Hao-Wen Ko, Takeshi Higuchi, Chun-Wei Chang, Ming-Hsiang Cheng, Komei Isono, Mu-Huan Chi, Hiroshi Jinnai, Jiun-Tai Chen

SOFT MATTER　13　(32)　5428-5436　2017/08

DOI： 10.1039/c7sm01024a 　

ISSN： 1744-683X

eISSN： 1744-6848
Synthesis of ordered carbonaceous frameworks from organic crystals Peer-reviewed

Hirotomo Nishihara, Tetsuya Hirota, Kenta Matsuura, Mao Ohwada, Norihisa Hoshino, Tomoyuki Akutagawa, Takeshi Higuchi, Hiroshi Jinnai, Yoshitaka Koseki, Hitoshi Kasai, Yoshiaki Matsuo, Jun Maruyama, Yuichiro Hayasaka, Hisashi Konaka, Yasuhiro Yamada, Shingi Yamaguchi, Kazuhide Kamiya, Takuya Kamimura, Hirofumi Nobukuni, Fumito Tani

NATURE COMMUNICATIONS　8　2017/07

DOI： 10.1038/s41467-017-00152-z 　

ISSN： 2041-1723
Three-Dimensional Visualization and Characterization of Polymeric Self-Assemblies by Transmission Electron Microtomography International-journal International-coauthorship Peer-reviewed

Hiroshi Jinnai, Takeshi Higuchi, Xiaodong Zhuge, Akihito Kumamoto, Kees Joost Batenburg, Yuichi Ikuhara

ACCOUNTS OF CHEMICAL RESEARCH　50　(6)　1293-1302　2017/06

DOI： 10.1021/acs.accounts.7b00103 　

ISSN： 0001-4842

eISSN： 1520-4898
Direct three-dimensional imaging of the fracture of fiber-reinforced plastic under uniaxial extension: Effect of adhesion between fibers and matrix Peer-reviewed

Haruko Saito, Yuko Aoyanagi, Takaaki Mihara, Teruhisa Tanaka, Takeshi Higuchi, Hiroshi Morita, Hiroshi Jinnai

POLYMER　116　556-564　2017/05

DOI： 10.1016/j.polymer.2017.01.072 　

ISSN： 0032-3861

eISSN： 1873-2291
Automated discrete electron tomography - Towards routine high-fidelity reconstruction of nanomaterials International-journal International-coauthorship Peer-reviewed

Xiaodong Zhuge, Hiroshi Jinnai, Rafal E. Dunin-Borkowski, Vadim Migunov, Sara Bals, Pegie Cool, Anton-Jan Bons, Kees Joost Batenburg

ULTRAMICROSCOPY　175　87-96　2017/04

DOI： 10.1016/j.ultramic.2017.01.009 　

ISSN： 0304-3991

eISSN： 1879-2723
Liquid Marbles from Polymer Particles: Formation Mechanism, Physical Characterizations, and Applications Peer-reviewed

Daisuke MATSUKUMA, Hirohmi WATANABE, Hui WU, Shigesaburo OGAWA, Hiroshi JINNAI, Atsushi TAKAHARA

KOBUNSHI RONBUNSHU　74　(1)　26-35　2017
Publisher: Society of Polymer Science, Japan
DOI： 10.1295/koron.2016-0050 　

ISSN： 0386-2186

eISSN： 1881-5685
Observation of constraint surface dynamics of polystyrene thin films by functionalization of a silsesquioxane cage Peer-reviewed

Taiki Hoshino, Shiki Nojima, Masanao Sato, Tomoyasu Hirai, Yuji Higaki, So Fujinami, Daiki Murakami, Shigesaburo Ogawa, Hiroshi Jinnai, Atsushi Takahara, Masaki Takata

POLYMER　105　487-499　2016/11

DOI： 10.1016/j.polymer.2016.08.040 　

ISSN： 0032-3861

eISSN： 1873-2291
Multipod Structures of Lamellae-Forming Diblock Copolymers in Three-Dimensional Confinement Spaces: Experimental Observation and Computer Simulation International-journal International-coauthorship Peer-reviewed

Takeshi Higuchi, Marco Pinna, Andrei V. Zvelindovsky, Hiroshi Jinnai, Hiroshi Yabu

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS　54　(17)　1702-1709　2016/09

DOI： 10.1002/polb.24072 　

ISSN： 0887-6266

eISSN： 1099-0488
Lateral Growth of 1D Core-Crystalline Micelles upon Annealing in Solution Peer-reviewed

Gerald Guerin, Paul Rupar, Gregory Molev, Ian Manners, Hiroshi Jinnai, Mitchell A. Winnik

MACROMOLECULES　49　(18)　7004-7014　2016/09

DOI： 10.1021/acs.macromol.6b01487 　

ISSN： 0024-9297

eISSN： 1520-5835
Swollen structure and electrostatic interactions of polyelectrolyte brush in aqueous solution Peer-reviewed

Daiki Murakami, Motoyasu Kobayashi, Yuji Higaki, Hiroshi Jinnai, Atsushi Takahara

POLYMER　98　464-469　2016/08

DOI： 10.1016/j.polymer.2016.04.041 　

ISSN： 0032-3861

eISSN： 1873-2291
Direct Characterization of In-Plane Phase Separation in Polystyrene Brush/Cyclohexane System Peer-reviewed

Daiki Murakami, Yuki Norizoe, Yuji Higaki, Atsushi Takahara, Hiroshi Jinnai

MACROMOLECULES　49　(13)　4862-4866　2016/07

DOI： 10.1021/acs.macromol.6b00151 　

ISSN： 0024-9297

eISSN： 1520-5835
Direct observation of polyelectrolyte brushes under wet and dry conditions by atmospheric scanning electron microscopy Peer-reviewed

Takeshi Higuchi, Yuji Konyuba, Hidetoshi Nishiyama, Mitsuo Suga, Atsushi Takahara, Hiroshi Jinnai

MICROSCOPY　65　(2)　139-144　2016/04

DOI： 10.1093/jmicro/dfv357 　

ISSN： 2050-5698

eISSN： 2050-5701
Controlled incorporation behavior of gold nanoparticles into ABC triblock terpolymer with double-helical morphology Peer-reviewed

Takeshi Higuchi, Hidekazu Sugimori, Hiroshi Yabu, Hiroshi Jinnai

POLYMER JOURNAL　48　(4)　509-515　2016/04

DOI： 10.1038/pj.2016.19 　

ISSN： 0032-3896

eISSN： 1349-0540
Interface manipulated two-phase nanostructure in a triblock terpolymer with a short middle segment Peer-reviewed

Rina Maeda, Takeshi Higuchi, Kenta Okuhara, Ryohei Kikuchi, Atsushi Takahara, Christopher K. Ober, Hiroshi Jinnai, Teruaki Hayakawa

POLYMER JOURNAL　48　(4)　533-538　2016/04

DOI： 10.1038/pj.2016.25 　

ISSN： 0032-3896

eISSN： 1349-0540
Yolk/Shell Assembly of Gold Nanoparticles by Size Segregation in Solution Peer-reviewed

Jinjian Wei, Kenichi Niikura, Takeshi Higuchi, Takashi Kimura, Hideyuki Mitomo, Hiroshi Jinnai, Yasumasa Joti, Yoshitaka Bessho, Yoshinori Nishino, Yasutaka Matsuo, Kuniharu Ijiro

Journal of the American Chemical Society　138　(10)　3274-3277　2016/03/16
Publisher: American Chemical Society (ACS)
DOI： 10.1021/jacs.5b12456 　

ISSN： 0002-7863

eISSN： 1520-5126
Silver Nanoparticle Arrays Prepared by In Situ Automatic Reduction of Silver Ions in Mussel-Inspired Block Copolymer Films Peer-reviewed

Yuta Saito, Takeshi Higuchi, Hiroshi Jinnai, Mitsuo Hara, Shusaku Nagano, Yasutaka Matsuo, Hiroshi Yabu

MACROMOLECULAR CHEMISTRY AND PHYSICS　217　(6)　726-734　2016/03

DOI： 10.1002/macp.201500504 　

ISSN： 1022-1352

eISSN： 1521-3935
Highly robust crystalsome via directed polymer crystallization at curved liquid/liquid interface Peer-reviewed

Wenda Wang, Hao Qi, Tian Zhou, Shan Mei, Lin Han, Takeshi Higuchi, Hiroshi Jinnai, Christopher Y. Li

NATURE COMMUNICATIONS　7　2016/02

DOI： 10.1038/ncomms10599 　

ISSN： 2041-1723
How does dense phase CO2 influence the phase behaviour of block copolymers synthesised by dispersion polymerisation? Peer-reviewed

J. Jennings, S. P. Bassett, D. Hermida-Merino, G. Portale, W. Bras, L. Knight, J. J. Titman, T. Higuchi, H. Jinnai, S. M. Howdle

Polymer Chemistry　7　(4)　905-916　2016/01/28
Publisher: Royal Society of Chemistry
DOI： 10.1039/c5py01823d 　

ISSN： 1759-9962 1759-9954
Evaluation of the appropriate size of the finite element representative volume for filled rubber composite analyses Peer-reviewed

Kadowaki Hiroshi, Hashimoto Gaku, Okuda Hiroshi, Higuchi Takeshi, Jinnai Hiroshi, Seta Eisuke, Saguchi Takanari

MECHANICAL ENGINEERING JOURNAL　3　(5)　16-00372　2016

DOI： 10.1299/mej.16-00372 　

ISSN： 2187-9745

eISSN： 2187-9745
Salt Dependence of the Chain Stiffness and Excluded-Volume Strength for the Polymethacrylate-Type Sulfopropylbetaine in Aqueous NaCl Solutions Peer-reviewed

Moriya Kikuchi, Yuki Terayama, Tatsuya Ishikawa, Taiki Hoshino, Motoyasu Kobayashi, Noboru Ohta, Hiroshi Jinnai, Atsushi Takahara

MACROMOLECULES　48　(19)　7194-7204　2015/10

DOI： 10.1021/acs.macromol.5b01116 　

ISSN： 0024-9297

eISSN： 1520-5835
Frozen non-equilibrium structure for anisotropically deformed natural rubber with nanomatrix structure observed by 3D FIB-SEM and electron tomography Peer-reviewed

Lina Fukuhara, Kenichiro Kosugi, Yoshimasa Yamamoto, Hiroshi Jinnai, Hideo Nishioka, Hiroyuki Ishii, Masao Fukuda, Seiichi Kawahara

COLLOID AND POLYMER SCIENCE　293　(9)　2555-2563　2015/09

DOI： 10.1007/s00396-015-3631-7 　

ISSN： 0303-402X

eISSN： 1435-1536
Mixing of immiscible polymers using nanoporous coordination templates Peer-reviewed

Takashi Uemura, Tetsuya Kaseda, Yotaro Sasaki, Munehiro Inukai, Takaaki Toriyama, Atsushi Takahara, Hiroshi Jinnai, Susumu Kitagawa

NATURE COMMUNICATIONS　6　7473　2015/07

DOI： 10.1038/ncomms8473 　

ISSN： 2041-1723
One-step nanopatterning of conjugated polymers by electron-beam-assisted electropolymerization Peer-reviewed

Takeshi Higuchi, Hidetoshi Nishiyama, Mitsuo Suga, Hirohmi Watanabe, Atsushi Takahara, Hiroshi Jinnai

MICROSCOPY　64　(3)　205-212　2015/06

DOI： 10.1093/jmicro/dfv013 　

ISSN： 2050-5698

eISSN： 2050-5701
Correction: Real-space evidence of the equilibrium ordered bicontinuous double diamond structure of a diblock copolymer (Soft Matter (2015) 11 (1871-1876)) Peer-reviewed

C. Y. Chu, X. Jiang, H. Jinnai, R. Y. Pei, W. F. Lin, J. C. Tsai, H. L. Chen

Soft Matter　11　(20)　4142　2015/05/28
Publisher: Royal Society of Chemistry
DOI： 10.1039/c5sm90077h 　

ISSN： 1744-6848 1744-683X
Fabrication of NIR-Excitable SERS-Active Composite Particles Composed of Densely Packed Au Nanoparticles on Polymer Microparticles Peer-reviewed

Masaaki Kanahara, Hiroki Satoh, Takeshi Higuchi, Atsushi Takahara, Hiroshi Jinnai, Koji Harano, Satoshi Okada, Eiichi Nakamura, Yasutaka Matsuo, Hiroshi Yabu

Particle & Particle Systems Characterization　32　(4)　441-447　2015/04

DOI： 10.1002/ppsc.201400191 　

ISSN： 0934-0866

eISSN： 1520-5126
Gold Nanoparticles: Fabrication of NIR-Excitable SERS-Active Composite Particles Composed of Densely Packed Au Nanoparticles on Polymer Microparticles (Part. Part. Syst. Charact. 4/2015) Peer-reviewed

Masaaki Kanahara, Hiroki Satoh, Takeshi Higuchi, Atsushi Takahara, Hiroshi Jinnai, Koji Harano, Satoshi Okada, Eiichi Nakamura, Yasutaka Matsuo, Hiroshi Yabu

Particle & Particle Systems Characterization　32　(4)　401　2015/04
Publisher: Wiley-Blackwell
DOI： 10.1002/ppsc.201570012 　
Fabrication of NIR-Excitable SERS-Active Composite Particles Composed of Densely Packed Au Nanoparticles on Polymer Microparticles Peer-reviewed

Masaaki Kanahara, Hiroki Satoh, Takeshi Higuchi, Atsushi Takahara, Hiroshi Jinnai, Koji Harano, Satoshi Okada, Eiichi Nakamura, Yasutaka Matsuo, Hiroshi Yabu

PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION　32　(4)　441-447　2015/04

DOI： 10.1002/ppsc.201400191 　

ISSN： 0934-0866

eISSN： 1521-4117
Structural Analysis of Microphase Separated Interface in an ABC-Type Triblock Terpolymer by Combining Methods of Synchrotron-Radiation Grazing Incidence Small-Angle X-ray Scattering and Electron Microtomography Peer-reviewed

Ryohei Ishige, Takeshi Higuchi, Xi Jiang, Kazuki Mita, Hiroki Ogawa, Hideaki Yokoyama, Atsushi Takahara, Hiroshi Jinnai

MACROMOLECULES　48　(8)　2697-2705　2015/04

DOI： 10.1021/ma502596a 　

ISSN： 0024-9297

eISSN： 1520-5835
Real-space evidence of the equilibrium ordered bicontinuous double diamond structure of a diblock copolymer Peer-reviewed

C. Y. Chu, X. Jiang, H. Jinnai, R. Y. Pei, W. F. Lin, J. C. Tsai, H. L. Chen

Soft Matter　11　(10)　1871-1876　2015/03/14
Publisher: Royal Society of Chemistry
DOI： 10.1039/c4sm02608j 　

ISSN： 1744-6848 1744-683X
Morphological Investigation of Midblock-Sulfonated Block Ionomers Prepared from Solvents Differing in Polarity Peer-reviewed

Kenneth P. Mineart, Xi Jiang, Hiroshi Jinnai, Atsushi Takahara, Richard J. Spontak

MACROMOLECULAR RAPID COMMUNICATIONS　36　(5)　432-438　2015/03

DOI： 10.1002/marc.201400627 　

ISSN： 1022-1336

eISSN： 1521-3927
A compatible crosslinker for enhancement of CO2 capture of poly (amidoamine) dendrimer-containing polymeric membranes Peer-reviewed

Ikuo Taniguchi, Teruhiko Kai, Shuhong Duan, Shingo Kazama, Hiroshi Jinnai

JOURNAL OF MEMBRANE SCIENCE　475　175-183　2015/02

DOI： 10.1016/j.memsci.2014.10.015 　

ISSN： 0376-7388

eISSN： 1873-3123
X-ray Computerized Tomography Observation of the Interfacial Structure of Liquid Marbles Peer-reviewed

Daisuke Matsukuma, Hirohmi Watanabe, Aya Fujimoto, Kentaro Uesugi, Akihisa Takeuchi, Yoshio Suzuki, Hiroshi Jinnai, Atsushi Takahara

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN　88　(1)　84-88　2015/01

DOI： 10.1246/bcsj.20140260 　

ISSN： 0009-2673

eISSN： 1348-0634
FIB processing for natural rubber with nanomatrix structure Peer-reviewed

Lina Fukuhara, Kenichiro Kosugi, Yoshimasa Yamamoto, Hiroshi Jinnai, Hideo Nishioka, Hiroyuki Ishii, Seiichi Kawahara

POLYMER　57　143-149　2015/01

DOI： 10.1016/j.polymer.2014.11.020 　

ISSN： 0032-3861

eISSN： 1873-2291
Epitaxial Phase Transition between Double Gyroid and Cylinder Phase in Diblock Copolymer Thin Film Peer-reviewed

Jueun Jung, Junyoung Lee, Hae-Woong Park, Taihyun Chang, Hidekazu Sugimori, Hiroshi Jinnai

MACROMOLECULES　47　(24)　8761-8767　2014/12

DOI： 10.1021/ma5020275 　

ISSN： 0024-9297

eISSN： 1520-5835
The Role of Solvent Additive Processing in High Performance Small Molecule Solar Cells Peer-reviewed

Louis A. Perez, James T. Rogers, Michael A. Brady, Yanming Sun, Gregory C. Welch, Kristin Schmidt, Michael F. Toney, Hiroshi Jinnai, Alan J. Heeger, Michael L. Chabinyc, Guillermo C. Bazan, Edward J. Kramer

CHEMISTRY OF MATERIALS　26　(22)　6531-6541　2014/11

DOI： 10.1021/cm5031987 　

ISSN： 0897-4756

eISSN： 1520-5002
Molecular self-assembly of nylon-12 nanorods cylindrically confined to nanoporous alumina Peer-reviewed

Yan Cao, Hui Wu, Yuji Higaki, Hiroshi Jinnai, Atsushi Takahara

IUCRJ　1　439-445　2014/11

DOI： 10.1107/S2052252514020132 　

ISSN： 2052-2525
Cutting Edge of Imaging Techniques for Polymer Materials and Its Application of Nanofabrication Peer-reviewed

Takeshi Higuchi, Hiroshi Jinnai

SEN-I GAKKAISHI　70　(10)　650-654　2014/10

ISSN： 0037-9875
Liquid Marbles Supported by Monodisperse Poly(methylsilsesquioxane) Particles Peer-reviewed

Shigesaburo Ogawa, Hirohmi Watanabe, Liming Wang, Hiroshi Jinnai, Thomas J. McCarthy, Atsushi Takahara

LANGMUIR　30　(30)　9071-9075　2014/08

DOI： 10.1021/la5017142 　

ISSN： 0743-7463
Effect of Water Swelling on the Tribological Properties of PMMA Spin-Cast Film and Brush in Aqueous Environment Peer-reviewed

Myo Minn, Motoyasu Kobayashi, Hiroshi Jinnai, Hirohmi Watanabe, Atsushi Takahara

TRIBOLOGY LETTERS　55　(1)　121-129　2014/07

DOI： 10.1007/s11249-014-0339-7 　

ISSN： 1023-8883

eISSN： 1573-2711
Frustrated phases: Polymeric self-assemblies in a 3D confinement Peer-reviewed

Hiroshi Yabu, Takeshi Higuchi, Hiroshi Jinnai

Soft Matter　10　(17)　2919-2931　2014/05/07

DOI： 10.1039/c3sm52821a 　

ISSN： 1744-683X 1744-6848
Preparation and characterization of polycarbonate nanocornposites based on surface-modified halloysite nanotubes Peer-reviewed

Hui Jing, Yuji Higaki, Wei Ma, Jiang Xi, Hiroshi Jinnai, Hideyuki Otsuka, Atsushi Takahara

POLYMER JOURNAL　46　(5)　307-312　2014/05

DOI： 10.1038/pj.2013.100 　

ISSN： 0032-3896

eISSN： 1349-0540
Nanometer-scale Real-space Observation and Material Processing for Polymer Materials under Atmospheric Pressure: Application of Atmospheric Scanning Electron Microscopy Peer-reviewed

Takeshi Higuchi, Daiki Murakami, Hidetoshi Nishiyama, Mitsuo Suga, Atsushi Takahara, Hiroshi Jinnai

ELECTROCHEMISTRY　82　(5)　359-363　2014/05

DOI： 10.5796/electrochemistry.82.359 　

ISSN： 1344-3542
Large-scale self-assembled zirconium phosphate smectic layers via a simple spray-coating process Peer-reviewed

Minhao Wong, Ryohei Ishige, Kevin L. White, Peng Li, Daehak Kim, Ramanan Krishnamoorti, Robert Gunther, Takeshi Higuchi, Hiroshi Jinnai, Atsushi Takahara, Riichi Nishimura, Hung-Jue Sue

NATURE COMMUNICATIONS　5　5389　2014/04

DOI： 10.1038/ncomms4589 　

ISSN： 2041-1723
Organic Solar Cells Based on Three-Dimensionally Percolated Polythiophene Nanowires with Enhanced Charge Transport Peer-reviewed

Joo-Hyun Kim, Min Kim, Hiroshi Jinnai, Tae Joo Shin, Haena Kim, Jong Hwan Park, Sae Byeok Jo, Kilwon Cho

ACS APPLIED MATERIALS & INTERFACES　6　(8)　5640-5650　2014/04

DOI： 10.1021/am501358k 　

ISSN： 1944-8244
Wetting Transition from the Cassie-Baxter State to the Wenzel State on Textured Polymer Surfaces Peer-reviewed

Daiki Murakami, Hiroshi Jinnai, Atsushi Takahara

LANGMUIR　30　(8)　2061-2067　2014/03

DOI： 10.1021/la4049067 　

ISSN： 0743-7463
Two-dimensional percolation phenomena of single-component linear homopolymer brushes Peer-reviewed

Yuki Norizoe, Hiroshi Jinnai, Atsushi Takahara

JOURNAL OF CHEMICAL PHYSICS　140　(5)　2014/02

DOI： 10.1063/1.4863328 　

ISSN： 0021-9606

eISSN： 1089-7690
Synthesis of Titanium-Containing Block, Random, End-Functionalized, and Junction-Functionalized Polymers via Ruthenium-Catalyzed Living Radical Polymerization and Direct Observation of Titanium Domains by Electron Microscopy Peer-reviewed

Yasutaka Tsujimoto, Kotaro Satoh, Hidekazu Sugimori, Hiroshi Jinnai, Masami Kamigaito

MACROMOLECULES　47　(3)　944-953　2014/02

DOI： 10.1021/ma402332g 　

ISSN： 0024-9297

eISSN： 1520-5835
Linking experiment and theory for three-dimensional networked binary metal nanoparticle-triblock terpolymer superstructures Peer-reviewed

Zihui Li, Kahyun Hur, Hiroaki Sai, Takeshi Higuchi, Atsushi Takahara, Hiroshi Jinnai, Sol M. Gruner, Ulrich Wiesner

NATURE COMMUNICATIONS　5　3247　2014/02

DOI： 10.1038/ncomms4247 　

ISSN： 2041-1723
Electrical Performance of Organic Solar Cells with AdditiveAssisted Vertical Phase Separation in the Photoactive Layer Peer-reviewed

Min Kim, Joo-Hyun Kim, Hyun Ho Choi, Jong Hwan Park, Sae Byeok Jo, Myungsun Sim, Jong Soo Kim, Hiroshi Jinnai, Yeong Don Park, Kilwon Cho

ADVANCED ENERGY MATERIALS　4　(2)　2014/01

DOI： 10.1002/aenm.201300612 　

ISSN： 1614-6832

eISSN： 1614-6840
Development of CO2 Separation Membrane with Poly(amido amine) Dendrimer Peer-reviewed

Ikuo TANIGUCHI, Teruhiko KAI, Shuhong DUAN, Shingo KAZAMA, Hiroshi JINNAI

KOBUNSHI RONBUNSHU　71　(5)　202-210　2014

DOI： 10.1295/koron.71.202 　

ISSN： 0386-2186

eISSN： 1881-5685
Robust liquid marbles stabilized with surface-modified halloysite nanotubes Peer-reviewed

Hui Wu, Hirohmi Watanabe, Wei Ma, Aya Fujimoto, Takeshi Higuchi, Kentaro Uesugi, Akihisa Takeuchi, Yoshio Suzuki, Hiroshi Jinnai, Atsushi Takahara

Langmuir　29　(48)　14971-14975　2013/12/03

DOI： 10.1021/la4041858 　

ISSN： 0743-7463 1520-5827
Measurement of the Electrostatic Interaction between Polyelectrolyte Brush Surfaces by Optical Tweezers Peer-reviewed

Daiki Murakami, Ai Takenaka, Motoyasu Kobayashi, Hiroshi Jinnai, Atsushi Takahara

LANGMUIR　29　(52)　16093-16097　2013/12

DOI： 10.1021/la404133e 　

ISSN： 0743-7463
Dynamical crossover between hyperdiffusion and subdiffusion of polymer-grafted nanoparticles in a polymer matrix Peer-reviewed

Taiki Hoshino, Daiki Murakami, Yoshihito Tanaka, Masaki Takata, Hiroshi Jinnai, Atsushi Takahara

PHYSICAL REVIEW E　88　(3)　2013/09

DOI： 10.1103/PhysRevE.88.032602 　

ISSN： 1539-3755
Morphological Control of Helical Structures of an ABC-Type Triblock Terpolymer by Distribution Control of a Blending Homopolymer in a Block Copolymer Microdomain Peer-reviewed

Takeshi Higuchi, Hidekazu Sugimori, Xi Jiang, Song Hong, Kazuyuki Matsunaga, Takeshi Kaneko, Volker Abetz, Atsushi Takahara, Hiroshi Jinnai

MACROMOLECULES　46　(17)　6991-6997　2013/09

DOI： 10.1021/ma401193u 　

ISSN： 0024-9297

eISSN： 1520-5835
Arrangement of Block Copolymer Microdomains Confined inside Hemispherical Cavities Peer-reviewed

Dusik Bae, Gumhye Jeon, Hiroshi Jinnai, June Huh, Jin Kon Kim

MACROMOLECULES　46　(13)　5301-5307　2013/07

DOI： 10.1021/ma4009324 　

ISSN： 0024-9297
Electron tomography in soft materials Invited Peer-reviewed

Hiroshi Jinnai, Xi Jiang

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE　17　(3)　135-142　2013/06

DOI： 10.1016/j.cossms.2013.07.001 　

ISSN： 1359-0286

eISSN： 1879-0348
Counterion-Mediated Hierarchical Self-Assembly of an ABC Miktoarm Star Terpolymer Peer-reviewed

Andreas Hanisch, Andre H. Groeschel, Melanie Foertsch, Markus Drechsler, Hiroshi Jinnai, Thomas M. Ruhland, Felix H. Schacher, Axel H. E. Mueller

ACS NANO　7　(5)　4030-4041　2013/05

DOI： 10.1021/nn400031u 　

ISSN： 1936-0851
Polymer Janus particles containing block-copolymer stabilized magnetic nanoparticles Peer-reviewed

Hiroshi Yabu, Masaaki Kanahara, Masatsugu Shimomura, Toshihiko Arita, Koji Harano, Eiichi Nakamura, Takeshi Higuchi, Hiroshi Jinnai

ACS Applied Materials and Interfaces　5　(8)　3262-3266　2013/04/24

DOI： 10.1021/am4003149 　

ISSN： 1944-8244 1944-8252

eISSN： 1944-8252
Transmission electron microtomography in soft materials Invited Peer-reviewed

Hiroshi Jinnai, Toshihiko Tsuchiya, Sohei Motoki, Takeshi Kaneko, Takeshi Higuchi, Atsushi Takahara

MICROSCOPY　62　(2)　243-258　2013/04

DOI： 10.1093/jmicro/dfs070 　

ISSN： 2050-5698

eISSN： 2050-5701
Surface and Interface Analyses of Polymer Brushes by Synchrotron Radiation Peer-reviewed

Taiki Hoshino, Yoshihito Tanaka, Hiroshi Jinnai, Atsushi Takahara

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN　82　(2)　021014　2013/02

DOI： 10.7566/JPSJ.82.021014 　

ISSN： 0031-9015
Spreading and structuring of water on superhydrophilic polyelectrolyte brush surfaces Peer-reviewed

Daiki Murakami, Motoyasu Kobayashi, Taro Moriwaki, Yuka Ikemoto, Hiroshi Jinnai, Atsushi Takahara

Langmuir　29　(4)　1148-1151　2013/01/29

DOI： 10.1021/la304697q 　

ISSN： 0743-7463 1520-5827
Influence of trace amount of well-dispersed carbon nanotubes on structural development and tensile properties of polypropylene Peer-reviewed

Peng Liu, Kevin L. White, Hiroaki Sugiyama, Jiang Xi, Takeshi Higuchi, Taiki Hoshino, Ryohei Ishige, Hiroshi Jinnai, Atsushi Takahara, Hung-Jue Sue

Macromolecules　46　(2)　463-473　2013/01/22

DOI： 10.1021/ma3020323 　

ISSN： 0024-9297
Molecular simulation of 2-dimensional microphase separation of single-component homopolymers grafted onto a planar substrate

Y. Norizoe, H. Jinnai, A. Takahara

101　(1)　16006-16006　2013/01

DOI： 10.1209/0295-5075/101/16006 　
Thermal gradient effect on the dynamical behavior of nanoparticles observed using X-ray photon correlation spectroscopy Peer-reviewed

Taiki Hoshino, Daiki Murakami, Kiminori Ito, Yoshihito Tanaka, Sono Sasaki, Masaki Takata, Hiroshi Jinnai, Atsushi Takahara

POLYMER JOURNAL　45　(1)　94-99　2013/01

DOI： 10.1038/pj.2012.193 　

ISSN： 0032-3896
Novel neutron reflectometer SOFIA at J-PARC/MLF for in-situ soft-interface characterization Peer-reviewed

Koji Mitamura, Norifui L. Yamada, Hidenori Sagehashi, Naoya Torikai, Hiroshi Arita, Masami Terada, Motoyasu Kobayashi, Setsuo Sato, Hideki Seto, Shinji Goko, Michihiro Furusaka, Tatsuro Oda, Masahiro Hino, Hiroshi Jinnai, Atsushi Takahara

POLYMER JOURNAL　45　(1)　100-108　2013/01

DOI： 10.1038/pj.2012.156 　

ISSN： 0032-3896
Chain-mixing behavior at interface between polystyrene brushes and polystyrene matrices Peer-reviewed

Hiroshi Arita, Koji Mitamura, Motoyasu Kobayashi, Norifumi L. Yamada, Hiroshi Jinnai, Atsushi Takahara

Polymer Journal　45　(1)　117-123　2013/01

DOI： 10.1038/pj.2012.198 　

ISSN： 0032-3896 1349-0540

eISSN： 1349-0540
Experimental station for multiscale surface structural analyses of soft-material films at SPring-8 via a GISWAX/GIXD/XR-integrated system Peer-reviewed

Hiroki Ogawa, Hiroyasu Masunaga, Sono Sasaki, Shunji Goto, Takashi Tanaka, Takamitsu Seike, Sunao Takahashi, Kunikazu Takeshita, Nobuteru Nariyama, Haruhiko Ohashi, Toru Ohata, Yukito Furukawa, Tomohiro Matsushita, Yasuhide Ishizawa, Naoto Yagi, Masaki Takata, Hideo Kitamura, Atsushi Takahara, Kazuo Sakurai, Kohji Tashiro, Toshiji Kanaya, Yoshiyuki Amemiya, Kazuyuki Horie, Mikihito Takenaka, Hiroshi Jinnai, Hiroshi Okuda, Isamu Akiba, Isao Takahashi, Katsuhiro Yamamoto, Masamichi Hikosaka, Shinichi Sakurai, Yuya Shinohara, Yasunori Sugihara, Akihiko Okada

Polymer Journal　45　(1)　109-116　2013/01

DOI： 10.1038/pj.2012.194 　

ISSN： 0032-3896 1349-0540

eISSN： 1349-0540
Preparation of poly(lactic-acid)-particle stabilized liquid marble and the improvement of its stability by uniform shell formation through solvent vapor exposure Peer-reviewed

Daisuke Matsukuma, Hirohmi Watanabe, Myo Minn, Aya Fujimoto, Takamichi Shinohara, Hiroshi Jinnai, Atsushi Takahara

RSC ADVANCES　3　(21)　7862-7866　2013

DOI： 10.1039/c3ra40693h 　

ISSN： 2046-2069
Effect of the phase-separated structure on CO2 separation performance of the poly(amidoamine) dendrimer immobilized in a poly(ethylene glycol) network Peer-reviewed

Ikuo Taniguchi, Shuhong Duan, Teruhiko Kai, Shingo Kazama, Hiroshi Jinnai

JOURNAL OF MATERIALS CHEMISTRY A　1　(46)　14514-14523　2013

DOI： 10.1039/c3ta13711b 　

ISSN： 2050-7488

eISSN： 2050-7496
X-ray photon correlation spectroscopy using a fast pixel array detector with a grid mask resolution enhancer Peer-reviewed

Taiki Hoshino, Moriya Kikuchi, Daiki Murakami, Yoshiko Harada, Koji Mitamura, Kiminori Ito, Yoshihito Tanaka, Sono Sasaki, Masaki Takata, Hiroshi Jinnai, Atsushi Takahara

JOURNAL OF SYNCHROTRON RADIATION　19　988-993　2012/11

DOI： 10.1107/S0909049512038769 　

ISSN： 1600-5775

eISSN： 1600-5775
Tetragonally Perforated Lamellae of Polybutadiene-block-poly(2-vinylpyridine)-block-poly(tert-butyl methacrylate) (BVT) Triblock Terpolymers in the Bulk: Preparation, Cross-Linking, and Dissolution Peer-reviewed

Felix H. Schacher, Hidekazu Sugimori, Song Hong, Hiroshi Jinnai, Axel H. E. Mueller

MACROMOLECULES　45　(19)　7956-7963　2012/10

DOI： 10.1021/ma3012398 　

ISSN： 0024-9297

eISSN： 1520-5835
Structural analysis of poly(amidoamine) dendrimer immobilized in crosslinked poly(ethylene glycol) Peer-reviewed

Ikuo Taniguchi, Shingo Kazama, Hiroshi Jinnai

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS　50　(16)　1156-1164　2012/08

DOI： 10.1002/polb.23095 　

ISSN： 0887-6266

eISSN： 1099-0488
Tilt-angle measurement of a sample stage using a capacitive liquid-based inclinometer Peer-reviewed

Kyoko Matoba, Junichi Takagi, Takuo Yasunaga, Hiroshi Jinnai, Kenji Iwasaki

JOURNAL OF ELECTRON MICROSCOPY　61　(3)　193-198　2012/06

DOI： 10.1093/jmicro/dfs034 　

ISSN： 0022-0744
Highly oriented and ordered double-helical morphology in ABC triblock terpolymer films up to micrometer thickness by solvent evaporation Peer-reviewed

Song Hong, Takeshi Higuchi, Hidekazu Sugimori, Takeshi Kaneko, Volker Abetz, Atsushi Takahara, Hiroshi Jinnai

POLYMER JOURNAL　44　(6)　567-572　2012/06

DOI： 10.1038/pj.2012.69 　

ISSN： 0032-3896
Gold Nanoparticles Coated with Semi-Fluorinated Oligo(ethylene glycol) Produce Sub-100 nm Nanoparticle Vesicles without Templates Peer-reviewed

Kenichi Niikura, Naoki Iyo, Takeshi Higuchi, Takashi Nishio, Hiroshi Jinnai, Naoki Fujitani, Kuniharu Ijiro

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　134　(18)　7632-7635　2012/05

DOI： 10.1021/ja302122w 　

ISSN： 0002-7863
Recent Advances in Multi-Scale Tomographic Techniques in Polymer Research Peer-reviewed

Hiroshi JINNAI

KOBUNSHI RONBUNSHU　69　(7)　358-365　2012
Publisher: Society of Polymer Science, Japan
DOI： 10.1295/koron.69.358 　

ISSN： 0386-2186

eISSN： 1881-5685
Morphological transition of triblock copolymer cylindrical micelles responding to solvent change Peer-reviewed

Dehui Han, Xiaoyu Li, Song Hong, Hiroshi Jinnai, Guojun Liu

SOFT MATTER　8　(7)　2144-2151　2012

DOI： 10.1039/c2sm07020k 　

ISSN： 1744-683X
Three-dimensional observation of confined phase-separated structures in block copolymer nanoparticles Peer-reviewed

Takeshi Higuchi, Kiwamu Motoyoshi, Hidekazu Sugimori, Hiroshi Jinnai, Hiroshi Yabu, Masatsugu Shimomura

SOFT MATTER　8　(14)　3791-3797　2012

DOI： 10.1039/c2sm07139h 　

ISSN： 1744-683X
Creating suprapolymer assemblies: nanowires, nanorings, and nanospheres prepared from symmetric block-copolymers confined in spherical particles Peer-reviewed

Hiroshi Yabu, Shunsuke Sato, Takeshi Higuchi, Hiroshi Jinnai, Masatsugu Shimomura

JOURNAL OF MATERIALS CHEMISTRY　22　(16)　7672-7675　2012

DOI： 10.1039/c2jm30236e 　

ISSN： 0959-9428
Three-Dimensional Spatial Distributions of Pt Catalyst Nanoparticles on Carbon Substrates in Polymer Electrolyte Fuel Cells

Toshihiko ITO, Ukyo MATSUWAKI, Yuji OTSUKA, Masahiro HATTA, Katsuichiro HAYAKAWA, Koichi MATSUTANI, Tomoyuki TADA, Hiroshi JINNAI

Electrochemistry　79　(5)　374-376　2011/05
Publisher: The Electrochemical Society of Japan
DOI： 10.5796/electrochemistry.79.374 　

ISSN： 1344-3542

eISSN： 2186-2451
Multipurpose soft-material SAXS/WAXS/GISAXS beamline at SPring-8 Peer-reviewed

Hiroyasu Masunaga, Hiroki Ogawa, Takumi Takano, Sono Sasaki, Shunji Goto, Takashi Tanaka, Takamitsu Seike, Sunao Takahashi, Kunikazu Takeshita, Nobuteru Nariyama, Haruhiko Ohashi, Toru Ohata, Yukito Furukawa, Tomohiro Matsushita, Yasuhide Ishizawa, Naoto Yagi, Masaki Takata, Hideo Kitamura, Kazuo Sakurai, Kohji Tashiro, Atsushi Takahara, Yoshiyuki Amamiya, Kazuyuki Horie, Mikihito Takenaka, Toshiji Kanaya, Hiroshi Jinnai, Hiroshi Okuda, Isamu Akiba, Isao Takahashi, Katsuhiro Yamamoto, Masamichi Hikosaka, Shinichi Sakurai, Yuya Shinohara, Akihiko Okada, Yasunori Sugihara

POLYMER JOURNAL　43　(5)　471-477　2011/05

DOI： 10.1038/pj.2011.18 　

ISSN： 0032-3896
Single chain distribution analysis near a substrate using a combined method of three-dimensional imaging and SCF simulation Peer-reviewed

Hiroshi Morita, Hidekazu Sugimori, Masao Doi, Hiroshi Jinnai

EUROPEAN POLYMER JOURNAL　47　(4)　685-691　2011/04

DOI： 10.1016/j.eurpolymj.2010.09.038 　

ISSN： 0014-3057
New aspects of polymer alloys and TPES revealed by polymer nanotechnology

Nishi Toshio, Ken Nakajima, Hiroshi Jinnai

Chemicke Listy　105　(15)　s236-s239　2011

ISSN： 0009-2770 1213-7103
Structural characterization of the Fddd phase in a diblock copolymer thin film by electron microtomography Peer-reviewed

Jueun Jung, Hae-Woong Park, Junyoung Lee, Haiying Huang, Taihyun Chang, Yecheol Rho, Moonhor Ree, Hidekazu Sugimori, Hiroshi Jinnai

SOFT MATTER　7　(21)　10424-10428　2011

DOI： 10.1039/c1sm06236k 　

ISSN： 1744-683X
Phase Transition and Phase Transformation in Block Copolymer Nanoparticles Peer-reviewed

Takeshi Higuchi, Kiwamu Motoyoshi, Hidekazu Sugimori, Hiroshi Jinnai, Hiroshi Yabu, Masatsugu Shimomura

MACROMOLECULAR RAPID COMMUNICATIONS　31　(20)　1773-1778　2010/10

DOI： 10.1002/marc.201000299 　

ISSN： 1022-1336
Solvent-Driven Evolution of Block Copolymer Morphology under 3D Confinement Peer-reviewed

Le Li, Kazuyuki Matsunaga, Jintao Zhu, Takeshi Higuchi, Hiroshi Yabu, Masatsugu Shimomura, Hiroshi Jinnai, Ryan C. Hayward, Thomas P. Russell

MACROMOLECULES　43　(18)　7807-7812　2010/09

DOI： 10.1021/ma101529b 　

ISSN： 0024-9297
Current-Injected Spectrally-Narrowed Emissions from an Organic Transistor Peer-reviewed

Takeshi Yamao, Yoichi Sakurai, Kohei Terasaki, Yasuhiro Shimizu, Hiroshi Jinnai, Shu Hotta

ADVANCED MATERIALS　22　(33)　3708-+　2010/09

DOI： 10.1002/adma.201000171 　

ISSN： 0935-9648
Dependence of beam broadening on detection angle in scanning transmission electron microtomography Peer-reviewed

Sohei Motoki, Takeshi Kaneko, Yoshitaka Aoyama, Hideo Nishioka, Yoshihiro Okura, Yukihito Kondo, Hiroshi Jinnai

JOURNAL OF ELECTRON MICROSCOPY　59　S45-S53　2010/08

DOI： 10.1093/jmicro/dfq030 　

ISSN： 0022-0744
Effect of Film Thickness on the Phase Behaviors of Diblock Copolymer Thin Film Peer-reviewed

Jueun Jung, Hae-Woong Park, Sekyung Lee, Hyojoon Lee, Taihyun Chang, Kazuyuki Matsunaga, Hiroshi Jinnai

ACS NANO　4　(6)　3109-3116　2010/06

DOI： 10.1021/nn1003309 　

ISSN： 1936-0851
Transmission Electron Microtomography and Polymer Nanostructures Invited Peer-reviewed

Hiroshi Jinnai, Richard J. Spontak, Toshio Nishi

MACROMOLECULES　43　(4)　1675-1688　2010/02

DOI： 10.1021/ma902035p 　

ISSN： 0024-9297
3-Dimensional characterization of membrane with nanoporous structure using TEM tomography and image analysis Peer-reviewed

F. H. She, K. Nihara, W. M. Gao, P. D. Hodgson, H. Jinnai, L. X. Kong

Desalination　250　(2)　757-761　2010/01/15

DOI： 10.1016/j.desal.2008.11.036 　

ISSN： 0011-9164
電子線トモグラフィー法その1：原理

金子賢治, 馬場則男, 陣内浩司

顕微鏡　45　(1)　37-41　2010

DOI： 10.11410/kenbikyo.45.1_37 　
電子線トモグラフィー法その2：課題と応用例

金子賢治, 馬場則男, 陣内浩司

顕微鏡　45　(2)　109-113　2010

DOI： 10.11410/kenbikyo.45.2_109 　
Grating-Assisted Spectrally-Narrowed Emissions from an Organic Slab Crystal Excited with a Mercury Lamp Peer-reviewed

Shu Hotta, Yoichi Sakurai, Yuki Okuda, Tomoharu Miki, Kazuyuki Matsunaga, Fumio Hirato, Takeshi Yamao, Hiroshi Jinnai

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY　10　(1)　440-447　2010/01

DOI： 10.1166/jnn.2010.1743 　

ISSN： 1533-4880
Selected-area in situ generation of highly fluorescent organic nanowires embedded in a polymer film: the solvent-vapor-induced self-assembly process Peer-reviewed

Jong Won Chung, Byeong-Kwan An, Fumio Hirato, Jong H. Kim, Hiroshi Jinnai, Soo Young Park

JOURNAL OF MATERIALS CHEMISTRY　20　(36)　7715-7720　2010

DOI： 10.1039/c0jm00896f 　

ISSN： 0959-9428
Small-molecule-directed nanoparticle assembly towards stimuli-responsive nanocomposites Peer-reviewed

Yue Zhao, Kari Thorkelsson, Alexander J. Mastroianni, Thomas Schilling, Joseph M. Luther, Benjamin J. Rancatore, Kazuyuki Matsunaga, Hiroshi Jinnai, Yue Wu, Daniel Poulsen, Jean M. J. Frechet, A. Paul Alivisatos, Ting Xu

NATURE MATERIALS　8　(12)　979-985　2009/12

DOI： 10.1038/NMAT2565 　

ISSN： 1476-1122
Cylindrically Confined Diblock Copolymers Peer-reviewed

Priyanka Dobriyal, Hongqi Xiang, Matsunaga Kazuyuki, Jiun-Tai Chen, Hiroshi Jinnai, Thomas P. Russell

MACROMOLECULES　42　(22)　9082-9088　2009/11

DOI： 10.1021/ma901730a 　

ISSN： 0024-9297
TEM and STEM tomography for thick polymer sample Peer-reviewed

T. Kaneko, S. Motoki, Y. Aoyama, H. Nishioka, Y. Ohkura, Y. Kondo, H. Jinnai

Microscopy and Microanalysis　15　(2)　630-631　2009/07

DOI： 10.1017/S1431927609093696 　

ISSN： 1431-9276 1435-8115
Transmission electron microtomography in polymer research Invited Peer-reviewed

Hiroshi Jinnai, Richard J. Spontal

POLYMER　50　(5)　1067-1087　2009/02

DOI： 10.1016/j.polymer.2008.12.023 　

ISSN： 0032-3861
Detection Angle Dependence of Beam Broadening on STEM Tomography

Sohei Motoki, Takeshi Kaneko, Yoshitaka Aoyama, Hideo Nishioka, Yoshihiro Okura, Yukihito Kondo, Hiroshi Jinnai

Materia Japan　48　(12)　622-622　2009
Publisher: Japan Institute of Metals
DOI： 10.2320/materia.48.622 　

ISSN： 1340-2625
Polymer nanotechnology applied to polymeric nano-soft-materials

T. Nishi, S. Fujinami, K. Nakajima, H. Sugimori, M. Hatta, M. Weber, H. Jinnai

Journal of Physics: Conference Series　184　012030　2009
Publisher: Institute of Physics Publishing
DOI： 10.1088/1742-6596/184/1/012030 　

ISSN： 1742-6596 1742-6588
The interface dynamics of bicontinuous phase separating structure in a polymer blend

Haruko Saito, Masahiro Yoshinaga, Takaaki Mihara, Toshio Nishi, Hiroshi Jinnai

Journal of Physics: Conference Series　184　012029　2009
Publisher: Institute of Physics Publishing
DOI： 10.1088/1742-6596/184/1/012029 　

ISSN： 1742-6596 1742-6588
Field emission scanning electron microscopy combined with focused ion beam for rubbery material with nano-matrix structure

Keiichi Akabori, Yoshimasa Yamamoto, Seiichi Kawahara, Hiroshi Jinnai, Hideo Nishioka

Journal of Physics: Conference Series　184　012027　2009
Publisher: Institute of Physics Publishing
DOI： 10.1088/1742-6596/184/1/012027 　

ISSN： 1742-6596 1742-6588
New Epitaxial Phase Transition between DG and HEX in PS-b-PI Peer-reviewed

Hae-Woong Park, Jueun Jung, Taihyun Chang, Kazuyuki Matsunaga, Hiroshi Jinnai

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　131　(1)　46-+　2009/01

DOI： 10.1021/ja808259m 　

ISSN： 0002-7863
Self-Assembled ABC Triblock Copolymer Double and Triple Helices Peer-reviewed

John Dupont, Guojun Liu, Ken-ichi Niihara, Ryuhei Kimoto, Hiroshi Jinnai

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　48　(33)　6144-6147　2009

DOI： 10.1002/anie.200901517 　

ISSN： 1433-7851

eISSN： 1521-3773
A double helical structure formed from an amorphous, achiral ABC triblock terpolymer Peer-reviewed

Hiroshi Jinnai, Takeshi Kaneko, Kazuyuki Matsunaga, Clarissa Abetz, Volker Abetz

SOFT MATTER　5　(10)　2042-2046　2009

DOI： 10.1039/b901008d 　

ISSN： 1744-683X
A Transition from Cylindrical to Spherical Morphology in Diblock Copolymer Thin Films Peer-reviewed

Ken-ichi Niihara, Hidekazu Sugimori, Ukyo Matsuwaki, Fumio Hirato, Hiroshi Morita, Masao Doi, Hiroyasu Masunaga, Sono Sasaki, Hiroshi Jinnai

MACROMOLECULES　41　(23)　9318-9325　2008/12

DOI： 10.1021/ma801892p 　

ISSN： 0024-9297
Extreme-Performance Rubber Nanocomposites for and Probing Excavating Deep Oil Resources Using Multi-Walled Carbon Nanotubes Peer-reviewed

Morinobu Endo, Toru Noguchi, Masasei Ito, Kenji Takeuchi, Takuya Hayashi, Yoong Ahm Kim, Takashi Wanibuchi, Hiroshi Jinnai, Mauricio Terrones, Mildred S. Dresselhaus

ADVANCED FUNCTIONAL MATERIALS　18　(21)　3403-3409　2008/11

DOI： 10.1002/adfm.200801136 　

ISSN： 1616-301X

eISSN： 1616-3028
Nanohole Structure Prepared by a Polystyrene-block-poly(methyl methacrylate)/poly(methyl methacrylate) Mixture Film Peer-reviewed

Wonchul Joo, Seung Yun Yang, Jin Kon Kim, Hiroshi Jinnai

LANGMUIR　24　(21)　12612-12617　2008/11

DOI： 10.1021/la8021134 　

ISSN： 0743-7463
Sponge-like Heterogeneous Gels: Hierarchical Structures in Poly(N-isopropylacrylamide) Chemical Gels As Observed by Combined Scattering and Confocal Microscopy Method Peer-reviewed

Yoshitsugu Hirokawa, Takuya Okamoto, Kohtaro Kimishima, Hiroshi Jinnai, Satoshi Koizumi, Kazuya Aizawa, Takeji Hashimoto

MACROMOLECULES　41　(21)　8210-8219　2008/11

DOI： 10.1021/ma800518t 　

ISSN： 0024-9297
Three-dimensional visualization of a single block copolymer in lamellar nanodomains Peer-reviewed

Hiroshi Morita, Toshihiro Kawakatsu, Masao Doi, Toshio Nishi, Hiroshi Jinnai

MACROMOLECULES　41　(13)　4845-4849　2008/07

DOI： 10.1021/ma8003828 　

ISSN： 0024-9297
FIB-SEM and TEMT observation of highly elastic rubbery material with nanomatrix structure

Seiichi Kawahara, Yoshimasa Yamamoto, Shuji Fujii, Yoshinobu Isono, Ken-ichi Niihara, Hiroshi Jinnai, Hideo Nishioka, Akio Takaoka

MACROMOLECULES　41　(12)　4510-4513　2008/06

DOI： 10.1021/ma7028538 　

ISSN： 0024-9297
Self-sealing of nanoporous low dielectric constant patterns fabricated by nanoimprint lithography Peer-reviewed

Hyun Wook Ro, Huagen Peng, Ken-ichi Niihara, Hae-Jeong Lee, Eric K. Lin, Alamgir Karim, David W. Gidley, Hiroshi Jinnai, Do Y. Yoon, Christopher L. Soles

ADVANCED MATERIALS　20　(10)　1934-+　2008/05

DOI： 10.1002/adma.200701994 　

ISSN： 0935-9648
Mesoscopic mechanical analysis of filled elastomer with 3D-Finite Element Analysis and transmission electron microtomography Peer-reviewed

Keizo Akutagwa, Ken Yamaguchi, Atsushi Yamamoto, Hisashi Heguri, Hiroshi Jinnai, Yuki Shinbori

RUBBER CHEMISTRY AND TECHNOLOGY　81　(2)　182-189　2008/05

DOI： 10.5254/1.3548203 　

ISSN： 0035-9475
Morphology and photophysical properties of polymer thin films dispersed with dye nanoparticle Peer-reviewed

Shinjiro Machida, Takeshi Wakamatsu, Sadahiro Masuo, Hiroshi Jinnai, Akira Itaya

THIN SOLID FILMS　516　(9)　2615-2619　2008/03

DOI： 10.1016/j.tsf.2007.04.133 　

ISSN： 0040-6090
Observation of the three-dimensional structure of actin bundles formed with polycations Peer-reviewed

Kazuhiro Shikinaka, Hyuckjoon Kwon, Akira Kakugo, Hidemitsu Furukawa, Yoshihito Sada, Jian Ping Gong, Yoshitaka Aoyama, Hideo Nishioka, Hiroshi Jinnai, Takaharu Okajima

BIOMACROMOLECULES　9　(2)　537-542　2008/02

DOI： 10.1021/bm701068n 　

ISSN： 1525-7797
Maximum diameter of the rod-shaped specimen for transmission electron microtomography without the "missing wedge" Peer-reviewed

Mitsuro Kato, Noboru Kawase, Takeshi Kaneko, Shoichi Toh, Syo Matsumura, Hiroshi Jinnai

ULTRAMICROSCOPY　108　(3)　221-229　2008/02

DOI： 10.1016/j.ultramic.2007.06.004 　

ISSN： 0304-3991
三次元イメージング法の最近の進歩 Peer-reviewed

65　(9)　547-561　2008
Publisher:
DOI： 10.1295/koron.65.547 　

ISSN： 0386-2186

eISSN： 1881-5685
Direct Three-Dimensional Observations of Order-Order Transition from Gyroid to Cylindrical Structures in a Block Copolymer Peer-reviewed

Hidekazu Sugimori, Ken-ichi Nihara, Takeshi Kaneko, Wakana Miyoshi, Hiroshi Jinnai

PROGRESS OF THEORETICAL PHYSICS SUPPLEMENT　175　166-173　2008

ISSN： 0375-9687
Three-dimensional Structural Analysis of Block Copolymer Morphology During the Order-Order transition from Hexagonally Perforated Layer to Gyroid Phase

JINNAI Hiroshi, SAWA Koji, HIRATO Fumio

Materia Japan　46　(12)　799-799　2007/12/01
Publisher: The Japan Institute of Metals and Materials
DOI： 10.2320/materia.46.799 　

ISSN： 1340-2625
Three-dimensional Structural Analysis of Block Copolymer Morphology by Scanning Electron Microscopy Combined with Focused Ion Beam

KATO Mitsuro, KAWASE Noboru, JINNAI Hiroshi

Materia Japan　46　(12)　806-806　2007/12/01
Publisher: The Japan Institute of Metals and Materials
DOI： 10.2320/materia.46.806 　

ISSN： 1340-2625
Three-Dimensional Visualization of Polymeric Materials

JINNAI Hiroshi, KAWASE Noboru, KATO Mitsuro

Journal of the Japan Society of Colour Material　80　(10)　414-419　2007/10/20
Publisher: Japan Society of Colour Material
DOI： 10.4011/shikizai1937.80.414 　

ISSN： 0010-180X
Unusual phase behavior of end-functionalized polystyrene-block-poly(n-butyl methacrylate) copolymer with maleic anhydride Peer-reviewed

Jin Kon Kim, Myung Im Kim, Hye Jeong Kim, Dong Hyun Lee, Unyong Jeong, Hiroshi Jinnai, Kazuya Suda

MACROMOLECULES　40　(21)　7590-7593　2007/10

DOI： 10.1021/ma0712899 　

ISSN： 0024-9297

eISSN： 1520-5835
A novel structural analysis for a cylinder-forming block copolymer thin film using neutron reflectivity aided by transmission electron microtomography Peer-reviewed

Ken-ichi Niihara, Ukyo Matsuwaki, Naoya Torikai, Hironori Atarashi, Keiji Tanaka, Hiroshi Jinnai

MACROMOLECULES　40　(19)　6940-6946　2007/09

DOI： 10.1021/ma071334c 　

ISSN： 0024-9297

eISSN： 1520-5835
Three-dimensional structure of a nanocomposite material consisting of two kinds of nanofillers and rubbery matrix studied by transmission electron microtomography Peer-reviewed

Hiroshi Jinnai, Yuki Shinbori, Tatsuro Kitaoka, Keizo Akutagawa, Naruhiko Mashita, Toshio Nishi

MACROMOLECULES　40　(18)　6758-6764　2007/09

DOI： 10.1021/ma071102d 　

ISSN： 0024-9297
Perforated block copolymer vesicles with a highly folded membrane Peer-reviewed

Yongming Chen, Jianzhong Du, Ming Xiong, Hongxia Guo, Hiroshi Jinnai, Takeshi Kaneko

MACROMOLECULES　40　(13)　4389-4392　2007/06

DOI： 10.1021/ma0703195 　

ISSN： 0024-9297
Ultrastructural localization of the neurotrophin receptor (TrkA) in cultured rat pheochromocytoma PC12 cells: three-dimensional image analysis by high voltage electron microscopy Peer-reviewed

Tomoki Nishida, Yukhiro Nishikawa, Hiroshi Jinnai, Tatsuo Arii, Ryoichi Yoshimura, Yasuhisa Endo

BIOMEDICAL RESEARCH-TOKYO　28　(3)　161-167　2007/06

DOI： 10.2220/biomedres.28.161 　

ISSN： 0388-6107
Three-dimensional observation of macroporous silica gels and the study on structural formation mechanism Peer-reviewed

Haruko Saito, Kazuyoshi Kanamori, Kazuki Nakanishi, Kazuyuki Hirao, Yukihiro Nishikawa, Hiroshi Jinnai

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS　300　(1-2)　245-252　2007/06

DOI： 10.1016/j.colsurfa.2006.12.075 　

ISSN： 0927-7757

eISSN： 1873-4359
Local lamellar structures in banded spherulites analyzed by three-dimensional electron tomography Peer-reviewed

Takayuki Ikehara, Hiroshi Jinnai, Takeshi Kaneko, Hideo Nishioka, Toshio Nishi

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS　45　(9)　1122-1125　2007/05

DOI： 10.1002/polb.21133 　

ISSN： 0887-6266
Direct observation of HPL and DG structure in PS-b-PI thin film by transmission electron microscopy Peer-reviewed

Hae-Woong Park, Kyuhyun Im, Bonghoon Chung, Moonhor Ree, Taihyun Chang, Koji Sawa, Hiroshi Jinnai

MACROMOLECULES　40　(7)　2603-2605　2007/04

DOI： 10.1021/ma062826c 　

ISSN： 0024-9297
Stress prediction for polymer blends with various shapes of droplet phase Peer-reviewed

Masaoki Takahashi, Paulo H. P. Macaubas, Kenzo Okamoto, Hiroshi Jinnai, Yukihiro Nishikawa

POLYMER　48　(8)　2371-2379　2007/04

DOI： 10.1016/j.polymer.2007.02.056 　

ISSN： 0032-3861
Three-dimensional structural analysis of a block copolymer by scanning electron microscopy combined with a focused ion beam Peer-reviewed

Mitsuro Kato, Toshihiko Ito, Yoshitaka Aoyama, Koji Sawa, Takeshi Kaneko, Noboru Kawase, Hiroshi Jinnai

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS　45　(6)　677-683　2007/03

DOI： 10.1002/polb.21088 　

ISSN： 0887-6266
A(x)BA(x)-type block-graft polymers with middle soft segments and outer hard graft chains by ruthenium-catalyzed living radical polymerization: Synthesis and characterization Peer-reviewed

Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto, Takeshi Kaneko, Hiroshi Jinnai, Syuji Kobukata

MACROMOLECULES　40　(3)　465-473　2007/02

DOI： 10.1021/ma062098t 　

ISSN： 0024-9297

eISSN： 1520-5835
Three-dimensional observation of polymer blends with X-ray phase tomography Peer-reviewed

N. Higuchi, A. Momose, W. Yashiro, Y. Takeda, H. Jinnai, Y. Nishikawa, Y. Suzuki

AIP Conference Proceedings　879　1369-1372　2007

DOI： 10.1063/1.2436319 　

ISSN： 0094-243X 1551-7616
A Neutron Reflectivity Study on a Terraced Lamellar Morphology in a Block Copolymer Thin Film Peer-reviewed

Ken-ichi Niihara, Ukyo Matsuwaki, Naoya Torikai, Kotaro Satoh, Masami Kamigaito, Hiroshi Jinnai

POLYMER JOURNAL　39　(11)　1105-1111　2007

DOI： 10.1295/polymj.PJ2007100 　

ISSN： 0032-3896

eISSN： 1349-0540
Three-dimensional observation of phase-separated poly(methyl methacrylate)/poly(styrene-ran-4-bromostylene) blends by 3D NMR microscopy with X-ray microscopy Peer-reviewed

Satoshi Koizumi, Yuji Yamane, Shigeki Kuroki, Isao Ando, Yukihiro Nishikawa, Hiroshi Jinnai

JOURNAL OF APPLIED POLYMER SCIENCE　103　(1)　470-475　2007/01

DOI： 10.1002/app.24952 　

ISSN： 0021-8995
Transmission electron microtomography without the "missing wedge" for quantitative structural analysis Peer-reviewed

Noboru Kawase, Mitsuro Kato, Hideo Nishioka, Hiroshi Jinnai

ULTRAMICROSCOPY　107　(1)　8-15　2007/01

DOI： 10.1016/j.ultramic.2006.04.007 　

ISSN： 0304-3991
Dispersion state of zirconium oxide particles in polymer blends and viscoelastic behavior of the composites Peer-reviewed

Masaoki Takahashi, Satoru Osawa, Hiroshi Jinnai, Hideki Yamane, Haruhisa Shiomi

NIHON REOROJI GAKKAISHI　35　(1)　1-9　2007

DOI： 10.1678/rheology.35.1 　

ISSN： 0387-1533
A(x)BA(x)-type block-graft polymers with soft methacrylate middle segments and hard styrene outer grafts: Synthesis, morphology, and mechanical properties Peer-reviewed

Yu Miura, Takeshi Kaneko, Kotaro Satoh, Masami Kamigaito, Hiroshi Jinnai, Yoshio Okamoto

CHEMISTRY-AN ASIAN JOURNAL　2　(5)　662-672　2007

DOI： 10.1002/asia.200600403 　

ISSN： 1861-4728

eISSN： 1861-471X
Three-dimensional imaging in polymer science: Its application to block copolymer morphologies and rubber composites Peer-reviewed

Hidehiko Dohi, Hideaki Kimura, Marina Kotani, Takeshi Kaneko, Tatsuro Kitaoka, Toshio Nishi, Hiroshi Jinnai

POLYMER JOURNAL　39　(8)　749-758　2007

DOI： 10.1295/polymj.PJ2006259 　

ISSN： 0032-3896

eISSN： 1349-0540
Three-Dimensional Observation of Fuel Cell Electrode by Transmission Electron Microtomography

Toshihiko Ito, Yuji Otsuka, Hiroshi Jinnai

Materia Japan　45　(12)　858-858　2006/12
Publisher: Japan Institute of Metals
DOI： 10.2320/materia.45.858 　

ISSN： 1340-2625

eISSN： 1884-5843
&ldquo;Complete&rdquo; Electron Tomography by 180-degree Proiection for Nanocomoosite Material

Noboru Kawase, Mitsuro Kato, Hiroshi Jinnai

Materia Japan　45　(12)　859-859　2006/12
Publisher: Japan Institute of Metals
DOI： 10.2320/materia.45.859 　

ISSN： 1340-2625

eISSN： 1884-5843
Study on Three-dimensional Structures in Injection-molded iPP/Poly(ethylene-co-octene) by Transmission Electron Microtomography Peer-reviewed

Michio Ono, Hideo Nishioka, Hiroshi Jinnai, Ken Nakajima, Toshio Nishi

e-Journal of Soft Materials　2　56-61　2006/09
Publisher: Society of Rubber Industry, Japan
DOI： 10.2324/ejsm.2.56 　

eISSN： 1349-7308
The structural transitions of pi-complexes of poly(styrene-b-butadiene-b-styrene) block copolymers with silver salts and their relation to facilitated olefin transport Peer-reviewed

Jong Hak Kim, Dong Hoon Lee, Jongok Won, Hiroshi Jinnai, Yong Soo Kang

JOURNAL OF MEMBRANE SCIENCE　281　(1-2)　369-376　2006/09

DOI： 10.1016/j.memsci.2006.04.002 　

ISSN： 0376-7388
3D nanometer-scale study of coexisting bicontinuous morphologies in a block copolymer/homopolymer blend Peer-reviewed

Hiroshi Jinnai, Hirokazu Hasegawa, Yukihiro Nishikawa, G. J. Agur Sevink, Michael B. Braunfeld, David A. Agard, Richard J. Spontak

MACROMOLECULAR RAPID COMMUNICATIONS　27　(17)　1424-1429　2006/09

DOI： 10.1002/marc.200600344 　

ISSN： 1022-1336
Transmission electron microtomography (TEMT) of nanostructured polymers under dynamically evolving conditions

R. J. Spontak, M. B. Braunfeld, D. A. Agard, H. Jinnai

Microscopy and Microanalysis　12　(2)　182-183　2006/08

DOI： 10.1017/S1431927606069509 　

ISSN： 1431-9276 1435-8115
Direct observation of twisted grain boundary in a block copolymer lamellar nanostructure Peer-reviewed

Hiroshi Jinnai, Koji Sawa, Toshio Nishi

MACROMOLECULES　39　(17)　5815-5819　2006/08

DOI： 10.1021/ma0600153 　

ISSN： 0024-9297
Mutual consistency between simulated and measured pressure drops in silica monoliths based on geometrical parameters obtained by three-dimensional laser scanning confocal microscope observations Peer-reviewed

Haruko Saito, Kazuki Nakanishi, Kazuyuki Hirao, Hiroshi Jinnai

JOURNAL OF CHROMATOGRAPHY A　1119　(1-2)　95-104　2006/06

DOI： 10.1016/j.chroma.2006.03.087 　

ISSN： 0021-9673

eISSN： 1873-3778
Synthesis and characterization of AxBAx-type polymer with block and graft structure

Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto, Takeshi Kaneko, Hiroshi Jinnai

Polymer Preprints, Japan　55　(2)　2571-2572　2006
Structural observation of block copolymer thin films with transmission electron microtomography and neutron reflectivity

Ken-Ichi Niihara, Yukihiro Nishikawa, Hiroshi Jinnai, Naoya Torikai, Toshio Nishi

Polymer Preprints, Japan　55　(2)　4308-4309　2006
The SCF simulation based on images obtained by Transmission Electron Microtomography

Hidekazu Sugimori, Hiroshi Jinnai, Ukyo Matsuwaki, Hiroshi Morita, Masao Doi, Toshio Nishi

Polymer Preprints, Japan　55　(2)　3727-3728　2006
Observation of carbon nanotube/elastomer composites by atomic force microscopy [3]

Avako Niikura, Ken Nakajima, So Fujinami, Michio Ono, Toshio Nishi, Toru Noguchi, Akira Magario, Shuichi Shimizu, Junichi Beppu, Masayuki Seki, Hitoshi Iwabuki, Kazuya Nagata, Hiroshi Jinnai

Polymer Preprints, Japan　55　(2)　3597　2006
Three-dimensional structural analysis of rubber materials using scanning electron microscopy equipped with focused ion beam

Mitsuro Kato, Ito Toshihiko, Yoshitaka Aoyama, Koji Sawa, Takeshi Kaneko, Noboru Kawase, Hiroshi Jinnai

Polymer Preprints, Japan　55　(2)　3341-3342　2006
3D observation of microphase-separated structures of AxBA x-type graft copolymers

Takeshi Kaneko, Hiroshi Jinnai, Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto, Toshio Nishi

Polymer Preprints, Japan　55　(2)　3349-3350　2006
Three dimensional structure observation of giant actin complexes by transmission electron microtomography

Kazuhiro Shikinaka, Hyuckjoon Kwon, Akira Kakugo, Hidemitsu Furukawa, Jian Ping Gong, Yoshihito Osada, Hideo Nishioka, Hiroshi Jinnai

Polymer Preprints, Japan　55　(2)　3921-3922　2006
Development of transmission electron microtomography with electron energy loss spectroscopy

Masahiro Hatta, Hiroshi Jinnai, Yoshitaka Aoyama, Toshihiko Ito, Toshio Nishi

Polymer Preprints, Japan　55　(2)　3454　2006
3D observation of Hexagonally Perforated Layer (HPL)/gyroid grain boundary structures

Koji Sawa, Hiroshi Jinnai, Hae-Woong Park, Taihyun Chang, Toshio Nishi

Polymer Preprints, Japan　55　(2)　3588　2006
3D observation of terrace structures in a block copolymer thin film

Fumio Hirato, Ken-Ichi Niihara, Hiroshi Jinnai, Toshio Nishi

Polymer Preprints, Japan　55　(2)　3472　2006
Morphological change of microphase-separated structures in a block copolymer thin film studied by transmission electron microtomography and SCF simulations

Hidekazu Sugimori, Ukyo Matsuwaki, Hiroshi Morita, Masao Doi, Toshio Nishi, Hiroshi Jinnai

Polymer Preprints, Japan　55　(1)　1321　2006
Morphological change of microphase-separated structures in block copolymer thin films

Ukyo Matsuwaki, Hidekazu Sugimori, Ken-Ichi Niihara, Yukihiro Nishikawa, Hiroshi Jinnai, Toshio Nishi

Polymer Preprints, Japan　55　(1)　1320　2006
3D observation of microphase-separated structures of a block copolymer in thin film

Ken-Ichi Niihara, Ukyo Matsuwaki, Yukihiro Nishikawa, Hiroshi Jinnai, Naoya Torikai, Toshio Nishi

Polymer Preprints, Japan　55　(1)　1285　2006
Observation of carbon nanotube/elastomer composites by atomic force microscopy [2]

Ayako Niikura, So Fujinami, Ken Nakajima, Michio Ono, Toru Noguchi, Akira Magario, Shuichi Shimizu, Junichi Beppu, Masayuki Seki, Hitoshi Iwabuki, Kazuya Nagata, Hiroshi Jinnai, Toshio Nishi

Polymer Preprints, Japan　55　(1)　934　2006
Three-dimensional structural analysis of block copolymer using dual-beam focused ion beam system

Mitsuro Kato, Toshihiko Ito, Yoshitaka Aoyama, Koji Sawa, Takeshi Kaneko, Noboru Kawase, Hiroshi Jinnai

Polymer Preprints, Japan　55　(1)　903　2006
Domain spacing distribution in a lamellar-forming block copolymer

Kaoru Yasuda, Ken-Ichi Niihara, Koji Sawa, Yukihiro Nishikawa, Hiroshi Jinnai, Toshio Nishi

Polymer Preprints, Japan　55　(1)　928　2006
3D observation of polymeric material by using electron holography and transmission electron microtomography

Yoshitaka Aoyama, Hiroshi Jinnai, Daisuke Shindo

Polymer Preprints, Japan　55　(1)　1103　2006
Synthesis and characterization of new well-defined AxBA x-type graft polymers

Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto, Takeshi Kaneko, Hiroshi Jinnai

Polymer Preprints, Japan　55　(1)　381　2006
Three-dimensional structural analysis of polymer/inorganic nanocomposite by 180-degree projection TEMT (transmission electron microtomography)

Noboru Kawase, Mitsuro Kato, Hideo Nishioka, Takeshi Kaneko, Yukihiro Nishikawa, Hiroshi Jinnai

Polymer Preprints, Japan　55　(1)　1102　2006
3D observation of Hexagonally Perforated Layer (HPL) structure in block copolymer thin films

Koji Sawa, Yukihiro Nishikawa, Hiroshi Jinnai, Taihyun Chang, Toshio Nishi

Polymer Preprints, Japan　55　(1)　927　2006
Three-dimensional structural analysis of multi-component nano-fillers in rubbery matrix studied by transmission electron microtomography

Yuki Shinbori, Hidekazu Sugimori, Yukihiro Nishikawa, Hiroshi Jinnai, Keizo Akutagawa, Naruhiko Mashita, Toshio Nishi

Polymer Preprints, Japan　55　(1)　994　2006
Three-dimensionnal structural analysis of carbon black in rubbery matrix studies by transmission electron microtomography

Tatsuro Kitaoka, Yuki Shinbori, Hidekazu Sugimori, Hiroshi Jinnai, Yukihiro Nishikawa, Keizo Akutagawa, Naruhiko Mashita, Toshio Nishi

Polymer Preprints, Japan　55　(1)　995　2006
Three-dimensional structural analysis of carbon black in rubbery matrix studies by transmission electron microtomography

Tatsuro Kitaoka, Hidekazu Sugimori, Yukihiro Nishikawa, Keizo Akutagawa, Naruhiko Mashita, Toshio Nishi, Hiroshi Jinnai

Polymer Preprints, Japan　55　(2)　3339-3340　2006
特集「電子顕微鏡法による材料開発のための微細構造研究最前線 (6)」企画にあたって

45　(12)　837-837　2006
Publisher:
DOI： 10.2320/materia.45.837 　

ISSN： 1340-2625

eISSN： 1884-5843
Three-dimensional structure of a polymer/clay nanocomposite characterized by transmission electron microtomography Peer-reviewed

Hideo Nishioka, Ken-Ichi Niihara, Takeshi Kaneko, Junpei Yamanaka, Takashi Inoue, Toshio Nishi, Hiroshi Jinnai

COMPOSITE INTERFACES　13　(7)　589-603　2006

DOI： 10.1163/156855406778440695 　

ISSN： 0927-6440
Spatial arrangement of metal nanoparticles supported by porous polymer substrates studied by transmission electron microtomography Peer-reviewed

Hiroshi Jinnai, Takeshi Kaneko, Hideo Nishioka, Hirokazu Hasegawa, Toshio Nishi

CHEMICAL RECORD　6　(5)　267-274　2006

DOI： 10.1002/tcr.20095 　

ISSN： 1527-8999
Electric field alignment of asymmetric diblock copolymer thin films Peer-reviewed

T. Xu, A. V. Zvelindovsky, G. J.A. Sevink, K. S. Lyakhova, H. Jinnai, T. P. Russell

Macromolecules　38　(26)　10788-10798　2005/12/27

DOI： 10.1021/ma050521c 　

ISSN： 0024-9297
Dual-axis electron tomography for three-dimensional observations of polymeric nanostructures Peer-reviewed

H Sugimori, T Nishi, H Jinnai

MACROMOLECULES　38　(24)　10226-10233　2005/11

DOI： 10.1021/ma051705u 　

ISSN： 0024-9297
Reduction of anisotropic image resolution in transmission electron microtomography by use of quadrangular prism-shaped section Peer-reviewed

T Kaneko, H Nishioka, Y Nishikawa, T Nishi, H Jinnai

JOURNAL OF ELECTRON MICROSCOPY　54　(5)　437-444　2005/10

DOI： 10.1093/jmicor/dfi065 　

ISSN： 0022-0744
Tailoring spontaneous pillar structure using phase-separating organosiloxane sol-gel systems in micro-fabricated grooves Peer-reviewed

Kazuyoshi Kanamori, Kazuki Nakanishi, Kazuyuki Hirao, Hiroshi Jinnai

Journal of Sol-Gel Science and Technology　35　(3)　183-191　2005/09

DOI： 10.1007/s10971-005-4166-z 　

ISSN： 0928-0707
Three-dimensional observation of polymer blend by X-ray phase tomography Peer-reviewed

A Momose, A Fujii, H Kadowaki, H Jinnai

MACROMOLECULES　38　(16)　7197-7200　2005/08

DOI： 10.1021/ma050917o 　

ISSN： 0024-9297
Nanoprocessing and Nanofabrication of a Structured Polymer Film by the Focused-Ion-Beam Technique Peer-reviewed

Ken-ichi Niihara, Takeshi Kaneko, Toshiaki Suzuki, Yasuhiko Sato, Hideo Nishioka, Yukihiro Nishikawa, Toshio Nishi, Hiroshi Jinnai

Macromolecules　38　(8)　3048-3050　2005/03/17
Publisher: American Chemical Society (ACS)
DOI： 10.1021/ma048380m 　

ISSN： 0024-9297

eISSN： 1520-5835
Synthesis and characterization of AxBAx block-graft polymers by metal-catalyzed living radical polymerization

Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto, Takeshi Kaneko, Hiroshi Jinnai

Polymer Preprints, Japan　54　(2)　2808-2809　2005
Direct 3D observation of grain boundary in cylindrical microdomains

Kaoru Yasuda, Yukihiro Nishikawa, Hiroshi Jinnai, Toshio Nishi

Polymer Preprints, Japan　54　(2)　3458-3459　2005
3D image analysis of Pd particles formed on porous polymeric support

Yukihiro Nishikawa, Takeshi Kaneko, Kaoru Yasuda, Toshio Nishi, Hirokazu Hasegawa, Hiroshi Jinnai

Polymer Preprints, Japan　54　(1)　690　2005
Three-dimensional structural analysis of polymer/inorganic nanocomposite using FIB-TEMT (focused ion beam - Transmission electron microtomogaraphy)

Noboru Kawase, Mitsuro Kato, Toshiyasu Okui, Hideo Nishioka, Yukihiro Nishikawa, Hiroshi Jinnai

Polymer Preprints, Japan　54　(2)　3201-3202　2005
Three-dimensional observation of PS/PMMA blend with X-ray phase tomography

Akiko Fujii, Ichiro Koyama, Yoshio Suzuki, Hiroshi Jinnai, Yukihiro Nishikawa, Hidekazu Kadowaki, Atsushi Momose

Polymer Preprints, Japan　54　(1)　685　2005
Morphological transition in block copolymer thin films studied by transmission electron microtomography

Ukvo Matsuwaki, Hidekazu Sugimori, Ken-Ichi Nihara, Yukihiro Nishikawa, Hiroshi Jinnai, Toshio Nishi

Polymer Preprints, Japan　54　(2)　3315-3316　2005
3D observation of microphase-separated structures of a block copolymer thin films

Ken-Ichi Niihara, Ukyo Matsuwaki, Yukihiro Nishikawa, Hiroshi Jinnai, Naoya Torikai, Toshio Nishi

Polymer Preprints, Japan　54　(2)　3317-3318　2005
Three-dimensional observation of a block copolymer asymmetric nanostructure by Dual-Axis electron tomography

Hidekazu Sugimori, Takeshi Kaneko, Hiroshi Jinnai, Yukihiro Nishikawa, Toshio Nishi

Polymer Preprints, Japan　54　(1)　686　2005
Advantages of zero-loss imaging in transmission electron microtomography

Yukihiro Nishikawa, Takeshi Kaneko, Hideo Nishioka, Toshio Nishi, Hiroshi Jinnai

Polymer Preprints, Japan　54　(2)　3199-3200　2005
3D observation of microphase-separated structures of ABC triblock copolymers

Kazuya Suda, Takeshi Kaneko, Yukihiro Nishikawa, Hiroshi Jinnai, Kotaro Sato, Masami Kamigaito, Toshinori Kato, Tomohiro Ono, Eiji Nakamura, Toshio Nishi

Polymer Preprints, Japan　54　(1)　688　2005
Observation of carbon nanotube/elatomer composites by atomic force microscopy

Katsuyoshi Endoh, Ken Nakajima, Michio Ono, Toru Noguchi, Akira Magario, Shuichi Shimizu, Junichi Beppu, Masayuki Seki, Hitoshi Iwabuki, Kazuya Nagata, Hiroshi Jinnai, Toshio Nishi

Polymer Preprints, Japan　54　(1)　721　2005
Three-dimensional structural analysis of multi-component nano-fillers in rubbery matrix studied by transmission electron microtomography

Yuki Shinbori, Hiroshi Jinnai, Yukihiro Nishikawa, Takeshi Kaneko, Ken Ichi Niihara, Hideo Nishioka, Keizo Akutagawa, Naruhiko Mashita, Toshio Nishi

Polymer Preprints, Japan　54　(1)　711　2005
Three-dimensional structural analysis of multi-component nano-fillers in rubbery matrix studied by transmission electron microtomography

Yuki Shinbori, Hidekazu Sugimoril, Yukihiro Nishikawa, Hiroshi Jinnai, Hideo Nishioka, Keizo Akutagawa, Naruhiko Mashita, Toshio Nishi

Polymer Preprints, Japan　54　(2)　3484-3485　2005
三次元イメージングがもたらす新しい高分子構造解析 Peer-reviewed

62　(10)　488-501　2005
Publisher:
DOI： 10.1295/koron.62.488 　

ISSN： 0386-2186

eISSN： 1881-5685
三次元仮想イメージング実験を用いたソフトマテリアルの構造解析 Peer-reviewed

62　(10)　502-507　2005
Publisher:
DOI： 10.1295/koron.62.502 　

ISSN： 0386-2186

eISSN： 1881-5685
角柱状切片の利用による三次元電子顕微鏡像の改善 Peer-reviewed

62　(10)　508-513　2005
Publisher:
DOI： 10.1295/koron.62.508 　

ISSN： 0386-2186

eISSN： 1881-5685
Real space observation of phase separating structure in a sol-gel system

H. Saito, K. Kanamori, K. Nakanishi, K. Hirao, Y. Nishikawa, H. Jinnai

Polymer Preprints, Japan　54　(1)　705-　2005
Emerging Technologies for the 3D Analysis of Polymer Structures

Hiroshi Jinnai, Yukihiro Nishikawa, Takayuki Ikehara, Toshio Nishi

Advances in Polymer Science　170　115-167　2004/10
Publisher: Springer Berlin Heidelberg
DOI： 10.1007/b95533 　
Three-dimensional observation of phase-separated siloxane sol-gel structures in confined spaces using laser scanning confocal microscopy (LSCM) Peer-reviewed

Kazuyoshi Kanamori, Kazuki Nakanishi, Kazuyuki Hirao, Hiroshi Jinnai

Colloids and Surfaces A: Physicochemical and Engineering Aspects　241　(1-3)　215-224　2004/07/14

DOI： 10.1016/j.colsurfa.2004.04.022 　

ISSN： 0927-7757
Structural formation of hybrid siloxane-based polymer monolith in confined spaces Peer-reviewed

K Kanamori, H Yonezawa, K Nakanishi, K Hirao, H Jinnai

JOURNAL OF SEPARATION SCIENCE　27　(10-11)　874-886　2004/07

DOI： 10.1002/jssc.200401816 　

ISSN： 1615-9306

eISSN： 1615-9314
Transmission electron microtomography on polymeric materials

JINNAI Hiroshi, NISHI Toshio

Denshi kenbikyo　39　(1)　31-33　2004/03/31
Publisher: The Japanese Society of Microscopy
DOI： 10.11410/kenbikyo2004.39.31 　

ISSN： 1349-0958
Finite-size effects on surface segregation in polymer blend films above and below the critical point of phase separation Peer-reviewed

H Grull, L Sung, A Karim, JF Douglas, SK Satija, M Hayashi, H Jinnai, T Hashimoto, CC Han

EUROPHYSICS LETTERS　65　(5)　671-677　2004/03

DOI： 10.1209/epl/i2003-10176-1 　

ISSN： 0295-5075
Connectivity and topology of a phase-separating bicontinuous structure in a polymer mixture: Direct measurements of coordination number, inter-junction distances and Euler characteristic Peer-reviewed

Hiroshi Jinnai, Hideyuki Watashiba, Takashi Kajihara, Masaoki Takahashi

Journal of Chemical Physics　119　(14)　7554-7559　2003/10/08

DOI： 10.1063/1.1607912 　

ISSN： 0021-9606
Interface-directed web-to-pillar transition of microphase-separated siloxane gels Peer-reviewed

K Kanamori, K Nakanishi, K Hirao, H Jinnai

LANGMUIR　19　(22)　9101-9103　2003/10

DOI： 10.1021/la0347962 　

ISSN： 0743-7463
Nanofibrillar Networks in Poly(ethyl methacrylate) and Its Silica Nanocomposites

Elizabeth A. Wilder, Michael B. Braunfeld, Hiroshi Jinnai, Carol K. Hall, David A. Agard, Richard J. Spontak

The Journal of Physical Chemistry B　107　(42)　11633-11642　2003/09/27
Publisher: American Chemical Society (ACS)
DOI： 10.1021/jp035113u 　

ISSN： 1520-6106

eISSN： 1520-5207
Microdomain morphology in an ABC 3-miktoarm star terpolymer: A study by energy-filtering TEM and 3D electron tomography Peer-reviewed

K Yamauchi, K Takahashi, H Hasegawa, H Iatrou, N Hadjichristidis, T Kaneko, Y Nishikawa, H Jinnai, T Matsui, H Nishioka, M Shimizu, H Fukukawa

MACROMOLECULES　36　(19)　6962-6966　2003/09

DOI： 10.1021/ma034840k 　

ISSN： 0024-9297
Three-dimensional observation of phase-separated silica-based gels confined between parallel plates Peer-reviewed

Kazuyoshi Kanamori, Kazuki Nakanishi, Kazuyuki Hirao, Hiroshi Jinnai

Langmuir　19　(14)　5581-5585　2003/07/08

DOI： 10.1021/la026715s 　

ISSN： 0743-7463
Effect of confinement on phase-separation processes in a polymer blend observed by laser scanning confocal microscopy Peer-reviewed

H Jinnai, H Kitagishi, K Hamano, Y Nishikawa, M Takahashi

PHYSICAL REVIEW E　67　(2)　021801-021807　2003/02

DOI： 10.1103/PhysRevE.67.021801 　

ISSN： 1539-3755
Ｘ線ＣＴ法を用いた結晶性熱可塑性エラストマー／オイル系非水ゲルの３次元構造の直接観察 Peer-reviewed

60　(7)　373-376　2003
Publisher:
DOI： 10.1295/koron.60.373 　

ISSN： 0386-2186

eISSN： 1881-5685
Phase separation in methylsiloxane sol-gel systems in a small confined space Peer-reviewed

Kazuyoshi Kanamori, Norio Ishizuka, Kazuki Nakanishi, Kazuyuki Hirao, Hiroshi Jinnai

Journal of Sol-Gel Science and Technology　26　(1-3)　157-160　2003/01

DOI： 10.1023/A:1020722326072 　

ISSN： 0928-0707
Bone structure and mineralization demonstrated using synchrotron radiation computed tomography (SR-CT) in animal models: preliminary findings Peer-reviewed

M Ito, S Ejiri, H Jinnai, J Kono, S Ikeda, A Nishida, K Uesugi, N Yagi, M Tanaka, K Hayashi

JOURNAL OF BONE AND MINERAL METABOLISM　21　(5)　287-293　2003

DOI： 10.1007/s00774-003-0422-x 　

ISSN： 0914-8779
Topological similarity of sponge-like bicontinuous morphologies differing in length scale Peer-reviewed

H Jinnai, Y Nishikawa, M Ito, SD Smith, DA Agard, RJ Spontak

ADVANCED MATERIALS　14　(22)　1615-1618　2002/11

ISSN： 0935-9648
Monolithic silica columns with various skeleton sizes and through-pore sizes for capillary liquid chromatography Peer-reviewed

M Motokawa, H Kobayashi, N Ishizuka, H Minakuchi, K Nakanishi, H Jinnai, K Hosoya, T Ikegami, N Tanaka

JOURNAL OF CHROMATOGRAPHY A　961　(1)　53-63　2002/06

DOI： 10.1016/S0021-9673(02)00133-4 　

ISSN： 0021-9673
Surface curvatures of trabecular bone microarchitecture Peer-reviewed

H. Jinnai, H. Watashiba, T. Kajihara, Y. Nishikawa, M. Takahashi, M. Ito

Bone　30　(1)　191-194　2002

DOI： 10.1016/S8756-3282(01)00672-X 　

ISSN： 8756-3282
Formation of ordered macropores and templated nanopores in silica sol-gel system incorporated with EO-PO-EO triblock copolymer Peer-reviewed

Y Sato, K Nakanishi, K Hirao, H Jinnai, M Shibayama, YB Melnichenko, GD Wignall

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS　187　117-122　2001/08

DOI： 10.1016/S0927-7757(01)00626-4 　

ISSN： 0927-7757
Observation of fine structure in bicontinuous phase-separated domains of a polymer blend by laser scanning confocal microscopy Peer-reviewed

H Jinnai, H Yoshida, K Kimishima, Y Funaki, Y Hirokawa, AE Ribbe, T Hashimoto

MACROMOLECULES　34　(15)　5186-5191　2001/07

DOI： 10.1021/ma010190d 　

ISSN： 0024-9297
Measurements of interfacial curvatures of bicontinuous structure from three-dimensional digital images. 2. A sectioning and fitting method Peer-reviewed

Y Nishikawa, T Koga, T Hashimoto, H Jinnai

LANGMUIR　17　(11)　3254-3265　2001/05

ISSN： 0743-7463
Three-dimensional structure of a sintered macroporous silica gel Peer-reviewed

H Jinnai, K Nakanishi, Y Nishikawa, J Yamanaka, T Hashimoto

LANGMUIR　17　(3)　619-625　2001/02

DOI： 10.1021/la000949z 　

ISSN： 0743-7463
細線化を用いた３次元ネットワーク構造のトポロジー解析 Peer-reviewed

58　(1)　13-21　2001
Publisher:
DOI： 10.1295/koron.58.13 　

ISSN： 0386-2186

eISSN： 1881-5685
Interfacial and topological measurements of bicontinuous polymer morphologies Peer-reviewed

Hiroshi Jinnai, Takashi Kajihara, Hideyuki Watashiba, Yukihiro Nishikawa, Richard J. Spontak

Physical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics　64　(1)　010803(R)-010806(R)　2001

DOI： 10.1103/PhysRevE.64.010803 　

ISSN： 1063-651X
Dynamic interfacial properties of polymer blends under large step strains: Shape recovery of a single droplet Peer-reviewed

R. Hayashi, M. Takahashi, H. Yamane, H. Jinnai, H. Watanabe

Polymer　42　(2)　757-764　2001
Publisher: Elsevier BV
DOI： 10.1016/S0032-3861(00)00373-6 　

ISSN： 0032-3861
Validity of linear analysis in early-stage spinodal decomposition of a polymer mixture Peer-reviewed

M Hayashi, H Jinnai, T Hashimoto

JOURNAL OF CHEMICAL PHYSICS　113　(8)　3414-3422　2000/08

ISSN： 0021-9606
Morphological characterization of bicontinuous structures in polymer blends and microemulsions by the inverse-clipping method in the context of the clipped-random-wave model Peer-reviewed

H Jinnai, Y Nishikawa, SH Chen, S Koizumi, T Hashimoto

PHYSICAL REVIEW E　61　(6)　6773-6780　2000/06

ISSN： 1063-651X
Geometrical properties and interface dynamics: Time evolution of spinodal interface in a binary polymer mixture at the critical composition Peer-reviewed

H Jinnai, Y Nishikawa, H Morimoto, T Koga, T Hashimoto

LANGMUIR　16　(9)　4380-4393　2000/05

ISSN： 0743-7463
Two-step phase separation of a polymer mixture. II. Time evolution of structure factor Peer-reviewed

M Hayashi, H Jinnai, T Hashimoto

JOURNAL OF CHEMICAL PHYSICS　112　(15)　6897-6909　2000/04

ISSN： 0021-9606
Two-step phase separation of a polymer mixture. I. New scaling analysis for the main scattering peak Peer-reviewed

T Hashimoto, M Hayashi, H Jinnai

JOURNAL OF CHEMICAL PHYSICS　112　(15)　6886-6896　2000/04

ISSN： 0021-9606
Direct measurement of interfacial curvature distributions in a bicontinuous block copolymer morphology Peer-reviewed

H Jinnai, Y Nishikawa, RJ Spontak, SD Smith, DA Agard, T Hashimoto

PHYSICAL REVIEW LETTERS　84　(3)　518-521　2000/01

ISSN： 0031-9007
Influence of casting solvents on microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene Peer-reviewed

Y Funaki, K Kumano, T Nakao, H Jinnai, H Yoshida, K Kimishima, K Tsutsumi, Y Hirokawa, T Hashimoto

POLYMER　40　(25)　7147-7156　1999/12

ISSN： 0032-3861
Direct observation of internal structures in poly(N-isopropylacrylamide) chemical gels Peer-reviewed

Y Hirokawa, H Jinnai, Y Nishikawa, T Okamoto, T Hashimoto

MACROMOLECULES　32　(21)　7093-7099　1999/10

ISSN： 0024-9297
Small-angle neutron scattering studies on phase behavior of block copolymers Peer-reviewed

H Hasegawa, N Sakamoto, H Takeno, H Jinnai, T Hashimoto, D Schwahn, H Frielinghaus, S Janssen, M Imai, K Mortensen

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS　60　(8-9)　1307-1312　1999/08

ISSN： 0022-3697
Phase separation with multiple length scales in polymer mixtures induced by autocatalytic reactions Peer-reviewed

TC Qui, J Kawai, Y Nishikawa, H Jinnai

PHYSICAL REVIEW E　60　(2)　R1150-R1153　1999/08

ISSN： 1063-651X
Control of self-assembled structures in binary mixtures of A-B diblock copolymer and A-C diblock copolymer by changing the interaction between B and C block chains Peer-reviewed

Kimishima, I, H Jinnai, T Hashimoto

MACROMOLECULES　32　(8)　2585-2596　1999/04

ISSN： 0024-9297
Curvature distributions of spinodal interface in a condensed matter system Peer-reviewed

H Jinnai, Y Nishikawa, T Hashimoto

PHYSICAL REVIEW E　59　(3)　R2554-R2557　1999/03

ISSN： 1063-651X
Interfacial curvature in phase-separating binary fluids: comparison between computer simulation and experiments Peer-reviewed

T Koga, H Jinnai, T Hashimoto

PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS　263　(1-4)　369-377　1999/02

ISSN： 0378-4371

eISSN： 1873-2119
三次元画像解析が生み出す構造解析研究の新潮流界面の形態とそのダイナミクス Peer-reviewed

56　(8)　496-507　1999
Publisher:
DOI： 10.1295/koron.56.496 　

ISSN： 0386-2186

eISSN： 1881-5685
目で見る高分子高分子系がつくるパターンＩＩブロック共重合体のつくる共連続周期パターン界面に着目した構造解析 Peer-reviewed

56　(12)　837-844　1999
Publisher:
DOI： 10.1295/koron.56.837 　

ISSN： 0386-2186

eISSN： 1881-5685
Sponge-like structures corresponding to the universal scaled structure factor in binary critical mixtures of polymers and simple liquids

T Hashimoto, T Koga, H Jinnai, Y Nishikawa

NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS　20　(12BIS)　1947-1970　1998/12

ISSN： 0392-6737
Measurements of interfacial curvatures of bicontinuous structure from three-dimensional digital images. 1. A parallel surface method Peer-reviewed

Y Nishikawa, H Jinnai, T Koga, T Hashimoto, ST Hyde

LANGMUIR　14　(5)　1242-1249　1998/03

ISSN： 0743-7463
The effect of added polymers on n-butylammonium vermiculite swelling Peer-reviewed

MV Smalley, H Jinnai, T Hashimoto, S Koizumi

CLAYS AND CLAY MINERALS　45　(5)　745-760　1997/10

ISSN： 0009-8604
Curvature determination of spinodal interface in a condensed matter system Peer-reviewed

H Jinnai, T Koga, Y Nishikawa, T Hashimoto, ST Hyde

PHYSICAL REVIEW LETTERS　78　(11)　2248-2251　1997/03

ISSN： 0031-9007
Effect of oscillatory shear deformation on demixing processes of polymer blends Peer-reviewed

K Matsuzaka, H Jinnai, T Koga, T Hashimoto

MACROMOLECULES　30　(4)　1146-1152　1997/02

ISSN： 0024-9297
Sponge-like structures and their Gaussian curvatures in polymer mixtures and microemulsions

T Hashimoto, H Jinnai, Y Nishikawa, T Koga, M Takenaka

FORMATION AND DYNAMICS OF SELF-ORGANIZED STRUCTURES IN SURFACTANTS AND POLYMER SOLUTIONS　106　118-126　1997

ISSN： 0340-255X
Morphological characterization of bicontinuous phase-separated polymer blends and one-phase microemulsions Peer-reviewed

H Jinnai, T Hashimoto, D Lee, SH Chen

MACROMOLECULES　30　(1)　130-136　1997/01

ISSN： 0024-9297
Measurement of the Gaussian curvature of the surfactant film in an isometric bicontinuous one-phase microemulsion Peer-reviewed

SH Chen, DD Lee, K Kimishima, H Jinnai, T Hashimoto

PHYSICAL REVIEW E　54　(6)　6526-6531　1996/12

ISSN： 1063-651X
Complex image generation in the laser scanning confocal microscope of a polymer blend system Peer-reviewed

AE Ribbe, T Hashimoto, H Jinnai

JOURNAL OF MATERIALS SCIENCE　31　(22)　5837-5847　1996/11

ISSN： 0022-2461
The ordered structure of binary mixtures of A-B diblock copolymer and A-C diblock copolymer

Kohtaro Kimishima, Hiroshi Jinnai, Tadanori Koga, Takeji Hashimoto

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry　37　(2)　819-820　1996/08

ISSN： 0032-3934
Neutron scattering study of vermiculite-poly(vinyl methyl ether) mixtures Peer-reviewed

H Jinnai, MV Smalley, T Hashimoto, S Koizumi

LANGMUIR　12　(5)　1199-1203　1996/03

ISSN： 0743-7463
CRITICAL CROSSOVER PHENOMENA IN COMPATIBLE POLYMER BLENDS STUDIED WITH SANS Peer-reviewed

D SCHWAHN, S JANSSEN, L WILLNER, T SCHMACKERS, T SPRINGER, K MORTENSEN, H TAKENO, H HASEGAWA, H JINNAI, T HASHIMOTO, M IMAI

PHYSICA B-CONDENSED MATTER　213　685-687　1995/08

ISSN： 0921-4526
DIRECT OBSERVATION OF 3-DIMENSIONAL BICONTINUOUS STRUCTURE DEVELOPED VIA SPINODAL DECOMPOSITION Peer-reviewed

H JINNAI, Y NISHIKAWA, T KOGA, T HASHIMOTO

MACROMOLECULES　28　(13)　4782-4784　1995/06

ISSN： 0024-9297

eISSN： 1520-5835
MICROSTRUCTURAL EFFECTS ON THE GINZBURG NUMBER AND THE CROSSOVER-BEHAVIOR IN D-PB/PS BLENDS Peer-reviewed

D SCHWAHN, H TAKENO, L WILLNER, H HASEGAWA, H JINNAI, T HASHIMOTO, M IMAI

PHYSICAL REVIEW LETTERS　73　(25)　3427-3430　1994/12

ISSN： 0031-9007
LATE-STAGE SPINODAL DECOMPOSITION IN BINARY CRITICAL FLUIDS - SCALING FUNCTION OBTAINED OVER A WIDE Q-SPACE OF 4 ORDERS OF MAGNITUDE Peer-reviewed

T HASHIMOTO, H JINNAI, H HASEGAWA, CC HAN

PHYSICA A　204　(1-4)　261-276　1994/03

ISSN： 0378-4371
TIME-RESOLVED SMALL-ANGLE NEUTRON-SCATTERING STUDY OF SPINODAL DECOMPOSITION IN DEUTERATED AND PROTONATED POLYBUTADIENE BLENDS .2. Q-DEPENDENCE OF ONSAGER KINETIC COEFFICIENT Peer-reviewed

H JINNAI, H HASEGAWA, T HASHIMOTO, CC HAN

JOURNAL OF CHEMICAL PHYSICS　99　(10)　8154-8161　1993/11

ISSN： 0021-9606

eISSN： 1089-7690
TIME-RESOLVED SMALL-ANGLE NEUTRON-SCATTERING STUDY OF SPINODAL DECOMPOSITION IN DEUTERATED AND PROTONATED POLYBUTADIENE BLENDS .1. EFFECT OF INITIAL THERMAL FLUCTUATIONS Peer-reviewed

H JINNAI, H HASEGAWA, T HASHIMOTO, CC HAN

JOURNAL OF CHEMICAL PHYSICS　99　(6)　4845-4854　1993/09

ISSN： 0021-9606

eISSN： 1089-7690
PHASE-SEPARATION IN DEUTERATED POLYCARBONATE POLY(METHYLMETHACRYLATE) BLEND NEAR GLASS-TRANSITION TEMPERATURE Peer-reviewed

M MOTOWOKA, H JINNAI, T HASHIMOTO, Y QIU, CC HAN

JOURNAL OF CHEMICAL PHYSICS　99　(3)　2095-2100　1993/08

ISSN： 0021-9606
EFFECT OF CROSS-LINKS ON THE MISCIBILITY OF A DEUTERATED POLYBUTADIENE AND PROTONATED POLYBUTADIENE BLEND Peer-reviewed

H JINNAI, H HASEGAWA, T HASHIMOTO, RM BRIBER, CC HAN

MACROMOLECULES　26　(1)　182-188　1993/01

ISSN： 0024-9297

eISSN： 1520-5835
Inversion of the phase diagram from UCST to LCST in deuterated polybutadiene and protonated polybutadiene blends

Hiroshi Jinnai, Hirokazu Hasegawa, Takeji Hashimoto, Charles C. Han

Macromolecules　25　(22)　6078-6080　1992/10
Publisher: American Chemical Society (ACS)
DOI： 10.1021/ma00048a038 　

ISSN： 0024-9297

eISSN： 1520-5835
SCATTERING STUDIES OF SELF-ASSEMBLING PROCESSES OF POLYMER BLENDS IN SPINODAL DECOMPOSITION Peer-reviewed

T HASHIMOTO, M TAKENAKA, H JINNAI

JOURNAL OF APPLIED CRYSTALLOGRAPHY　24　457-466　1991/10

ISSN： 0021-8898
MICROSTRUCTURE EFFECTS ON THE LOWER CRITICAL SOLUTION TEMPERATURE PHASE-BEHAVIOR OF DEUTERATED POLYBUTADIENE AND PROTONATED POLYISOPRENE BLENDS STUDIED BY SMALL-ANGLE NEUTRON-SCATTERING Peer-reviewed

S SAKURAI, H JINNAI, H HASEGAWA, T HASHIMOTO, CC HAN

MACROMOLECULES　24　(17)　4839-4843　1991/08

ISSN： 0024-9297
TIME-RESOLVED SMALL-ANGLE NEUTRON-SCATTERING IN INTERMEDIATE-STAGE AND LATE-STAGE SPINODAL DECOMPOSITION OF DPB HPI BLENDS Peer-reviewed

H JINNAI, H HASEGAWA, T HASHIMOTO, CC HAN

MACROMOLECULES　24　(1)　282-289　1991/01

ISSN： 0024-9297
Microstructure effects on LCST phase behavior of polybutadiene and polyisoprene blends studied by SANs and LS

Shinichi Sakurai, Hiroshi Jinnai, Hirokazu Hasegawa, Takeji Hashimoto

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry　31　(2)　147-148　1990/08
Publisher: Publ by ACS
ISSN： 0032-3934
Time-resolved small-angle neutron scattering study on later stage spinodal decomposition of polymer blend

Hiroshi Jinnai, Hirokazu Hasegawa, Takeji Hashimoto, Charles C. Han

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry　31　(2)　141-142　1990/08
Publisher: Publ by ACS
ISSN： 0032-3934
MORPHOLOGY CONTROL OF POLYMER BLENDS BY A CHEMICAL PINNING OF SPINODAL DECOMPOSITION Peer-reviewed

T HASHIMOTO, M TAKENAKA, H JINNAI

POLYMER COMMUNICATIONS　30　(6)　177-179　1989/06

ISSN： 0263-6476

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Misc. 100

高分子結晶の本当の姿は？- 新しい計測技術が拓く高分子化学の温故知新 -」

陣内浩司

月刊化学　77　(4)　68-69　2022/04
Structure and Properties of Thermoplastic Elastomers Blended with Multicyclic Polymers

丸林弘典, 今崎篤, 海老井大和, 間藤芳允, 磯野拓也, 佐藤敏文, 陣内浩司

繊維学会予稿集(CD-ROM)　77　(1)　2022
Preparation of Silicone Rubbers with Rotaxane Cross-Linking Comprising of Multicyclic Polymer

江部陽, 磯野拓也, 山本拓矢, 田島健次, 佐藤敏文, 今崎篤, 丸林弘典, 陣内浩司

エラストマー討論会講演要旨集　32nd　2021
電子顕微鏡によるナノコンポジット材料の界面・高次構造評価の現状 Invited

佐藤庸平, 三好和加奈, 陣内浩司

2020/09
ナノコンポジット材料におけるナノ構造解析

陣内浩司

ナノファイバー学会誌　11　(1)　42-47　2020/07/31
ゴム/黄銅接着界面における破壊機構観察のための電子顕微鏡技術

清水克典, 宮田智衆, 陣内浩司

日本接着学会誌　56　(1)　34-40　2020/01
圧縮センシング技術との融合によるX線トモグラフィのフロンティアの開拓

矢代航, 上石正樹, 陣内浩司, 上田亮介, 工藤博幸

光アライアンス　30　(12)　23-30　2019/12
Publisher: 日本工業出版
ISSN： 0917-026X
動的ナノ構造観察のための電子顕微鏡技術 Invited

陣内浩司, 長尾知彦, 宮田智衆

プラスチックエージ　65　(11)　70-73　2019/11
ソフトマター用その場引っ張り3次元TEMホルダーの開発 Invited

陣内浩司

ソフトマター　(12)　13-15　2019/03
ブロック共重合体の自己組織化における“高分子らしさ”とは Invited

陣内浩司

高分子　68　(3)　111-114　2019/03
In situ Three-dimensional Observation of Rubber Materials Under Tensile Deformation Invited

Takeshi Higuchi, Hiroshi Jinnai

91　(10)　370-374　2018/10
Two-dimensional microphase separation of single-component homopolymer brushes

Norizoe Y, Murakami D, Higaki Y, Jinnai H, Takahara A

Meeting Abstracts of the Physical Society of Japan　72　(0)　3215-3215　2017
Publisher: The Physical Society of Japan

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分子シミュレーションにより、平板に均一にグラフトされた単成分均一鎖の高分子ブラシの構造を議論する。この系のパラメータが、高分子バルク溶液の相図でのバイノーダル線内側に相当する場合、系は多様な2次元ミクロ相分離構造を示す。
電子線トモグラフィーによるソフトマテリアルの三次元構造観察

陣内浩司, 樋口剛志

現代化学　(536)　23-27　2015/11
Publisher: 東京化学同人
ISSN： 0386-961X
Dewetting現象で作製した微細構造中におけるミクロ相分離構造の観察

平井裕太郎, 樋口剛志, 陣内浩司, 藪浩, 藪浩

高分子学会予稿集(CD-ROM)　64　(2)　2015
ジブロック共重合体微粒子の内部相分離構造に関する実験・理論面からの考察

樋口剛志, PINNA Marco, ZVELINDOVSKY Andrei V., 陣内浩司, 藪浩, 藪浩

高分子学会予稿集(CD-ROM)　64　(1)　2015
Ene-thiol反応を利用したハニカム状多孔質膜表面へのカルボキシ基の導入

平野光司, 樋口剛志, 陣内浩司, 藪浩, 藪浩

東北大学多元物質科学研究所研究発表会講演予稿集　15th　2015
Dynamical Fluctuation of Silsesquioxane Functionalized Polystyrene Thin Film Studied by Grazing Incidence X-ray Photon Correlation Spectroscopy

HOSHINO TAIKI, MURAKAMI DAIKI, OGAWA SHIGESABURO, HIGAKI YUJI, SATO MASANAO, HIRAI TOMOYASU, TANAKA YOSHIHITO, TAKATA MASAKI, JINNAI HIROSHI, TAKAHARA ATSUSHI

高分子学会予稿集(CD-ROM)　63　(1)　ROMBUNNO.2L25　2014/05/09
Electron tomography

陣内浩司

軽金属　64　(3)　117-120　2014/03
Publisher: 軽金属学会
ISSN： 0451-5994
8aAM-5 Particle Monte Carlo simulation of binary hard particle systems simultaneously connected to four reservoirs of constant μ_A, μ_B, P, and T

Norizoe Y, Kawakatsu T, Jinnai H, Takahara A

Meeting Abstracts of the Physical Society of Japan　69　(0)　199-199　2014
Publisher: The Physical Society of Japan (JPS)
ISSN： 1342-8349
Cutting Edge of Imaging Techniques for Polymer Materials and Its Application of Nanofabrication

HIGUCHI TAKESHI, JINNAI HIROSHI

Sen'i Gakkaishi　70　(10)　P-650-P-654　2014
Publisher: The Society of Fiber Science and Technology, Japan
DOI： 10.2115/fiber.70.P-650 　

ISSN： 0037-9875
Three-Dimensional Structural Analysis by Tomographic Methods

陣内浩司

成形加工 = Journal of the Japan Society of Polymer Processing : プラスチック整形加工学会誌　25　(11)　512-516　2013/11
Publisher: プラスチック成形加工学会
ISSN： 0915-4027
Structural Analysis of Polymer ( Nano ) Structures by Three-Dimensional Imaging Technique Based on Tomography

JINNAI Hiroshi

ぶんせき　(465)　528-533　2013/09/05
Publisher: 日本分析化学会
ISSN： 0386-2178
Crystal Orientations and Kinetics Studies of Nylon-12 Crystallization in Nanocylinders

CAO YAN, WU HUI, FUJIMOTO AYA, WATANABE HIROHMI, JINNAI HIROSHI, TAKAHARA ATSUSHI

高分子学会予稿集(CD-ROM)　62　(2)　ROMBUNNO.2M07　2013/08/28
Molecular Aggregation States of Isotactic Polystyrene Crystallized in Nanorods Characterized by Micro-beam X-Ray Diffraction and Electron Diffraction

WU HUI, CAO YAN, ISHIGE RYOHEI, HIGAKI YUJI, HOSHINO TAIKI, OHTA NOBORU, WATANABE HIROHMI, JINNAI HIROSHI, TAKAHARA ATSUSHI

高分子学会予稿集(CD-ROM)　62　(1)　ROMBUNNO.2G05　2013/05/14
Preparation and Characterization of Liquid Marble Stabilized with Hydrophobidized Halloysite

WU HUI, WATANABE HIROHMI, FUJIMOTO AYA, MINN MYO, JINNAI HIROSHI, TAKAHARA ATSUSHI

高分子学会予稿集(CD-ROM)　62　(1)　ROMBUNNO.2M09　2013/05/14
Dynamical study of polymer surfaces in microscopic scale using Grazing Incidence X-ray Photon Correlation Spectroscopy

HOSHINO TAIKI, MURAKAMI DAIKI, ARITA HIROSHI, OGAWA SHIGESABURO, HIRAI TOMOYASU, TANAKA YOSHIHITO, TAKATA MASAKI, JINNAI HIROSHI, TAKAHARA ATSUSHI

Abstr JSAP MRS Jt Symp (CD-ROM)　ROMBUNNO.16P-M7-2　2013
X-ray photon correlation spectroscopy using a fast pixel array detector with a grid mask resolution enhancer

Taiki Hoshino, Moriya Kikuchi, Daiki Murakami, Yoshiko Harada, Koji Mitamura, Kiminori Ito, Yoshihito Tanaka, Sono Sasaki, Masaki Takata, Hiroshi Jinnai, Atsushi Takahara

Journal of Synchrotron Radiation　19　(6)　988-993　2012/11

DOI： 10.1107/S0909049512038769 　

ISSN： 0909-0495 1600-5775

eISSN： 1600-5775
Compartmentalized colloidal particles via bulk crosslinking of ABC triblock terpolymers Peer-reviewed

Tobias Rudolph, Markus Drechsler, Hidekazu Sugimori, Hiroshi Jinnai, Axel H. E. Mueller, Felix H. Schacher

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　243　2012/03

ISSN： 0065-7727
ABCトリブロック共重合体が形成するミクロ相分離構造の金属化

樋口剛志, 樋口剛志, XI Jinag, 藪浩, 藪浩, 高原淳, 高原淳, 陣内浩司, 陣内浩司

高分子学会予稿集(CD-ROM)　61　(2)　2012
Event Report on Microscopy Conference MC 2011

JINNAI Hiroshi

顕微鏡 = Microscopy　46　(4)　291-291　2011/12/30

ISSN： 1349-0958
Measurements and analysis of adhesion between self-assembled monolayers and polymer by JKR method

HARADA YOSHIKO, JINNAI HIROSHI, TAKAHARA ATSUSHI

高分子学会予稿集(CD-ROM)　60　(2 Disk1)　ROMBUNNO.3H09　2011/09/13
Three-Dimensional Spatial Distributions of Pt Catalyst Nanoparticles on Carbon Substrates in Polymer Electrolyte Fuel Cells

Toshihiko Ito, Ukyo Matsuwaki, Yuji Otsuka, Masahiro Hatta, Katsuichiro Hayakawa, Koichi Matsutani, Tomoyuki Tada, Hiroshi Jinnai

ELECTROCHEMISTRY　79　(5)　374-376　2011/05

DOI： 10.5796/electrochemistry.79.374 　

ISSN： 1344-3542
有機・高分子トモグラフィーを用いた高分子不均一構造の3次元可視化の最前線

陣内浩司

未来材料　11　(4)　27-35　2011/04
Publisher: エヌ・ティー・エス
ISSN： 1346-0986
相分離構造を持つ微粒子からの“Suprapolymer Assembly”の創出

佐藤駿介, 樋口剛志, 陣内浩司, 藪浩, 藪浩, 下村政嗣, 下村政嗣

東北大学多元物質科学研究所研究発表会講演予稿集　11th　2011
28pGT-9 Fracture simulation in an elastic composite body contains cylindrical fillers under the uniaxial extension

Aoyanagi Yuko, Morita Hiroshi, Saito Haruko, Jinnai Hiroshi

Meeting Abstracts of the Physical Society of Japan　66　(0)　420-420　2011
Publisher: The Physical Society of Japan (JPS)
ISSN： 1342-8349
Swelling and interfacial characterization of multi-walled carbon nanotubes/natural rubber composites

TAKEUCHI Kenji, UEKI Hiroyuki, INUKAI Shigeki, IINOU Satoshi, JINNAI Hiroshi, KIM Yoong Ahm, FUJISHIGE Masatsugu, NOGUCHI Toru

TANSO　(244)　147-152　2010/09/01
Publisher: THE CARBON SOCIETY OF JAPAN
DOI： 10.7209/tanso.2010.147 　

ISSN： 0371-5345

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We have studied the solvent resistance characteristics of non-cross-linked and cross-linked natural rubber composites reinforced by multi-walled carbon nanotubes (MWCNTs). All the MWCNTs were individually dispersed within the rubber matrix where a three-dimensional cellulation structure was created when the added amount of MWCNTs exceeded 16 wt%. The non-cross-linked MWCNT-filled rubber composite was not soluble, but swelled in toluene. Upon detailed studies on the dried sample, it was found that a new phase was formed due to a strong bonding between the MWCNTs and the rubber matrix resulting in the cellulation structure. We found that a continuous three-dimensional structure at the interface between the MWCNTs and the natural rubber was extremely tough, and thus contributed to the improvement in the elastic modulus and thermal stability of natural rubber composites.
高分子階層構造のナノ・メゾスケール3次元観察・解析 (3D技法の最前線)

陣内浩司

分析電子顕微鏡討論会予稿集　26　48-50　2010/08/31
Publisher: 日本顕微鏡学会分析電子顕微鏡分科会
Self-assembling nano-structure of a block copolymer studied by transmission electron tomography

Hiroshi Jinnai, Hidekazu Sugimori, Kazuyuki Matsunaga, Song Hong, Takeshi Kaneko, Volker Abetz

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　240　2010/08

ISSN： 0065-7727
フィラー含有ゴムのフィラー3次元分散状態と力学物性の解明

陣内浩司

日本ゴム協會誌　83　(7)　206-206　2010/07/15

ISSN： 0029-022X
Helical micelles from the solution assembly of ABC triblock copolymers

Hongjing Dou, John Dupont, Guojun Liu, Ken-ichi Niihara, Ryuhei Kimoto, Hiroshi Jinnai

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　239　2010/03

ISSN： 0065-7727
高分子複合材料の3次元"その場"構造解析 (特集接着に関する分析技術)

齋藤明子, 陣内浩司

接着の技術　30　(1)　8-15　2010
Publisher: 日本接着学会
ISSN： 0289-8225
A Joint Effort between Industry and Academia in the Development of Transmission Electron Microtomography for Nano-scale Three-dimensional (3D) Visualization

Hiroshi Jinnai

SEN-I GAKKAISHI　65　(10)　P377-P380　2009/10

DOI： 10.2115/fiber.65.P_377 　

ISSN： 0037-9875
Soft material with nanomatrix structure

Seiichi Kawahara, Yoshimasa Yamamoto, Keiichi Akabori, Ken-ichi Niihara, Hiroshi Jinnai, Hideo Nishioka

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　238　2009/08

ISSN： 0065-7727
Nanoscale three-dimensional structural analysis of polymeric materials by transmission electron microtomography

JINNAI Hiroshi

應用物理　78　(7)　663-667　2009/07/10
Publisher: 応用物理学会
ISSN： 0369-8009
ブロックコポリマー微粒子中における内部相分離構造の3次元観察

樋口剛志, 樋口剛志, 本吉究, 小池和孝, 藪浩, 藪浩, 松永和之, 杉森秀一, 陣内浩司, 下村政嗣, 下村政嗣, 下村政嗣

高分子学会予稿集(CD-ROM)　58　(2 Disk1)　2009
ナノ構造を持つポリマー微粒子の作製と有機-無機ハイブリッド化

藪浩, 藪浩, 小池和孝, 本吉究, 樋口剛志, 陣内浩司, 陣内浩司, 下村政嗣, 下村政嗣

東北大学多元物質科学研究所研究発表会講演予稿集　9th　2009
Three-Dimensional Direct Observation and Crystallographic Analysis on a Bicontinuous Block Copolymer Morphology(<Special Issue>The Front Line of Pseudo-Crystalline Structures Formed by Complex Polymers)

Jinnai Hiroshi

Journal of the Japanese Association for Crystal Growth　36　(1)　24-29　2009
Publisher: The Japanese Association for Crystal Growth
DOI： 10.19009/jjacg.36.1_24 　

ISSN： 0385-6275

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Block copolymers, consisting of multiple, chemically dissimilar sequences covalently linked together, exhibit highly periodic nano-scale structures. Classical block copolymer nanostructures include spheres of A (B) on a body-centered cubic lattice in a B (A) matrix, cylinders of A (B) on a hexagonal lattice in a B (A) matrix, and coalternating lamellae. Of considerable recent interest are several complex (bicontinuous) nanostructures-the perforated lamellar (PL), gyroid (G), and double-diamond (D) morphologies. Here we show direct three-dimensional (3D) visualization of the gyroid structure using an emerging 3D imaging technique, the transmission electron microtomography (TEMT). Some crystallographical analysis to determine the space group of the gyroid will be given. In addition, epitaxial relation during the order-order transition from the gyroid to cylinders was clearly demonstrated using the 3D structures obtained using TEMT.
Three-dimensional direct observations and characterization of polymeric bicontinuous morphologies

陣内浩司

Journal of network polymer,Japan　30　(1)　41-48　2009
Publisher: 合成樹脂工業協会
DOI： 10.11364/networkpolymer.30.41 　

ISSN： 1342-0577
高分子材料の3次元構造解析--最新技術と可能性 (特集 "視る"技術が導く新しい高分子材料の分析・評価技術)

齋藤明子, 陣内浩司

ポリファイル　45　(10)　34-39　2008/10
Publisher: 大成社
ISSN： 0910-2175
Three-dimensional Imaging on Polymer Alloys

JINNAI Hiroshi

Journal of the Japan Society of Polymer Processing　20　(2)　100-105　2008/02/20
Publisher: プラスチック成形加工学会
ISSN： 0915-4027
Three-dimensional structural analysis on multi-component polymer materials by transmission electron microtomography

The micromeritics　(51)　49-51　2008
Publisher: ホソカワ粉体技術研究所
ISSN： 0429-9051
Evolution of High Peel Strength via Cavitation in Acrylic Rubber/Epoxy Resin Adhesive by Reaction-Induced Phase Decomposition

GOH Yutaka, AOYAMA Yoshitaka, TAKAHARA Atsushi, JINNAI Hiroshi, INOUE Takashi

Journal of Network Polymer,Japan　29　(1)　31-37　2008
Publisher: Japan Thermosetting Plastics Industry Association
DOI： 10.11364/networkpolymer1996.29.31 　

ISSN： 1342-0577

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We recently found that the acrylic rubber (ACM) /epoxy adhesive via reaction-induced spinodal decomposition showed high peel strength when it was cured with diaminodiphenylmethane. Transmission electron microscopy observation revealed : (1) epoxy-rich particles are densely deposited near the surface of polyimide film (adherend), (2) by peeling, the particles are highly deformed and then fragmented via cavitation, and (3) a lot of cavities of 10-30nm diameter are generated also in ACM-rich matrix. The damaged zone by cavitation is formed in deep (800nm depth from the interface). It implies that a huge peeling energy is consumed by the massive damage and it leads to the high peel strength. By contrast, in a week adhesive cured with 1-cyanoethyl-2-phenylimidazole, the damaged zone was very thin (ca.20nm).
Multi-scale Analysis on Structure and Properties of Polymers

NISHI Toshio, NAKAJIMA Ken, JINNAI Hiroshi

Journal of the Japan Society of Polymer Processing　19　(8)　468-472　2007/08/20
Publisher: プラスチック成形加工学会
ISSN： 0915-4027
Recent Development of Three-Dimensional Imaging Techniques and Their Perspective

JINNAI Hiroshi

Kobunshi　56　(5)　352-357　2007/05/01
Publisher: The Society of Polymer Science, Japan
DOI： 10.1295/kobunshi.56.352 　

ISSN： 0454-1138
反応誘起相分解性アクリルゴム/エポキシ樹脂系接着材料の相分離構造制御

郷豊, 青山佳敬, 井上隆, 陣内浩司, 高原淳

ネットワークポリマー　28　(0)　57-60　2007
Publisher: Japan Thermosetting Plastics Industry Association
DOI： 10.11364/networkpolymer1996.28.Supplement_57 　
Novel Structural Analyses of Polymeric Materials by Three-Dimensional Microscopy

JINNAI Hiroshi

Hyomen Kagaku　28　(8)　467-474　2007
Publisher: The Surface Science Society of Japan
DOI： 10.1380/jsssj.28.467 　

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Recently, three-dimensional (3D) direct observations and analysis of polymer morphologies draw considerable attention because they not only provide intuitive understanding of the morphologies but also offer novel structural parameters that can never be obtained by other technique. The most sophisticated transmission electron microtomography (TEMT) achieves spatial resolution of less than 1 nm in the 3D reconstructed images. In the present paper, applications of TMET to polymer nanostructures, that is microphase-separated structures of block copolymers (Gyroid-structures), were reported in order to demonstrate huge and promising capabilities of the new technique.
Introduction of Electron Beam Tomography and Three Dimentional Analysis for Nano-composite Materials

FURUKAWA Hiromitsu, SHIMIZU Miyoko, JINNAI Hiroshi

Materials science and technology　43　(5)　218-222　2006/10/20
Publisher: 日本材料科学会
ISSN： 1347-4774
Self-Assembling Processes and Their Structures Studied by Three-Dimensional Microscopy

陣内浩司

高分子　55　(9)　767-767　2006/09/01

ISSN： 0454-1138
Award Address: Molecular-level information of block copolymer systems from 3D characterization

Richard J. Spontak, Hiroshi Jinnai, David A. Agard, Kim O. Rasmussen, G. J. Agur Sevink, Steven D. Smith

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　231　2006/03

ISSN： 0065-7727
三次元電子顕微鏡によるゴム中のフィラーの三次元構造解析

陣内浩司, 西敏夫

接着　50　(2)　71-75　2006/02
Publisher: 高分子刊行会
ISSN： 0037-0495
The morphological change in block copolymer thin films analyzed by SCF simulation :

Sugimori Hidekazu, Jinnai Hiroshi, Matsuwaki Ukyo, Morita Hiroshi, Doi Masao, Nishi Toshio

87　(1)　189-190　2006
Publisher: 物性研究刊行会
ISSN： 0525-2997
Single chain distributions at the interface in micro phase separated structures obtained by self consistent field calculations :

Morita Hiroshi, Jinnai Hiroshi, Sugimori Hidekazu, Kawakatsu Toshihiro, Nishi Toshio, Doi Masao

87　(1)　174-175　2006
Publisher: 物性研究刊行会
ISSN： 0525-2997
Observation of polymer blends by X-ray phase tomography Peer-reviewed

A. Momose, A. Fujii, Y. Suzuki, H. Kadowaki, Y. Nishikawa, H. Jinnai

IPAP Conf. Series　7　279-281　2006
Three-Dimensional Structure and Liquid Transport Behavior of Silica Gels with Co-continuous Macropores

Saito Haruko, Nakanishi Kazuki, Hirao Kazuyuki, Nishikawa Yukihiro, Jinnai Hiroshi, Morisato Kei, Minakuchi Hiroyoshi

Preprints of Annual Meeting of The Ceramic Society of Japan Preprints of Fall Meeting of The Ceramic Society of Japan　2006　(0)　388-388　2006
Publisher: The Ceramic Society of Japan
DOI： 10.14853/pcersj.2006F.0.388.0 　

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In a sol-gel system accompanied by spinodal decomposition, co-continuous macroporous silica has been obtained as a result of structure freeze by gelation and solvent phase desolvation. The obtained co-continuous macroporous silica has been a fascinating separation media, but the flow behavior in co-continuous structure is still poorly understood. In order to prove the relationship between liquid transport behavior and geometry in co-continuous structure, three dimensional observation of the obtained co-continuous macroporous silica has been done by laser scanning confocal microscopy and Hg porosimetry. The influence of silica phase viscoelaticity has been considered on the structural formation.
A "ladder" morphology in an ABC triblock copolymer

Takeshi Kaneko, Kazuya Suda, Kotaro Satoh, Masami Kamigaito, Toshinori Kato, Tomohiro Ono, Eiji Nakamura, Toshio Nishi, Hiroshi Jinnai

MACROMOLECULAR SYMPOSIA　242　80-86　2006

DOI： 10.1002/masy.200651013 　

ISSN： 1022-1360
Three-dimensional observations of grain boundary morphologies in a cylinder-forming block copolymer

Hiroshi Jinnai, Kaoru Yasuda, Toshio Nishi

MACROMOLECULAR SYMPOSIA　245　170-174　2006

DOI： 10.1002/masy.200651324 　

ISSN： 1022-1360
Three dimensional structure and liquid transport behavior or siloxane gels with co-continuous macropores

H. Saito, K. Nakanishi, K. Hirao, H. Jinnai, K. Morisato, H. Minakuchi

Materials Research Society Symposium Proceedings　847　203-208　2005/12/19

ISSN： 0272-9172
高分子材料における電子線トモグラフィーを用いた三次元観察と構造解析 (先端材料への新展開)

陣内浩司, 西川幸宏

分析電子顕微鏡討論会予稿集　21　50-56　2005/08/30
Publisher: 日本顕微鏡学会分析電子顕微鏡分科会
Grain boundary morphologies of block copolymer nanostructures studied by transmission electron microtomography

H Jinnai, K Sawa, H Sugimori, K Yasuda, Y Nishikawa, T Nishi

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　230　U4159-U4159　2005/08

ISSN： 0065-7727
2軸傾斜透過型電子線トモグラフィー法による高分子ナノ構造の3次元観察 (〔機能材料〕創刊24周年特集高分子の3次元イメージングによる材料の評価と構造解析(Part 1))

陣内浩司, 杉森秀一, 西川幸宏

機能材料　25　(7)　9-14　2005/07
Publisher: シーエムシー出版
ISSN： 0286-4835
ナノコンポジット材料と表面・界面の精密構造解析 (特集1 ナノテクノロジー)

中嶋健, 小村元憲, 陣内浩司

月刊トライボロジー　19　(2)　22-25　2005/02
Publisher: 新樹社
ISSN： 0914-6121
Self consistent field simulation on the structure obtained by 3D TEM(Soft Matter as Structured Materials) :

Morita Hiroshi, Jinnai Hiroshi, Nishikawa Yukihiro, Kawakatsu Toshihiro, Uneyama Takashi, Nishi Toshio, Doi Masao

84　(6)　837-838　2005
Publisher: 物性研究刊行会
ISSN： 0525-2997
3D Observation of Nano-Structures in a Block Copolymer Thin Film by Transmission Electron Microtomography

NIIHARA Kenichi, JINNAI Hiroshi

Journal of The Adhesion Society of Japan　41　(5)　203-208　2005
Publisher: The Adhesion Society of Japan
DOI： 10.11618/adhesion.41.203 　

ISSN： 0916-4812
3次元電子顕微鏡の概要と高分子ナノ構造の観察 (特集ナノファイバーの評価法)

古河弘光, 清水美代子, 陣内浩司

機能材料　24　(10)　33-42　2004/10
Publisher: シーエムシー出版
ISSN： 0286-4835
Analysis of Nano-materials by Three-Dimensional Microscopy

JINNAI Hiroshi

Journal of the Japan Society of Polymer Processing　16　(6)　342-345　2004/06/20
Publisher: プラスチック成形加工学会
ISSN： 0915-4027
Three-dimensional observation of phase-separated sol-gel structures using Laser Scanning Confocal Microscopy (LSCM)

K Kanamori, K Nakanishi, K Hirao, H Jinnai

APPLIED CRYSTALLIGRAPHY　367-372　2004

DOI： 10.1142/9789812702913_0072 　
Electron Microtomography and Three-Dimensional Image Analysis in Polymer Nano-Science

JINNAI Hiroshi

NIPPON GOMU KYOKAISHI　76　(10)　384-389　2003/10/15
Publisher: THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN
DOI： 10.2324/gomu.76.384 　

ISSN： 0029-022X

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A microscopy that can offer three-dimensional (3D) images of nanometer-scale has been developed. The methodology, called transmission electron microtomography (TEMT), is a combination of the conventional transmission electron microscopy (TEM) and computerized tomography (CT). A series of TEM images of an object taken at different tilting angles ranged from 60&deg; to the other side of 60&deg; with an increment of a couple of degrees is subjected to CT in order to reconstruct 3D images of the object. TEMT was used to investigate a self-organized nano-scale structure of a block copolymer. Under the conventional TEM, the structure appeared to be too complicated to characterize, while a periodic double-network structure consisting of one of the block constituents was clearly observed by TEMT. A 3D image analysis, i.e. 3D thinning, was used to estimate geometry of the network structure, which revealed that the coordination number at junctions were mainly 3. Combining this experimental result with crystallographic analysis of the network structure undoubtedly demonstrated that it has Ia3d symmetry and hence is based on one of the periodic minimal surfaces, Gyroid. Moreover, it is worth noting that the structures so far unexplored due to the lack of dimensionality, e.g., defects and grain boundary in crystals, will be able to be studied only by TEMT.
3次元顕微鏡で見る高分子の自己組織化構造

陣内浩司

未来材料　3　(10)　42-49　2003/10
Publisher: エヌ・ティー・エス
ISSN： 1346-0986
解説高分子ナノ計測 (特集ナノテクで変わる高分子材料)

西川幸宏, 陣内浩司

工業材料　51　(6)　27-30　2003/06
Publisher: 日刊工業新聞社
ISSN： 0452-2834
Morphology evolution in phase-separated siloxane sol-gel systems in a confined space

Kanamori Kazuyoshi, Nakanishi Kazuki, Hirao Kazuyuki, Jinnai Hiroshi

Preprints of Annual Meeting of The Ceramic Society of Japan Preprints of Fall Meeting of The Ceramic Society of Japan　2003　(0)　341-341　2003
Publisher: The Ceramic Society of Japan
DOI： 10.14853/pcersj.2003S.0.341.0 　

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Phase-separated siloxane gels with co-continuous porous structures in the length scale from nanometers to micrometers have been synthesized in confined spaces especially in short cylindrical pores within porous medium. Morphology of the phase-separated gels derived from both methyltrimethoxysilane (MTMS) and tetramethoxysilane (TMOS) inside the porous medium was significantly affected by preferential wetting by siloxane phase on the internal surface of the mold. When spinodal wavelength of the guest gel becomes larger than pore size of the porous medium, wetting transition has been observed in the systems with strong affinity between siloxane phase and the internal surface of the mold.
"Sponge-like" structures in polymer blends: Visualization, physico-mathematical analysis, and universality

T Hashimoto, H Jinnai, Y Nishikawa, T Koga

MACROMOLECULAR SYMPOSIA　190　9-22　2002/11

ISSN： 1022-1360
元素識別型3次元電子顕微鏡の開発 (特集高分子ナノ計測・加工) -- (Part1 高分子ナノ計測)

西川幸宏, 陣内浩司, 古河弘光

機能材料　22　(10)　11-19　2002/10
Publisher: シーエムシー出版
ISSN： 0286-4835
高分解能X線顕微鏡の開発 (特集高分子ナノ計測・加工) -- (Part1 高分子ナノ計測)

陣内浩司, 澄川清志

機能材料　22　(10)　26-32　2002/10
Publisher: シーエムシー出版
ISSN： 0286-4835
Three-Dimensional Observation and Structural Analysis of Bicontinuous Morphologies

JINNAI Hiroshi

Kobunshi　51　(10)　830-830　2002/10/01
Publisher: The Society of Polymer Science, Japan
DOI： 10.1295/kobunshi.51.830 　

ISSN： 0454-1138
Observation of phase separated structure in siloxane sol-gel systems in a confined space

Kanamori Kazuyoshi, Nakanishi Kazuki, Hirao Kazuyuki, Jinnai Hiroshi

Preprints of Annual Meeting of The Ceramic Society of Japan Preprints of Fall Meeting of The Ceramic Society of Japan　2002　(0)　118-118　2002
Publisher: The Ceramic Society of Japan
DOI： 10.14853/pcersj.2002F.0.118.0 　

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Siloxane gel with co-continuous structure derived from methyltrimethoxysilane (MTMS) and tetramethoxysilane (TMOS) were synthesized in 2- and O-dimensional confined spaces by inducing spinodal decomposition during sol-gel transition. The resultant macroporous gel morphology was 3-dimensionally examined by a laser scanning confocal microscopy (LSCM). The depth profile of volume fraction of gel phase oscillated near both hydrophobic and hydrophilic glass surfaces due to the attractive interactions between phase-separating siloxane phase and surfaces and/or shrinkage during aging stage. In 0-D confined space, surprisingly fine but disordered TMOS-derived gel has formed in broadened composition rage while MTMS-derived gel did not.
Interfacial and topological measurements of bicontinuous polymer morphologies (vol E 64, art. no. 010803, 2001)

H Jinnai, T Kajihara, H Watashiba, Y Nishikawa, RJ Spontak

PHYSICAL REVIEW E　64　(6)　2001/12

DOI： 10.1103/PhysRevE.64.069903 　

ISSN： 1539-3755
Porous gel coatings obtained by phase separation in ORMOSIL system

Kazuki Nakanishi, Souichi Kumon, Kazuyuki Hirao, Hiroshi Jinnai

Materials Research Society Symposium - Proceedings　628　2000/01/01

ISSN： 0272-9172
Measurements of Geometrical Properties of Phase-separated Polymer Mixtures

JINNAI Hiroshi, NISHIKAWA Yukihiro, HASHIMOTO Takeji

Fiber　54　(11)　382-386　1998/11/10
Publisher: 繊維学会
DOI： 10.2115/fiber.54.11_P382 　

ISSN： 0037-9875
Curvature determination of spinodal interface in a phase separated polymer blend(International Workshop on Amphiphilic Systems) :

陣内浩司, 西川幸宏, 古賀毅, 橋本竹治

物性研究　70　(1)　86-87　1998
Publisher: 物性研究刊行会
ISSN： 0525-2997

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この論文は国立情報学研究所の電子図書館事業により電子化されました。
Geometrical Properties of Interface of Phase-Separated Structures(International Workshop on Amphiphilic Systems) :

古賀毅, 陣内浩司, 西川幸宏, 橋本竹治

物性研究　70　(1)　90-91　1998
Publisher: 物性研究刊行会
ISSN： 0525-2997

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この論文は国立情報学研究所の電子図書館事業により電子化されました。
Measurements of Geometrical Properties of Phase-separated Polymer Mixtures

Hiroshi Jinnai, Yukihiro Nishikawa, Takeji Hashimoto

Sen'i Gakkaishi　54　(11)　P382-P386　1998
Publisher: The Society of Fiber Science and Technology, Japan
DOI： 10.2115/fiber.54.11_P382 　

ISSN： 0037-9875
高分子多成分系におけるメゾパタ-ンの発現と制御--共連続構造の三次元構築と界面の微分幾何学的解析

橋本竹治, 陣内浩司, 西川幸宏

日本化学繊維研究所講演集　(53)　57-65　1996/11
Publisher: 日本化学繊維研究所
ISSN： 0368-6280
The ordered structure in binary mixtures of A-B diblock copolymer and A-C diblock copolymer

K Kimishima, H Jinnai, T Koga, T Hashimoto

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　212　142-POLY　1996/08

ISSN： 0065-7727
Curvature measurement of interface in bicontinuous phase-separated structures of a polymer blend

H Jinnai, Y Nishikawa, T Koga, T Hashimoto

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　212　109-PMSE　1996/08

ISSN： 0065-7727
THE EFFECT OF SHEAR-FLOW ON THE DEMIXING PROCESS OF POLYMER BLENDS

K MATSUZAKA, H JINNAI, T HASHIMOTO

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　208　65-PMSE　1994/08

ISSN： 0065-7727
SANS STUDIES OF EARLY STAGE SPINODAL DECOMPOSITION Peer-reviewed

T HASHIMOTO, H JINNAI, H HASEGAWA, CC HAN

ORDERING IN MACROMOLECULAR SYSTEMS　273-290　1994
高分子混合系のスピノーダル分解

陣内浩司

波紋　4　(3)　25-30　1994
Publisher: 日本中性子科学会
DOI： 10.5611/hamon.4.3_25 　

ISSN： 1349-046X
MICROSTRUCTURE EFFECTS ON THE EQUILIBRIUM PHASE-BEHAVIOR OF ELASTOMER BLENDS STUDIED BY SANS

CC HAN, S SAKURAI, H JINNAI, H HASEGAWA, T HASHIMOTO

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　205　147-PMSE　1993/03

ISSN： 0065-7727
MICROSTRUCTURE EFFECTS ON LCST PHASE-BEHAVIOR OF POLYBUTADIENE AND POLYISOPRENE BLENDS STUDIED BY SANS AND LS

S SAKURAI, H JINNAI, H HASEGAWA, T HASHIMOTO, CC HAN

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　200　84-POLY　1990/08

ISSN： 0065-7727
TIME-RESOLVED SMALL-ANGLE NEUTRON-SCATTERING STUDY ON LATER STAGE SPINODAL DECOMPOSITION OF POLYMER BLEND

H JINNAI, H HASEGAWA, T HASHIMOTO, CC HAN

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　200　78-POLY　1990/08

ISSN： 0065-7727

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Books and Other Publications 8

ポリマーの強靱化技術最前線 : 破壊機構、分子結合制御、しなやかタフポリマーの開発

共著

エヌ・ティー・エス　2020/05

ISBN: 9784860436681
Nanoparticle technology handbook

Hiroshi Jinnai

Elsevier　2012/04/27

ISBN: 9780444563361
Polymer science : a comprehensive reference,10 Volume Set

Hiroshi Jinnai

Elsevier　2012

ISBN: 9780444533494
Experimental methods in polymer science : modern methods in polymer research and technology

M. Shibayama, H. Jinnai, T. Hashimoto

Academic Press　2000

ISBN: 012683265X
静的光散乱ー高分子集合体・多成分系（高分子実験学第6巻高分子の構造(2)）

陣内浩司, 橋本竹治

共立出版　1997/09

ISBN: 4320043316
Interfacial aspects of multicomponent polymer materials

H Jinnai, Y Nishikawa, T Koga, T Hashimoto

Plenum Press　1997

ISBN: 0306457180
SANS Studies of Early Stage Spinodal Decomposition

T. Hashimoto, H. Jinnai, H. Hasegawa, C. C. Han

Springer, Berlin, Heidelberg　1994

ISBN: 9783642788956
Slow dynamics in condensed matter

H JINNAI, H HASEGAWA, T HASHIMOTO, CC HAN

American Institute of Physics　1992/01/01

ISBN: 0883189380

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Presentations 142

ソフトマテリアルの薄片化・染色とその注意点陣内浩司日本顕微鏡学会ソフトマテリアル分科会第2回講演会 2024年12月17〜18日 2024年12月17日招待講演東レ総合研修センターソフトマテリアルの薄片化・染色とその注意点 Invited

陣内浩司

日本顕微鏡学会ソフトマテリアル分科会第2回講演会　2024/12/17
ナノスケールから見たソフト/ハード界面の接着・破壊挙動の観察と解析 Invited

陣内浩司

超分子研究会・精密ネットワークポリマー研究会第8回合同講座　2024/11/22
ポリマー結晶内部の分子配向可視化 Invited

陣内浩司

第123回プラスチックフィルム研究会　2024/07/11
FIB によるソフトマテリアルの加工と３次元観察 Invited

陣内浩司

日本顕微鏡学会第67回シンポジウム　2024/11/02
Multi-dimensional static and dynamic Structural analysis of polymeric materials by electron microscopy Invited

2024/10/31
原子分解能観察によるソフト/ハード界面の接着・破壊機構の解明 Invited

原子分解能観察によるソフト, ハード界面の接着, 破壊機構の解明

CREST「ナノ力学」領域 2024年度公開シンポジウム　2024/10/20
Crystalline Structures Studied by Advanced Electron Microscopy Invited

Hiroshi Jinnai

International Discussion Meeting on Polymer Crystallization 2024 (IDMPC 2024)　2024/09/19
高分子多成分系の無染色ナノスケール観察 Invited

陣内浩司

2024年電子顕微鏡解析技術フォーラム　2024/08/24
ポリオレフィン結晶のナノスケール精密構造解析 Invited

陣内浩司

第62回高分子材料自由討論会　2024/06/27
Nano-scale structures of polymer crystals studied by advanced electron microscopy Invited

Hiroshi Jinnai

The 14th International Symposium on Polymer Physics, PP 2024　2024/06/10
電子顕微鏡によるソフトマテリアル研究の現状と将来展望 Invited

陣内浩司

公益社団法人日本顕微鏡学会第80回学術講演会　2024/06/04
Reassessing chain tilt in the lamellar crystals of polyethylene by electron-diffraction imaging Invited

Hiroshi Jinnai

ACS Spring Meeting 2024　2024/03/20
先端電子顕微鏡で観る複合ゴムの変形・破壊 Invited

陣内浩司

2024/03/18
Overview of the JST-CREST project on high-resolution analysis of polymer-inorganic adhesive interfaces

Hiroshi Jinnai

CREST-NIST joint mini-symposium　2024/03/15
電子顕微鏡による高分子結晶の分子レベル解析 Invited

陣内浩司

高分子のためのキャラクタリゼーションセミナー2023 〜基礎から最新分析情報まで〜　2024/03/07
電子顕微鏡による高分子材料のナノスケール構造解析 Invited

陣内浩司

23-2高分子学会講演会構造と物性を解き明かす～ポリマー分析技術の最先端～　2024/02/21
ナノスケールから見たソフト/ハード界面の接着・破壊機構について Invited

陣内浩司

第288回ゴム技術シンポジウム　2023/12/22
Order-Order Transition in Polystyrene-block-Poly(2-vinylpyridine) Using Time-Resolved 3D Transmission Electron Microtomography Invited

Hiroshi Jinnai

Symposium of “Block Copolymer Self-Assembly” for Prof. Jin Kon Kim’s honor　2023/11/10
Reassessing chain tilt in the lamellar crystals of polyethylene by electron-diffraction imaging Invited

Hiroshi Jinnai

KAUST Research Conference, Designing Macromolecules for a Sustainable Future　2023/11/06
ポリマーの階層構造と破壊過程 - 無染色でのポリマー、高分子の構造観察 -

陣内浩司

「次世代電子顕微鏡技術共同研究部門」成果報告会　2023/10/13
Static and Dynamic Structural Analysis of Soft Materials by Electron Microscopy Invited

Hiroshi Jinnai

European Advanced Materials Congress, Session 05: Structural & Engineering Materials　2023/09/24
Nanoscale structural characterization of polymer hierarchical structures - from the static and dynamic viewpoints – Invited

Hiroshi jinnai

20th International Microscopy Congress　2023/09/11
Nanoscale Structural Analysis of Polymer Crystals Using Advanced Electron Microscopy Invited

Hiroshi Jinnai

2023/09/10
Static and Dynamic Behaviors of Polymer Nanostructures studied by Advanced Transmission Electron Microscopy Invited

Hiroshi Jinnai

IMC20 SATELLITE SYMPOSIUM　2023/09/07
Nanoscale static and dynamic characterization of polymer hierarchical structures for sustainable engineering Invited

Hiroshi Jinnai

ACS Fall 2023　2023/08/16
電子顕微鏡を用いたソフトマテリアルの観察技術

陣内浩司

令和５年度みやぎ県民大学「学校等開放講座」　2023/07/28
Nanoscale Structural Analysis of Polymer Crystals Using Electrons Invited

Hiroshi Jinnai

International Conference on Materials for Advanced Technologies (ICMAT) 2023 Symposium　2023/06/26
高分子多成分系の相分離構造における３次元界面の形態とダイナミクス

陣内浩司

JST CREST第 5 回 CREST ナノ力学研究会:「界面制御と力学物性」　2023/06/23
電子顕微鏡によるソフトマテリアルの構造可視化・解析

陣内浩司

JST CREST「分解と安定化」領域第3回Webinar　2023/05/16
Static and Dynamic Behaviors of Polymer Nanostructures studied by Advanced Transmission Electron Microscopy Invited

Hiroshi Jinnai

Trilateral Conference at the Annual Meeting of Taiwan Polymer Meeting　2023/01/17
A new nano-scale imaging for polymer crystals: Nano-diffraction imaging Invited

Hiroshi Jinnai

China-Japan Polymers Cooperation & Development Forum　2022/12/27
材料解析のためのポリマー材料の試料作製 Invited

陣内浩司

第37回分析電子顕微鏡討論会　2022/12/09
新世代電子顕微鏡によるソフトマテリアルの静的・動的ナノスケール計測 Invited

陣内浩司

JAIMA 「未踏分析技術イノベーションウェビナー」　2022/12/06
架橋ゴム複合材料の延伸その場観察 Invited

陣内浩司

日本顕微鏡学会ソフトマテリアル分科会第1回講演会　2022/11/25
電子顕微鏡のソフトマテリアルへの応用の現状と将来 Invited

陣内浩司

第11回「次世代電子顕微鏡法」講演会　2022/11/22
高分子材料の変形挙動のナノスケール直接観察と解析 Invited

陣内浩司

第31回ポリマー材料フォーラム　2022/11/16
原子分解能観察によるソフト/ハード界面の接着・破壊機構の解明

陣内浩司

CREST/さきがけ「ナノ力学」領域第1回公開シンポジウム　2022/10/22
Nanoscale stress distribution and crack propagation in rubber-based nano-composites under stretching Invited

Hiroshi Jinnai

The 11th International Conference on Materials Science and Technology　2022/08/31
Structural Analysis of Polymers using Electron Microscopy Invited

International Summer School on Soft Matter in Cargese　2022/07/13
Precise Analysis of Environmental Micro-plastics Originated from Polyolefins

Tomoko Kajiwara, Yingjun An, Padermshoke Adchara, Akemi Kumagai, Hironori Marubayshi, Yuka Ikemoto, Hiroshi Jinnai, Atsuhiko Isobe, Atsushi Takahara

2022/06/07
Nano-diffraction Imaging of Polymer Crystals Invited

Hiroshi Jinnai

2022/06/07
ELECTRON MICROSCOPY (TOMOGRAPHY) OF SOFT MATERIALS Invited

Hiroshi Jinnai

33rd International Symposium of Polymer Analysis and Characterization (ISPAC) 2022　2022/06/05
Self-assemblies of block copolymers studied by electron microscopy Invited

4th Workshop & Progress Meeting POLYSTORAGE-ETN　2022/05/19
高分子系における液-液相分離構造の3次元形態観察とトポロジー解析 Invited

陣内浩司

第127回日本解剖学会総会・全国学術集会　2022/03/28
エラストマーの延伸挙動の直接その場観察 Invited

陣内浩司

日本ゴム協会関東支部 2月技術講演会　2022/02/04
高分子結晶のナノ回折イメージングによる詳細構造解析 Invited

陣内浩司

ダイナミック・アライアンス 2021年度合同WEB分科会　2022/02/02
Atomic-resolution electron microscopy study on a soft/hard nano-composite interface for adhesiveness Invited

Hiroshi Jinnai

The Material Research Meeting 2021　2021/12/13
ソフトマテリアルの電子顕微鏡観察における最近の話題 Invited

陣内浩司

日本顕微鏡学会第64回シンポジウム　2021/11/25
高分子ナノ構造における静的・動的挙動の電子顕微鏡観察と解析 Invited

陣内浩司

先端分析技術シンポジウム 2021　2021/11/16
高分子ナノ構造の静的・動的観察の現状 Invited

陣内浩司

2021年度第10回ナノ構造ポリマー研究協会nano webinar　2021/11/10
Nano-diffraction Imaging of Polymer Crystals Invited

Hiroshi Jinnai

The 5th Symposium for The Core Research Clusters for Materials Science and Spintronics　2021/10/26
高分子構造の静的・動的な姿をナノスケールで観る Invited

陣内浩司

関東高分子若手研究会 2021 ミニシンポジウム　2021/09/11
高分子研究における電子顕微鏡 - 基礎から応用まで Invited

陣内浩司

第70回高分子討論会　2021/09/08
ナノ構造計測におけるAI活用計測評価の応用と今後への期待 Invited

陣内浩司

NBCIテクノロジー委員会計測評価分科会主催講演会　2021/08/31
Nanoscale Stress Distribution in Silica Nanoparticle-filled Rubber as Observed by Transmission Electron Microscopy Invited

Hiroshi Jinnai

WebSymposium on Functional Polymeric Materials　2021/05/04
Visualization of chemical bonding in a silica-filled rubber nanocomposite using STEM-EELS Invited

Hiroshi Jinnai

The 38th International Conference of the Microscopy Society of Thailand　2021/03/24
電子顕微鏡によるナノコンポジット材料の界面・高次構造評価の現状 Invited

陣内浩司

第69回高分子討論会　2020/09/16
Static and dynamical 3D characterizations of the organic-inorganic interface in nano-composite materials using electron microscopy Invited

Hiroshi Jinnai

12th Asia-Pacific Microscopy Conference (APMC-2020)　2020/02/05
ソフトマテリアル電子顕微鏡観察におけるコントラスト増強とその場観察へ向けての取り組み

陣内浩司

高分子のためのキャラクタリゼーションセミナー　2019/12/12
変形下にある高分子材料の(TEMによる)その場観察

陣内浩司

第29回日本MRS年次大会 P:変形下にある高分子材料の解析技術最前線　2019/11/28
Dynamical characterizations of organic-inorganic interface in nano-composite materials using advanced electron microscopy International-presentation

Hiroshi Jinnai

the 9th International Conference on Advanced Fibers and Polymer Materials (ICAFPM 2019)　2019/11/19
Dynamical Characterization of Organic-Inorganic Interface in a Nano-Composite Using Electron Microscopy International-presentation

Hiroshi Jinnai

The 11th Anniversary of Federation of Asian Polymer Societies (FAPS)　2019/10/27
電子顕微鏡によるやわらかい材料の構造解析 – 産学連携による材料開発の一例 -

陣内浩司

第8回MaSC技術交流会”Real Exchange” テーマ「続・究極の見える化 – 電子顕微鏡があばくやわからかい材料の正体 -」　2019/10/15
ソフト/ハードナノハイブリッド材料の3次元構造と特性 – 産学連携による材料開発の一例 -

陣内浩司

2019年度微細構造解析プラットフォームシンポジウム　2019/09/20
Recent Developments in Electron Tomography and FIB/SEM Serial Sectioning for 3D Morphological Analysis in Polymer Composites International-presentation

Hiroshi Jinnai

The 82nd Annual Meeting of the Meteoritical Society“Workshop on Minerals, Organics, and Water in 3D View”　2019/07/07
Development of 3D Tomography Holder for Tensile Deformation for Soft Materials International-presentation

Hiroshi Jinnai

10th International Conference on Materials for Advanced Technologies　2019/06/26
Dynamical characterizations of organic-inorganic interface in nano-composite materials using advanced electron microscopy International-presentation

Hiroshi Jinnai

European Polymer Congress 2019　2019/06/13
Direct visualization of organic-inorganic interface by atomic force microscopy and electron tomography International-presentation

Hiroshi Jinnai

Microscopy characterization of organic-inorganic interfaces 2019　2019/03/07
Recent developments of morphological characterization in nano-composite materials by electron microscopy International-presentation

Hiroshi Jinnai

American Physical Soceity March Meeting 2019　2019/03/04
高分子ナノ構造のホントウの姿を覗いてみませんか？

陣内浩司

第36回コロイド・界面技術シンポジウム　2019/01/25
Electron microscopy for morphological studies in soft materials International-presentation

Hiroshi Jinnai

Nanyang Technological University for attending the FACTS Opening workshop　2019/01/11
Nano-Scale Visualization of a Rubber Composites under Uniaxial Deformation by Electron Microscopy International-presentation

Hiroshi Jinnai

MRS-J 2018 F-9: Design and Characterization of Tough Polymer　2018/12/20
Morphological and Dynamical Characterizations of Rubber Composites Observed by Advanced Microscopy Techniques International-presentation

Hiroshi Jinnai

The International Conference on Polymer Science and Engineering (PSD2018)　2018/12/15
Direct Visualization of "Bound Rubber" in Rubber Nano-Composites International-presentation Invited

Hiroshi Jinnai

2018 International Symposium for Soft Matter Science and Technology　2018/11/05
Helical microphase-separated structures of an ABC-type block copolymer studied by electron tomography International-presentation Invited

Hiroshi Jinnai

Reimund Stadler Symposium　2018/10/15
Direct Visualization of "Bound Rubber" in Rubber Nano-Composites International-presentation Invited

Hiroshi Jinnai

The International Symposium on Polymer Science and Engineering　2018/10/13
Development of 3D tobmography holder for tensile deformation of soft materials International-presentation Invited

Hiroshi Jinnai

Materials Science Engineering (MSE) 2018　2018/09/26
Direct visualization of Interphase region between fillers and matrix in rubber composites observed by electron tomography with mechanical mapping International-presentation Invited

Hiroshi Jinnai

256th ACS National Meeting　2018/08/21
Nano-scale visualization of deformation and fracture phenomena in soft materials International-presentation Invited

Hiroshi Jinnai

256th ACS National Meeting　2018/08/19
Direct morphological observations of nano-composites under tensile deformation International-presentation Invited

Hiroshi Jinnai

The 13th International Symposium on Polymer Physics (PP’2018)　2018/06/11
3D imaging of polymeric nanostructures by electron microscopy - towards large volume dynamical 3D imaging International-presentation Invited

Hiroshi Jinnai

The 35th International Conference of the Microscopy Society of Thailand (MST35)　2018/01/31
In situ nano-scale observations of polymeric materials under extension by electron microscopy International-presentation Invited

Hiroshi Jinnai

Japan-Taiwan Bilateral Symposium – Polymeric Materials for Future Vehicles　2017/11/20
Some challenges for 3D imaging of polymeric nanostructures by electron microscopy International-presentation Invited

Hiroshi Jinnai

International Symposium on Polymer and Condensed Matter Physics　2017/11/09
Nano-scale structural observations of unstained polymeric materials by transmission electron microscopy International-presentation Invited

Hiroshi Jinnai

Japan-Taiwan Bilateral Polymer Symposium 2017　2017/09/06
Nano-scale structural observations of unstained polymeric materials by transmission electron microscopy International-presentation Invited

Hiroshi Jinnai

the International Conference on Frontiers in Materials Processing, Applications, Research and Technology (FiMPART) 2017　2017/07/09
Challenges for 3D imaging of polymeric nanostructures by electron microscopy -towards large volume dynamical 3D imaging International-presentation Invited

Hiroshi Jinnai

30th International Symposium on Polymer Analysis and Characterization　2017/06/11
Structure-property relationship of polymeric materials studied by electron tomography International-presentation Invited

Hiroshi Jinnai

9th International Conference on Materials Science and Technology (MSAT-9)　2016/12/14
Challenges for nano-scale imaging of soft materials by electron microscopy International-presentation Invited

Hiroshi Jinnai

International symposium on Electrocatalysis: A key of sustainable society (ECAT2016)　2016/09/11
Challenges for nano-scale imaging of polymeric nanostructures by electron microscopy International-presentation Invited

Hiroshi Jinnai

International Conference on POLYMER SCIENCE & ENGINEERING 2016　2016/08/22
Electron Microscopy of Soft Materials International-presentation Invited

Hiroshi Jinnai

29th International Symposium on Polymer Analysis and Characterization (ISPAC-2016)　2016/06/12
Direct Characterization of In-Plane Phase Separation in a Polymer Brush in Solvent International-presentation Invited

Hiroshi Jinnai

29th International Symposium on Polymer Analysis and Characterization　2016/06/12
Challenges for nano-scale imaging of soft materials by electron microscopy International-presentation Invited

Hiroshi Jinnai

Pacifichem2015 “New Perspectives of Synthetic and Biological Soft Matter　2015/12/15
Dynamical aspects and nano‐fabrication of polymeric materials studied by electron microscopy International-presentation Invited

Hiroshi Jinnai

International Workshop on Advanced and In-situ Microscopies of Functional Nanomaterials and Devices (IAMNano 2015)　2015/07/08
Defects” of polymer nanostructures characterized by electron tomography International-presentation Invited

Hiroshi Jinnai

2015 TAC Meeting, Agenda: “Characterization of defects in high performance heterogeneous materials”　2015/05/20
Dynamical aspects and nano‐fabrication of polymeric materials studied by electron microscopy International-presentation Invited

Hiroshi Jinnai

International Workshop on Nanofluid and their Application　2015/05/13
Polymer nanostructures observed by electron microscopy International-presentation Invited

Hiroshi Jinnai

8th International Conference on Materials Science and Technology Tailand-Japan Polymer Initiative　2014/12/15
Characterization and fabrication of polymeric nano-structures by advanced environmental electron microscopy International-presentation Invited

Hiroshi Jinnai

AsiaNano 2014　2014/10/26
Electron tomography on soft materials: 3D observation and structural analysis on polymer nano-structures International-presentation Invited

Hiroshi Jinnai

1st ExxonMobil Scattering/Tomography Symposium - Quantitative Interpretation of Scattering and Tomography Images　2014/10/14
Control and fabrication of polymer nano-structures studied by electron microscopy International-presentation Invited

Hiroshi Jinnai

18th International Microscopy Congress (IMC2014)　2014/09/07
Control and Fabrication of Polymer Nanostructures International-presentation Invited

Hiroshi Jinnai

The IUMRS-ICA 2014 (International Union of Materials Research Societies, International Conference in Asia)　2014/08/24
Polymer nano-structures fabricated and observed by electron microscopy International-presentation Invited

Hiroshi Jinnai

The 11th International Symposium of Polymer Physics (PP'2014)　2014/06/08
Polymer nanostructures studied by electron microscopy International-presentation Invited

Hiroshi Jinnai

The 2014 EMN (Energy Materials Nanotechnology) Spring Meeting　2014/02/27
Morphologies and Fabrication of a Conjugated Polymer on Surfaces Studied by Electron Microscop International-presentation Invited

Hiroshi Jinnai

The 13th Pacific Polymer Conference　2013/11/17
Three dimensional structure characterization of composite material - from nano to meso - International-presentation Invited

Hiroshi Jinnai

2012 EFFoST Annual Meeting　2012/11/20
Multi-scale three-dimensional imaging in polymeric materials International-presentation Invited

Hiroshi Jinnai

ISAEM-2012 The 5th International Symposium on Designing, Processing and Properties of Advanced Engineering Materials　2012/11/05
Self-Assemblies in an ABC Triblock Terpolymer International-presentation Invited

Hiroshi Jinnai

2012 Japan-Taiwan Bilateral Polymer Symposium (2012 JTBPS)　2012/09/05
Exploring nano-structured materials with transmission electron tomography International-presentation Invited

Hiroshi Jinnai

The 2012 Polymer Physics Gordon Research Conference　2012/07/22
Electron tomography of micron-thick specimens for hierarchical meso-structured materials International-presentation Invited

Hiroshi Jinnai

The International Union of Pure and Applied Chemistry (IUPAC) World Polymer Congress　2012/06/24
Block copolymer self-assemblies and their orientation control studied by electron mictoromography International-presentation Invited

Hiroshi Jinnai

The International Union of Pure and Applied Chemistry (IUPAC) World Polymer Congress　2012/06/24
Exploring structured materials with tomography International-presentation Invited

Hiroshi Jinnai

International Symposium on Polymer Physics 2012　2012/06/04
Electron Tomography on Polymeric Self-Assembling Structures International-presentation Invited

Hiroshi Jinnai

The 2011 MRS Fall Meeting　2011/11/28
Polymer Nanostructures based on Block Copolymer Self-assemblies International-presentation Invited

Hiroshi Jinnai

The 12th Pacific Polymer Conference　2011/11/13
Three-dimensional morphologies of multi-component block copolymers International-presentation Invited

Hiroshi Jinnai

Bayreuth Polymer Symposium 2011　2011/09/11
Self-assemblies of Multi-component Block Copolymers Studied by Transmission Electron Tomography International-presentation Invited

Hiroshi Jinnai

Microscopy Conference 2011　2011/08/28
Three-Dimensional Structural Studies on Nano-Composite Materials International-presentation Invited

Hiroshi Jinnai

KICK-OFF SYMPOSIUM “Establishment of Carbon -Cycle-System with Natural Rubber” Project　2011/08/02
Block Copolymer Self-Assemblies Studied by Transmission Electron Tomography International-presentation Invited

Hiroshi Jinnai

94th Canadian Chemistry Conference and Exhibition (CSC2011)　2011/06/05
Transmission electron microtomograpy for better understanding of complicated block copolymer self-assemblies International-presentation Invited

Hiroshi Jinnai

The 8th Greek Polymer Society Symposium on Polymer Science and Technology honoring Professor Nikos Hadjichristidis　2010/10/24
Self-assembly in an ABC-type Triblock Terpolymer International-presentation Invited

Hiroshi Jinnai

10th International Symposium on Advanced Organic Photonics (ISAOP-10) and 1st International Symposium on Super-hybrid Materials (ISSM-1)　2010/10/02
Epitaxial Phase Transitions in Block Copolymer Nano-Structures International-presentation Invited

Hiroshi Jinnai

International Conference on Nanoscopic Colloid and Surface Science (NCSS2010); 35th Anniversary of Division of Colloid and Interface Chemistry, The Chemical Society of Japan　2010/09/19
Recent Development of Electron Tomography for Polymeric Nano- and Meso-Structures International-presentation Invited

Hiroshi Jinnai

International Microscopy Congress 17 (IMC17)　2010/09/19
Self-assembling nano-structure of a bolck copolymer studied by transmission electron tomography International-presentation Invited

Hiroshi Jinnai

American Chemical Society (ACS) Fall Meeting, Symposium Title: Nano-Scaled Phenomena in Polymeric Systems　2010/08/22
Self-assembly in an ABC-type Triblock Terpolymer International-presentation Invited

Hiroshi Jinnai

Taiwan-Japan Bilateral Symposium on Surface/Interface Science and Nanosoft Materials　2010/07/01
Self-assembly in an ABC-type Triblock Terpolymer studied by Transmission Electron Microtomography International-presentation Invited

Hiroshi Jinnai

The 3rd International Symposium on Polymer Morphology & Microscopy (PMM2010)　2010/06/13
elf-assembly in an ABC-type Triblock Terpolymer”, by Hiroshi Jinnai, 9th International Symposium of Polymer Physics (PP’2010) International-presentation Invited

Hiroshi Jinnai

International Symposium on Polymer Analysis and Characterization (ISPAC) 2010　2010/05/31
Electron tomography of soft polymeric materials International-presentation Invited

Hiroshi Jinnai

the SofTEAM workshop　2010/03/08
Electron tomography for thick polymeric samples of the order of micrometer International-presentation Invited

Hiroshi Jinnai

10-th International Symposium on Biomimetic Materials Processing (BMMP-10)　2010/01/26
3D Elemental Mapping of Soft Materials using Transmission Electron Microtomography International-presentation Invited

Hiroshi Jinnai

7th International Symposium on Atomic Level Characterizations for New Materials and Devices ’09 (ALC’09)　2009/12/06
Self-assembled polymer nano-structures International-presentation Invited

Hiroshi Jinnai

Supergreen 2009 international symposium in supercritical fluid　2009/10/15
Helical structures formed from an amorphous, achiral ABC triblock terpolymer International-presentation Invited

Hiroshi Jinnai

International Symposium on Nano Structured Polymeric Materials: Synthesis, Characterization, and Application　2009/10/07
Microphase-separated structure in a cylinder-forming block copolymer thin film studied by neutron reflectivity aided by transmission electron microtomography International-presentation Invited

Hiroshi Jinnai

Structure of Nanophase Materials (SAS) in 2009 ACA (American Crystallographic Association) Meeting　2009/07/25
Quantitative electron tomography and its application to polymer nanostructures International-presentation Invited

Hiroshi Jinnai

Focus Session: Grazing Incidence Scattering and New Imaging Techniques in 2009 APS (American Physical Society) March Meeting　2009/03/16
Electron Tomography and its Applications to Self-Assembling Polymeric Nanostructures International-presentation Invited

Hiroshi Jinnai

WPI-AIMR (World Premier International Research Center Advanced Institute for Materials Research) Annual Workshop 2009　2009/03/01
Electron Tomography on Soft Materials: A self-assembly in a block copolymer International-presentation Invited

Hiroshi Jinnai

APCET (Asia-Pacific Congress on Electron Tomography)　2009/01/31
Electron Tomography on Soft Materials: A self-assembly in a block copolymer International-presentation Invited

Hiroshi Jinnai

9-th International Symposium on Biomimetic Materials Processing (BMMP-9)　2009/01/20
Direct Three-Dimensional Visualization and Morphological Analysis of Fuel Cell Electrodes by Transmission Electron Micro-Tomography International-presentation Invited

Hiroshi Jinnai

Pacific Rim Meeting on Electrochemical and Solid-State Science　2008/10/12
Quantitative Electron Tomography on Polymer Systems and its Applications to Block Copolymers International-presentation Invited

Hiroshi Jinnai

European Microscopy Congress 2008 (EMC2008)　2008/09/01
Self-Assembling Nano-Structures in Multi-components Block Copolymers International-presentation Invited

Hiroshi Jinnai

Taiwan-Japan Bilateral Symposium on Surface/Interface Science and nanosoft Materials　2008/08/08
A Block Copolymer Superstructures Studied by Transmission Electron Microtomography International-presentation Invited

Hiroshi Jinnai

International Symposium on Polymer Physics (PP'2008)　2008/06/08
Non-Equilibrium Processes and Three-Dimensional Morphologies in Soft Matter Systems International-presentation Invited

Hiroshi Jinnai

International Symposium on Non-Equilibrium Soft Matter　2008/06/02
Self-Assembling Nano-Structures in Multi-Components Block Copolymers International-presentation Invited

Hiroshi Jinnai

International Symposium on Engineering Micro-/Nano-Materials based on Self-Assembling and Self-Organization (ISEM2008)　2008/03/03
Advanced Electron Microscopy for beam-sensitive materials Invited

Hiroshi Jinnai

International Conference on Smart Materials and Nanotechnology (SMARTMAT@2024)　2024/11/07
ナノコンポジット材料におけるナノ構造解析 Invited

陣内浩司

ナノファイバー学会第 10 回年次大会　2020/10/16

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