Details of the Researcher

PHOTO

Kazumasa Sugiyama
Section
Institute for Materials Research
Job title
Specially Appointed Research Fellow
Degree
  • 理学博士(東京大学)

Committee Memberships 14

  • Crystallographic Sciety of Japan president

    2024/04 - 2026/03

  • R032委員会 産業イノベーションのための結晶作製委員会 代表庶務幹事

    2021/04 - 2026/03

  • 日本鉱物科学会 欧文誌編集委員

    2006/04 - 2022/12

  • 日本学術振興会 結晶成長の科学と技術 第161委員会 代表幹事

    2013/04 - 2021/03

  • 日本結晶学会 日本結晶学会 行事委員長

    2016/04 - 2018/03

  • 日本結晶学会 日本結晶学会誌 編集幹事

    2016/04 - 2018/03

  • 日本鉱物科学会 評議員

    2014/04 - 2016/08

  • 日本結晶学会 日本結晶学会誌 編集委員長

    2014/04 - 2016/03

  • 日本結晶学会 日本結晶学会誌 編集委員長

    2014/04 - 2016/03

  • 日本結晶学会 日本結晶学会誌 編集副委員長

    2008/04 - 2014/03

  • 日本結晶学会 日本結晶学会誌 編集副委員長

    2008/04 - 2014/03

  • 日本学術振興会 結晶成長の科学と技術 第161委員会 運営委員

    2007/04 - 2012/03

  • 日本学術振興会 結晶成長の科学と技術 第161委員会 運営委員

    2007/04 - 2012/03

  • ゼオライト学会 編集委員

    2006/04 - 2009/12

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Research Interests 6

  • synchrotoron radiation

  • material science

  • mineral

  • crystal

  • structure

  • X-ray

Research Areas 1

  • Nanotechnology/Materials / Functional solid-state chemistry /

Awards 17

  1. ポスター奨励賞

    2023/10 日本金属学会東北支部 蓄電池正極材開発に向けた3×4のMnO2トンネル型構造の結晶化学;woodruffite中の Znの挙動

  2. ポスター奨励賞

    2023/10 日本金属学会東北支部 オリビン型Li(Fe,Mn)PO4およびその脱リチウム体(Fe,Mn)PO4の結晶構造

  3. ポスター奨励賞

    2023/10 日本金属学会東北支部 卓上型試験機を用いた薄帯状非晶質合金の引張試験

  4. 日本結晶学会 ポスター賞

    2023/10 日本結晶学会 希土類イオンをドープしたβ-Ca3(PO4)2蛍光体の発光特性と希土類元素の分布

  5. BEST POSTER PRIZE

    2023/07 18th European Conference on Solid State Chemistry High-Pressure Synthesis of Alkaline Metal Niobates with Tetragonal Tungsten Bronze-type Structure

  6. ポスター奨励賞

    2022/10 日本金属学会東北支部 Maghemiteの低温酸化プロセス

  7. ポスター奨励賞

    2022/10 日本金属学会東北支部 X線異常分散項の物質構造解析への応用 Cyrilovite (NaFe3(PO4)・2(H2O)) のキラリティ

  8. 日本金属学会 2022年秋期大会優秀ポスター賞

    2022/09 日本金属学会 X線異常散乱法を用いたHf-Ni系非晶質合金の構造評価

  9. 日本金属学会 2011年秋期大会優秀ポスター賞

    2011/11 日本金属学会 AXS-RMC 法による ZrCu 系非晶質合金の最近接-中距離領域構造解析

  10. 日本鉱物科学会賞

    2011/09/10 日本鉱物科学会 複雑構造を有する物質群の構造解析法の開発研究

  11. 日本結晶学会学術賞

    2009/12/05 日本結晶学会 周期構造を持たないランダム系物質の構造解析

  12. 日本鉄鋼協会山岡賞

    2007/03/28 日本鉄鋼協会

  13. 澤村論文賞

    2006/03/21 日本鉄鋼協会

  14. 資源素材学会論文賞

    1998/04/02 資源素材学会

  15. 鉱物学会奨励賞

    1993/06/05 日本鉱物学会

  16. 本多記念研究奨励賞

    1991/05/15 財団法人 本多記念会

  17. 金属研究奨励賞

    1990/07/02 財団法人 金属研究助成会

Show all ︎Show 5

Papers 311

  1. Structural investigation based on the 4D-STEM observation for superstructures of Rh octahedra in Cu3Au/anti-perovskite type ScRh3B0.75 compound

    Kunio Yubuta, Masateru Shibata, Haruka Murayama, Akira Yasuhara, Akiko Nomura, Kazumasa Sugiyama, Toetsu Shishido

    JOURNAL OF ALLOYS AND COMPOUNDS 1021 2025/04/05

    DOI: 10.1016/j.jallcom.2025.179694  

    ISSN: 0925-8388

    eISSN: 1873-4669

  2. Bonding nature of Cu2+ in distorted tetragonal pyramidal coordination in clinoclase and callaghanite Peer-reviewed

    Masaaki MISAWA, Akira YOSHIASA, Fuyuki SHIMOJO, Makoto TOKUDA, Satoko ISHIMARU, Ginga KITAHARA, Kazumasa SUGIYAMA

    Journal of Mineralogical and Petrological Sciences 120 (1) n/a-n/a 2025

    Publisher: Japan Association of Mineralogical Sciences

    DOI: 10.2465/jmps.240925  

    ISSN: 1345-6296

    eISSN: 1349-3825

  3. Fine structural analysis of red beryl from Utah, USA using anomalous X-ray scattering Peer-reviewed

    Y. Kodama, T. Kawamata, S. Imashuku, K. Sugiyama, T. Mikouchi

    Journal of Crystal Growth 650 127943-127943 2025/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2024.127943  

    ISSN: 0022-0248

  4. Distribution of Eu and Er in Ca9RE(PO4)7 phosphors analyzed by anomalous X-ray scattering Peer-reviewed

    K. Hiraoka, R. Yamane, M. Tokuda, K. Sugiyama

    Journal of Crystal Growth 650 127955-127955 2025/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2024.127955  

    ISSN: 0022-0248

  5. Growth of copper single crystal using cone die Czochralski method Peer-reviewed

    Kazuya Takahashi, Tsuyoshi Kumagai, Marilou Cadatal-Raduban, Nobuhiko Sarukura, Toru Kawamata, Kazumasa Sugiyama, Tsuguo Fukuda

    Journal of Crystal Growth 649 127957-127957 2025/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2024.127957  

    ISSN: 0022-0248

  6. Ultraviolet optical properties of CaSrF2 crystal grown by the cone die Czochralski method Peer-reviewed

    Yugo Akabe, Kotaro Enomoto, Keito Shinohara, Marilou Raduban, Toshihiko Shimizu, Nobuhiko Sarukura, Rui Okumura, Ryosuke Kodama, Kazuya Takahashi, Toru Kawamata, Kazumasa Sugiyama, Tsuguo Fukuda

    Journal of Crystal Growth 649 127949-127949 2025/01

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2024.127949  

    ISSN: 0022-0248

  7. Phase Equilibria of the Iron-rich Corner of the CaO–Fe2O3–Al2O3 System at 1240°C in Air Peer-reviewed

    Hirokazu Sato, Maksym Shevchenko, Kazumasa Sugiyama, Siyu Cheng, Jiang Chen, Peter Charles Hayes, Evgueni Jak, Miyuki Hayashi

    ISIJ International 64 (15) 2098-2106 2024/12/30

    Publisher: Iron and Steel Institute of Japan

    DOI: 10.2355/isijinternational.isijint-2024-260  

    ISSN: 0915-1559

    eISSN: 1347-5460

  8. Fine structural analysis of calcium–niobium–gallium garnet (CNGG) by single-crystal anomalous X-ray scattering Peer-reviewed

    Ryo Yamane, Hiroaki Takeda, Takahiro Kuribayashi, Kazumasa Sugiyama, Tsuguo Fukuda

    Journal of Crystal Growth 127947-127947 2024/10

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2024.127947  

    ISSN: 0022-0248

  9. Fcc-Based Superstructure in CrCoNi System Induced by Annealing of Amorphous Cr-Co-Ni-Si-B-P Alloy Peer-reviewed

    T. Kawamata, T. Ban, M. Shibata, H. Murayama, A. Yasuhara, K. Yubuta, K. Sugiyama

    Materials Transactions 65 (9) 1034-1040 2024/09/01

    DOI: 10.2320/matertrans.MT-MA2024008  

    ISSN: 1345-9678

  10. Tailored Sugar-Mediated Porous Particle Structures for Improved Dispersion of Drug Nanoparticles in Spray-Freeze-Drying Peer-reviewed

    Kumi Semba, Kazunori Kadota, Tero Kämäräinen, Yuzuki Nakayama, Yuta Hatanaka, Hiromasa Uchiyama, Hiroshi Arima-Osonoi, Kazumasa Sugiyama, Yuichi Tozuka

    Langmuir 40 (28) 14440-14454 2024/07/16

    DOI: 10.1021/acs.langmuir.4c01165  

    ISSN: 0743-7463

    eISSN: 1520-5827

  11. Millimeter-scale growth of YCrB4 single crystals and observation of the metallic surface state Peer-reviewed

    Xiaoni Zhang, Yuki Tsujikawa, Kazuki Yamaguchi, Masashige Miyamoto, Masafumi Horio, Kunio Yubuta, Hiroshi Ando, Mei Yuan, Kenichi Ozawa, Kazumasa Sugiyama, Takahiro Kondo, Iwao Matsuda

    Physical Review Materials 8 (5) , 054001-, 054001 2024/05

    DOI: 10.1103/PhysRevMaterials.8.054001  

    eISSN: 2475-9953

  12. Short-Range Ordering Structure Found in Pd82Ge18; Amorphous Alloy Determined from Anomalous X-ray Scattering (AXS) Data by Applying Reverse Monte-Carlo (RMC) Simulation Method Peer-reviewed

    T. Kawamata, R. Hayashi, K. Sugimoto, K. Sugiyama

    MATERIALS TRANSACTIONS 65 (4) 362-367 2024/04/01

    Publisher: Japan Institute of Metals

    DOI: 10.2320/matertrans.mt-m2023189  

    ISSN: 1345-9678

    eISSN: 1347-5320

  13. Crystal structure and properties of perovskite-type rubidium niobate, a high-pressure phase of RbNbO<inf>3</inf> International-journal Peer-reviewed

    Ayako Yamamoto, Kimitoshi Murase, Takeru Sato, Kazumasa Sugiyama, Toru Kawamata, Yoshiyuki Inaguma, Jun Ichi Yamaura, Kazuki Shitara, Rie Yokoi, Hiroki Moriwake

    Dalton Transactions 53 (16) 7044-7052 2024/04/01

    DOI: 10.1039/d4dt00190g  

    ISSN: 1477-9226

    eISSN: 1477-9234

  14. Crystal growth and characterization of large Ca<inf>0.582</inf>Sr<inf>0.418</inf>F<inf>2</inf> single crystal by Czochralski method using cone die Peer-reviewed

    Kazuya Takahashi, Marilou Cadatal-Raduban, Nobuhiko Sarukura, Toru Kawamata, Kazumasa Sugiyama, Tsuguo Fukuda

    Journal of Crystal Growth 628 127541-127541 2024/02/15

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2023.127541  

    ISSN: 0022-0248

  15. Chemical composition, crystal structure and spontaneous polarization of swedenborgite Peer-reviewed

    Keiichiro Murai, Akira Yoshiasa, Satoko Ishimaru, Mayu Yoshihara, Ginga Kitahara, Makoto Tokuda, Hidetomo Hongu, Koichi Momma, Kazumasa Sugiyama

    Journal of Mineralogical and Petrological Sciences 119 (1) 119:017-119:017 2024

    Publisher: Japan Association of Mineralogical Sciences

    DOI: 10.2465/JMPS.240209  

    ISSN: 1345-6296

    eISSN: 1349-3825

  16. Li intercalation in 2D iron phosphate synthesized from the partial dehydration and deprotonation of vivianite. International-journal Peer-reviewed

    Ryo Yamane, Hongyi Li, Tetsu Ichitsubo, Kazumasa Sugiyama

    Physical chemistry chemical physics : PCCP 25 (45) 31346-31351 2023/11/22

    DOI: 10.1039/d3cp02463f  

    ISSN: 1463-9076

  17. Redetermination of the crystal structure of yttrium chromium tetra-boride, YCrB4, from single-crystal X-ray diffraction data. International-journal Peer-reviewed

    Makoto Tokuda, Kunio Yubuta, Toetsu Shishido, Kazumasa Sugiyama

    Acta crystallographica. Section E, Crystallographic communications 79 (Pt 11) 1072-1075 2023/11/01

    Publisher: International Union of Crystallography (IUCr)

    DOI: 10.1107/S2056989023008952  

    eISSN: 2056-9890

  18. Effect of strontium substitution on growth and piezoelectric properties of calcium magnesium silicate Ca2MgSi2O7 single crystals Peer-reviewed

    Hiroaki Takeda, Takumi Uehara, Genki Hirano, Shohei Kodama, Ikuo Yanase, Kazumasa Sugiyama

    Japanese Journal of Applied Physics 62 (SM) SM1027-SM1027 2023/09/11

    Publisher: IOP Publishing

    DOI: 10.35848/1347-4065/acf2a5  

    ISSN: 0021-4922

    eISSN: 1347-4065

  19. Origin of spin glass magnetic behavior and phase stability of flux-grown RE(Al, Cr, Fe)B<inf>4</inf> (RE = Ho and Er) single crystals Peer-reviewed

    Kunio Yubuta, Akira Yasuhara, Akiko Nomura, Toetsu Shishido, Kazumasa Sugiyama, Kaoru Kouzu, Shigeru Okada, Takao Mori

    Solid State Sciences 142 107243-107243 2023/08

    Publisher: Elsevier BV

    DOI: 10.1016/j.solidstatesciences.2023.107243  

    ISSN: 1293-2558

  20. Structure of hexagonal ζ´-AlMnCo Peer-reviewed

    Yuki Makino, Toru Kawamata, Kazumasa Sugiyama

    Journal of Physics: Conference Series 2461 (1) 012010-012010 2023/03/01

    Publisher: IOP Publishing

    DOI: 10.1088/1742-6596/2461/1/012010  

    ISSN: 1742-6588

    eISSN: 1742-6596

  21. Syntheses and structures of ammonium transition-metal dialuminium tris(phosphate) dihydrates (NH4)MAl4(PO4)3·2H2O (M = Mn and Ni) Peer-reviewed

    Makoto Tokuda, Keita Tanaka, Kazumasa Sugiyama

    Acta Crystallographica Section E Crystallographic Communications 79 (2) 116-119 2023/02/01

    Publisher: International Union of Crystallography (IUCr)

    DOI: 10.1107/s2056989023000555  

    eISSN: 2056-9890

  22. Short- and medium-range ordering in Al3Mn amorphous alloy prepared by magnetron sputtering Peer-reviewed

    T Kawamata, K Sugiyama

    Journal of Physics: Conference Series 2461 (1) 012017-012017 2023/01

    Publisher: IOP Publishing

    DOI: 10.1088/1742-6596/2461/1/012017  

    ISSN: 1742-6588

    eISSN: 1742-6596

  23. Determination of orientational ordering of hydroxy groups in kulanite between 120-353 K using single-crystal X-ray diffraction Peer-reviewed

    Ryo YAMANE, Makoto TOKUDA, Kazumasa SUGIYAMA

    Journal of Mineralogical and Petrological Sciences 118 (1) 118:003-118:003 2023

    Publisher: Japan Association of Mineralogical Sciences

    DOI: 10.2465/jmps.220701  

    ISSN: 1345-6296

    eISSN: 1349-3825

  24. Crystal structures of rhodium-containing erlichmanite-laurite solid solutions (Os1-x-yRu x Rh y S2: x = 0.09–0.60, y = 0.07–0.10) with unique compositional dependence Peer-reviewed

    Ginga Kitahara, Akira Yoshiasa, Satoko Ishimaru, Kunihisa Terai, Makoto Tokuda, Daisuke Nishio–Hamane, Takahiro Tanaka, Kazumasa Sugiyama

    Mineralogical Magazine 87 (3) 1-51 2022/12/22

    Publisher: Mineralogical Society

    DOI: 10.1180/mgm.2022.139  

    ISSN: 0026-461X

    eISSN: 1471-8022

  25. Single-crystal structure refinements and Debye temperatures of Ir<inf>2</inf>S<inf>3</inf> kashinite and Rh<inf>2</inf>S<inf>3</inf> bowieite Peer-reviewed

    Akira Yoshiasa, Ginga Kitahara, Makoto Tokuda, Satoko Ishimaru, Shin Ichiro Ono, Kunihisa Terai, Akihiko Nakatsuka, Kazumasa Sugiyama

    Acta crystallographica. Section C, Structural chemistry 78 (11) 606-611 2022/11/01

    DOI: 10.1107/S2053229622009603  

    ISSN: 2053-2296

    eISSN: 2053-2296

  26. Atomic distribution and local structure in ice VII from in situ neutron diffraction International-journal Peer-reviewed

    Keishiro Yamashita, Takanori Hattori, Tetsuo Irifune, Toru Shinmei, Kazuki Komatsu, Shinichi Machida, Maria T. Fernandez-Dıaz, Jun Abe, Kazumasa Sugiyama, Toru Kawamata, Hiroyuki Kagi, Oscar Fabelo, Stefan Klotz

    Proceedings of the National Academy of Sciences of the United States of America 119 (40) e2208717119 2022/10/04

    DOI: 10.1073/pnas.2208717119  

    ISSN: 0027-8424

    eISSN: 1091-6490

  27. Formation and evolution of carbonaceous asteroid Ryugu: Direct evidence from returned samples Peer-reviewed

    T. Nakamura, M. Matsumoto, K. Amano, Y. Enokido, M. E. Zolensky, T. Mikouchi, H. Genda, S. Tanaka, M. Y. Zolotov, K. Kurosawa, S. Wakita, R. Hyodo, H. Nagano, D. Nakashima, Y. Takahashi, Y. Fujioka, M. Kikuiri, E. Kagawa, M. Matsuoka, A. J. Brearley, A. Tsuchiyama, M. Uesugi, J. Matsuno, Y. Kimura, M. Sato, R. E. Milliken, E. Tatsumi, S. Sugita, T. Hiroi, K. Kitazato, D. Brownlee, D. J. Joswiak, M. Takahashi, K. Ninomiya, T. Takahashi, T. Osawa, K. Terada, F. E. Brenker, B. J. Tkalcec, L. Vincze, R. Brunetto, A. Aléon-Toppani, Q. H.S. Chan, M. Roskosz, J. C. Viennet, P. Beck, E. E. Alp, T. Michikami, Y. Nagaashi, T. Tsuji, Y. Ino, J. Martinez, J. Han, A. Dolocan, R. J. Bodnar, M. Tanaka, H. Yoshida, K. Sugiyama, A. J. King, K. Fukushi, H. Suga, S. Yamashita, T. Kawai, K. Inoue, A. Nakato, T. Noguchi, F. Vilas, A. R. Hendrix, C. Jaramillo-Correa, D. L. Domingue, G. Dominguez, Z. Gainsforth, C. Engrand, J. Duprat, S. S. Russell, E. Bonato, C. Ma, T. Kawamoto, T. Wada, S. Watanabe, R. Endo, S. Enju, L. Riu, S. Rubino, P. Tack, S. Takeshita, Y. Takeichi, A. Takeuchi, A. Takigawa, D. Takir, T. Tanigaki, A. Taniguchi, K. Tsukamoto, T. Yagi, S. Yamada, K. Yamamoto, Y. Yamashita, M. Yasutake, K. Uesugi, I. Umegaki

    Science 379 (6634) 2022/09/22

    DOI: 10.1126/science.abn8671  

    ISSN: 0036-8075

    eISSN: 1095-9203

  28. High-Pressure Synthesis of High-Entropy Metal Disulfides with Pyrite-Type Structure Peer-reviewed

    Anna Z. Laila, Marco Fronzi, Shinya Kumegai, Kazumasa Sugiyama, Ryota Furui, Ayako Yamamoto

    Journal of the Physical Society of Japan 91 (8) 084802-084802 2022/08/15

    Publisher: Physical Society of Japan

    DOI: 10.7566/jpsj.91.084802  

    ISSN: 0031-9015

    eISSN: 1347-4073

  29. Crystal structure, XANES and charge distribution investigation of krennerite and sylvanite: analysis of Au-Te and Te-Te bonds in Au1-xAgxTe2 group minerals. International-journal Peer-reviewed

    Ginga Kitahara, Akira Yoshiasa, Makoto Tokuda, Massimo Nespolo, Hidetomo Hongu, Koichi Momma, Ritsuro Miyawaki, Kazumasa Sugiyama

    Acta crystallographica Section B, Structural science, crystal engineering and materials 78 (Pt 2) 117-132 2022/04/01

    DOI: 10.1107/S2052520622000804  

    ISSN: 2052-5192

    eISSN: 2052-5206

  30. Magnetic Properties and Substructure of Iron–Gallium Alloy Single Crystals Processed from Ingot to Wafers Peer-reviewed

    Masaki Chiba, Takenori Tanno, Maho Abe, Shuichiro Hashi, Kazushi Ishiyama, Toru Kawamata, Rie Y. Umestu, Kazumasa Sugiyama, Shigeo Sato, Yosuke Mochizuki, Koji Yatsushiro, Tsuyoshi Kumagai, Tsuguo Fukuda, Shun-Ichiro Tanaka, Shigeru Suzuki

    MATERIALS TRANSACTIONS 63 (4) 502-507 2022

    Publisher: Japan Institute of Metals

    DOI: 10.2320/matertrans.mt-m2021217  

    ISSN: 1345-9678

    eISSN: 1347-5320

  31. Improvement of nano-polycrystalline diamond anvil cells with Zr-based bulk metallic glass cylinder for higher pressures: application to Laue-TOF diffractometer Peer-reviewed

    Keishiro Yamashita, Kazuki Komatsu, Takashi Ohhara, Koji Munakata, Tetsuo Irifune, Toru Shinmei, Kazumasa Sugiyama, Toru Kawamata, Hiroyuki Kagi

    HIGH PRESSURE RESEARCH 42 (1) 121-135 2022/01

    DOI: 10.1080/08957959.2022.2045982  

    ISSN: 0895-7959

    eISSN: 1477-2299

  32. Redetermination of the crystal structures of rare-earth trirhodium diboride RERh3B2 (RE = Pr, Nd and Sm) from single-crystal X-ray data. International-journal Peer-reviewed

    Makoto Tokuda, Kunio Yubuta, Toetsu Shishido, Kazumasa Sugiyama

    Acta crystallographica. Section E, Crystallographic communications 78 (Pt 1) 76-79 2022/01/01

    DOI: 10.1107/S2056989021013311  

    ISSN: 2056-9890

    eISSN: 2056-9890

  33. Incorporation mechanism of Fe and Al into bridgmanite in a subducting mid-ocean ridge basalt and its crystal chemistry. International-journal Peer-reviewed

    Akihiko Nakatsuka, Hiroshi Fukui, Seiji Kamada, Naohisa Hirao, Makio Ohkawa, Kazumasa Sugiyama, Takashi Yoshino

    Scientific reports 11 (1) 22839-22839 2021/11/24

    DOI: 10.1038/s41598-021-00403-6  

    eISSN: 2045-2322

  34. Growth of nickel single crystals with a diameter of 8 in. using the Czochralski method Peer-reviewed

    T. Kawamata, K. Takahashi, T. Kumagai, K. Sugiyama, T. Fukuda

    Journal of Crystal Growth 573 126271-126271 2021/11

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2021.126271  

    ISSN: 0022-0248

  35. X-ray diffraction analysis and X-ray topography of high-quality ScAlMgO4 substrates Peer-reviewed

    Katsuhiko Inaba, Kazumasa Sugiyama, Takashi Fujii, Tsuguo Fukuda

    Journal of Crystal Growth 574 126322-126322 2021/11

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2021.126322  

    ISSN: 0022-0248

  36. Crystal synthesis and Debye temperature determination of PdSb2: Usefulness of single crystal precise structure analysis Peer-reviewed

    Akira Yoshiasa, Makoto Tokuda, Ginga Kitahara, Kohei Unoki, Hiroshi Isobe, Akihiko Nakatsuka, Kazumasa Sugiyama

    Journal of Crystal Growth 574 126327-126327 2021/11

    DOI: 10.1016/j.jcrysgro.2021.126327  

    ISSN: 0022-0248

    eISSN: 1873-5002

  37. Growth of bulk single crystal ScAlMgO4 boules and GaN films on ScAlMgO4 substrates for GaN-based optical devices, high-power and high-frequency transistors Peer-reviewed

    Tsuguo Fukuda, Yuji Shiraishi, Toki Nanto, Takashi Fujii, Kazumasa Sugiyama, Rayko Simura, Hiroyuki Iechi, Kazuyuki Tadatomo

    Journal of Crystal Growth 574 126286-126286 2021/11

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2021.126286  

    ISSN: 0022-0248

  38. Distribution of Ce in orthophosphate Sr3(PO4)2 Peer-reviewed

    Makoto Tokuda, Yui Kodama, Shintaro Niiyama, Kozo Shinoda, Kazumasa Sugiyama

    Journal of Crystal Growth 571 126267-126267 2021/10

    DOI: 10.1016/j.jcrysgro.2021.126267  

    ISSN: 0022-0248

    eISSN: 1873-5002

  39. Generating Mechanism of Catalytic Effect for Hydrogen Absorption/Desorption Reactions in NaAlH4–TiCl3 Peer-reviewed

    Kazutaka Ikeda, Fumika Fujisaki, Toshiya Otomo, Hidetoshi Ohshita, Takashi Honda, Toru Kawamata, Hiroshi Arima, Kazumasa Sugiyama, Hitoshi Abe, Hyunjeong Kim, Kouji Sakaki, Yumiko Nakamura, Akihiko Machida, Toyoto Sato, Shigeyuki Takagi, Shin-ichi Orimo

    Applied Sciences 11 (18) 8349-8349 2021/09/09

    Publisher: MDPI AG

    DOI: 10.3390/app11188349  

    eISSN: 2076-3417

  40. Characterization and performance of large-sized Fe–Ga alloy single crystals grown using the Czochralski method Peer-reviewed

    Shigeru Suzuki, Osamu Taguchi, Toru Kawamata, Kazumasa Sugiyama, Jin Ono, Tsuyoshi Kumagai, Tsuguo Fukuda

    Journal of Crystal Growth 570 126227-126227 2021/09

    DOI: 10.1016/j.jcrysgro.2021.126227  

    ISSN: 0022-0248

    eISSN: 1873-5002

  41. In-house-built single-crystal anomalous X-ray diffraction measurement system using white X-rays and an energy dispersive detector Peer-reviewed

    Rayko Simura, Hisanori Yamane, Terutoshi Sakakura, Kazumasa Sugiyama

    Journal of the Ceramic Society of Japan 129 (9) 594-600 2021/09/01

    DOI: 10.2109/jcersj2.21046  

    ISSN: 1882-0743

    eISSN: 1348-6535

  42. Local structure investigations of Sn and Mn doped in β-Ga2O3 by X-ray absorption spectroscopy Peer-reviewed

    H. Arima-Osonoi, K. Yamazaki, R. Simura, T. Sugawara, K. Yubuta, K. Sugiyama, A. Yoshiasa

    Journal of Crystal Growth 570 126223-126223 2021/09

    Publisher: Elsevier BV

    DOI: 10.1016/j.jcrysgro.2021.126223  

    ISSN: 0022-0248

  43. Crystal structure refinements of stoichiometric Ni<inf>3Se</inf>2 and NiSe International-journal Peer-reviewed

    Kohei Unoki, Akira Yoshiasa, Ginga Kitahara, Tadao Nishiayama, Makoto Tokuda, Kazumasa Sugiyama, Akihiko Nakatsuka

    Acta Crystallographica Section C: Structural Chemistry 77 (Pt 4) 169-175 2021/04

    DOI: 10.1107/S2053229621002187  

    ISSN: 2053-2296

    eISSN: 2053-2296

  44. Crystal structure refinement and crystal chemistry of parasymplesite and vivianite Peer-reviewed

    Hidetomo Hongu, Akira Yoshiasa, Ginga Kitahara, Yumiko Miyano, Karin Han, Koichi Momma, Ritsuro Miyawaki, Makoto Tokuda, Kazumasa Sugiyama

    Journal of Mineralogical and Petrological Sciences 116 (4) 183-192 2021

    DOI: 10.2465/JMPS.200904  

    ISSN: 1345-6296

    eISSN: 1349-3825

  45. Structure refinement of prehnite from Passaic County, New Jersey, USA Peer-reviewed

    Kazumasa Sugiyama, Toru Kawamata, Takahiro Kuribayashi

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 116 (5) 272-276 2021

    DOI: 10.2465/jmps.210318  

    ISSN: 1345-6296

    eISSN: 1349-3825

  46. XANES analyses on minor elements and X–ray single crystal structure analyses of Ce– and Nb–perovskite Peer-reviewed

    Ginga KITAHARA, Akira YOSHIASA, Makoto TOKUDA, Tsubasa TOBASE, Kazumasa SUGIYAMA

    Journal of Mineralogical and Petrological Sciences 116 (1) 45-55 2021

    Publisher: Japan Association of Mineralogical Sciences

    DOI: 10.2465/jmps.200424  

    ISSN: 1345-6296

    eISSN: 1349-3825

  47. Spinifex-like textured metaperidotites from the higo metamorphic rocks, japan, a possible high-pressure dehydration product of antigorite serpentinite Peer-reviewed

    Tadao Nishiyama, Hibiki Eguchi, Dai Shiosaki, Akira Yoshiasa, Nobutatsu Mochizuki, Yasushi Mori, Kazumasa Sugiyama, Hiroshi Arima, Kunio Yubuta

    Island Arc 30 (1) 1-20 2021

    DOI: 10.1111/iar.12382  

    ISSN: 1038-4871

    eISSN: 1440-1738

  48. Fine structure of Zr<inf>80</inf>Pt<inf>20</inf> amorphous alloy determined from anomalous X-ray scattering (AXS) data by applying reverse monte-carlo (RMC) simulation method Peer-reviewed

    T. Kawamata, T. Muto, K. Sugiyama

    Materials Transactions 62 (1) 20-26 2021/01/01

    DOI: 10.2320/matertrans.MT-M2020246  

    ISSN: 1345-9678

  49. Surface characterization of functional iron–gallium alloys annealed under different conditions Peer-reviewed

    Toru Kawamata, Kozo Shinoda, Kazumasa Sugiyama, Shigeru Suzuki

    Surface and Interface Analysis 52 (12) 1098-1103 2020/12

    DOI: 10.1002/sia.6841  

    ISSN: 0142-2421

    eISSN: 1096-9918

  50. Single-stranded β-1,3–1,6-glucan as a carrier for improved dissolution and membrane permeation of poorly water-soluble compounds International-journal Peer-reviewed

    Hiromasa Uchiyama, Mayu Dowaki, Kazunori Kadota, Hiroshi Arima, Kazumasa Sugiyama, Yuichi Tozuka

    Carbohydrate Polymers 247 116698-116698 2020/11

    DOI: 10.1016/j.carbpol.2020.116698  

    ISSN: 0144-8617

    eISSN: 1879-1344

  51. Control of thermophysical properties of langasite-type La<inf>3</inf>Ta<inf>0.5</inf>Ga<inf>5.5</inf>O<inf>14</inf> crystals for pressure sensors Peer-reviewed

    Haruki Usui, Makoto Tokuda, Kazumasa Sugiyama, Takuya Hoshina, Takaaki Tsurumi, Kheirreddine Lebbou, Ikuo Yanase, Hiroaki Takeda

    Crystals 10 (10) 1-9 2020/10

    DOI: 10.3390/cryst10100936  

    ISSN: 2073-4352

    eISSN: 2073-4352

  52. Structure and electrical properties of Ba3TaGa3Si2O14 single crystals grown by Czochralski method Peer-reviewed

    Haruki Usui, Hiraku Kusakabe, Makoto Tokuda, Kazumasa Sugiyama, Takuya Hoshina, Takaaki Tsurumi, Hiroaki Takeda

    Journal of the Ceramic Society of Japan 128 (8) 441-446 2020/08/01

    DOI: 10.2109/jcersj2.20016  

    ISSN: 1882-0743

    eISSN: 1348-6535

  53. The location of Mn and Fe in axinite-(Fe) from Nandan, China determined by anomalous X-ray scattering (AXS) Peer-reviewed

    Daitaro Kitahara, Hiroshi Arima, Toru Kawamata, Kazumasa Sugiyama, Takashi Mikouchi

    Journal of Mineralogical and Petrological Sciences 115 (3) 227-235 2020/06/01

    Publisher: Japan Association of Mineralogical Sciences

    DOI: 10.2465/jmps.190110  

    ISSN: 1345-6296

    eISSN: 1349-3825

  54. Nanostructure with diffuse streaks in ScRh<inf>3</inf>B<inf>0.6</inf> compound studied by electron microscopy Peer-reviewed

    K. Yubuta, A. Nomura, K. Kouzu, T. Yamasaki, S. Okada, T. Mori, A. Yoshikawa, K. Sugiyama, T. Shishido

    Solid State Sciences 102 106177-106177 2020/04

    Publisher: Elsevier BV

    DOI: 10.1016/j.solidstatesciences.2020.106177  

    ISSN: 1293-2558

  55. The synthesis of metavivianite and the oxidation sequence of vivianite Peer-reviewed

    Kohei Chiba, Misaki Takahashi, Eriko Ohshima, Toru Kawamata, Kazumasa Sugiyama

    Journal of Mineralogical and Petrological Sciences 115 (6) 485-489 2020

    DOI: 10.2465/JMPS.200417  

    ISSN: 1345-6296

    eISSN: 1349-3825

  56. The local structure around Ge atoms in Ge-doped magnetite thin films Peer-reviewed

    Kozo Shinoda, Seishi Abe, Kazumasa Sugiyama, Yoshio Waseda

    High Temperature Materials and Processes 39 (1) 645-662 2020/01/01

    DOI: 10.1515/htmp-2020-0099  

    ISSN: 0334-6455

    eISSN: 2191-0324

  57. A nano-polycrystalline diamond anvil cell with bulk metallic glass cylinder for single-crystal neutron diffraction Peer-reviewed

    Keishiro Yamashita, Kazuki Komatsu, Stefan Klotz, Maria T. Fernandez-Diaz, Oscar Fabelo, Tetsuo Irifune, Kazumasa Sugiyama, Tooru Kawamata, Hiroyuki Kagi

    HIGH PRESSURE RESEARCH 40 (1) 88-95 2020/01

    DOI: 10.1080/08957959.2019.1700980  

    ISSN: 0895-7959

    eISSN: 1477-2299

  58. Natural arsenic with a unique order structure: potential for new quantum materials International-journal Peer-reviewed

    Akira Yoshiasa, Makoto Tokuda, Masaaki Misawa, Fuyuki Shimojo, Koichi Momma, Ritsuro Miyawaki, Satoshi Matsubara, Akihiko Nakatsuka, Kazumasa Sugiyama

    Scientific Reports 9 (1) 6275-6275 2019/12/01

    DOI: 10.1038/s41598-019-42561-8  

    ISSN: 2045-2322

    eISSN: 2045-2322

  59. XAFS study of Sb and As in Cretaceous-Tertiary boundary sediments: an index of soiling of the global environment with dust and ashes from impact ejecta falls Peer-reviewed

    Hidetomo Hongu, Akira Yoshiasa, Tsubasa Tobase, Maki Okube, Kazumasa Sugiyama, Tsutomu Sato

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 114 (5) 224-230 2019/10

    DOI: 10.2465/jmps.180927  

    ISSN: 1345-6296

    eISSN: 1349-3825

  60. Crystal structure, large distortion of the Zn tetrahedron, and statistical displacement of water molecules in skorpionite Peer-reviewed

    Tsubasa Tobase, Akira Yoshiasa, Satoshi Jinnouchi, Ginga Kitahara, Hidetomo Hongu, Makoto Tokuda, Maki Okube, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 114 (4) 178-188 2019/09

    DOI: 10.2465/jmps.180801  

    ISSN: 1345-6296

    eISSN: 1349-3825

  61. Titanium local coordination environments in Cretaceous-Paleogene and Devonian-Carboniferous boundary sediments as a possible marker for large meteorite impact Peer-reviewed

    Tsubasa Tobase, Akira Yoshiasa, Toshifumi Komatsu, Takumi Maekawa, Hidetomo Hongu, Maki Okube, Hiroshi Arima, Kazumasa Sugiyama

    PHYSICS AND CHEMISTRY OF MINERALS 46 (7) 675-685 2019/07

    DOI: 10.1007/s00269-019-01030-4  

    ISSN: 0342-1791

    eISSN: 1432-2021

  62. Improved water dispersibility and photostability in folic acid nanoparticles with transglycosylated naringin using combined processes of wet-milling and freeze-drying International-journal Peer-reviewed

    Kumi Semba, Kazunori Kadota, Hiroshi Arima, Akihito Nakanishi, Mahamadou Tandia, Hiromasa Uchiyama, Kazumasa Sugiyama, Yuichi Tozuka

    FOOD RESEARCH INTERNATIONAL 121 108-116 2019/07

    DOI: 10.1016/j.foodres.2019.03.034  

    ISSN: 0963-9969

    eISSN: 1873-7145

  63. Crystal structure refinement of MnTe2, MnSe2, and MnS2: cation-anion and anion-anion bonding distances in pyrite-type structures Peer-reviewed

    Makoto Tokuda, Akira Yoshiasa, Tsutomu Mashimo, Hiroshi Arima, Hidetomo Hongu, Tsubasa Tobase, Akihiko Nakatsuka, Kazumasa Sugiyama

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS 234 (6) 371-377 2019/06

    DOI: 10.1515/zkri-2018-2134  

    ISSN: 2194-4946

    eISSN: 2196-7105

  64. Crystal structure and XANES investigation of petzite, Ag3AuTe2. International-journal Peer-reviewed

    Hidetomo Hongu, Akira Yoshiasa, Massimo Nespolo, Tsubasa Tobase, Makoto Tokuda, Kazumasa Sugiyama

    Acta crystallographica Section B, Structural science, crystal engineering and materials 75 (Pt 2) 273-278 2019/04/01

    DOI: 10.1107/S2052520619002166  

    ISSN: 2052-5192

    eISSN: 2052-5206

  65. Determination of the locations of Mn and Fe in Mn-bearing andalusite by anomalous X-ray scattering and X-ray absorption fine structure analyses Peer-reviewed

    Hiroshi Arima, Yuki Tani, Kazumasa Sugiyama, Akira Yoshiasa

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 113 (6) 273-279 2018/12

    DOI: 10.2465/jmps.180520  

    ISSN: 1345-6296

    eISSN: 1349-3825

  66. Site occupancy of Fe2+, Fe3+ and Ti4+ in titanomagnetite determined by valence-difference contrast in synchrotron X-ray resonant scattering International-journal Peer-reviewed

    Maki Okube, Taro Oshiumi, Toshiro Nagase, Ritsuro Miyawaki, Akira Yoshiasa, Satoshi Sasaki, Kazumasa Sugiyama

    JOURNAL OF SYNCHROTRON RADIATION 25 (Pt 6) 1694-1702 2018/11

    DOI: 10.1107/S1600577518013954  

    ISSN: 1600-5775

    eISSN: 1600-5775

  67. Structural variations accompanied by thermal expansion of diaspore: in-situ single-crystal and powder X-ray diffraction study Peer-reviewed

    Teruki Sugiura, Hiroshi Arima, Takaya Nagai, Kazumasa Sugiyama

    PHYSICS AND CHEMISTRY OF MINERALS 45 (10) 1003-1010 2018/11

    DOI: 10.1007/s00269-018-0981-y  

    ISSN: 0342-1791

    eISSN: 1432-2021

  68. Dehydroxylation Kinetics of Clay Minerals and Its Application to Friction Heating Along an Imbricate Thrust in an Accretionary Prism Peer-reviewed

    Hirokazu Masumoto, Jun Kameda, Hiroshi Arima, Kazumasa Sugiyama, Takaya Nagai, Yuzuru Yamamoto

    GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS 19 (9) 2991-3003 2018/09

    DOI: 10.1029/2018GC007472  

    ISSN: 1525-2027

    eISSN: 1525-2027

  69. Pre‐Transitional Behavior in Tetragonal to Cubic Phase Transition in HfO2 Revealed by High Temperature Diffraction Experiments Peer-reviewed

    Tsubasa Tobase, Akira Yoshiasa, Hiroshi Arima, Kazumasa Sugiyama, Osamu Ohtaka, Tomotaka Nakatani, Ken‐ichi Funakoshi, Shinji Kohara

    physica status solidi (b) 255 (11) 1800090 2018/08/14

    DOI: 10.1002/pssb.201800090  

    ISSN: 0370-1972

    eISSN: 1521-3951

  70. Crystal structure refinement and chemical formula of prosopite, CaAl2F4[(OH)(4-x)F-x] x=0.0-1.0 Peer-reviewed

    Hidetomo Hongu, Akira Yoshiasa, Aya Teshima, Hiroshi Isobe, Kazumasa Sugiyama, Hiroshi Arima, Akihiko Nakatsuka, Koichi Momma, Ritsuro Miyawaki

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 113 (3) 152-158 2018/06

    DOI: 10.2465/jmps.170418  

    ISSN: 1345-6296

    eISSN: 1349-3825

  71. The location of Mn (MnO: 2.0 wt%) in fluorapatite from Lavra da Golconda, near Governador Valadares, Minas Gerais, Brazil Peer-reviewed

    Hiroshi Arima, Yusuke Kida, Takashi Mikouchi, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 113 (3) 119-125 2018/06

    DOI: 10.2465/jmps.170928  

    ISSN: 1345-6296

    eISSN: 1349-3825

  72. Determination of elastic constants of single-crystal chromian spinel by resonant ultrasound spectroscopy and implications for fluid inclusion geobarometry Peer-reviewed

    Kenya Ono, Yuya Harada, Akira Yoneda, Junji Yamamoto, Akira Yoshiasa, Kazumasa Sugiyama, Hiroshi Arima, Tohru Watanabe

    PHYSICS AND CHEMISTRY OF MINERALS 45 (3) 237-247 2018/03

    DOI: 10.1007/s00269-017-0912-3  

    ISSN: 0342-1791

    eISSN: 1432-2021

  73. Textural and Optical Properties of Ce-Doped YAG/Al2O3 Melt Growth Composite Grown by Micro-Pulling-Down Method Peer-reviewed

    Rayko Simura, Tetsuo Taniuchi, Kazumasa Sugiyama, Tsuguo Fukuda

    HIGH TEMPERATURE MATERIALS AND PROCESSES 37 (2) 127-131 2018/02

    DOI: 10.1515/htmp-2016-0152  

    ISSN: 0334-6455

    eISSN: 2191-0324

  74. Nanometer-Sized Crystalline Clusters of IGZO Films Determined from the Grazing Incidence X-ray Scattering and Anomalous X-ray Scattering Data Combined with Reverse Monte Carlo Simulations Peer-reviewed

    Yoshio Waseda, Kazumasa Sugiyama, Toru Kawamata

    MATERIALS TRANSACTIONS 59 (11) 1691-1700 2018

    DOI: 10.2320/matertrans.M2018231  

    ISSN: 1345-9678

    eISSN: 1347-5320

  75. Emergent composite structures following the amorphization of itraconazole with alpha-glucosyl rutin by over-grinding Peer-reviewed

    Kazunori Kadota, Hiroshi Arima, Ryosuke Shakudo, Kumi Semba, Hiromasa Uchiyama, Kazumasa Sugiyama, Yuichi Tozuka

    POWDER TECHNOLOGY 323 69-75 2018/01

    DOI: 10.1016/j.powtec.2017.10.002  

    ISSN: 0032-5910

    eISSN: 1873-328X

  76. Phase Transition and Thermal Expansion of Ba3RB3O9 (R = Sm-Yb, and Y) Peer-reviewed

    Rayko Simura, Shohei Kawai, Kazumasa Sugiyama

    HIGH TEMPERATURE MATERIALS AND PROCESSES 36 (8) 763-769 2017/09

    DOI: 10.1515/htmp-2015-0290  

    ISSN: 0334-6455

    eISSN: 2191-0324

  77. XAFS study on the location of Cu and Mn in a greenish blue elbaite from Alto dos Quntos mine, Brazil Peer-reviewed

    Kazumasa Sugiyama, Hiroshi Arima, Hayato Konno, Takashi Mikouchi

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 112 (4) 139-146 2017/08

    DOI: 10.2465/jmps.161011  

    ISSN: 1345-6296

    eISSN: 1349-3825

  78. Structure of Single-Crystal Rutile (TiO2) Prepared by High-Temperature Ultracentrifugation Peer-reviewed

    Tsutomu Mashimo, Rabaya Bagum, Yudai Ogata, Makoto Tokuda, Maki Okube, Kazumasa Sugiyama, Yoshiaki Kinemuchi, Hiroshi Isobe, Akira Yoshiasa

    CRYSTAL GROWTH & DESIGN 17 (4) 1460-1464 2017/04

    DOI: 10.1021/acs.cgd.6b01818  

    ISSN: 1528-7483

    eISSN: 1528-7505

  79. Medium Range Ordering realized in Zr80Pt20Amorphous Alloy Peer-reviewed

    K Sugiyama, T Kawamata, T Muto

    Journal of Physics: Conference Series 809 012005-012005 2017/02

    DOI: 10.1088/1742-6596/809/1/012005  

    ISSN: 1742-6588

    eISSN: 1742-6596

  80. Precursor phenomenon before phase transitions in PbTiO3 and BaTiO3 Peer-reviewed

    Akira Yoshiasa, Tomotaka Nakatani, Akihiko Nakatsuka, Maki Okube, Hiroshi Arima, Kazumasa Sugiyama

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 73 C989-C989 2017

    DOI: 10.1107/S2053273317085850  

    ISSN: 2053-2733

  81. Crystal Structure of the C-AlRuNi Phase Peer-reviewed

    Rayko Simura, Kazumasa Sugiyama, Shota Suzuki, Toru Kawamata

    MATERIALS TRANSACTIONS 58 (8) 1101-1105 2017

    DOI: 10.2320/matertrans.M2017106  

    ISSN: 1345-9678

    eISSN: 1347-5320

  82. Structural refinement of kottigite-parasymplesite solid solution: Unique cation site occupancy and chemical bonding with water molecules Peer-reviewed

    Akira Yoshiasa, Yumiko Miyano, Hiroshi Isobe, Kazumasa Sugiyama, Hiroshi Arima, Akihiko Nakatsuka, Koichi Momma, Ritsuro Miyawaki

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 111 (5) 363-369 2016/10

    DOI: 10.2465/jmps.151207  

    ISSN: 1345-6296

    eISSN: 1349-3825

  83. A new high-pressure strontium germanate, SrGe2O5. International-journal Peer-reviewed

    Akihiko Nakatsuka, Kazumasa Sugiyama, Makio Ohkawa, Osamu Ohtaka, Keiko Fujiwara, Akira Yoshiasa

    Acta crystallographica. Section C, Structural chemistry 72 (Pt 10) 716-719 2016/10/01

    DOI: 10.1107/S205322961601353X  

    ISSN: 2053-2296

    eISSN: 2053-2296

  84. Erratum: “High-temperature thermal expansion of ScAlMgO Peer-reviewed

    Simura Rayko, Sugiyama Kazumasa, Nakatsuka Akihiko, Fukuda Tsuguo

    Jpn. J. Appl. Phys. 55 (9) 99201-99201 2016/08/10

    Publisher: Institute of Physics

    DOI: 10.7567/JJAP.55.099201  

    ISSN: 0021-4922

  85. High-temperature single-crystal X-ray diffraction study of tetragonal and cubic perovskite-type PbTiO3 phases International-journal Peer-reviewed

    Akira Yoshiasa, Tomotaka Nakatani, Akihiko Nakatsuka, Maki Okube, Kazumasa Sugiyama, Tsutomu Mashimo

    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS 72 (Pt 3) 381-388 2016/06

    DOI: 10.1107/S2052520616005114  

    ISSN: 2052-5206

  86. Distribution of Mn in pink elbaitic tourmaline from Mogok, Myanmar Peer-reviewed

    Kazumasa Sugiyama, Hiroshi Arima, Hayato Konno, Toru Kawamata

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 111 (1) 1-8 2016/02

    DOI: 10.2465/jmps.150827  

    ISSN: 1345-6296

    eISSN: 1349-3825

  87. Crystal structure refinements of legrandite, adamite, and paradamite: The complex structure and characteristic hydrogen bonding network of legrandite Peer-reviewed

    Satoshi Jinnouchi, Akira Yoshiasa, Kazumasa Sugiyama, Reiko Shimura, Hiroshi Arima, Koichi Momma, Ritsurou Miyawaki

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 111 (1) 35-43 2016/02

    DOI: 10.2465/jmps.141216  

    ISSN: 1345-6296

    eISSN: 1349-3825

  88. Temperature dependence of Zr and Ti K-edge XANES spectra for para- and ferro-electric perovskite-type PbZrO3, PbTiO3 and BaTiO3 Peer-reviewed

    A. Yoshiasa, T. Nakatani, T. Hiratoko, T. Tobase, A. Nakatsuka, M. Okube, H. Arima, K. Sugiyama

    16TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS16) 712 012121 2016

    DOI: 10.1088/1742-6596/712/1/012121  

    ISSN: 1742-6588

    eISSN: 1742-6596

  89. Local structures of Ca, Ti and Fe in meteorite fusion crusts Peer-reviewed

    T. Tobase, A. Yoshiasa, T. Hiratoko, H. Hongu, H. Isobe, A. Nakatsuka, H. Arima, K. Sugiyama

    16TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS16) 712 012095 2016

    DOI: 10.1088/1742-6596/712/1/012095  

    ISSN: 1742-6588

  90. Weathering and precipitation after meteorite impact of Ni, Cr, Fe, Ca and Mn in K-T boundary clays from Stevns Klint Peer-reviewed

    Yumiko Miyano, Akira Yoshiasa, Tsubasa Tobase, Hiroshi Isobe, Hidetomo Hongu, Maki Okube, Akihiko Nakatsuka, Kazumasa Sugiyama

    16TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS16) 712 012097 2016

    DOI: 10.1088/1742-6596/712/1/012097  

    ISSN: 1742-6588

    eISSN: 1742-6596

  91. Structural Study of Fe80B20Amorphous Alloy by Anomalous X-ray Scattering Coupled with Neutron Diffraction Peer-reviewed

    Hiroshi Arima, Toru Kawamata, Yoshihiko Yokoyama, Kazumasa Sugiyama, Toshiya Otomo

    Proceedings of the 2nd International Symposium on Science at J-PARC (031019) 9 2015/09/25

    Publisher: Journal of the Physical Society of Japan

    DOI: 10.7566/jpscp.8.031019  

  92. Crystal structure of post-perovskite-type CaIrO3reinvestigated: new insights into atomic thermal vibration behaviors Peer-reviewed

    Akihiko Nakatsuka, Kazumasa Sugiyama, Akira Yoneda, Keiko Fujiwara, Akira Yoshiasa

    Acta Crystallographica Section E Crystallographic Communications 71 (9) 1109-1113 2015/08/29

    DOI: 10.1107/s2056989015015649  

    ISSN: 2056-9890

    eISSN: 2056-9890

  93. High-temperature thermal expansion of ScAlMgO4 for substrate application of GaN and ZnO epitaxial growth Peer-reviewed

    Rayko Simura, Kazumasa Sugiyama, Akihiko Nakatsuka, Tsuguo Fukuda

    JAPANESE JOURNAL OF APPLIED PHYSICS 54 (7) 075503 2015/07

    DOI: 10.7567/JJAP.54.075503  

    ISSN: 0021-4922

    eISSN: 1347-4065

  94. Zr-based bulk metallic glass as a cylinder material for high pressure apparatuses Peer-reviewed

    Kazuki Komatsu, Koji Munakata, Kazuyuki Matsubayashi, Yoshiya Uwatoko, Yoshihiko Yokoyama, Kazumasa Sugiyama, Masaaki Matsuda

    HIGH PRESSURE RESEARCH 35 (3) 254-262 2015/07

    DOI: 10.1080/08957959.2015.1041939  

    ISSN: 0895-7959

    eISSN: 1477-2299

  95. Local structure around Ge in lithium germanate glasses analyzed by AXS and EXAFS techniques Peer-reviewed

    Hiroshi Arima, Toru Kawamata, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 110 (2) 60-64 2015/04

    DOI: 10.2465/jmps.141022f  

    ISSN: 1345-6296

    eISSN: 1349-3825

  96. XAFS study of Zr in Cretaceous-Tertiary boundary clays from Stevns Klint Peer-reviewed

    Tsubasa Tobase, Akira Yoshiasa, Ling Wang, Tatsuya Hiratoko, Hidetomo Hongu, Maki Okube, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 110 (2) 88-91 2015/04

    DOI: 10.2465/jmps.141022a  

    ISSN: 1345-6296

    eISSN: 1349-3825

  97. Cz grown 2-in. size Ce:Gd-3(Al,Ga)(5)O-12 single crystal; relationship between Al, Ga site occupancy and scintillation properties Peer-reviewed

    Kei Kamada, Shunsuke Kurosawa, Petr Prusa, Martin Nikl, Vladimir V. Kochurikhin, Takanori Endo, Kousuke Tsutumi, Hiroki Sato, Yuui Yokota, Kazumasa Sugiyama, Akira Yoshikawa

    OPTICAL MATERIALS 36 (12) 1942-1945 2014/10

    DOI: 10.1016/j.optmat.2014.04.001  

    ISSN: 0925-3467

    eISSN: 1873-1252

  98. F-AlCoPdGe Alloy with Three Types of Pseudo-Mackay Clusters Peer-reviewed

    K. Sugiyama, K. Yubuta, Y. Yokoyama, S. Suzuki, R. Simura

    ACTA PHYSICA POLONICA A 126 (2) 588-593 2014/08

    DOI: 10.12693/APhysPolA.126.588  

    ISSN: 0587-4246

    eISSN: 1898-794X

  99. Structure of Al87Y8Ni5 Amorphous Alloy Analyzed by Anomalous Xnomalous X-ray Scattering Peer-reviewed

    H.Arima, T.Kawamata, Y.Yokoyama, K.Sugiyama

    Proceedings of the 12th Asia Pacific Physics Conference 012107 2014

  100. Site Determination of Sr in Sr3YB3O9 Crystals by Anomalous X-ray Scattering Peer-reviewed

    R. Simura, K. Sugiyama

    1ST CONFERENCE ON LIGHT AND PARTICLE BEAMS IN MATERIALS SCIENCE 2013 (LPBMS2013) 502 012028 2014

    DOI: 10.1088/1742-6596/502/1/012028  

    ISSN: 1742-6588

  101. Structural Study of Zr-Cu-Ag Bulk Metallic Glasses Using the Anomalous X-ray Scattering Method Peer-reviewed

    T. Kawamata, K. Sugiyama, Y. Yokoyama, T. Fujita

    1ST CONFERENCE ON LIGHT AND PARTICLE BEAMS IN MATERIALS SCIENCE 2013 (LPBMS2013) 502 012027 2014

    DOI: 10.1088/1742-6596/502/1/012027  

    ISSN: 1742-6588

  102. Local structure of iron in tektites and natural glass: An insight through X-ray absorption fine structure spectroscopy Peer-reviewed

    Ling Wang, Akira Yoshiasa, Maki Okube, Tatsuya Hiratoko, Yuan Hu, Hiroshi Arima, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 108 (5) 288-294 2013/10

    DOI: 10.2465/jmps.130212  

    ISSN: 1345-6296

    eISSN: 1349-3825

  103. Crystal Structure and Pseudo-Mackay Clusters of R-AIPdCo Peer-reviewed

    Rayko Simura, Shota Suzuki, Kunio Yubuta, Kazumasa Sugiyama

    MATERIALS TRANSACTIONS 54 (8) 1385-1391 2013/08

    DOI: 10.2320/matertrans.M2013058  

    ISSN: 1345-9678

    eISSN: 1347-5320

  104. Temperature dependence of pre-edge features in Ti K-edge XANES spectra for ATiO3 (A = Ca and Sr), A2TiO4 (A = Mg and Fe), TiO2 rutile and TiO2 anatase International-journal Peer-reviewed

    Tatsuya Hiratoko, Akira Yoshiasa, Tomotaka Nakatani, Maki Okube, Akihiko Nakatsuka, Kazumasa Sugiyama

    JOURNAL OF SYNCHROTRON RADIATION 20 (Pt 4) 641-643 2013/07

    DOI: 10.1107/S0909049513009175  

    ISSN: 0909-0495

  105. Static Measurements of α- and β-Relaxations in Zr-based Bulk Metallic Glasses Peer-reviewed

    HARUYAMA Osami, SAWADA Hiroyuki, YOSHIKAWA Kazuhiro, KAWAMATA Toru, YOKOYAMA Yoshihiko, SUGIYAMA Kazumasa

    Journal of the Japan Society of Powder and Powder Metallurgy 60 (5) 217-223 2013/05/15

    Publisher: Japan Society of Powder and Powder Metallurgy

    DOI: 10.2497/jjspm.60.217  

    ISSN: 0532-8799

    eISSN: 1880-9014

  106. Characterization of free volume in cold-rolled Zr55Cu 30Ni5Al10 bulk metallic glasses Peer-reviewed

    O. Haruyama, K. Kisara, A. Yamashita, K. Kogure, Y. Yokoyama, K. Sugiyama

    Acta Materialia 61 (9) 3224-3232 2013/05

    DOI: 10.1016/j.actamat.2013.02.010  

    ISSN: 1359-6454

  107. The structure of hydrated copper-silicate gels, an analogue compound for natural chrysocolla Peer-reviewed

    Tsuyoshi Hariu, Hiroshi Arima, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 108 (2) 111-115 2013/04

    DOI: 10.2465/jmps.121022c  

    ISSN: 1345-6296

    eISSN: 1349-3825

  108. Structure of τ 2-Al3Co, a Monoclinic Approximant of the Al–Co Decagonal Quasicrystal Peer-reviewed

    K. Sugiyama, A. Yasuhara, K. Hiraga

    Aperiodic Crystals 237-242 2013

    Publisher: Springer Netherlands

    DOI: 10.1007/978-94-007-6431-6_32  

  109. Structure of ϵ 16 Phase in Al–Pd–Co System Studied by HREM and X-Ray Diffraction Peer-reviewed

    K. Yubuta, S. Suzuki, R. Simura, K. Sugiyama

    Aperiodic Crystals 231-236 2013

    Publisher: Springer Netherlands

    DOI: 10.1007/978-94-007-6431-6_31  

  110. Valence state of dopant and scintillation properties of Ce-doped Sr3Y(BO3)(3) crystal Peer-reviewed

    Rayko Simura, Shohei Kawai, Kazumasa Sugiyama, Takayuki Yanagida, Takamasa Sugawara, Toetsu Shishido, Akira Yoshikawa

    JOURNAL OF CRYSTAL GROWTH 362 296-299 2013/01

    DOI: 10.1016/j.jcrysgro.2011.11.089  

    ISSN: 0022-0248

    eISSN: 1873-5002

  111. Growth of Ce-doped Ba3Gd(BO3)3 and Sr3Gd(BO3)(3) single crystals by micro-pulling-down method and analysis of luminescence properties Peer-reviewed

    Rayko Simura, Tatsushi Yagi, Kazumasa Sugiyama, Takayuki Yanagida, Akira Yoshikawa

    JOURNAL OF CRYSTAL GROWTH 362 145-148 2013/01

    DOI: 10.1016/j.jcrysgro.2011.11.086  

    ISSN: 0022-0248

    eISSN: 1873-5002

  112. Structural relations and pseudosymmetries in the andorite homologous series Peer-reviewed

    Massimo Nespolo, Tohru Ozawa, Yusuke Kawasaki, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 107 (6) 226-243 2012/12

    DOI: 10.2465/jmps.120730  

    ISSN: 1345-6296

    eISSN: 1349-3825

  113. Crystal structure of lithium potassium yttrium pentafluoride LiKYF5 prepared from high-temperature melt, F10K2Li2Y2 Peer-reviewed

    Kazumasa Sugiyama, Yuki Furuya, Akira Yoshikawa

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES 227 (4) 433-434 2012/12

    DOI: 10.1524/ncrs.2012.0252  

    ISSN: 1433-7266

  114. The Crystalline Structure of O-AlFePd Peer-reviewed

    Kazumasa Sugiyama, Tatsuo Obata, Kenji Hiraga

    MATERIALS TRANSACTIONS 53 (8) 1357-1362 2012/08

    DOI: 10.2320/matertrans.M2012130  

    ISSN: 1345-9678

    eISSN: 1347-5320

  115. Triclinic modification of diaqua-bis-(5-carb-oxy-1H-imidazole-4-carboxyl- ato-k2N 3,O 4)iron(II) Peer-reviewed

    Eriko Ohshima, Kazuki Yoshida, Kazumasa Sugiyama, Hidehiro Uekusa

    Acta Crystallographica Section E: Structure Reports Online 68 (Pt 8) m1093-4 2012/08/01

    DOI: 10.1107/S1600536812031753  

    ISSN: 1600-5368

  116. Improving the purity of GaN grown by the ammonothermal method with in-autoclave gas-phase acidic mineralizer synthesis Peer-reviewed

    D. Tomida, S. F. Chichibu, Y. Kagamitani, Q. Bao, K. Hazu, R. Simura, K. Sugiyama, C. Yokoyama, T. Ishiguro, T. Fukuda

    JOURNAL OF CRYSTAL GROWTH 348 (1) 80-84 2012/06

    DOI: 10.1016/j.jcrysgro.2012.03.037  

    ISSN: 0022-0248

  117. Local atomic arrangement of amorphous Zr50Ni50 alloy analyzed by AXS-RMC method Peer-reviewed

    T. Kawamata, Y. Yokoyama, K. Sugiyama

    MATERIALS INTEGRATION 508 146-151 2012

    DOI: 10.4028/www.scientific.net/KEM.508.146  

    ISSN: 1013-9826

  118. Environmental structural analysis of Raney Ru(Ni) fine particles Peer-reviewed

    Reiko Murao, Kazumasa Sugiyama, Satoshi Kameoka, An-Pang Tsai

    MATERIALS INTEGRATION 508 304-309 2012

    DOI: 10.4028/www.scientific.net/KEM.508.304  

    ISSN: 1013-9826

  119. Crystal structure of tridecaaluminium tetra(nickel,ruthenium), Al13Ni1.26Ru2.74 Peer-reviewed

    Shota Suzuki, Reiko Murao, Rayko Simura, Kazumasa Sugiyama

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES 227 (1) 5-6 2012

    DOI: 10.1524/ncrs.2012.0003  

    ISSN: 1433-7266

  120. Features of the Mackay clusters with and without a center atom in Al based approximants of icosahedral quasicrystals Peer-reviewed

    Shota Suzuki, Rayko Simura, Kazumasa Sugiyama

    MATERIALS INTEGRATION 508 353-356 2012

    DOI: 10.4028/www.scientific.net/KEM.508.353  

    ISSN: 1013-9826

  121. ZrSiO(4) Precursor in ZrO2-SiO2 Dried Gel Inferred from the Pair Distribution Function Analysis Data Peer-reviewed

    R. Murao, K. Sugiyama

    HIGH TEMPERATURE MATERIALS AND PROCESSES 30 (6) 593-598 2012/01

    DOI: 10.1515/HTMP.2011.120  

    ISSN: 0334-6455

  122. A design of backing seat and gasket assembly in diamond anvil cell for accurate single crystal x-ray diffraction to 5 GPa Peer-reviewed

    K. Komatsu, H. Kagi, T. Yasuzuka, T. Koizumi, R. Iizuka, K. Sugiyama, Y. Yokoyama

    REVIEW OF SCIENTIFIC INSTRUMENTS 82 (10) 105107 2011/10

    DOI: 10.1063/1.3646460  

    ISSN: 0034-6748

  123. The Structure of an Al-Ni-Ru Monoclinic Phase Al13(Ru,Ni)4 Peer-reviewed

    Reiko Murao, Michiyo Genba, Kazumasa Sugiyama, Wei Sun

    MATERIALS TRANSACTIONS 52 (7) 1344-1348 2011/07

    DOI: 10.2320/matertrans.M2011070  

    ISSN: 1345-9678

    eISSN: 1347-5320

  124. Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion Peer-reviewed

    Tatsuya Miyazaki, Daisuke Terada, Yoji Miyajima, Challapalli Suryanarayana, Reiko Murao, Yoshihiko Yokoyama, Kazumasa Sugiyama, Minoru Umemoto, Yoshikazu Todaka, Nobuhiro Tsuji

    JOURNAL OF MATERIALS SCIENCE 46 (12) 4296-4301 2011/06

    DOI: 10.1007/s10853-010-5240-7  

    ISSN: 0022-2461

  125. Tough Hypoeutectic Zr-Based Bulk Metallic Glasses Peer-reviewed

    Yoshihiko Yokoyama, Hitoo Tokunaga, Alain Reza Yavari, Toru Kawamata, Tohru Yamasaki, Kazutaka Fujita, Kazumasa Sugiyama, Peter K. Liaw, Akihisa Inoue

    METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE 42A (6) 1468-1475 2011/06

    DOI: 10.1007/s11661-011-0631-1  

    ISSN: 1073-5623

    eISSN: 1543-1940

  126. Single crystal structure analysis of the Se-incorporated mordenite, coupled with the anomalous X-ray scattering Peer-reviewed

    N. Togashi, K. Sugiyama, J. Yu, S. Qiu, O. Terasaki

    SOLID STATE SCIENCES 13 (4) 684-690 2011/04

    DOI: 10.1016/j.solidstatesciences.2010.10.018  

    ISSN: 1293-2558

    eISSN: 1873-3085

  127. Structural analysis of metal nano-particles prepared by leaching Peer-reviewed

    Reiko Murao, Kazumasa Sugiyama, Satoshi Kameoka, An-Pang Tsai

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 67 C423-C423 2011

    DOI: 10.1107/S0108767311089379  

    ISSN: 2053-2733

  128. Structural study on zr-based metallic glasses by anomalous X-ray scattering coupled with reverse Monte-Carlo simulation Peer-reviewed

    Kazumasa Sugiyama, Toru Kawamata, Taku Muto, Yoshio Waseda

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 67 C418-C418 2011

    DOI: 10.1107/S0108767311089501  

    ISSN: 2053-2733

  129. Crystal structure of -AlPdRe Peer-reviewed

    Shota Suzuki, Rayko Simura, Kazumasa Sugiyama

    PHILOSOPHICAL MAGAZINE 91 (19-21) 2610-2616 2011

    DOI: 10.1080/14786435.2010.544268  

    ISSN: 1478-6435

    eISSN: 1478-6443

  130. Atomic pair distribution function (PDF) analysis of Raney Pd and Rh fine particles Peer-reviewed

    R. Murao, K. Sugiyama, Y. Kashiwagi, S. Kameoka, A. P. Tsai

    PHILOSOPHICAL MAGAZINE 91 (19-21) 2954-2961 2011

    DOI: 10.1080/14786435.2010.541167  

    ISSN: 1478-6435

    eISSN: 1478-6443

  131. Structure of a glassy Zr70Pd30 alloy analysed by anomalous X-ray scattering coupled with reverse Monte Carlo simulation (AXS-RMC) Peer-reviewed

    K. Sugiyama, T. Muto, T. Kawamata, Y. Yokoyama, Y. Waseda

    PHILOSOPHICAL MAGAZINE 91 (19-21) 2962-2970 2011

    DOI: 10.1080/14786435.2010.536175  

    ISSN: 1478-6435

    eISSN: 1478-6443

  132. Crystal structure of a new orthorhombic Al72Pd18Mn5Si5 approximant phase Peer-reviewed

    Rayko Simura, Nobutaka Kaji, Kazumasa Sugiyama, Kenji Hiraga

    PHILOSOPHICAL MAGAZINE 91 (19-21) 2603-2609 2011

    DOI: 10.1080/14786435.2010.509288  

    ISSN: 1478-6435

    eISSN: 1478-6443

  133. 非晶質合金の構造に関する最近の話題:AXS-RMC法をもちいたアプローチ Peer-reviewed

    杉山和正, 川又透, 早稲田嘉夫

    東北大学多元物質科学研究所素材工学研究彙報 66 (1,2) 33-43 2010/12

    Publisher: 東北大学多元物質科学研究所素材工学研究棟

    ISSN: 1348-4052

  134. Ammonothermal epitaxy of wurtzite GaN using an NH4I mineralizer Peer-reviewed

    Y. Kagamitani, T. Kuribayashi, K. Hazu, T. Onuma, D. Tomida, R. Simura, S. F. Chichibu, K. Sugiyama, C. Yokoyama, T. Ishiguro, T. Fukuda

    JOURNAL OF CRYSTAL GROWTH 312 (22) 3384-3387 2010/11

    DOI: 10.1016/j.jcrysgro.2010.07.065  

    ISSN: 0022-0248

  135. Structural Study of Zr50Cu50 Amorphous Alloy by Anomalous X-ray Scattering Coupled with Reverse Monte-Carlo Simulation Peer-reviewed

    T. Kawamata, Y. Yokoyama, M. Saito, K. Sugiyama, Y. Waseda

    MATERIALS TRANSACTIONS 51 (10) 1796-1801 2010/10

    DOI: 10.2320/matertrans.MAW201016  

    ISSN: 1345-9678

    eISSN: 1347-5320

  136. Development and Evaluations of Apatite Crystal Scintillators Peer-reviewed

    Takayuki Yanagida, Yutaka Fujimoto, Yoshihumi Ohgi, Yuui Yokota, Akira Yoshikawa, Hiroyuki Kagi, Kazumasa Sugiyama, Kei Kamada

    IEEE TRANSACTIONS ON NUCLEAR SCIENCE 57 (3) 1308-1311 2010/06

    DOI: 10.1109/TNS.2010.2042966  

    ISSN: 0018-9499

    eISSN: 1558-1578

  137. Crystal Growth and Characterization of Sr3Y(BO3)3 Peer-reviewed

    Yutaka Fujimoto, Yuui Yokota, Takayuki Yanagida, Jan Pejchal, Hayato Konno, Kazumasa Sugiyama, Martin Nikl, Akira Yoshikawa

    IEEE TRANSACTIONS ON NUCLEAR SCIENCE 57 (3) 1264-1267 2010/06

    DOI: 10.1109/TNS.2009.2035695  

    ISSN: 0018-9499

    eISSN: 1558-1578

  138. The structure of Y-Al13-xCo4 (x=0.8) analyzed by single crystal X-ray diffraction coupled with anomalous X-ray scattering Peer-reviewed

    Kazumasa Sugiyama, Michiyo Genba, Kenji Hiraga, Yoshio Waseda

    JOURNAL OF ALLOYS AND COMPOUNDS 494 (1-2) 98-101 2010/04

    DOI: 10.1016/j.jallcom.2009.11.117  

    ISSN: 0925-8388

    eISSN: 1873-4669

  139. A Study on Chemical Short Range Ordering in Pd40Ni40P20 Bulk Metallic Glass by Anomalous X-ray Scattering Peer-reviewed

    Osami Haruyama, Takahiro Makimura, Tomoki Miyakawa, Kazumasa Sugiyama

    HIGH TEMPERATURE MATERIALS AND PROCESSES 29 (5-6) 381-392 2010

    DOI: 10.1515/HTMP.2010.29.5-6.381  

    ISSN: 0334-6455

    eISSN: 2191-0324

  140. Electron Density Distribution in Liquid Ga Estimated from the Anomalous X-ray Scattering Measurements Peer-reviewed

    Masatoshi Saito, Kazumasa Sugiyama, Yoshio Waseda

    HIGH TEMPERATURE MATERIALS AND PROCESSES 29 (5-6) 393-403 2010

    DOI: 10.1515/HTMP.2010.29.5-6.393  

    ISSN: 0334-6455

    eISSN: 2191-0324

  141. A Peculiar Site Preference of Boron in MgAl2-xBxO4 (x=0.0, 0.11, and 0.13) Spinel under High-Pressure and High-Temperature Peer-reviewed

    Akira Yoshiasa, Tomokazu Ito, Kazumasa Sugiyama, Akihiko Nakatsuka, Maki Okube, Masanori Kurosawa, Tomoo Katsura

    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 636 (3-4) 472-475 2010

    DOI: 10.1002/zaac.200900418  

    ISSN: 0044-2313

  142. Superconducting phase prepared from Ta3Si under high pressure Peer-reviewed

    R. Murao, M. Kikuchi, T. Atou, K. Kusaba, K. Fukuoka, K. Sugiyama, Y. Syono, T. Kikegawa

    INTERNATIONAL CONFERENCE ON HIGH PRESSURE SCIENCE AND TECHNOLOGY, JOINT AIRAPT-22 AND HPCJ-50 215 012139 2010

    DOI: 10.1088/1742-6596/215/1/012139  

    ISSN: 1742-6588

  143. Crystallography of hornblende amphibole in LAP04840 R chondrite and implication for its metamorphic history Peer-reviewed

    Kouhei Ota, Takashi Mikouchi, Kazumasa Sugiyama

    JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 104 (4) 215-225 2009/08

    DOI: 10.2465/jmps.080903  

    ISSN: 1345-6296

    eISSN: 1349-3825

  144. Synthesis of single crystal (Mg<inf>1-x</inf>Fe<inf>x</inf>)<inf>1-δ</inf>O (x=0.001-1.00) solid-solution and electrical conduction mechanism at high temperature and pressure Peer-reviewed

    Akira Yoshiasa, Kazumasa Sugiyama, Shunsuke Sakai, Hiroshi Isobe, Daisuke Sakamoto, Ken'ichi Ota, Hiroshi Arima, Humihiko Takei

    Journal of Crystal Growth 311 (3) 974-977 2009/01/15

    DOI: 10.1016/j.jcrysgro.2008.09.119  

    ISSN: 0022-0248

  145. High-resolution stress mapping of Al2O3/monoclinic ZrO2 and Al2O3/cubic ZrO2(Y2O3) eutectics using scanning near-field optical microscopy Peer-reviewed

    S. Fukura, H. Kagi, M. Nakai, K. Sugiyama, T. Fukuda

    JOURNAL OF CRYSTAL GROWTH 311 (3) 998-1004 2009/01

    DOI: 10.1016/j.jcrysgro.2008.09.150  

    ISSN: 0022-0248

  146. Crystal structure and chemistry of conichalcote CaCu(AsO4)(OH) Peer-reviewed

    S.Sakai, A.Toshiasa, K.Sugiyama, R.Miyawaki

    J. Mineral. Petro. Sci. 104 125-131 2009

    DOI: 10.2465/jmps.080430  

  147. Crystal structure of ammonium tetrairon trisphosphate(V), [NH4][Fe-4(PO4)3] Peer-reviewed

    Kazumasa Sugiyama, Makoto Kimiyama

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES 224 (3) 369-370 2009

    DOI: 10.1524/ncrs.2009.0161  

    ISSN: 1433-7266

  148. Microstructure and Crystal Chemistry of Eutectic Al2O3/Y3Al5O12 Fibers Modified by the Partial Substitution of Sc2O3 for Al2O3. Peer-reviewed

    K. Sugiyama, M. Nakai, A. Yoshikawa, T. Fukuda

    HIGH TEMPERATURE MATERIALS AND PROCESSES 28 (1-2) 89-95 2009

    DOI: 10.1515/HTMP.2009.28.1-2.89  

    ISSN: 0334-6455

  149. Crystal structure of imidazolium trialuminium dodecaoxotriphosphate monohydroxide, [C3H5N2][Al3P 3O12(OH)], AIPO4-21 Peer-reviewed

    Kazumasa Sugiyama, Junya Takashima, Michiyo Genba, Tokuhei Tagai

    Zeitschrift fur Kristallographie - New Crystal Structures 224 (1) 140-142 2009

    DOI: 10.1524/ncrs.2009.0063  

    ISSN: 1433-7266

  150. Structural study of liquid LiNbO3 by the high-temperature energy dispersive X-ray diffraction coupled with reverse Monte Carlo simulation Peer-reviewed

    K. Sugiyama, M. Saito, Y. Waseda

    JOURNAL OF CRYSTAL GROWTH 311 (3) 966-969 2009/01

    DOI: 10.1016/j.jcrysgro.2008.09.117  

    ISSN: 0022-0248

  151. Crystal growth and structural characterizations of Ce-doped Gd-9.33(SiO4)(6)O-2 single crystals Peer-reviewed

    Y. Ohgi, H. Kagi, H. Arima, A. Ohta, K. Kamada, A. Yoshikawa, K. Sugiyama

    JOURNAL OF CRYSTAL GROWTH 311 (3) 526-529 2009/01

    DOI: 10.1016/j.jcrysgro.2008.09.148  

    ISSN: 0022-0248

  152. Peculiar site preferences of B and Ga in MgAl2O4 spinel solid solutions

    A. Yoshiasa, S. Sakai, H. Maekawa, K. Sugiyama, A. Nakatsuka, E. Ito

    Acta Crystallographica A64 (Supplement) C500-C501 2008

    DOI: 10.1107/S010876730808392X  

    ISSN: 2053-2733

  153. Crystal structure of tri(4-methylimidazolium) trialuminium tetraphosphorous oxide, [Al3P4O16][C4H7N2]3 Peer-reviewed

    Kazumasa Sugiyama, Jyunya Takashima, Tokuhei Tagai

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES 223 (3) 200-202 2008

    DOI: 10.1524/ncrs.2008.0083  

    ISSN: 1433-7266

  154. A local structure change of bulk Pd40Ni40P20 glass during full relaxation Peer-reviewed

    O. Haruyama, K. Sugiyama, M. Sakurai, Y. Waseda

    JOURNAL OF NON-CRYSTALLINE SOLIDS 353 (32-40) 3053-3056 2007/10

    DOI: 10.1016/j.jnoncrysol.2007.05.071  

    ISSN: 0022-3093

  155. Crystal structure of aluminum germanium manganese (72.0 : 26.3 : 57.7), Al72.0Ge26.3Mn57.7 Peer-reviewed

    Kazumasa Sugiyama, Hironori Sato, Yoshihiko Yokoyama, Kenji Hiraga, Kenji Yoza

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES 222 (1) 3-5 2007

    DOI: 10.1524/ncrs.2007.0002  

    ISSN: 1433-7266

  156. Effect of crystal defects on laser-induced-damage tolerance of organic crystal, 4-dimethylamino-N-methyl-4-stilbazolium tosylate Peer-reviewed

    Yoshinori Takahashi, Kazumasa Sugiyama, Srinivasan Brahadeeswaran, Shinji Onzuka, Tomosumi Kamimura, Masashi Yoshimura, Yusuke Mori, Kunio Yoshida, Takatomo Sasaki

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS 46 (1) 318-323 2007/01

    DOI: 10.1143/JJAP.46.318  

    ISSN: 0021-4922

  157. Determination of the Fe oxidation state of the Chassigny kaersutite: A microXANES spectroscopic study Peer-reviewed

    Akira Monkawa, Takashi Mikouchi, Eisuke Koizumi, Kazumasa Sugiyama, Masamichi Miyamoto

    METEORITICS & PLANETARY SCIENCE 41 (9) 1321-1329 2006/09

    DOI: 10.1111/j.1945-5100.2006.tb00524.x  

    ISSN: 1086-9379

    eISSN: 1945-5100

  158. Stabilization by a divalent transition metal in lead indium quaternary selenide, Fe0.47Pb8.04In17.37Se34, and specific indium coordination International-journal Peer-reviewed

    Yoshitaka Matsushita, Kazumasa Sugiyama, Yutaka Ueda

    INORGANIC CHEMISTRY 45 (17) 6598-6600 2006/08

    DOI: 10.1021/ic0611600  

    ISSN: 0020-1669

    eISSN: 1520-510X

  159. Development of a "built-in" scanning near field microscope head for an atomic force microscope system and stress mapping of an Al2O3/ZrO2 eutectic composite Peer-reviewed

    Tatsuo Nakagawa, Satoshi Fukura, Munenori Nakai, Kazumasa Sugiyama, Ryohei Kokawa, Hiroyuki Kagi

    OPTICAL REVIEW 13 (4) 269-275 2006/07

    DOI: 10.1007/s10043-006-0269-1  

    ISSN: 1340-6000

    eISSN: 1349-9432

  160. Crystallographic orientation relationship of an Al2O3/Y3Al5O12 eutectic fiber produced by the micro-pulling down (mu-PD) method. Peer-reviewed

    M. Nakai, J. H. Lee, A. Yoshikawa, K. Sugiyama, T. Fukuda, Y. Waku

    HIGH TEMPERATURE MATERIALS AND PROCESSES 25 (4) 197-201 2006

    DOI: 10.1515/HTMP.2006.25.4.197  

    ISSN: 0334-6455

  161. Crystal structure of disamarium undecaoxotetratellurate(IV), Sm2Te4O11 Peer-reviewed

    K Sugiyama, R Simura, B Wedel

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES 220 (2) 131-132 2005

    DOI: 10.1524/ncrs.2005.220.14.141  

    ISSN: 1433-7266

  162. Crystal structure of the SFCAM phase Ca2(Ca,Fe,Mg,Al)6(Fe,Al,Si)6O20 Peer-reviewed

    K Sugiyama, A Monkawa, T Sugiyama

    ISIJ INTERNATIONAL 45 (4) 560-568 2005

    DOI: 10.2355/isijinternational.45.560  

    ISSN: 0915-1559

  163. Eutectic Al2O3/Y3Al5O12 fibers modified by the substitution of Sc2O3, Fe2O3 or Cr2O3 Peer-reviewed

    M Nakai, H Kaiden, JH Lee, A Yoshikawa, K Sugiyama, T Fukuda

    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY 25 (8) 1405-1410 2005

    DOI: 10.1016/j.jeurceramsoc.2005.01.020  

    ISSN: 0955-2219

  164. Bis(2-methylimidazolium) hydroxodiphosphatoaluminium. International-journal Peer-reviewed

    Junya Takashima, Kazumasa Sugiyama, Tokuhei Tagai, Osamu Terasaki, Jihong Yu

    Acta crystallographica. Section C, Crystal structure communications 60 (Pt 7) m333-4-M334 2004/07

    DOI: 10.1107/S0108270104011990  

    ISSN: 0108-2701

  165. Crystal structure of rhombohedral lambda-AlFeSi Peer-reviewed

    K Sugiyama, N Kaji, K Hiraga

    JOURNAL OF ALLOYS AND COMPOUNDS 368 (1-2) 251-255 2004/04

    DOI: 10.1016/j.jallcom.2003.08.065  

    ISSN: 0925-8388

  166. Crystal structure of a 2/1 cubic approximant in an Al-Rh-Si alloy Peer-reviewed

    K Sugiyama, W Sun, K Hiraga

    JOURNAL OF NON-CRYSTALLINE SOLIDS 334 156-160 2004/03

    DOI: 10.1016/j.jnoncrysol.2003.11.031  

    ISSN: 0022-3093

  167. Anomalous X-ray scattering study for determining cation distribution in ZnFe2O4 and NiFe2O4. Peer-reviewed

    K Sugiyama, T Okamoto, Y Waseda

    HIGH TEMPERATURE MATERIALS AND PROCESSES 23 (5-6) 357-364 2004

    DOI: 10.1515/HTMP.2004.23.5-6.357  

    ISSN: 0334-6455

    eISSN: 2191-0324

  168. Energy dispersive X-ray diffraction method for structural characterization of non-crystalline oxides Peer-reviewed

    Y Waseda, K Sugiyama

    HIGH TEMPERATURE MATERIALS AND PROCESSES 22 (3-4) 211-219 2003

    DOI: 10.1515/HTMP.2003.22.3-4.211  

    ISSN: 0334-6455

    eISSN: 2191-0324

  169. Structural characterization of non-crystalline oxides by the anomalous X-ray scattering (AXS) method Peer-reviewed

    Y Waseda, K Sugiyama

    HIGH TEMPERATURE MATERIALS AND PROCESSES 22 (2) 103-121 2003

    DOI: 10.1515/HTMP.2003.22.2.103  

    ISSN: 0334-6455

    eISSN: 2191-0324

  170. The structural characteristics of Al-Co-Ni decagonal quasicrystals and crystalline approximants Peer-reviewed

    K Hiraga, T Ohsuna, W Sun, K Sugiyama

    JOURNAL OF ALLOYS AND COMPOUNDS 342 (1-2) 110-114 2002/08

    DOI: 10.1016/S0925-8388(02)00153-6  

    ISSN: 0925-8388

  171. Structure of a W-(AlCoNi) crystalline phase related to Al-Co-Ni decagonal quasicrystals, studied by single crystal X-ray diffraction Peer-reviewed

    K Sugiyama, S Nishimura, K Hiraga

    JOURNAL OF ALLOYS AND COMPOUNDS 342 (1-2) 65-71 2002/08

    DOI: 10.1016/S0925-8388(02)00135-4  

    ISSN: 0925-8388

  172. On the crystal structures of the Al-Cu-Cr alloy system Peer-reviewed

    K Sugiyama, H Saito, K Hiraga

    JOURNAL OF ALLOYS AND COMPOUNDS 342 (1-2) 148-152 2002/08

    DOI: 10.1016/S0925-8388(02)00161-5  

    ISSN: 0925-8388

  173. Crystal structure of a cubic Al17Zn37Mg46; a 2/1 rational approximant structure for the AI-Zn-Mg icosahedral phase Peer-reviewed

    K Sugiyama, W Sun, K Hiraga

    JOURNAL OF ALLOYS AND COMPOUNDS 342 (1-2) 139-142 2002/08

    DOI: 10.1016/S0925-8388(02)00159-7  

    ISSN: 0925-8388

  174. Crystalline structure of a Cu-substituted lambda-Al13Fe4 phase by means of the anomalous X-ray scattering Peer-reviewed

    A Genba, K Sugiyama, K Hiraga, Y Yokoyama

    JOURNAL OF ALLOYS AND COMPOUNDS 342 (1-2) 143-147 2002/08

    DOI: 10.1016/S0925-8388(02)00160-3  

    ISSN: 0925-8388

  175. Arrangement of atomic clusters in a 2/1 cubic approximant in the Al-Zn-Mg alloy system Peer-reviewed

    K Hiraga, K Sugiyama, Y Ishii

    PHILOSOPHICAL MAGAZINE LETTERS 82 (6) 341-347 2002/06

    DOI: 10.1080/09500830210135571  

    ISSN: 0950-0839

  176. Changes in the Chemical State and Composion of the Surface of Iron Oxids due to Argon Ion Sputtering. Peer-reviewed

    Shigeru Suzuki, Kazumasa Sugiyama, Yoshio Waseda

    Journal of Surface Analysis 9 (3) 455-458 2002/04

    Publisher: The Surface Analysis Society of Japan

    DOI: 10.1384/jsa.9.455  

    ISSN: 1341-1756

    More details Close

    XPS has been used for investigating the influence of argon ion sputtering on the chemical state and composition of the surface of three iron oxides, Fe2O3, Fe2NiO4 and Fe2ZnO4. XPS spectra of these oxides were measured, while bombardment by argon ions of 3keV were interrupted. The chemical state of the surface of these oxides was found to change from Fe3+ to Fe2+ by argon ion bombardment, suggesting the reduction of the surface of these oxides. This behavior was attributed to a decrease of the oxygen composition of the surface of these oxides. Then, particular attention should be paid in analysis of a layered structure of oxides formed on the iron and steel surface.

  177. Model for the microstructure of oxide eutectics and comparison with experimental observations Peer-reviewed

    H Kaiden, SD Durbin, A Yoshikawa, JH Lee, K Sugiyama, T Fukuda

    JOURNAL OF ALLOYS AND COMPOUNDS 336 (1-2) 259-264 2002/04

    DOI: 10.1016/S0925-8388(01)01876-X  

    ISSN: 0925-8388

  178. Crystal structure of dicopper nickel hexaoxotellurate, Cu<inf>2</inf>NiTeO<inf>6</inf> Peer-reviewed

    B. Wedel, I. Kimio, K. Sugiyama

    Zeitschrift fur Kristallographie - New Crystal Structures 216 (3) 323-324 2001/12/01

    DOI: 10.1524/ncrs.2001.216.14.345  

    ISSN: 1433-7266

  179. Structural characteristics of Al-Co-Ni decagonal quasicrystals and crystalline approximants Peer-reviewed

    Kenji Hiraga, Tetsu Ohsuna, Wei Sun, Kazumasa Sugiyama

    Materials Transactions 42 (11) 2354-2367 2001/01/01

    Publisher:

    DOI: 10.2320/matertrans.42.2354  

    ISSN: 1345-9678

  180. Structure refinement of (Al, Zn)(49)Mg-32-type phases by single-crystal X-ray diffraction Peer-reviewed

    W Sun, FJ Lincoln, K Sugiyama, K Hiraga

    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING 294 327-330 2000/12

    DOI: 10.1016/S0921-5093(00)01094-7  

    ISSN: 0921-5093

  181. Al13M4-type structures and atomic models of their twins Peer-reviewed

    K Saito, K Sugiyama, K Hiraga

    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING 294 279-282 2000/12

    DOI: 10.1016/S0921-5093(00)01213-2  

    ISSN: 0921-5093

  182. Cubic approximants in the Al-Pd-Fe and Al-Pd-Ru systems Peer-reviewed

    K Sugiyama, K Hiraga, K Saito

    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING 294 345-347 2000/12

    DOI: 10.1016/S0921-5093(00)01124-2  

    ISSN: 0921-5093

  183. Partial structural functions of molten copper halides CuX (X = Br, I) estimated from the anomalous x-ray scattering measurements Peer-reviewed

    Y. Waseda, S. Kang, K. Sugiyama, M. Kimura, M. Saito

    Journal of Physics Condensed Matter 12 (8A) A195-A201 2000/12/01

    DOI: 10.1088/0953-8984/12/8A/323  

    ISSN: 0953-8984

  184. Rational synthesis of microporous aluminophosphates with an inorganic open framework analogous to Al4P5O20H center dot C6H18N2 Peer-reviewed

    JH Yu, JY Li, KX Wang, RR Xu, K Sugiyama, O Terasaki

    CHEMISTRY OF MATERIALS 12 (12) 3783-3787 2000/12

    DOI: 10.1021/cm000448z  

    ISSN: 0897-4756

    eISSN: 1520-5002

  185. Crystal structure of a new 1/1-rational approximant for the Al-Cu-Ru icosahedral phase Peer-reviewed

    K Sugiyama, T Kato, T Ogawa, K Hiraga, K Saito

    JOURNAL OF ALLOYS AND COMPOUNDS 299 (1-2) 169-174 2000/03

    DOI: 10.1016/S0925-8388(99)00677-5  

    ISSN: 0925-8388

  186. New 1/1 cubic approximant phases in the Al-Cu-Ru-Si system studied by electron diffraction and high-resolution electron microscopy Peer-reviewed

    K Saito, K Sugiyama, K Hiraga

    PHILOSOPHICAL MAGAZINE LETTERS 80 (2) 73-78 2000/02

    DOI: 10.1080/095008300176326  

    ISSN: 0950-0839

  187. [Al12P13O52]3-[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity Peer-reviewed

    W. Yan, J. Yu, R. Xu, G. Zhu, F. Xiao, Y. Han, K. Sugiyama, O. Terasaki

    Chemistry of Materials 12 (9) 2517-2519 2000

    DOI: 10.1021/cm000280h  

    ISSN: 0897-4756

  188. Strain affected properties of icosahedral Al-Pd-Mn single ingot Peer-reviewed

    Yoshihiko Yokoyama, Yoshihiro Yamada, Kenzo Fukaura, Hisakichi Sunada, Ryunosuke Note, Akihisa Inoue, Kazumasa Sugiyama, Kenji Hiraga

    Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers 38 (3) 1495-1499 1999/12/01

    Publisher: The Japan Society of Applied Physics

    DOI: 10.1143/JJAP.38.1495  

    ISSN: 0021-4922

  189. Formation of a new layered aluminophosphate [Al<inf>3</inf>P<inf>4</inf>O<inf>16</inf>] [C<inf>5</inf>N<inf>2</inf>H<inf>9</inf>]<inf>2</inf>[NH<inf>4</inf>] Peer-reviewed

    J. Yu, J. Li, K. Sugiyama, N. Togashi, O. Terasaki, K. Hiraga, B. Zhou, S. Qiu, R. Xu

    Chemistry of Materials 11 (7) 1727-1732 1999/12/01

    DOI: 10.1021/cm981095v  

    ISSN: 0897-4756

  190. A one-dimensionally extended chain aluminophosphate Peer-reviewed

    K Sugiyama, K Hiraga, JH Yu, S Zheng, SL Qiu, RR Xu, O Terasaki

    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 55 1615-1617 1999/10

    DOI: 10.1107/S0108270199000360  

    ISSN: 0108-2701

  191. Crystal structure of μ7-MgZnSm Peer-reviewed

    Kazumasa Sugiyama, Kenichi Yasuda, Yasuyoshi Horikawa, Tetsu Ohsuna, Kenji Hiraga

    Journal of Alloys and Compounds 285 (1-2) 172-178 1999/06/30

    Publisher: Elsevier Sequoia SA

    DOI: 10.1016/S0925-8388(98)01048-2  

    ISSN: 0925-8388

  192. Partial Structural Functions of Molten AgBr Estimated from the Anomalous X-Ray Scattering Data Coupled with Neutron diffraction Peer-reviewed

    SAITO Masatoshi, KANG Shinchul, SUGIYAMA Kazumasa, WASEDA Yoshio

    Journal of the Physical Society of Japan 68 (6) 1932-1938 1999/06/15

    Publisher: The Physical Society of Japan (JPS)

    DOI: 10.1143/JPSJ.68.1932  

    ISSN: 0031-9015

  193. On the crystal chemistry of the first lead zinc silicon tellurium oxyde PbZn4SiTeO10 Peer-reviewed

    B Wedel, K Sugiyama, K Hiraga, K Itagaki

    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 54 (4) 469-472 1999/04

    ISSN: 0932-0776

  194. EXAFS- and XANES-like spectra obtained by x-ray-excited scanning tunneling microscope tip current measurement Peer-reviewed

    K Tsuji, K Wagatsuma, K Sugiyama, K Hiraga, Y Waseda

    SURFACE AND INTERFACE ANALYSIS 27 (3) 132-135 1999/03

    DOI: 10.1002/(SICI)1096-9918(199903)27:3<132::AID-SIA491>3.0.CO;2-D  

    ISSN: 0142-2421

    eISSN: 1096-9918

  195. Monoclinic InPO4 center dot 2H(2)O Peer-reviewed

    K Sugiyama, JH Yu, K Hiraga, O Terasaki

    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 55 279-281 1999/03

    DOI: 10.1107/S010827019801292X  

    ISSN: 0108-2701

  196. Crystal structure of sodium iron aluminium tellurate, a new tellurium compound with garnet structure, Na-3(Fe,Al)(3)Te2O12 Peer-reviewed

    B Wedel, K Sugiyama

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES 214 (2) 151-152 1999

    DOI: 10.1515/ncrs-1999-0206  

    ISSN: 1433-7266

  197. On a lead nickel manganese tellurium oxide PbMn2Ni6Te3O18 containing Mn2+ in trigonal prismatic oxygen coordination Peer-reviewed

    B. Wedel, K. Sugiyama, K. Hiraga, K. Itagaki

    Materials Research Bulletin 34 (14) 2193-2199 1999

    Publisher: Elsevier Science Ltd

    DOI: 10.1016/S0025-5408(99)00231-7  

    ISSN: 0025-5408

  198. A New X-ray Guinier-type Diffractometer in the Transmission Mode with Asymmetrical Curved Monochromator and its Application to the Structural Analysis of Amorphous Metarials Peer-reviewed

    Saito Masatoshi, Sugiyama Kazumasa, Waseda Yoshio

    Bulletin of the Institute for Advanced Materials Processing, Tohoku University 54 (1) 49-60 1998/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

  199. Synthesis and structure of a 2-D-aluminophosphate Al3P4O16 center dot 3CH(3)CH(2)CH(2)NH(3) Peer-reviewed

    N Togashi, J Yu, S Zheng, K Sugiyama, K Hiraga, O Terasaki, W Yan, S Qiu, R Xu

    JOURNAL OF MATERIALS CHEMISTRY 8 (12) 2827-2830 1998/12

    DOI: 10.1039/a805423a  

    ISSN: 0959-9428

  200. Synthesis and characterization of a new two-dimensional aluminophosphate layer and structural diversity in anionic aluminophosphates with Al2P3O123- stoichiometry Peer-reviewed

    J Yu, K Sugiyama, K Hiraga, N Togashi, O Terasaki, Y Tanaka, S Nakata, S Qiu, R Xu

    CHEMISTRY OF MATERIALS 10 (11) 3636-3642 1998/11

    DOI: 10.1021/cm980379c  

    ISSN: 0897-4756

  201. Structural study of molten albite (NaAlSi3O8) by the high temperature energy dispersive X-ray diffraction (EDXD) method Peer-reviewed

    K Sugiyama, T Shinkai, Y Waseda

    HIGH TEMPERATURE MATERIALS AND PROCESSES 17 (3) 155-161 1998/07

    DOI: 10.1515/HTMP.1998.17.3.155  

    ISSN: 0334-6455

  202. Connection of (TeO6)(6) and (TeO6)(3)(NiO6)(3) hexagons by TeNiO9 octahedra double in Pb3Ni4.5Te2.5O15 Peer-reviewed

    B Wedel, K Sugiyama, H Muller-Buschbaum

    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 53 (5-6) 527-531 1998/05

    ISSN: 0932-0776

  203. Al16P20O80H4.4C(6)H(18)N(2): A new microporous aluminophosphate containing intersecting 12- and 8-membered ring channels Peer-reviewed

    J Yu, K Sugiyama, S Zheng, S Qiu, J Chen, R Xu, Y Sakamoto, O Terasaki, K Hiraga, M Light, MB Hursthouse, JM Thomas

    CHEMISTRY OF MATERIALS 10 (5) 1208-1211 1998/05

    ISSN: 0897-4756

  204. A large dodecahedral cluster containing about 480 atoms in a 2/1 cubic crystalline approximant Peer-reviewed

    K Hiraga, T Ohsuna, K Sugiyama

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN 67 (5) 1501-1504 1998/05

    DOI: 10.1143/JPSJ.67.1501  

    ISSN: 0031-9015

  205. Re-refinement of alpha-(AlMnSi) Peer-reviewed

    K Sugiyama, N Kaji, K Hiraga

    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 54 445-447 1998/04

    DOI: 10.1107/S0108270197015989  

    ISSN: 0108-2701

  206. Crystal structure of a cubic Al70Pd23Mn6Si; a 2/1 rational approximant of an icosahedral phase Peer-reviewed

    K. Sugiyama, N. Kaji, K. Hiraga, T. Ishimasa

    Zeitschrift fur Kristallographie - New Crystal Structures 213 (2) 90-95 1998/04/01

    DOI: 10.1524/zkri.1998.213.2.90  

    ISSN: 1433-7266

  207. Crystal structure of a cubic Al67Pd11Mn14Si7; a new 1/1 rational approximant for the Al-Pd-Mn icosahedral phase Peer-reviewed

    K. Sugiyama, N. Kaji, K. Hiraga, T. Ishimasa

    Zeitschrift fur Kristallographie - New Crystal Structures 213 (3) 168-173 1998/04/01

    DOI: 10.1524/zkri.1998.213.3.168  

    ISSN: 1433-7266

  208. The structures of hexagonal phases in Mg-Zn-RE (RE = Sm and Gd) alloys Peer-reviewed

    K Sugiyama, K Yasuda, T Ohsuna, K Hiraga

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE 213 (10) 537-543 1998

    ISSN: 0044-2968

  209. Crystal structure of a cubic Al70Pd23Mn6Si; a 2/1 rational approximant of an icosahedral phase Peer-reviewed

    K Sugiyama, N Kaji, K Hiraga, T Ishimasa

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE 213 (2) 90-95 1998

    ISSN: 0044-2968

  210. Crystal structure of a cubic Al67Pd11Mn14Si7; a new 1/1 rational approximant for the Al-Pd-Mn icosahedral phase Peer-reviewed

    K Sugiyama, N Kaji, K Hiraga, T Ishimasa

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE 213 (3) 168-173 1998

    ISSN: 0044-2968

  211. On the structure of the Al4Cr epsilon phase and its relation to the Al-Cr-Ni kappa phase Peer-reviewed

    XZ Li, HX Sui, KH Kuo, K Sugiyama, K Hiraga

    JOURNAL OF ALLOYS AND COMPOUNDS 264 (1-2) L9-L12 1998/01

    ISSN: 0925-8388

  212. Atom cluster arrangements in cubic approximant phases of icosahedral quasicrystals Peer-reviewed

    Kenji Hiraga, Kazumasa Sugiyama, Tetsu Ohsuna

    Philosophical Magazine A: Physics of Condensed Matter, Structure, Defects and Mechanical Properties 78 (5) 1051-1064 1998

    DOI: 10.1080/01418619808239973  

    ISSN: 0141-8610

  213. The structures of hexagonal phases in Mg-Zn-RE (RE = Sm and Gd) alloys Peer-reviewed

    K. Sugiyama, K. Yasuda, T. Ohsuna, K. Hiraga

    Zeitschrift fur Kristallographie - New Crystal Structures 213 (10) 537-543 1998/01/01

    DOI: 10.1524/zkri.1998.213.10.537  

    ISSN: 1433-7266

  214. The crystal stucture of a γ-(Al-Cu-Ru-Si) cubic phase: A new approximant phase for the Al-Cu-Ru icosahedral quasicrystal Peer-reviewed

    Kazumasa Sugiyama, Takeshi Kato, Kaichi Saito, Kenji Hiraga

    Philosophical Magazine Letters 77 (3) 165-171 1998

    DOI: 10.1080/095008398178615  

    ISSN: 1362-3036 0950-0839

  215. F-type icosahedral phase and a related cubic phase in the Al-Rh-Cu system Peer-reviewed

    X. Z. Li, K. T. Park, K. Sugiyama, K. Hiraga

    Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science 29 (6) 1559-1563 1998

    Publisher: Minerals, Metals and Materials Society

    DOI: 10.1007/s11661-998-0078-1  

    ISSN: 1073-5623

  216. An Atom Cluster Model of F-Type Icosahedral Quasicrystals, Derived from the Structure of 1/1 Cubic Approximant Phase (α-(AIPdMnSi)) Peer-reviewed

    HIRAGA Kenji, OHSUNA Tetsu, SUGIYAMA Kazumasa

    Journal of the Physical Society of Japan 66 (12) 3700-3702 1997/12/15

    Publisher: The Physical Society of Japan (JPS)

    DOI: 10.1143/JPSJ.66.3700  

    ISSN: 0031-9015

  217. Structural study of amorphous Pd<inf>41</inf>Ni<inf>41</inf>Si<inf>18</inf> alloy associated with structural relaxation by anomalous X-ray scattering Peer-reviewed

    O. Haruyama, K. Sugiyama, S. Kumazawa, Y. Waseda

    Journal of Materials Science Letters 16 1157-1160 1997/12/01

    ISSN: 0261-8028

  218. Partial Structural Functions of Liquid Bi_<30>Ga_<70> Alloy Estimated from the Anomalous X-Ray Scattering Measurement in Asymmetrical Reflection Geometry with Synchrotron Radiation Peer-reviewed

    SAITO Masatoshi, PARK Changyong, SUGIYAMA Kazumasa, WASEDA Yoshio

    Journal of the Physical Society of Japan 66 (10) 3120-3126 1997/10/15

    Publisher: The Physical Society of Japan (JPS)

    DOI: 10.1143/JPSJ.66.3120  

    ISSN: 0031-9015

  219. Crystal growth and structural characterization of new piezoelectric material La3Ta0.5Ga5.5O14 Peer-reviewed

    H Takeda, K Sugiyama, K Inaba, K Shimamura, T Fukuda

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS 36 (7B) L919-L921 1997/07

    DOI: 10.1143/jjap.36.L919  

  220. partial Structural Functions of Molten CuBr Estimated from the Anomalous X-Ray Scattering Measurements Peer-reviewed

    SAITO Masatoshi, PARK Changyong, OMOTE Kazuhiko, SUGIYAMA Kazumasa, WASEDA Yoshio

    Journal of the Physical Society of Japan 66 (3) 633-640 1997/03/15

    Publisher: The Physical Society of Japan (JPS)

    DOI: 10.1143/JPSJ.66.633  

    ISSN: 0031-9015

  221. Crystal structure of orthorhombic epsilon-Al4Cr Peer-reviewed

    XZ Li, K Sugiyama, K Hiraga, A Sato, A Yamamoto, HX Sui, KH Kuo

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE 212 (9) 628-633 1997

    ISSN: 0044-2968

  222. STRUCTURE OF A 2/1 CUBIC APPROXIMANT IN THE AL-PD-MN-SI SYSTEM Invited Peer-reviewed

    K. SUGIYAMA, N. KAJI, K. YUBUTA, K. HIRAGA AND T, ISHIMASA

    Proceeding of the 6th International Conference on Quasicrystals 199 1997

  223. STRUCTURE OF AN Al-Pd-Co CRYSTALLINE APPROXIMANT WITH NON-CENTRALSYMMETRY Peer-reviewed

    K. YUBUTA, K. SUGIYAMA, AND K, HIRAGA

    Proceeding of the 6th International Conference on Quasicrystals 235 1997

  224. The structure of an Al3Mn-type Al3(Mn, Pd) crystal studied by single-crystal X-ray diffraction analysis Peer-reviewed

    Y. Matsuo, M. Kaneko, T. Yamanoi, N. Kaji, K. Sugiyama, K. Hiraga

    Philosophical Magazine Letters 76 (5) 357-362 1997

    DOI: 10.1080/095008397178968  

    ISSN: 1362-3036 0950-0839

  225. Crystal structure of orthorhombic ε-Al<inf>4</inf>Cr

    X. Z. Li, K. Sugiyama, K. Hiraga, A. Sato, A. Yamamoto, H. X. Sui, K. H. Kuo

    Zeitschrift fur Kristallographie - New Crystal Structures 212 628-633 1997/01/01

    DOI: 10.1524/zkri.1997.212.9.628  

    ISSN: 1433-7266

  226. Crystal growth and structural characterization of new piezoelectric material La<inf>3</inf>Ta<inf>0.5</inf>Ga<inf>5.5</inf>O<inf>14</inf>

    Hiroaki Takeda, Kazumasa Sugiyama, Katsuhiko Inaba, Kiyoshi Shimamura, Tsuguo Fukuda

    Japanese Journal of Applied Physics, Part 2: Letters 36 1997/01/01

    ISSN: 0021-4922

  227. Enhancement of acid extraction of magnesium and silicon from serpentine by mechanochemical treatment Peer-reviewed

    Qiwu Zhang, Kazumasa Sugiyama, Fumio Saito

    Hydrometallurgy 45 (3) 323-331 1997

    Publisher: Elsevier

    DOI: 10.1016/S0304-386X(96)00087-4  

    ISSN: 0304-386X

  228. Energy-dispersive X-ray diffraction (EDXD) technique for structural studies of disordered materials. Application to SiO2, SrP2O6, Pd80Si20, Fe40Ni40P14B6 glasses and liquid Hg Peer-reviewed

    K Sugiyama, VP Petkov, AS Takeda

    HIGH TEMPERATURE MATERIALS AND PROCESSES 16 (1) 49-56 1997/01

    DOI: 10.1515/HTMP.1997.16.1.49  

    ISSN: 0334-6455

  229. Correlation between Changes of the Chemical State and Preferential Sputtering in the Surface of Fe2O3, NiFe2O4 and ZnFe2O4 by Argon Ion Bombardment Peer-reviewed

    Shigeru Suzuki, Kazumasa Sugiyama, Hirobumi Inoue, Yoshio Waseda

    Bulletin of the Institute for Advanced Materials Processing, Tohoku University 52 (1) 74-80 1996/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

  230. 遊星ミルによるドロマイトの粉砕に及ぼす水分の影響 Peer-reviewed

    板橋 大介, 葛西 栄輝, 杉山 和正

    石灰石 (284) 23-27 1996/11

    Publisher: 石灰石鉱業協会

    ISSN: 0287-3761

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    資料形態 : テキストデータ プレーンテキスト

  231. Structure and dynamical properties of molten V2O5 Peer-reviewed

    S Takeda, Y Kawakita, M Inui, K Maruyama, S Tamaki, K Sugiyama, Y Waseda

    JOURNAL OF NON-CRYSTALLINE SOLIDS 205 151-154 1996/10

    DOI: 10.1016/S0022-3093(96)00434-6  

    ISSN: 0022-3093

  232. New ADXD/EDXD spectrometer for determining the structure of melts at high temperature Peer-reviewed

    K Sugiyama, T Shinkai, Y Waseda

    SCIENCE REPORTS OF THE RESEARCH INSTITUTES TOHOKU UNIVERSITY SERIES A-PHYSICS CHEMISTRY AND METALLURGY 42 (1) 231-237 1996/03

    ISSN: 0040-8808

  233. Determination of Cation Distribution in ZnFe2O4, NiFe2O4 and NiAl2O4 Spinels by An In-house Anomalous X-ray Scattering Method Peer-reviewed

    K. Shinoda, K. Sugiyama, K. Omote, Y. Waseda

    International Journal of the Society of Materials Engineering for Resources 4 (1) 20-29 1996

    DOI: 10.5188/ijsmer.4.20  

    ISSN: 1884-6629 1347-9725

  234. Extraction of Magnesium from Mechanochemically Activated Talc by Acid Leaching. Peer-reviewed

    SANCHEZ Ezequiel Cruz, SUGIYAMA Kazumasa, SAITO Fumio

    Shigen-to-Sozai 112 (10) 719-722 1996

    Publisher: The Mining and Materials Processing Institute of Japan

    DOI: 10.2473/shigentosozai.112.719  

    ISSN: 0916-1740

    eISSN: 1880-6244

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    Extraction of magnesium from the mechanochemically activated talc samples was conducted at 298 K and 333 K using 0.5mol/dm3 H2SO4 or 0.5mol/dm3 HCl solutions. Talc is transformed from crystalline state into disordered one by dry grinding within about 30 minutes in a planetary ball mill. The structural change is accelerated by the prolonged grinding. This structural change means that the environmental structure around magnesium in the talc crystalline is drastically changed by grinding, while silicon tetrahedra remain unchanged. Therefore, the disordering of the structure leads to an easy magnesium extraction and preferentially by the acid solutions. 30 minutes leaching is enough time to extract magnesium from the talc samples. The magnesium yield is significantly increased to about 40% as the grinding progresses up to 30 minutes. Leaching of the 180 minutes ground sample using the H2SO4 and HCl solutions of 298 K enables us to extract magnesium at about 70% and 63%, respectively. On the contrary, the yield of silicon is supressed below about 3%.

  235. Chemical Analysis of Copper and Gold Ores from Papua New Guinea (PNG) by means of X-ray Fluorescence Analysis Peer-reviewed

    Kazumasa SUGIYAMA, PANGUM Lemas S., Witney John Y., WASEDA Yoshio

    Bulletin of the Institute for Advanced Materials Processing, Tohoku University 51 (1) 63-70 1995/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

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    X-ray fluorescence analysis (XRF) has been made for determining the contents of copper and gold in ores from PNG mines. An internal standard method of Cu K α/Er L β_1 was used for the analysis of the common copper porphyry samples. The results clearly indicate that this technique is quite effective for analyzing any copper ores with complicated matrix elements. On the other hand, an addition method of the diluted Au solution was applied to gold ores. The results of the present XRF analysis were found to reasonably agree with those obtained by the inductively coupled plasma (ICP) technique.X-ray fluorescence analysiscopper oregold oreinternal standard methodaddition method

  236. Phase Transformation of Calcite by Grinding Peer-reviewed

    Armando H. SHINOHARA, SUGIYAMA Kazumasa, SAITO Fumio, WASEDA Yoshio

    Bulletin of the Institute for Advanced Materials Processing, Tohoku University 51 (1) 71-79 1995/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

  237. Cation distribution of ZnFe2O4 and CoFe2O4 spinels from anomalous X-ray scattering Peer-reviewed

    Y Waseda, K Shinoda, K Sugiyama

    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 50 (12) 1199-1204 1995/12

    DOI: 10.1515/zna-1995-1226  

    ISSN: 0932-0784

  238. Distribution Coefficient of Rare-Earth Active Ions in Calcium Niobium Gallium Garnet Peer-reviewed

    SHIMAMURA Kiyoshi, SUGIYAMA Kazumasa, UDA Satoshi, FUKUDA Tsuguo

    Japanese journal of applied physics. Pt. 1, Regular papers & short notes 34 (9) 4894-4897 1995/09/01

    Publisher: The Japan Society of Applied Physics

    DOI: 10.1143/JJAP.34.4894  

    ISSN: 0021-4922

  239. DIRECT DETERMINATION OF THE LOCAL-STRUCTURE IN MOLTEN ALUMINA BY HIGH-TEMPERATURE X-RAY-DIFFRACTION Peer-reviewed

    Y WASEDA, K SUGIYAMA, JM TOGURI

    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 50 (8) 770-774 1995/08

    DOI: 10.1515/zna-1995-0809  

    ISSN: 0932-0784

  240. STRUCTURAL STUDY OF LIQUID V2O5 Peer-reviewed

    S TAKEDA, M INUI, Y KAWAKITA, K MARUYAMA, S TAMAKI, K SUGIYAMA, Y WASEDA

    PHYSICA B 213 499-501 1995/08

    DOI: 10.1016/0921-4526(95)00192-C  

    ISSN: 0921-4526

  241. High Temperature X-Ray Diffraction Study of Melt Structure of Silicon Peer-reviewed

    WASEDA Yoshio, SHINODA Kozo, SUGIYAMA Kazumasa, TAKEDA Susumu, TERASHIMA Kazutaka, TOGURI James Makoto

    Japanese Journal of Applied Physics 34 (8) 4124-4128 1995/08/01

    DOI: 10.1143/JJAP.34.4124  

    ISSN: 0021-4922

  242. EFFECT OF GRINDING OF THE STARTING MATERIAL ON HYDROTHERMAL SYNTHESIS OF KAOLINITE Peer-reviewed

    MIYAWAKI Ritsuro, TOMURA Shinji, OKAZAKI Masaharu, SATOKAWA Shigeo, SUGIYAMA Kazumasa

    Clay Sci. 9 (4) 199-217 1995/06

    Publisher: The Clay Science Society of Japan

    ISSN: 0009-8574

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    It has been found that initial grinding of starting materials is effective in promoting reactivity in the synthesis of kaolinite. A mixture of amorphous silica and aluminum hydroxide with a Si/Al atomic ration of 1.0 was ground and then used as the starting material for hydrothermal synthesis. The starting material was placed in a Teflon reaction vessel together with distilled water, and kept at 220℃. The characterization of the starting materials and products was carried out with XRD, IR, DTA-TG, ^<29>Si-and ^<27>Al-MAS/NMR, and TEM. The starting material which had been ground for 200 h was an amorphous aluminosilicate with four-and sixcoordinated Al. Kaolinite could be obtained from this well-ground starting material in a relatively short reaction time in comparison to mixtures not subjected to the pre-grinding process. In the latter case, bayerite was changed into bohmite, and was then converted to well crystallized kaolinite with euhedral morphology of the hexagonal plate. The differences in the local structures of the starting material around the Si, Al atoms, and OH groups, which had been brought about by the mechanochemical reaction during the grinding, are likely to have an influence on formation of kaolinite.

  243. X-RAY-DIFFRACTION STUDY ON THE STRUCTURE OF LIQUID LI2O-B2O3 Peer-reviewed

    K SUGIYAMA, K NOMURA, S KIMURA

    HIGH TEMPERATURE MATERIALS AND PROCESSES 14 (2) 131-136 1995/04

    DOI: 10.1515/HTMP.1995.14.2.131  

    ISSN: 0334-6455

  244. An Improved X-ray Structural Analysis for Determining Cation Distribution in ZnFe2O4 and ZnFe2O4-Fe3O4 Solid Solutions. Peer-reviewed

    SHINODA Kozo, SUGIYAMA Kazumasa, REYNALES Cecilia, WASEDA Yoshio, Thomas JACOB K.

    Shigen-to-Sozai 111 (11) 801-806 1995

    Publisher: The Mining and Materials Processing Institute of Japan

    DOI: 10.2473/shigentosozai.111.801  

    ISSN: 0916-1740

    eISSN: 1880-6244

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    The distribution of zinc cation between crystallographically nonequivalent positions in ZnFe204 has been determined by anomalous X-ray scattering near the Zn K absorption edge. Measured intensity ratio with two energies close to the edge can be quantitatively explained only by assigning all zinc cations to the tetrahedral position in the approximately cubic close packed array of oxygen ions. A similar conclusion has also been reached for ZnxFe3-xO4 solid solutions with x=0.73, 0.54 and 0.35 employing the improved X-ray method. This is consistent with the EXAFS results which indicate an almost unchanged environmental structure around zinc cation in these solid solutions.

  245. Anomalous X-ray Scattering Study of Local Structures in the Superionic Conducting Glass (CuI)0.3(Cu2O)0.35(MoO3)0.35 Peer-reviewed

    Masatoshi Saito, Kazumasa Sugiyama, Eiichiro Matsubara, K. Thomas Jacob, Yoshio Waseda

    Materials Transactions, JIM 36 (12) 1434-1439 1995

    DOI: 10.2320/matertrans1989.36.1434  

    ISSN: 0916-1821

  246. Structural analysis of amorphous ZrYAlNi alloy by anomalous X-ray scattering Peer-reviewed

    Kazumasa Sugiyama, Armando H Shinohara, Yoshio Waseda, Akihisa Inoue

    Journal of Non-Crystalline Solids 192-193 376-379 1995

    DOI: 10.1016/0022-3093(95)00447-5  

    ISSN: 0022-3093

  247. Anomalous Scattering Factors near the Zn K Absorption Edge Estimated from the Absorption Coefficient Measurement of ZnFe2O4 Peer-reviewed

    K. Shinoda, K. Sugiyama, Y. Waseda

    High Temperature Materials and Processes 14 (2) 75-80 1995/01/01

    Publisher: Walter de Gruyter GmbH

    DOI: 10.1515/HTMP.1995.14.2.75  

    ISSN: 0334-6455

    eISSN: 2191-0324

  248. Structural Characterization of Oxide Materials by the Anomalous X-ray Scattering Method (Commemoration Issue Dedicated to Professor Sumio Sakka On the Occasion of His Retirement) Peer-reviewed

    Waseda, Yoshio, Sugiyama, Kazumasa

    Bulletin of the Institute for Chemical Research, Kyoto University 72 (2) 286-304 1994/10/31

    Publisher: Institute for Chemical Research, Kyoto University

    ISSN: 0023-6071

  249. Study on dry grinding of gibbsite (hydrargillite) Peer-reviewed

    SUGIYAMA Kazumasa, SHINOHARA Hideki, SAITO Fumio, WASEDA Yoshio

    Mineralogical Journal 17 (3) 101-110 1994/07/01

    Publisher: Japan Association of Mineralogical Sciences

    DOI: 10.2465/minerj.17.101  

    ISSN: 0544-2540

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    The structural change of gibbsite induced by dry grinding has been investigated by means of BET analysis, SEM observation, XRD, MAS/NMR spectroscopy and TG-DTA. The crystalline structure of gibbsite changes into a disordered one with the progress of grinding and subsequent RDF analysis of ground gibbsite samples suggests the structural variation in the local atomic arrangement around aluminum. MAS/NMR measurement also supports this change and indicates the formation of a tetra- and penta-coordinated aluminum at the expense of parent octahedral ones. Low temperature dehydroxylation reaction and new exothermic peaks at about 800 and 1000&deg;C of ground samples were detected in TG-DTA.

  250. Neutron Diffraction Study on Molten Salt Mixtures; CuCl–CuBr and AgBr–AgI Systems Peer-reviewed

    Shirakawa Yoshiyuki, Tamaki Shigeru, Usuki Takeshi, Sugiyama Kazumasa, Waseda Yoshio

    J Phys Soc Jpn 63 (5) 1814-1820 1994/05/15

    Publisher: The Physical Society of Japan (JPS)

    DOI: 10.1143/JPSJ.63.1814  

    ISSN: 0031-9015

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    Neutron diffraction experiments have been carried out for moltenCuCl–CuBr and AgBr–AgI systems along their liquidus curves.For molten CuCl–CuBr mixtures, the contraction of the interionicdistance has been found. The concentration dependence of theresult is consistent with that found in the magnetic susceptibilitiesfor this system. Molten AgBr–AgI mixture shows an expansion ofthe interionic distance in their concentration dependence.

  251. STRUCTURAL STUDY OF ZR33Y27AL15NI25 AMORPHOUS-ALLOYS BY ANOMALOUS X-RAY-SCATTERING (AXS) Peer-reviewed

    E MATSUBARA, K SUGIYAMA, AH SHINOHARA, Y WASEDA, A INOUE, T ZHANG, T MASUMOTO

    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING 179 444-447 1994/05

    DOI: 10.1016/0921-5093(94)90243-7  

    ISSN: 0921-5093

  252. STRUCTURAL STUDY OF MOLTEN GERMANIUM BY ENERGY-DISPERSIVE X-RAY-DIFFRACTION Peer-reviewed

    PETKOV, V, S TAKEDA, Y WASEDA, K SUGIYAMA

    JOURNAL OF NON-CRYSTALLINE SOLIDS 168 (1-2) 97-105 1994/02

    DOI: 10.1016/0022-3093(94)90124-4  

    ISSN: 0022-3093

    eISSN: 1873-4812

  253. Structural change of kaolinite and pyrophyllite induced by dry grinding Peer-reviewed

    SUGIYAMA Kazumasa, FILIO James M., SAITO Fumio, WASEDA Yoshio

    Journal of Mineralogical and Petrological Sciences 17 (1) 28-41 1994/01/01

    Publisher: Japan Association of Mineralogical Sciences

    DOI: 10.2465/minerj.17.28  

    ISSN: 0544-2540

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    The structural analysis of ground kaolinite and pyrophyllite prepared by dry grinding with the different periods has been made by determining the radial distribution functions from X-ray diffraction data. The SiO4 tetrahedra remain unchanged in either sample of ground kaolinite and pyrophyllite. Whereas, the increment of grinding time has been found to induce the decrease of oxygen coordination number and the corresponding interatomic distance around aluminum.

  254. STRUCTURAL-ANALYSIS OF 70GEO230BI2O3 GLASS BY X-RAY-DIFFRACTION Peer-reviewed

    Y WASEDA, K SUGIYAMA, Y SUNAMORI, K OMOTE, M ASHIZUKA

    SCIENCE REPORTS OF THE RESEARCH INSTITUTES TOHOKU UNIVERSITY SERIES A-PHYSICS CHEMISTRY AND METALLURGY 39 (2) 175-182 1994/01

    ISSN: 0040-8808

  255. Hydrothermal Synthesis of Kaolinite from Water Quenched Blast Furnace Slag. Peer-reviewed

    MIYAWAKI Ritsuro, TOMURA Shinji, INUKAI Keiichi, OKAZAKI Masaharu, KONISHI Yoshinari, SUGIYAMA Kazumasa, SATOKAWA Shigeo

    Journal of the Clay Science Society of Japan (in Japanese) 34 (1) 11-21 1994

    Publisher: The Clay Science Society of Japan

    DOI: 10.11362/jcssjnendokagaku1961.34.11  

    ISSN: 0470-6455

    eISSN: 2186-3563

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    Water quenched blast furnace slag was examined as raw material for the hydrothermal synthesis of kaolinite at 220&deg;C. Kaolinite could not be obtained from the raw slag with a lower polycondensation state of unhydrated silica nor from the annealed slag with gehienite-structure. The HCl-treatment of the slag successively makes hydration and polycondensation of the silica so as to form a silica-gel consisting of hydrated silanol and unhydrated silica. The obtained silica-gel reacts with aluminum hydroxide under the hydrothermal condition to form kaolinite with b&ouml;hmite. The uses of acidic solutions as the hydrothermal liquids can improve the formation of kaolinite. Spherical kaolinite was dominantly formed with the reaction in the H2SO4-solution, whereas platy kaolinite was crystallized in the HNO3-solution.

  256. Small angle x-ray scattering study for determining the particle size of colloidal materials Peer-reviewed

    Armando H. Shinohara, Kazumasa Sugiyama, Daisuke Shindo

    High Temperature Materials and Processes 13 (2) 133-140 1994

    DOI: 10.1515/HTMP.1994.13.2.133  

    ISSN: 2191-0324 0334-6455

  257. MECHANOCHEMICAL CHANGES IN NATURAL AND SYNTHETIC ZEOLITES BY DRY GRINDING USING A PLANETARY BALL MILL Peer-reviewed

    E KASAI, H MIMURA, K SUGIYAMA, F SAITO, K AKIBA, Y WASEDA

    ADVANCED POWDER TECHNOLOGY 5 (2) 189-203 1994

    DOI: 10.1016/S0921-8831(08)60614-7  

    ISSN: 0921-8831

  258. Effect of Water Content on Grindability of Dolomite and Its Structural Change Peer-reviewed

    Daisuke Itabashi, Kazumasa Sugiyama, Eiki Kasai, Fumio Saitc

    Journal of Chemical Engineering of Japan 27 (3) 279-283 1994

    DOI: 10.1252/jcej.27.279  

    ISSN: 0021-9592

  259. A study on talc ground by tumbling and planetary ball mills Peer-reviewed

    James M. Filio, Kazumasa Sugiyama, Fumio Saito, Yoshio Waseda

    Powder Technology 78 (2) 121-127 1994

    DOI: 10.1016/0032-5910(93)02775-6  

    ISSN: 0032-5910

  260. Anomalous Saxs Study on Structural Inhomogeneity in Amorphous Zr33Y27Ali5Ni25Alloy Peer-reviewed

    K. Sugiyama, A. H. Shinohara, Y. Waseda

    Materials Transactions, JIM 35 (7) 481-484 1994

    DOI: 10.2320/matertrans1989.35.481  

    ISSN: 0916-1821

  261. <Review Article>New Energy Dispersive X-ray Diffraction Facility for Structural Characterization of Disordered Materials Peer-reviewed

    Kazumasa SUGIYAMA, Yasutada SUNAMORI, Yoshio WASEDA

    Bulletin of the Institute for Advanced Materials Processing, Tohoku University 49 (1) p110-118 1993/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

  262. SYNTHESIS AND SEARCH FOR EQUILIBRIUM COMPOSITIONS OF BORATES WITH THE HUNTITE STRUCTURE Peer-reviewed

    CHANI, VI, K SHIMAMURA, K INOUE, T FUKUDA, K SUGIYAMA

    JOURNAL OF CRYSTAL GROWTH 132 (1-2) 173-178 1993/09

    DOI: 10.1016/0022-0248(93)90259-Y  

    ISSN: 0022-0248

  263. SEGREGATION COEFFICIENTS IN BETA-GA2O2CR CRYSTALS GROWN FROM A B2O3 BASED FLUX Peer-reviewed

    CHANI, VI, K INOUE, K SHIMAMURA, K SUGIYAMA, T FUKUDA

    JOURNAL OF CRYSTAL GROWTH 132 (1-2) 335-336 1993/09

    DOI: 10.1016/0022-0248(93)90278-5  

    ISSN: 0022-0248

  264. ENERGY-DISPERSIVE X-RAY-DIFFRACTION (EDXD) APPARATUS FOR LIQUIDS AT HIGH-TEMPERATURE Peer-reviewed

    K SUGIYAMA, VG PETKOV, S TAKEDA, Y WASEDA

    SCIENCE REPORTS OF THE RESEARCH INSTITUTES TOHOKU UNIVERSITY SERIES A-PHYSICS CHEMISTRY AND METALLURGY 38 (1) 1-13 1993/03

    ISSN: 0040-8808

  265. STRUCTURAL STUDY OF TIN FLUOROPHOSPHATE GLASSES BY X-RAY-DIFFRACTION Peer-reviewed

    S TAKEDA, K SUGIYAMA, Y WASEDA, K MORINAGA

    JOURNAL OF MATERIALS SCIENCE LETTERS 12 (5) 291-293 1993/03

    DOI: 10.1007/BF01910081  

    ISSN: 0261-8028

  266. The Mechano-chemical Change of Synthetic Mordenite by Dry-grinding. Changes in the Characteristics of Cation Adsorption.:Changes in the Characteristics of Cation Adsorption Peer-reviewed

    KASAI Eiki, MIMURA Hitoshi, SUGIYAMA Kazumasa, SAITO Fumio, AKIBA Kenichi, WASEDA Yoshio

    Journal of the Society of Powder Technology, Japan 30 (9) 635-640 1993

    Publisher: The Society of Powder Technology, Japan

    DOI: 10.4164/sptj.30.9_635  

    ISSN: 0386-6157

    eISSN: 1883-7239

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    The effect of dry grinding on the adsorption characteristics, e. g., distribution coefficient and saturated amount of adsorbed cations, of synthetic mordenite has been studied using a radioisotope of 137Cs+ as a tracer. The grinding operation for different periods of time, i. e., 15 to 360min, was carried out using a planetary ball mill.<br>The grinding operation had no effect on the distribution coefficient onto the mordenite sample at the relatively lower concentration of Cs+ in the neutral and alkaline solutions, though the coefficient significantly decreased in the acidic solutions with an increase in grinding time. The saturated amount of Cs+ adsorbed on the mordenite sample in both neutral and acidic solutions decreased markedly during the early stage of grinding. However, for more than 30 minutes of grinding, the amount of absorbed Cs+ in the neutral solution increased slightly, while in the acidic solution it gradually decreased with grinding time. These observations may be interpreted from the formation of the hydroxyl group on the fractured surface, as well as from the considerable distortion of the channel structure of mordenite induced by grinding.

  267. Effects of moisture on grinding of natural calcite by a tumbling ball mill Peer-reviewed

    Armando H. Shinohara, Kazumasa Sugiyama, Eiki Kasai, Fumio Saito, Yoshio Waseda

    Advanced Powder Technology 4 (4) 311-319 1993

    DOI: 10.1016/S0921-8831(08)60638-X  

    ISSN: 0921-8831

  268. Formation of mullite from ground product of a kaolinite-aluminum trihydroxide mixture by solid phase reaction Peer-reviewed

    Hojin Ryu, Eiki Kasai, Kazumasa Sugiyama, Fumio Saito, Yoshio Waseda, Hiromichi Ohta

    Particulate Science and Technology 11 (3-4) 157-164 1993

    DOI: 10.1080/02726359308906631  

    ISSN: 1548-0046 0272-6351

  269. Energy dispersive X-ray diffraction (EDXD) facility for determining structure of high temperature melts with a stationary specimen goniometer Peer-reviewed

    Susumu Takeda, Valery G. Petkov, Kazumasa Sugiyama, Yoshio Waseda

    Materials Transactions, JIM 34 (5) 410-414 1993

    Publisher: Publ by Japan Inst of Metals

    DOI: 10.2320/matertrans1989.34.410  

    ISSN: 0916-1821

  270. Feasibility Study for Chemical Analysis by X-ray Spectrometer Using the Fundamental Parameter Method Peer-reviewed

    K. Sugiyama, Y. Waseda, J. W. Essel

    High Temperature Materials and Processes 12 (3) 167-174 1993

    DOI: 10.1515/HTMP.1993.12.3.167  

    ISSN: 2191-0324 0334-6455

  271. Small-Angle X-Ray Scattering Study of the Structure of Mesophase Carbon Powders Peer-reviewed

    A. H. Shinohara, K. Sugiyama, Y. Waseda, H. Hatano

    High Temperature Materials and Processes 12 (4) 193-198 1993

    DOI: 10.1515/HTMP.1993.12.4.193  

    ISSN: 2191-0324 0334-6455

  272. Structural analysis of molten bismuth germanate compounds Peer-reviewed

    Susumu Takeda, Kazumasa Sugiyama, Yoshio Waseda

    Japanese Journal of Applied Physics 32 (12 R) 5633-5636 1993

    DOI: 10.1143/JJAP.32.5633  

    ISSN: 1347-4065 0021-4922

  273. Local ordering structure of meta-kaolinite and meta-dickite by the X-ray radial distribution function analysis Peer-reviewed

    K. Sugiyama, H. J. Ryu, Y. Waseda

    Journal of Materials Science 28 (10) 2783-2788 1993/01

    Publisher: Kluwer Academic Publishers

    DOI: 10.1007/BF00356219  

    ISSN: 0022-2461 1573-4803

  274. Effect of dry mixed grinding of talc, kaolinite and gibbsite on preparation of cordierite ceramics Peer-reviewed

    James M. Filio, Kazumasa Sugiyama, Eiki Kasai, Fumio Saito

    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 26 (5) 565-569 1993

    DOI: 10.1252/jcej.26.565  

    ISSN: 0021-9592

  275. Effect of Mixed Grinding of Powders On Superconducting Properties of Yba2Cu307-yCeramics Peer-reviewed

    Hojin Ryu, Kazumasa Sugiyama, Eiki Kasai, Daisuke Shindo, Fumio Saito

    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 26 (6) 627-632 1993

    DOI: 10.1252/jcej.26.627  

    ISSN: 0021-9592

  276. Diffuse Scattering of Superionic Phase of Cu2Se Peer-reviewed

    Takashi Sakuma, Fumihito Suzuki, Shoji Saitoh, Kazumasa Sugiyama, Eiichiro Matsubara, Yoshio Waseda

    Journal of the Physical Society of Japan 62 (10) 3513-3518 1993

    DOI: 10.1143/JPSJ.62.3513  

    ISSN: 1347-4073 0031-9015

  277. <Review Article>X-ray Fluorescence Analysis by using Fundamental Parameter Method Peer-reviewed

    Kazumasa SUGIYAMA, Jacob WILLIAM ESSEL, Tsuyoshi KITAMURA, Yoshio WASEDA

    Bulletin of the Institute for Advanced Materials Processing, Tohoku University 48 (1) p140-150 1992/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

  278. Kinetic study of the GeO<inf>2</inf> transition under high pressures using synchrotron x-radiation Peer-reviewed

    Takamitsu Yamanaka, Kazumasa Sugiyama, Kiyoshi Ogata

    Journal of Applied Crystallography 25 (pt 1) 11-15 1992/02/01

    DOI: 10.1107/S0021889891008750  

    ISSN: 0021-8898

  279. Work Index and Physical Properties of Slage Produced in Non-ferrous Metallurgical Processes. Peer-reviewed

    SHINOHARA Armando H., SUGIYAMA Kazumasa, SAITO Fumio, WASEDA Yoshio, TOGURI James M.

    Shigen-to-Sozai 108 (7) 525-528 1992

    Publisher: The Mining and Materials Processing Institute of Japan

    DOI: 10.2473/shigentosozai.108.525  

    ISSN: 0916-1740

    eISSN: 1880-6244

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    The slag samples from various non-ferrous metallurgical smelters have been characterized by determining Bond's work index, density and Vickers hardness coupled with X-ray powder diffraction and optical microscopic observation. Bond's work index for a slag consisting almost of glassy phase shows relatively higher index value than that of the crystalline slags and brittle minerals like quartz and feldspar, although a consistent index for zinc slag could not be obtained due to a large amount of co-existing metallic phase.<BR>The following empirical equation for crystalline brittle materials has been developed to describe the correlation between work index; Wi [kWh/t] and the product of Mohs' hardness; HM and density;ρ[Mg/m3]. Wi=0.42 (HM·ρ) +6.56<BR>This equation is suitable for the range up to 30×103 in the values of HM·ρ with corresponding correlation coefficient of 0.83. Using this equation, the work index for the brittle portion of zinc slag, which is mainly constituted of oxide and silicate minerals, was estimated to be 16 kWh/t.

  280. Quantitative X-ray Diffraction Analysis of Quartz and Anatase in Kaolin by Applying the Prolonged Grinding Technique. Peer-reviewed

    SUGIYAMA Kazumasa, RYU Hojin, SAITO Fumio, WASEDA Yoshio, MIYAWAKI Ritsuro

    Shigen-to-Sozai 108 (1) p19-23 1992/01

    Publisher: The Mining and Materials Processing Institute of Japan

    DOI: 10.2473/shigentosozai.108.19  

    ISSN: 0916-1740

    eISSN: 1880-6244

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    X-ray powder diffraction method coupled with the prolonged grinding technique has been used for analyzing quartz and anatase in several kaolin samples. Kaolin minerals easily change from crystalline state to amorphous one by the prolonged dry grinding. This contrasts to the behavior of quartz and anatase. Because of this selective feature, Bragg reflections of quartz and anatase can readily be identified in the X-ray diffraction profiles of ground kaolin samples. The internal standard method was applied to the ground kaolin samples and quantitative analysis of constituent quartz and anatase was carried out. Gibbsite is known to become amorphous state by the prolonged dry grinding. Thus, present technique was also applied to the analysis of natural bauxite samples. The results clearly indicate that the present technique is promising for the analysis of quartz and anatase in kaolin and bauxite samples by reducing the difficulties unsolved in the conventional X-ray powder diffraction method.

  281. Structural study of molten pseudo-binary B2O3{single bond}Na2O · 2SiO2 system by X-ray diffraction and molecular dynamics simulation Peer-reviewed

    Hiroshi Ogawa, Kazumasa Sugiyama, Yoshio Waseda, Yutaka Shiraishi

    Journal of Non-Crystalline Solids 143 (C) 201-206 1992

    DOI: 10.1016/S0022-3093(05)80568-X  

    ISSN: 0022-3093

  282. Refinement on the structure of geo glass by the least-squares variational method coupled with the anomalous x-Ray Scattering Data Peer-reviewed

    K. Sugiyama, E. Matsubara

    High Temperature Materials and Processes 10 (3) 177-188 1992

    DOI: 10.1515/HTMP.1992.10.3.177  

    ISSN: 2191-0324 0334-6455

  283. Novel application of anomalous small-Angle X-ray scattering to characterize inhomogeneities in materials Peer-reviewed

    A. H. Shinohara, K. Sugiyama, Y. Waseda

    High Temperature Materials and Processes 10 (3) 159-176 1992

    DOI: 10.1515/HTMP.1992.10.3.159  

    ISSN: 2191-0324 0334-6455

  284. On the Structure of Barium Borate Melt Just After Melting Peer-reviewed

    S. Takeda, S. Kimura, K. Sugiyama

    High Temperature Materials and Processes 10 (4) 209-214 1992

    DOI: 10.1515/HTMP.1992.10.4.209  

    ISSN: 2191-0324 0334-6455

  285. <Technical Note>Advanced Structural Analyses of Non-Crystalline Materials by Anomalous X-ray Scattering (AXS) Method Peer-reviewed

    Kazumasa SUGIYAMA, Eiichiro MATSUBARA, Yoshio WASEDA

    Bulletin of the Research Institute of Mineral Dressing and Metallurgy, Tohoku University 47 (1) p145-153 1991/12

    Publisher: 東北大學選鉱製錬研究所

    ISSN: 0040-876X

  286. X-RAY-DIFFRACTION STUDY OF GROUND TALC MG3SI4O10(OH)2 Peer-reviewed

    K SUGIYAMA, PF JAMES, F SAITO, Y WASEDA

    JOURNAL OF MATERIALS SCIENCE 26 (19) 5297-5300 1991/10

    DOI: 10.1007/BF01143224  

    ISSN: 0022-2461

  287. Dry Fine Grinding of Granulated Blast Furnace Slag Quenched by Water and its Reactivity during Grinding. Peer-reviewed

    FILIO James M., SUGIYAMA Kazumasa, SAITO Fumio, WASEDA Yoshio

    Shigen-to-Sozai 107 (11) 795-799 1991

    Publisher: The Mining and Materials Processing Institute of Japan

    DOI: 10.2473/shigentosozai.107.795  

    ISSN: 0916-1740

    eISSN: 1880-6244

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    In order to reveal the effect of grinding aids and size of grinding media on grindability of water-quenched glassy slag of blast furnace, dry fine grinding has been carried out using tumbling and vibrating ball mills. Triethanolamine (TEA) was found to be excellent grinding aid, and the slag was ground most effectively when small amount of TEA was added every 10 hours. In the single ball-size system, it would be effective when balls of large size are changed to balls of small size after some extended grinding. Grinding efficiency can be also improved in single stage grinding using a mixture of 20mm diameter and 5mm diameter balls as well as a single ball-size system of 5mm diameter balls. The reaction between the ground slag and water, by which calcite is formed in the drying process, becomes active with the progress of grinding.

  288. A study on the strength and grindability of granulated copper smelting slag produced by water quenching. Peer-reviewed

    RYU Hojin, SUGIYAMA Kazumasa, SAITO Fumio

    Shigen-to-Sozai 107 (1) 47-51 1991

    Publisher: The Mining and Materials Processing Institute of Japan

    DOI: 10.2473/shigentosozai.107.47  

    ISSN: 0916-1740

    eISSN: 1880-6244

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    The strength and grindability of copper smelting slag produced by water quenching have been investigated in the framework of single particle crushing and corrective grinding tests. X-ray diffraction analysis clearly indicated that the slag samples are the mixture of glassy and crystalline components, such as fayalite and magnetite. The amount of crystalline component of as-quenched samples increases as the particle size increases. The particle compressive strength of 10-20μm diameter particles of a sample mainly composed of glassy component appears to be almost twice as high as that of a sample including a large amount of crystalline components.

  289. THE CRYSTAL-STRUCTURE OF RUTILE AS A FUNCTION OF TEMPERATURE UP TO 1600-DEGREES-C Peer-reviewed

    K SUGIYAMA, Y TAKEUCHI

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE 194 (3-4) 305-313 1991

    ISSN: 0044-2968

  290. Environmental structure around germanium atoms in GeO2-P2O5 glasses by the anomalous X-ray scattering method Peer-reviewed

    K. Sugiyama, Y. Waseda, M. Ashizuka

    Materials Transactions, JIM 32 (11) 1030-1033 1991

    DOI: 10.2320/matertrans1989.32.1030  

    ISSN: 0916-1821

  291. The crystal structure of rutile as a function of temperature up to 1600°C Peer-reviewed

    Kazumasa Sugiyama, Yoshio Takéuchi

    Zeitschrift fur Kristallographie - New Crystal Structures 194 305-313 1991/01/01

    DOI: 10.1524/zkri.1991.194.3-4.305  

    ISSN: 1433-7266

  292. Structural investigation of water quenched blast furnace slags by X-ray diffraction Peer-reviewed

    K. Sugiyama, H. J. Ryu, Y. Waseda, J. M. Toguri

    Canadian Metallurgical Quarterly 30 (3) 145-151 1991/01/01

    DOI: 10.1179/cmq.1991.30.3.145  

    ISSN: 1879-1395 0008-4433

  293. STRUCTURAL-ANALYSIS OF HYDROLYTIC CONDENSED ZIRCONIUM-OXIDE BY THE ANOMALOUS X-RAY-SCATTERING METHOD Peer-reviewed

    K SUGIYAMA, Y WASEDA, S KUDO

    ISIJ INTERNATIONAL 31 (11) 1362-1367 1991

    DOI: 10.2355/isijinternational.31.1362  

    ISSN: 0915-1559

    eISSN: 1347-5460

  294. The Local Ordering of Molten LiNbO3 by X-ray Diffraction Peer-reviewed

    K. Sugiyama, K. Nomura, Y. Waseda, P. Andonov, S. Kimura, K. Shigematsu

    Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences 45 (11-12) 1325-1327 1990/12/01

    DOI: 10.1515/zna-1990-11-1215  

    ISSN: 1865-7109 0932-0784

  295. STRUCTURAL STUDY OF BINARY PHOSPHATE-GLASSES BY X-RAY AND NEUTRON-DIFFRACTION Peer-reviewed

    Y WASEDA, E MATSUBARA, K SUGIYAMA, IK SUH, T KAWAZOE, O KASU, M ASHIZUKA, E ISHIDA

    SCIENCE REPORTS OF THE RESEARCH INSTITUTES TOHOKU UNIVERSITY SERIES A-PHYSICS CHEMISTRY AND METALLURGY 35 (1) 19-33 1990/03

    ISSN: 0040-8808

  296. Qualitative and quantitative powder analysis of Cu2S in a calcium-ferrite matrix by the anomalous X-ray scattering (AXS) technique. Peer-reviewed

    SUGIYAMA Kazumasa, SHIKIDA Aki, WASEDA Yoshio, HINO Junzo, TOGURI James M.

    Shigen-to-Sozai 106 (8) 485-489 1990

    Publisher: The Mining and Materials Processing Institute of Japan

    DOI: 10.2473/shigentosozai.106.485  

    ISSN: 0916-1740

    eISSN: 1880-6244

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    The application of the anomalous X-ray scattering (AXS) technique has been tested for obtaining qualitative and quantitative powder diffraction analysis of a multi-component mixture having a relatively complicated chemical composition and containing two elements of nearly the same atomic number. The system selected for analysis consisted of three chemically different mixtures of Cu2S and CaFe204. The differential intensity pattern obtained from the measurements at two energies, 8.955 keV and 8.680 keV, corresponding to 25 eV and 300 eV below the Cu K absorption edge (8.980 keV), enabled the isolation of the Bragg reflections of Cu2S from the calcium ferrite matrix and provided information for the quantitative determination of the Cu2S component. The results indicate that the AXS technique is promising in reducing the unsolved difficulties associated with the conventional X-ray powder diffraction method. The quantitative analysis of Cu2S in industrial copper smelting slags was also carried out by this new method

  297. Partial Structural Functions of GeO2 Glass Determined by the Anomalous X-ray Scattering Data Coupled with Neutron Diffraction Peer-reviewed

    Y. Waseda, K. Sugiyama, E. Matsubara, K. Harada

    Materials Transactions, JIM 31 (5) 421-424 1990

    DOI: 10.2320/matertrans1989.31.421  

    ISSN: 0916-1821

  298. STRUCTURAL-ANALYSIS OF ZINC METAPHOSPHATE GLASS BY ANOMALOUS X-RAY-SCATTERING Peer-reviewed

    E MATSUBARA, K SUGIYAMA, Y WASEDA, M ASHIZUKA, E ISHIDA

    JOURNAL OF MATERIALS SCIENCE LETTERS 9 (1) 14-16 1990/01

    DOI: 10.1007/BF00722854  

    ISSN: 0261-8028

  299. <Technical Note>Characterization of the Mechanical Grinding of Water Cooled Blast Furnace Slags by means of X-ray Diffraction Peer-reviewed

    Kazumasa SUGIYAMA, Aki SHIKIDA, Yoshio WASEDA, Hitoshi HASHIMOTO, Saburo YASHIMA

    Bulletin of the Research Institute of Mineral Dressing and Metallurgy, Tohoku University 45 (2) p143-151 1989/12

    Publisher: 東北大學選鉱製錬研究所

    ISSN: 0040-876X

  300. STRUCTURAL STUDY OF THE MOLTEN CAO-FE2O3 SYSTEM BY X-RAY-DIFFRACTION Peer-reviewed

    IK SUH, K SUGIYAMA, Y WASEDA, JM TOGURI

    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 44 (6) 580-584 1989/06

    DOI: 10.1515/zna-1989-0615  

    ISSN: 0932-0784

  301. Determination of the structural parameters of local ordering in oxide melts and glasses from X-ray diffraction data Peer-reviewed

    K SUGIYAMA, E MATSUBARA, IK SUH, Y WASEDA, JM TOGURI

    Science Reports of the Research Institutes Tohoku University Series A 34 (2) 143-152 1989

    Publisher: Tohoku University

    ISSN: 0040-8808

  302. Determination of the Crystal Structure of Superionic Phase of Cu2Se Peer-reviewed

    T. Sakuma, K. Sugiyama, E. Matsubara, Y. Waseda

    Materials Transactions, JIM 30 (5) 365-369 1989

    DOI: 10.2320/matertrans1989.30.365  

    ISSN: 0916-1821

  303. Structural Study of a YBa2Cu3O7-x Superconductor by Anomalous X-ray Scattering Peer-reviewed

    K. Sugiyama, Y. Waseda

    Materials Transactions, JIM 30 (4) 235-241 1989

    DOI: 10.2320/matertrans1989.30.235  

    ISSN: 0916-1821

  304. On the Determination of Crystalline Components in Slags Produced by Water Quenching Peer-reviewed

    Kazumasa SUGIYAMA, Yoshio WASEDA

    Bulletin of the Research Institute of Mineral Dressing and Metallurgy, Tohoku University 44 (2) p246-252 1988/12

    Publisher: 東北大學選鉱製錬研究所

    ISSN: 0040-876X

  305. STRUCTURAL STUDY FOR A NEW SUPERCONDUCTING PHASE IN THE BI-SR-CU-O SYSTEM Peer-reviewed

    K SUGIYAMA, Y WASEDA, K MOROISHI, A INOUE, T MASUMOTO

    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 43 (6) 517-520 1988/06

    DOI: 10.1515/zna-1988-0601  

    ISSN: 0932-0784

  306. DIRECT ESTIMATION OF LOCAL ENVIRONMENTAL STRUCTURE AROUND COPPER IN SUPERCONDUCTING OXIDES OF BA2YCU3O7-X Peer-reviewed

    K SUGIYAMA, E MATSUBARA, Y WASEDA, A INOUE, T MASUMOTO

    JOURNAL OF MATERIALS SCIENCE LETTERS 7 (5) 450-452 1988/05

    DOI: 10.1007/BF01730685  

    ISSN: 0261-8028

  307. ANOMALOUS X-RAY-SCATTERING FACILITY FOR STRUCTURAL CHARACTERIZATION OF MATERIALS USING SYNCHROTRON RADIATION Peer-reviewed

    Y WASEDA, E MATSUBARA, K SUGIYAMA

    SCIENCE REPORTS OF THE RESEARCH INSTITUTES TOHOKU UNIVERSITY SERIES A-PHYSICS CHEMISTRY AND METALLURGY 34 (1) 1-14 1988/03

    ISSN: 0040-8808

  308. STRUCTURE AND CRYSTAL-CHEMISTRY OF A DENSE POLYMORPH OF TRICALCIUM PHOSPHATE CA3(PO4)2 - A HOST TO ACCOMMODATE LARGE LITHOPHILE ELEMENTS IN THE EARTHS MANTLE Peer-reviewed

    K SUGIYAMA, M TOKONAMI

    PHYSICS AND CHEMISTRY OF MINERALS 15 (2) 125-130 1987

    DOI: 10.1007/BF00308774  

    ISSN: 0342-1791

  309. Distribution of cations and water molecules in the heulandite-type framework Peer-reviewed

    K. Sugiyama, Y. Takeuchi

    Studies in Surface Science and Catalysis 28 (C) 449-456 1986

    Publisher: Elsevier Inc.

    DOI: 10.1016/S0167-2991(09)60906-X  

    ISSN: 0167-2991

  310. UNUSUAL THERMAL-EXPANSION OF A B-O BOND IN THE STRUCTURE OF DANBURITE CAB2SI2O8 Peer-reviewed

    K SUGIYAMA, Y TAKEUCHI

    ZEITSCHRIFT FUR KRISTALLOGRAPHIE 173 (3-4) 293-304 1985

    DOI: 10.1524/zkri.1985.173.3-4.293  

    ISSN: 0044-2968

  311. 昭和49年7月静岡地方の集中豪雨で発生した崩壊について

    富松 功光, 増本 真一, 田中 元, 清水 弘一, 藤原 啓人, 杉山 輝芳, 渡辺 仁, 杉山 和正, 茨木 晴之

    静岡地学 = Shizuoka Chigaku 31 (31) 8-11 1976/03/31

    Publisher: 静岡県地学会

    DOI: 10.14945/00025709  

    ISSN: 0285-0753

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Misc. 35

  1. Formation of C-type asteroids inferred from mineral chemistry of samples returned by Hayabusa2 mission

    中村智樹, 杉山和正, 正橋直哉

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2022 2023

  2. Fabricating single-phase bulk samples of Ni-Si-Mn ternary intermetallic compounds produced in nuclear reactor pressure vessel steels by irradiation

    松川義孝, 原田晃一, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2022 2023

  3. Structural study of short-range ordering in amorphous alloys induced by diversification of bond lengths of homologous element pairs

    川又透, 徳田誠, 山根崚, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2022 2023

  4. Structural role of low concentration elements in amorphous alloys

    川又透, 徳田誠, 中村由梨江, 湯葢邦夫, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2020 2021

  5. Elucidation of early solar system evolution based on mineral chemistry of primitive solar system material

    中村智樹, 高橋実樹, 橋本幸菜, 松本恵, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2019 2020

  6. Structural role of low concentration elements in amorphous alloys

    川又透, 徳田誠, 中村友梨江, 湯葢邦夫, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2019 2020

  7. Fine Structure Analysis of Natural Apatite Minerals

    杉山和正, 有馬寛

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2018 2019

  8. Elucidation of early solar system evolution based on mineral chemistry of primitive solar system material

    中村智樹, 吉崎昂, 高橋実樹, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2018 2019

  9. Fine Structure Analysis of Natural Apatite Minerals

    杉山和正, 有馬寛

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2017 161‐162 2018/06/25

  10. Elucidation of early solar system evolution based on mineral chemistry of primitive solar system material

    中村智樹, 吉崎昂, 高橋実樹, 榎戸祐馬, 菊池知紀, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2017 105‐106 2018/06/25

  11. Variable-temperature single-crystal X-ray diffraction study of a tetragonal hydrogarnet in the system Ca-Ge-O-H

    A. Nakatsuka, A. Yoshiasa, K. Sugiyama, M. Okube, H. Arima

    Inter-university Cooperative Research Report of the Institute for Materials Research, Tohoku University 238-239 2018

  12. The crystal structure analyses of proton conductor vivianite and metavivianite

    A. Yoshiasa, A. Nakatsuka, K. Sugiyama, H. Arima

    Inter-university Cooperative Research Report of the Institute for Materials Research, Tohoku University 234-237 2018

  13. 球外物質中カンラン石のX線回折による衝撃変成度合いの見積もり

    杉山 和正

    金属材料研究所共同利用報告書 - 2017

  14. Elucidation of early solar system evolution based on mineral chemistry of primitive solar system material

    中村智樹, 吉崎昂, 高橋実樹, 榎戸祐馬, 百合本はる妃, 中嶋大輔, 杉山和正

    東北大学金属材料研究所新素材共同研究開発センター共同利用研究報告書(CD-ROM) 2016 2017

  15. Precise structure analyses of advanced materials annealed under super strong gravity and shock compression

    A. Yoshiasa, T. Tobase, H. Hongu, M. Tokuda, T. Mashimo, A. Nakatsuka, H. Arima, K. Sugiyama

    Inter-university Cooperative Research Report of the Institute for Materials Research, Tohoku University 10-13 2017

  16. Precise Structure Analyses and Properties in Spinel- and Perovskite-type Advanced Compounds

    A. Yoshiasa, S. Jinnouchi, A. Nakatsuka, K. Sugiyama, H. Arima

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 12-15 2016

  17. Elastic property and structural stability of post-perovskite type CaIrO3 by precise single-crystal X-ray diffraction analysis

    A. Nakatsuka, A. Yoshiasa, K. Sugiyama, H. Arima

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 283-284 2016

  18. TRANSMISSION ELECTRON MICROSCOPY OF SILICO-APATITE IN D'ORBIGNY.

    T. Mikouchi, K. Sugiyama, A. Yasuhara, T. Mihira

    METEORITICS & PLANETARY SCIENCE 50 2015/08

    ISSN: 1086-9379

    eISSN: 1945-5100

  19. Hydrogen positions and structural disorder of hydrogarnets in the system Ca-Ge-O-H

    A. Nakatsuka, A. Yoshiasa, K. Sugiyama, H. Arima

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 171-171 2015

  20. The crystal structure analyses of paradamite-type proton conductors

    A. Yoshiasa, S. Jinnouchi, A. Nakatsuka, H. Arima, K. Sugiyama

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 169-170 2015

  21. Structural disorder and cation-cation interaction of Na3M2Li3F12 (M = Al, Fe, Ga) garnet-type fluoride

    A. Nakatsuka, A. Yoshiasa, K. Sugiyama, H. Arima

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 153-153 2014

  22. Detailed structure of TiO2 anatase single crystal annealed under super strong gravity

    A. Yoshiasa, T. Mashimo, A. Nakatsuka, H. Arima, K. Sugiyama

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 152-152 2014

  23. Effective pair potential for Ca-O bonds in CaGeO<inf>3</inf> polymorphs Peer-reviewed

    A. Koganemaru, A. Yoshiasa, L. Wang, T. Nakatani, A. Nakatsuka, M. Okube, H. Arima, K. Sugiyama

    Journal of Physics: Conference Series 430 (1) 012068-4 2013

    DOI: 10.1088/1742-6596/430/1/012068  

    ISSN: 1742-6588

    eISSN: 1742-6596

  24. Structural disorder and cation-cation interaction of Na-Al-Li garnet-type fluoride

    A. Nakatsuka, A. Yoshiasa, K. Sugiyama, H. Arima

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 154-154 2013

  25. Crystal Chemistry of MgAl_2O_4 Spinel Solid Solution : Peculiar Site Preference of Cation Observed Under Substitution and Pressure

    YOSHIASA Akira, MAEKAWA Hidemi, SUGIYAMA Kazumasa

    Nihon Kessho Gakkaishi 53 (1) 13-18 2011/02/28

    Publisher: The Crystallographic Society of Japan

    DOI: 10.5940/jcrsj.53.13  

    ISSN: 0369-4585

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    Considerable efforts have been devoted to the structural studies of spinel group minerals or type compounds because of their importance as constituents of the Earth&rsquo;s crust and mantle. Despite their simple structures, many spinel type compounds exhibit complex disordering phenomena involving the mixing of cation on two sites, which have important consequences for both thermodynamic and physical properties. The cation distributions and the structural variation in MgAl2-xGaxO4 solid-solution have been clarified using 27Al MAS NMR measurements and single crystal X-ray diffraction. The determined local distance in the solid solution corresponds with the bond distance expected from the effective ionic radii except Al-O distance in the tetrahedral site. We have revealed that the Al-O distance in the tetrahedral site in spinel solid solution is about 0.15 &Aring; longer than the expected value. Boron is the same group element as Al and Ga and its ionic radius is considerably small. Single crystals of MgAl2-xBxO4 spinel were synthesized under high pressure and high temperature. The maximum content of boron was about x = 0.13 at 1273 K and 11 GPa. The smallest B ion occupies the octahedral site in top priority in the spinel solid solution of the Mg-Al-B systems. The B3+ ions can replace considerably bigger Al3+ ion under pressure. These spinel solid-solutions are largely disordered crystals. Only the positional shifts of oxygen ion have been relaxing the disorder in the solid solution.

  26. 鏡笵面の金属鋳込みに伴う皮殻形成の研究その4塗型材の分析 Peer-reviewed

    田賀井 篤平, 白 雲翔, 三船 温尚, 韓 偉東, 清水 康二, 杉山 和正

    アジア鋳造技術史学会研究発表概要集 4号 13-16 2010

  27. 鏡笵面の金属鋳込みにともなう化学変化の研究その3鏡笵面の黒色皮殻の構成物質 Peer-reviewed

    田賀井 篤平, 白 雲翔, 三船 温尚, 韓 偉東, 清水 康二, 杉山 和正

    アジア鋳造技術史学会研究発表概要集 3号 72-74 2009

  28. X線異常散乱法を用いた、ゼオライトに内包される遷移元素と有機分子の相互作用の解明

    杉山 和正, 田中 雅彦

    平成14年-平成16年度科学研究費補助金(基盤研究(B)(2))研究成果報告書 2005

    Publisher: 杉山和正

  29. Iron micro-xanes analysis of Martian kaersutites

    A Monkawa, T Mikouchi, E Koizumi, J Chokai, K Sugiyama, M Miyamoto

    METEORITICS & PLANETARY SCIENCE 39 (8) A71-A71 2004/08

    DOI: 10.1111/j.1945-5100.2004.tb00346.x  

    ISSN: 1086-9379

    eISSN: 1945-5100

  30. X線異常散乱法を用いたAl-Ni-Co系準結晶および近似結晶の精密構造解析

    杉山 和正

    2002

    Publisher: 杉山和正

  31. 53 (1) 140-140 1998/03/27

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

  32. 組成評価研究分野 (1995. 1-1995. 12)(研究活動報告)

    早稲田 嘉夫, 井上 博文, 鈴木 茂, 杉山 和正, 齋藤 正敏, 岡部 徹, 小坂 知己, 篠田 弘造, 佐藤 成男, 前田 吉彦, 新貝 剛史, 洞口 武夫, 表 和彦, Darjaa T., Shinohara A. H., Witne John Y., Maragau Guli

    東北大学素材工学研究所彙報 = Bulletin of the Institute for Advanced Materials Processing, Tohoku University 51 (1) 126-127 1995/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

    More details Close

    application/pdf 紀要類(bulletin) 179824 bytes

  33. 組成評価研究分野 (1994. 1-1994. 12) (研究活動報告)

    早稲田 嘉夫, 井上 博文, 杉山 和正, 齋藤 正敏, 小坂 知己, 篠田 弘造, 小川 浩, 田辺 克行, Darjaa T., Shinohara A. H., Pangum Lemas S., Witne John Y.

    東北大学素材工学研究所彙報 = Bulletin of the Institute for Advanced Materials Processing, Tohoku University 50 (1) 208-209 1994/12

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

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  34. A. H. Shinohara, C. Reynales, T. Darjaa, L. S. Pangum

    東北大学素材工学研究所彙報 = Bulletin of the Institute for Advanced Materials Processing, Tohoku University 49 (1) 158-159 1994/03/30

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

  35. G. Petkov, A. H. Shinohara, J. W. Essel, C. Reynales

    東北大学素材工学研究所彙報 = Bulletin of the Institute for Advanced Materials Processing, Tohoku University 48 (1) 184-185 1993/03/30

    Publisher: 東北大学素材工学研究所

    ISSN: 0919-4827

Show all ︎Show first 5

Books and Other Publications 35

  1. 学術のクロスロード結晶学

    杉山 和正

    日本結晶学会 2024/05/31

    DOI: 10.5940/jcrsj.66.59  

  2. 鉱物・宝石の科学事典

    日本鉱物科学会

    朝倉書店 2019/09

    ISBN: 9784254162769

  3. Earth and Planetary Dynamism Revealed by Mineral Crystallography

    NAKATSUKA Akihiko, SUGIYAMA Kazumasa, GOTOH Yoshito

    The Crystallographic Society of Japan 2018

    DOI: 10.5940/jcrsj.60.1  

  4. SACLA

    IGARASHI Noriyuki, SUGIYAMA Kazumasa, BABA Seiki, YABASHI Makina, MORI Shigeo

    The Crystallographic Society of Japan 2017

    DOI: 10.5940/jcrsj.59.1  

  5. Fascinating Molecular Aggregations:~Heterogeneity, Hierarchy and Polymorphs~

    ABE Hiroshi, SEKINE Akiko, SUGIYAMA Kazumasa

    The Crystallographic Society of Japan 2016

    DOI: 10.5940/jcrsj.58.1  

  6. Mineralogy and Crystallography

    SUGIYAMA Kazumasa, NAKATSUKA Akihiko

    The Crystallographic Society of Japan 2014

    DOI: 10.5940/jcrsj.56.149  

  7. 銀笵面の金属鋳込みに伴う皮殻形成の研究 (3)塗型材と黒色皮殻の構成物質

    田賀井 篤平, 白雲翔, 三船温尚, 韓偉東, 清水康二, 杉山和正, 三河内岳

    2011/12

  8. Crystal Chemistry of MgAl_2O_4 Spinel Solid Solution : Peculiar Site Preference of Cation Observed Under Substitution and Pressure

    YOSHIASA Akira, MAEKAWA Hidemi, SUGIYAMA Kazumasa

    The Crystallographic Society of Japan 2011/02/28

    DOI: 10.5940/jcrsj.53.13  

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    Considerable efforts have been devoted to the structural studies of spinel group minerals or type compounds because of their importance as constituents of the Earth&rsquo;s crust and mantle. Despite their simple structures, many spinel type compounds exhibit complex disordering phenomena involving the mixing of cation on two sites, which have important consequences for both thermodynamic and physical properties. The cation distributions and the structural variation in MgAl2-xGaxO4 solid-solution have been clarified using 27Al MAS NMR measurements and single crystal X-ray diffraction. The determined local distance in the solid solution corresponds with the bond distance expected from the effective ionic radii except Al-O distance in the tetrahedral site. We have revealed that the Al-O distance in the tetrahedral site in spinel solid solution is about 0.15 &Aring; longer than the expected value. Boron is the same group element as Al and Ga and its ionic radius is considerably small. Single crystals of MgAl2-xBxO4 spinel were synthesized under high pressure and high temperature. The maximum content of boron was about x = 0.13 at 1273 K and 11 GPa. The smallest B ion occupies the octahedral site in top priority in the spinel solid solution of the Mg-Al-B systems. The B3+ ions can replace considerably bigger Al3+ ion under pressure. These spinel solid-solutions are largely disordered crystals. Only the positional shifts of oxygen ion have been relaxing the disorder in the solid solution.

  9. Advanced Diversity of Mineralogical Crystallography ; Recent Development and Challenge

    SUGIYAMA Kazumasa, OKUDERA Hiroki, YOSHIASA Akira

    The Crystallographic Society of Japan 2011/02/28

    DOI: 10.5940/jcrsj.53.1  

  10. AXS-RMC Analysis for Structural Characterization for Disordered Materials

    SUGIYAMA Kazumasa

    The Crystallographic Society of Japan 2010/06/30

    DOI: 10.5940/jcrsj.52.166  

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    The anomalous X-ray scattering (AXS) coupled with a model calculation using reverse Monte Carlo (RMC) simulation, has recently received much attention for analyzing the detailed structure for disordered materials. The usefulness of this advanced AXS-RMC method is demonstrated with some selected examples of molten AgBr, Zr50Cu50 metallic glass and Zr70Pd30 metallic glass.

  11. 周期構造を持たないランダム系物質の構造解析

    The Crystallographic Society of Japan 2009

    DOI: 10.5940/jcrsj.51.s3  

  12. MS84:Quasicrystals and Related Giant Crystalline Alloys

    ABE Eiji, McGrath Ronan, SUGIYAMA Kazumasa, YUBUTA Kunio, HIRAGA Kenji, DOTERA Tomonari

    The Crystallographic Society of Japan 2009

    DOI: 10.5940/jcrsj.51.121  

  13. Natural Mineral Seriese (1), Clinoptilolite and heulandite

    Kazumasa Sugiyama, Shigeki Ogiwara

    日本ゼオライト学会 2008

    DOI: 10.20731/zeoraito.25.4.155  

  14. The Crystal Structure of a W-(AlCoNi) Approximant for Al-Co-Ni Decagonal Phases

    SUGIYAMA Kazumasa, HIRAGA Kenji

    The Crystallographic Society of Japan 2007/02/27

    DOI: 10.5940/jcrsj.49.40  

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    The structure of a W- (AlCoNi) approximant phase allows us to discuss a local atomic arrangement for a variety of Al-Co-Ni decagonal phases, by serving an ideal frame of the pentagonal columnar structure of 2 nm in diameter. The present approach also demonstrates that the combinatory analysis of the single crystal X-ray diffraction coupled with electron microscopy such as HAADF-STEM and HRTEM is one of powerful tools for the structural analysis of complicated structures.

  15. Recent Development of Quasicrystalline Research in Japan

    TAKAKURA Hiroyuki, TERAUCHI Masami, SUGIYAMA Kazumasa, YOSHIASA Akira

    The Crystallographic Society of Japan 2007/02/27

    DOI: 10.5940/jcrsj.49.1  

  16. MGC材料の微細組織 (特集 新しい超耐熱材料--MGC材料の開発最前線(上))

    杉山 和正, 中井 宗紀, 鍵 裕之

    アグネ技術センター 2006/05

  17. The Structural Analysis of Non-crystalline Materials by the Anomalous X-ray Scattering Coupled with Reverse Monte Carlo Simulation

    SUGIYAMA Kazumasa, SAITO Masatoshi

    The Crystallographic Society of Japan 2006/02/27

    DOI: 10.5940/jcrsj.48.81  

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    The anomalous X-ray scattering (AXS) coupled with model calculation using reverse Monte Carlo (RMC) simulation, has recently received much attention for analyzing the middlerange ordering for non-crystalline materials. The usefulness of this new method was demonstrated with some selected examples of a Bi30Ga70high temperature liquid alloy and an amorphous ZrO2.

  18. Disorder- and Random-System in Crystallography (Structure Analysis of Disordered Crystal, Superionic Conductor, Amorphous, Glass and Melt)

    YOSHIASA Akira, SUGIYAMA Kazumasa, YASHIMA Masatomo, TAKATA Masaki

    The Crystallographic Society of Japan 2006/02/27

    DOI: 10.5940/jcrsj.48.2  

  19. Synthesis and Structural Analysis of the Al–P–O Materials with the Chabazite Type Framework

    Takashima Junya, Sugiyama Kazumasa, Tagai Tokuhei

    Japan Association of Zeolite 2003

    DOI: 10.20731/zeoraito.20.4.156  

  20. Structural analysis for disordered materials by the anomalous X-ray scattering.

    SUGIYAMA Kazumasa

    Japan Association of Mineralogical Sciences 2001/03/30

    DOI: 10.2465/gkk.30.82  

  21. Approximants for the Icosahedral Quasicrystalline Phase

    SUGIYAMA Kazumasa, HIRAGA Kenji

    The Japan Institute of Metals and Materials 2000/08/20

    DOI: 10.2320/materia.39.635  

  22. Development of Inorganic Solid Materials and Mineralogy

    Yoshiasa A., Miyawaki R., Sugiyama K., Akaogi M.

    Japan Association of Mineralogical Sciences 2000

    DOI: 10.2465/gkk1952.29.31  

  23. 元素の識別--X線照射による元素分析型STMの試み (特集 ナノワールドへご招待(1)新しい手法編)

    辻 幸一, 我妻 和明, 杉山 和正

    コンパス社 1999/08

    More details Close

    資料形態 : テキストデータ プレーンテキスト

  24. 粉末X線回折法と非晶質X線回折法

    杉山 和正, 早稲田 嘉夫

    粉体工学会 1998/01/10

  25. Structure Analysis of Disordered Materials by the Anomalous X-ray Scattering(AXS) Method.

    SUGIYAMA Kazumasa, SAITO Masatoshi, WASEDA Yoshio, MATSUBARA Eiichiro

    The Crystallographic Society of Japan 1997/02/28

    DOI: 10.5940/jcrsj.39.20  

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    The anomalous X-ray scattering method has recently received much attention for obtaining the fine structure of disordered materials, coupled with the synchrotron radiation source. This paper demonstrates the usefulness of the AXS method for determining the local environmental structure around a specific element as a function of distance, by providing fundamentals with some selected examples of high temperature CuBr liquid, 70GeO230Bi2O3 oxide glass and Zr-Y-Al-Ni metallic glasses.

  26. Synchrotron-Radiation Crystallography for the Last Fifteen Years

    SASAKI Satoshi, TAKAHASHI Toshio, SUGIYAMA Kazumasa

    The Crystallographic Society of Japan 1997/02/28

    DOI: 10.5940/jcrsj.39.1  

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    This article provides introductory remarks of our special issue and an overview of synchrotron radiation researches.

  27. Structural Analysis of Inorganic Substances by the Anomalous X-ray Scattering(AXS).

    SUGIYAMA Kazumasa

    Japan Association of Mineralogical Sciences 1994

    DOI: 10.2465/gkk1952.23.69  

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    The anomalous X-ray scattering(AXS) has received much attention for the structural characterization of various inorganic substances. This review provides the fundamentals of AXS technique and its potential power for determining the environmental structure around a specific element as a function of radial distance. The usefulness of this method was demonstrated with the selected examples of GeO2-Bi2O3 glasses and a YBa2Cu3O7-x superconductor. The quantitative analysis for the multiphase system by the AXS measurements has also been discussed using the result of Cu2S/CaFe2O4 mixtures.

  28. Structural Analysis of Bariumborate (BaOB_2O_3)Melt by X-ray Diffraction(<Special Issue>Bulk Crystal Growth(I))

    Takeda Susumu, Kimura Shigeyuki, Sugiyama Kazumasa, Waseda Yoshio

    The Japanese Association for Crystal Growth 1993

    DOI: 10.19009/jjacg.20.1_27  

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    Structural analysis of bariumborate (BaOB_2O_3) melts prepared from a-phase or β-phase has been described with special reference to the relationships between melt structure and crystal structure before melting. The difference of crystal structure before melting was not well recognized in the RDF data. It was, however, ascertained that the different behavior, indicating the characteristic features deduced from crystal structutes before melting, is detected in the profiles of 3rd and 4th peaks of the reduced interference function.

  29. Synchrotron radiation ― the application of an X‐ray anomalous scattering ( use of AXS‐1 ).

    早稲田嘉夫, 松原英一郎, 杉山和正

    1992/11

  30. Structural Analysis of Disordered Materials by the Anomaolous X-ray Scattering (AXS) Method.

    SUGIYAMA Kazumasa, WASEDA Yoshio

    The Crystallographic Society of Japan 1992

    DOI: 10.5940/jcrsj.34.222   10.7209/tanso.2018.185_references_DOI_24CymxpcPFHym9VQlkaEYgjyyo8   10.5940/jcrsj.52.166_references_DOI_24CymxpcPFHym9VQlkaEYgjyyo8  

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    The anomalous X-ray scattering (AXS) method has recently received much attention for analyzing the disordered materials. This paper discusses the fundamentals of AXS method and its potential power for determining the local chemical environment around a specific element as a function of radial distance. The usefulness of this method was demonstrated with the some selected examples of GeO2-P2O5 glasses, amorphous CoFe2O4-x thin film and amorphous ZrO2.

  31. X線異常散乱法を応用した、非晶質ジルコニアの構造解析

    杉山 和正, 早稲田 嘉夫

    日本結晶学会 1991

    DOI: 10.5940/jcrsj.33.Supplement_115  

  32. Structural analysis of inorganic substances by the anomalous X‐ray scattering(AXS) method.

    早稲田嘉夫, 松原英一郎, 杉山和正

    1990/03

  33. X線異常散乱法を用いた、非晶質系物質の構造解析

    杉山 和正, 早稲田 嘉夫

    日本結晶学会 1990

    DOI: 10.5940/jcrsj.32.Supplement_49  

  34. Structural characterization of crystalline materials by the anomalous X-ray scattering.

    Sakuma Takashi, Sugiyama Kazumasa, Waseda Yoshio

    The Japan Institute of Metals 1989

    DOI: 10.2320/materia1962.28.195  

  35. The characteristic features of perovskite-type oxide structures and the latest topics on the perovskite derivative structures.

    Sugiyama Kazumasa, Waseda Yoshio

    The Japan Institute of Metals 1987

    DOI: 10.2320/materia1962.26.771  

Show all Show first 5

Presentations 512

  1. Revisiting the seat selectivity of Cu/Zn in amorphous copper ores by synchrotron anomalous scattering.

    2024/03/06

  2. Determination of the distribution of Cu and Zn in Renierite by anomalous scattering.

    2024/03/06

  3. Determination of metal element distribution in pentland ores using anomalous X-ray scattering

    2024/03/06

  4. 凍結噴霧乾燥における糖を媒体とした多孔質粒子形成による薬物ナノ粒子の分散性向上

    仙波久実, KAEMAERAEINEN Tero, 中山結月, 畑中友太, 有馬寛, 杉山和正, 内山博雅, 門田和紀, 戸塚裕一

    日本薬剤学会年会講演要旨集(CD-ROM) 2024

  5. High-pressure synthesis and crystal structural phase-transition in solid state solution of KNbO3 and RbNbO3

    前田理貴, 山本文子, 村瀬公俊, 川又透, 杉山和正, 山浦淳一

    日本セラミックス協会年会講演予稿集(Web) 2024

  6. CZ法を用いて作製したTb-Dy-Fe合金の結晶性および磁歪特性の評価

    川又透, 熊谷毅, 鈴木茂, 杉山和正, 福田承生

    第52回結晶成長国内会議(JCCG-52) 2023/12

  7. CZ法によるTb0.3Dy0.7Fe1.9結晶作製の溶融原料組成を相図より検討、及び結晶試作

    熊谷毅, 高橋和也, 川又透, 杉山和正, 鈴木茂, 福田承生

    第52回結晶成長国内会議(JCCG-52) 2023/12

  8. Tensile testing of thin strip amorphous alloys using a table-top testing machine.

    22nd Meeting of The Japan Institute of Metals and Materials, Tohoku 2023/10/30

  9. Crystal structure of olivine-type Li(Fe,Mn)PO4 and its delithiated form (Fe,Mn)PO4.

    22nd Meeting of The Japan Institute of Metals and Materials, Tohoku 2023/10/30

  10. Crystal chemistry of 3×4 MnO2 tunnel-type structures for the development of battery cathode materials; behaviour of Zn in woodruffite.

    22nd Meeting of The Japan Institute of Metals and Materials, Tohoku 2023/10/30

  11. 単結晶X線異常散乱法による元素分布解析: 中宇利鉱山産 Cobaltpentlandite (Co,Fe,Ni)9S8 の解析

    徳田誠, 三河内岳, 杉山和正

    日本結晶学会年会2023 2023/10

  12. X線異常散乱法によるTennantite中のZnの空間分布の解明

    山根崚, 杉山和正, 栗林貴弘

    日本結晶学会年会 2023/10

  13. 希土類イオンをドープしたβ-Ca3(PO4)2蛍光体の発光特性と希土類元素の分布

    平岡和樹, 山根崚, 川又透, 徳田誠, 杉山和正

    日本結晶学会年会 2023/10

  14. Ir2S3kashiniteとRh2S3bowieiteの結晶構造・Debye温度と地殻-マントル境界付近の白金族鉱物の産状について

    吉朝朗, 北原銀河, 徳田誠, 石丸聡子, 中塚晃彦, 杉山和正

    日本結晶学会年会 2023/10

  15. 多成分カルシウムフェライトSFCA-I相の結晶化学

    佐藤晴士, 川又透, 杉山和正

    日本鉄鋼協会第186回秋季講演大会 2023/09/21

  16. FeNi基非晶質合金の非晶質構造および結晶化におよぼす添加元素の影響

    伴智也, 川又透, 杉山和正

    日本金属学会講演大会(Web) 2023/09

  17. Syntheses and single crystal structure analyses of Ir2S3 kashinite and Rh2S3 bowieite

    吉朝朗, 徳田誠, 北原銀河, 石丸聡子, 中塚晃彦, 杉山和正

    日本鉱物科学会年会 2023/09

  18. Ordered Distribution of Ag and Cu in cosalite studied by Anomalous X-ray Scattering

    山根崚, 三河内岳, 杉本邦久, 小澤徹, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2023/09

  19. Temperature dependence of crystal structure and dielectric properties of ferroelectric perovskite-type RbNbO3

    山本文子, 村瀬公俊, 川又透, 杉山和正, 稲熊宜之, 山浦淳一

    日本セラミックス協会秋季シンポジウム講演予稿集(Web) 2023/09

  20. Transition metal elements in coloured beryl: application of anomalous X-ray scattering

    Kazumasa Sugiyama, Makoto Tokuda, Toru Kawamata

    26TH CONGRESS AND GENERAL ASSEMBLY OF THE INTERNATIONAL UNION OF CRYSTALLOGRAPHY 2023/08

  21. Investigation of oxidation progress and structural change in hydrous iron phosphates, vivianite and santabarbaraite, by Li-intercalation

    R. Yamane, H. Li, T. Ichitsubo, K. Sugiyama

    Twenty-Sixth Congress and General Assembly of the International Union of Crystallography 2023/08

  22. High-pressure Synthesis of Alkaline Metal Niobates with Tetragonal Tungsten Bronze-type Structure

    K. Murase, T. Sato, A. Yamamoto, K. Sugiyama

    18th European Conference on Solid State Chemistry 2023/07

  23. Perovskite-type RbNbO3 as a High-pressure Polymorphism

    A. Yamamoto, K. Murase, K. Sugiyama, T. Kawamata

    18th European Conference on Solid State Chemistry 2023

  24. Crystal structure refinements of Os1-x-yRuxRhyS2 solid-solutions and related platinum-group sulfides

    吉朝朗, 北原銀河, 徳田誠, 石丸聡子, 浜根大輔, 杉山和正

    量子ビームサイエンスフェスタ 2023/03

  25. Crystal structure and dielectric properties of ferroelectric perovskite-type RbNbO3

    村瀬公俊, 山本文子, 杉山和正, 川又透

    日本セラミックス協会年会講演予稿集 2023/03

  26. Single crystal XRD of Au1-xAgxTe2 minerals and incommensurate structure of AuTe2

    北原銀河, 吉朝朗, 徳田誠, 本宮秀朋, 門馬綱一, 宮脇律郎, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2023

  27. L10-FeNi ordered phase crystallized from Fe-Ni amorphous alloys

    伴智也, 川又透, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2023

  28. Investigation of the composition of molten raw materials for Tb0.3Dy0.7Fe1.9 crystal growth by the CZ method from the phase diagram, and test crystal growth

    熊谷毅, 高橋和也, 川又透, 杉山和正, 鈴木茂, 福田承生

    結晶成長国内会議予稿集(CD-ROM) 2023

  29. 単結晶X線異常散乱法による元素分布解析:中宇利鉱山産Cobaltpentlandite(Co,Fe,Ni)9S8の解析

    徳田誠, 三河内岳, 杉山和正

    日本結晶学会年会講演要旨集 2023

  30. Local Structure around Ge in the Fe3O4-GeFe2O4 spinel solid solutions

    K. Shinoda, Y. Inoue, T. Kawamata, K. Sugiyama

    Asia-Oceania Conference on Synchrotron Radiation Instrumentation 2022 2022/12/11

  31. Single-crystal anomalous X-ray diffraction measurements of two different valence sites of copper in tennantite-(Cu)

    R. Yamane, T. Kuribayashi, K. Sugiyama, A. Yoshiasa

    ” Asia-Oceania Conference on Synchrotron Radiation Instrumentation 2022 2022/12/11

  32. Fine structural analysis of Zr-Co binary amorphous alloys with anomalous X-ray scattering method

    T. Kawamata, T. Oshida, R. Kuroda, K. Sugiyama

    Asia-Oceania Conference on Synchrotron Radiation Instrumentation 2022 2022/12/11

  33. New Equipment for Single-Crystal Anomalous X-ray Scattering (Synergy-AXS) using Synchrotron Radiation Source

    K. Sugiyama, T. Kawamata, M. Tokuda1, and T. Hasegawa

    Asia-Oceania Conference on Synchrotron Radiation Instrumentation 2022 2022/12/11

  34. Fine structure analysis of natural violarite (Fe, Co, Ni)3S4 using single-crystal anomalous X-ray Scattering

    M. Tokuda, T. Ichimura, R. Miyawaki, A. Yoshiasa, K. Sugiyama

    Asia-Oceania Conference on Synchrotron Radiation Instrumentation 2022 2022/12/11

  35. High-pressure Synthesis, Crystal Structure, and Properties of High-entropy Chalcogenides with NiAs-type and Pyrite-type Structure

    A. Yamamoto, A. Zakiyatul, R. Furui, H. Yokoyama, D. Murata, S. Kumegai, K. Sugiyama, N. Dragoe, M. Fronzi

    ” 10th Asia Conf. High-Pressure Research(ACHPR-10)

  36. Crystal Chemistry of SFCA(M14O20) Formed in Sintered Ore

    K. Sugiyama, T. Kawamata, T. Murakami, T. Mikouchi

    The 1st International Symposium on Iron Ore Agglomerates 2022/11/23

  37. Single Crystal Structure Refinements and Debye Temperatures of Ir2S3 Kashinite and Rh2S3 Bowieite

    Akira Yoshiasa, Ginga Kitahara, Makoto Tokuda, Satoko Ishimaru, Shin-ichiro Ono, Kunihisa Terai, Akihiko Nakatsuka, Kazumasa Sugiyama

    Acta Crystallographica 2022/11

  38. ペロブスカイト型RbNbO3の高圧合成とその結晶構造および物性

    村瀨 公俊, 佐藤 健, 杉山 和正, 山根 崚, 山本 文子

    第63回高圧討論会

  39. ペロフスカイト型および正方晶タングステンブロンズ型構造を有する RbNbO3 および関連物質の高圧合成と結晶構造

    山本 文子, 村瀬 公俊, 佐藤 健, 杉山 和正, 山根 崚

    第63回高圧討論会

  40. X線異常分散項の物質構造解析への応用 Cyrilovite (NaFe3(PO4)・2(H2O)) のキラリティ

    平岡和樹, 川又透, 杉山和正

    第21回 日本金属学会東北支部研究発表大会 2022/10/04

  41. Maghemiteの低温酸化プロセス

    佐藤晴士, 川又透, 杉山和正, 興野純

    第21回 日本金属学会東北支部研究発表大会 2022/10/04

  42. Ga浸透電磁鋼板の磁気特性と結晶構造評価

    横田尚也, 川又透, 杉山和正, 鈴木茂

    日本金属学会 2022秋期第171回講演大会 2022/09/20

  43. X線異常散乱法を用いたHf-Ni系非晶質合金の構造評価

    新妻佑斗, 川又透, 杉山和正

    日本金属学会 2022秋期第171回講演大会 2022/09/20

  44. Ba含有カルサイトにおける炭酸イオンの静的無秩序状態の実験的証拠

    鍵 裕之, 丸形 詩歩, 伊地知 雄太, 小松 一生, 薛 献宇, 杉山 和正

    日本鉱物学会2022年度年会

  45. 山根 崚,川又 透,杉山 和正,大嶋 江利子 Vivianiteの脱水・酸化に伴う構造変化 、新潟 9/17-19

    日本鉱物学会2022年度年会 2022/09/18

  46. 黄鉄鉱型PtP2,PtSb2,AuSb2の合成と単結晶構造解析

    吉朝 朗, 徳田 誠, 北原 銀河, 中塚 晃彦, 杉山 和正

    日本鉱物学会2022年度年会

  47. Hopeite型(Fe,Co,Ni)Zn2(PO4)2・4H2Oの脱水挙動と結晶構造の変化

    田沼 怜, 山根 崚, 杉山 和正

    日本鉱物学会2022年度年会

  48. Local density fluctuation realized in Nb-Ni amorphous alloys

    Toru Kawamata, Naoki Takehara, Ryo Kuroda, Kazumasa Sugiyama

    The 18th International Conference on Liquid and Amorphous Metals 2022/09/09

  49. Structure of hexagonal;ζ‘-AlMnCo

    Yuki Makino, Kazumasa Sugiyama, Toru Kawamata

    International Conference on Aperiodic Crystals

  50. Short and medium range ordering in Al3Mn amorphous alloy prepared by magnetron sputtering

    Toru Kawamata, Kazumasa Sugiyama

    Aperiodic;h International Conference on;Aperiodic Crystals

  51. Fe-Ni系アモルファス合金から結晶化するL10-FeNi規則相

    伴智也, 川又透, 杉山和正

    2022年度量子ビームサイエンスフェスタ

  52. 放射光X線異常散乱法を用いた非晶質金属の構造不均一性解析 Invited

    川又透, 杉山和正

    日本放射光学会年会・放射光科学合同シンポジウム(Web) 2022/01/07

  53. High-pressure synthesis and structure analysis of A-Nb-O (A=Li, K, Rb)

    村瀬公俊, 佐藤健, 山本文子, 杉山和正, 山根崚

    日本セラミックス協会関東支部研究発表会講演要旨集 2022

  54. High-pressure synthesis of novel Nb oxides containing Rb

    山本文子, 佐藤健, 村瀬公俊, 杉山和正, 山根崚

    日本セラミックス協会秋季シンポジウム講演予稿集(Web) 2022

  55. Application of X-ray Anomalous Dispersion Terms to Structure Analysis: Chirality of Cyrilovite (NaFe3(PO4)2(OH)4・2(H2O))

    平岡和樹, 川又透, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2022

  56. Low-temperature oxidation process of magnetite

    佐藤晴士, 川又透, 杉山和正, 興野純

    日本金属学会東北支部研究発表大会予稿集 2022

  57. Crystal growth and properties of Ca0.582Sr0.418F2(CSF) single crystal

    高橋和也, 熊谷毅, 川又透, 杉山和正, 石地耕太朗, 藤井高志, 猿倉信彦, 福田承生

    応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2022

  58. Dehydration Behavior of Hopeite-type (Fe,Co,Ni)Zn2(PO4)2

    田沼怜, 山根崚, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2022

  59. Structural change of vivianite induced by dehydration and oxidization

    山根崚, 川又透, 杉山和正, 大嶋江利子

    日本鉱物科学会年会講演要旨(Web) 2022

  60. Syntheses and single crystal structure analyses of pyrite-type PtP2,PtSb2,AuSb2.

    吉朝朗, 徳田誠, 北原銀河, 中塚晃彦, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2022

  61. AXS-analysis of Hf10Co90 and Hf70Co30 amorphous alloys

    新妻佑斗, 川又透, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2022

  62. Single Crystal AXS Diffraction at BL-6C

    徳田誠, 川又透, 市村卓視, 井上裕太郎, 牧野友紀, 栗林貴弘, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2022

  63. Material development of new dielectric materials in (Rb,K,Li)-Nb-O system with tetragonal tungsten-bronze type structure

    佐藤健, 山本文子, 杉山和正, 山根崚, LAFFEZ Isabelle

    日本セラミックス協会年会講演予稿集(Web) 2022

  64. Crystal growth of large diameter fluoride solid solution Ca1-xSrxF2 single crystal

    高橋和也, 熊谷毅, 川又透, 杉山和正, 猿倉信彦, 福田承生

    応用物理学会春季学術講演会講演予稿集(CD-ROM) 2022

  65. NaAlH4-TiCl3の水素放出再吸蔵過程における中性子・X線散乱による構造解析と触媒効果の発現

    池田一貴, 池田一貴, 池田一貴, 藤崎布美佳, 藤崎布美佳, 大友季哉, 大友季哉, 大友季哉, 大友季哉, 大下英敏, 本田孝志, 本田孝志, 本田孝志, 川又透, 有馬寛, 有馬寛, 杉山和正, 阿部仁, 阿部仁, 阿部仁, KIM Yunjeong, 榊浩司, 中村優美子, 町田晃彦, 佐藤豊人, 佐藤豊人, 高木成幸, 折茂慎一

    日本金属学会講演大会(Web) 2022

  66. 黄鉄鉱型PdSb2とRhSe2の単結晶構造解析とDebye温度の有効利用

    吉朝朗, 北原銀河, 大野真一朗, 徳田誠, 中塚晃彦, 杉山和正

    日本結晶学会年会講演要旨集 2021/11/20

  67. Au1-xAgxTe2組成calaverite,krennerite,sylvaniteの単結晶構造解析と化学式・変調構造・銀の役割の再考察

    北原銀河, 吉朝朗, 本宮秀朋, 徳田誠, 門馬綱一, 宮脇律郎, 杉山和正

    日本結晶学会年会講演要旨集 2021/11/20

  68. 単結晶X線異常散乱法による陽イオン分布と価数分布解析:BabingtoniteおよびUngarettiiteの解析

    徳田誠, 栗林貴弘, 杉山和正

    日本結晶学会年会講演要旨集 2021/11/20

  69. The distribution of Fe2+ and Fe3+ in ilvarite analyzed by Single Crystal-AXS technique

    井上裕太郎, 川又透, 三河内岳, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2021/11/19

  70. Synthesis and AXS-analysis of Hf-M (M=Co, Ni, Fe, Cu) amorphous alloys

    新妻佑斗, 川又透, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2021/11/19

  71. Magnetic properties of Ga-doped directional grain oriented silicon steel sheet

    横田尚也, 川又透, 杉山和正, 鈴木茂

    日本金属学会東北支部研究発表大会予稿集 2021/11/19

  72. Variation of dehydration behavior and structure of hopeite type (Fe, Co, Ni)Zn2(PO4)2

    田沼怜, 山根崚, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2021/11/19

  73. Fine Structural Analysis of violarite using synchrotron radiation

    市村卓視, 徳田誠, 吉朝朗, 宮脇律郎, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2021/11/19

  74. Crystal structure of ζ-phase and the distribution of icosahedron-typed unit structure

    牧野友紀, 川又透, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2021/11/19

  75. Control of thermophysical properties of La3Ta0.5Ga5.5O14 crystal by Sr substitution

    武田博明, 蕎麦田雄大, 臼井晴紀, 徳田誠, 杉山和正, 小玉翔平, 柳瀬郁夫, 保科拓也, 鶴見敬章, VILLORA Encarnacion G., 島村清史

    結晶成長国内会議予稿集(CD-ROM) 2021/10/27

  76. High-pressure synthesis, crystal structure, and physical properties of high-entropy chalcogenides with NiAs- and Pyrite-type structures

    ZAKIYATUL A., 古井凌太, 村田大地, 横山遥香, 粂谷慎也, 杉山和正, DRAGOE N., 山本文子

    日本物理学会講演概要集(CD-ROM) 2021/09/21

  77. Synthesis and Crystal Structure of Ferroelectric Materials in Rb-Nb-O System

    佐藤健, 山本文子, MONOT-LAFFEZ Isabelle, 杉山和正

    日本セラミックス協会関東支部研究発表会講演要旨集 2021/09/21

  78. Accurate structure analysis of ice VII by single-crystal and powder neutron diffraction under high pressure

    山下恵史朗, 小松一生, KLOTZ Stefan, FABERO Oscar, FERNANDEZ-DIAZ Maria T., 阿部淳, 町田真一, 服部高典, 入舩徹男, 新名亨, 杉山和正, 川又透, 鍵裕之

    分子科学討論会講演プログラム&要旨(Web) 2021/09/18

  79. 非晶質金属や固溶体に観察できる短範囲規則性 Invited

    杉山和正, 川又透

    日本金属学会 2021 年秋期講演(第169 回)大会 2021/09/15

  80. Crystal growth of Si doped Fe metal single crystal by CZ method

    Kumagai Tsuyoshi, Ando Hiroyuki, Kawamata Toru, Sugiyama Kazumasa, Shigeru Suzuki, Fukuda Tsuguo

    JSAP Annual Meetings Extended Abstracts 2021/08/26

  81. Crystal growth of Si doped Fe metal single crystal by CZ method

    熊谷毅, 安藤宏孝, 川又透, 杉山和正, 鈴木茂, 福田承生

    応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2021/03/17

  82. The effect of metallic elements for Gallium Nitride crystal growth under a normal pressure nitrogen atmosphere

    秋山晋也, 八木橋和弘, 高橋芳美, 長谷川洋, 林部和弥, 杉山和正

    応用物理学会春季学術講演会講演予稿集(CD-ROM) 2021/03/17

  83. Growth conditions and defects of ScAlMgO4 single crystal.

    白石裕児, 南都十輝, 福田承生, 藤井高志, 藤井高志, 杉山和正, 石地耕太郎, 稲葉克彦

    応用物理学会春季学術講演会講演予稿集(CD-ROM) 2021/03/17

  84. Crystal growth of Cu metal single crystal by CZ method

    熊谷毅, 安藤宏孝, 渡邊清和, 高橋和也, 藤井高志, 川又透, 杉山和正, 鈴木茂, 福田承生

    応用物理学会春季学術講演会講演予稿集(CD-ROM) 2021/03/17

  85. Structural Analysis of ilvaite using Anomalous X-ray Scattering

    井上裕太郎, 川又透, 杉山和正, 三河内岳

    量子ビームサイエンスフェスタ(Web) 2021/03/10

  86. Structural Analysis of Al-based approximant crystals by Anomalous X-ray Scattering

    牧野友紀, 川又透, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2021/03/10

  87. Cation distribution in violarite

    市村卓視, 徳田誠, 吉朝朗, 宮脇律郎, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2021/03/10

  88. Crystal synthesis and Debye temperature determination of PdSb2: usefulness of single crystal precise structure analysis

    Akira Yoshiasa, Makoto Tokuda, Ginga Kitahara, Kohei Unoki, Hiroshi Isobe, Akihiko, Nakatsuka, Kazumasa Sugiyama

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/02

  89. Distribution of Ce in orthophosphate Sr3(PO4)2

    Makoto Tokuda, Yui Kodama, Shintaro Niiyama, Kozo Shinoda, Kazumasa Sugiyama

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/02

  90. Characterization and performance of large-sized Fe-Ga alloy single crystals grown by the Czochralski method

    Shigeru Suzuki, Osamu Taguchi, Toru Kawamata, Kazumasa Sugiyama, Tsuyoshi Kumagai, Tsuguo Fukuda

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/02

  91. Local structure investigations of Mn and Sn doped in β-Ga2O3 by X-ray absorption spectroscopy

    H. Arima-Osonoi, K. Yamazaki, R. Simura, T. Sugawara, K. Yubuta, K. Sugiyama, A.Yoshiasa

    2021/03/02

  92. Crystal Growth of commercially available metal nickel single crystals by the Czochralski method

    Toru Kawamata, Kazuya Takahashi, Tsuyoshi Kumagai, Kazumasa Sugiyama, Tsuguo Fukuda

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/02

  93. Growth and magnetostrictive properties of large Fe-Ga single crystals by CZ method using resistance and high frequency induction furnaces

    Kumagai Tsuyoshi, Kazuya Takahashi, Hirotaka Ando, Toru Kawamata, Kazumasa, Sugiyama, Osamu Taguchi, Shigeru Suzuki, Tsuguo Fukuda

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/02

  94. Effect of element substitution on thermophysical properties of langasite-type crystals

    Hiroaki Takeda, Yudai Sobata, Haruki Usui, Makoto Tokuda, Kazumasa Sugiyama, Takuya Hoshina, Takaaki Tsurumi, Ikuo Yanase, Kheirreddine Lebbou

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/02

  95. Crystal growth of ScAlMgO₄ and GaN on ScAlMgO₄ for GaN based optical devices, highpower and high-frequency transistors Invited

    Tsuguo Fukuda, Yuji shiraishi, Toki Nanto, Takashi Fujii, Kazumasa Sugiyama, Rayko, Simura, Hiroyuki Iechi, Kazuyuki Tadatomo, Takashi Matsuoka

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/01

  96. X-ray Diffraction Analysis of high-quality ScAlMgO4 substrates

    Katsuhiko Inaba, Kazumasa Sugiyama, Takashi Fujii, Tsuguo Fukuda

    The 8th Asian Conference on Crystal Growth and Crystal Technology (CGCT-8) 2021/03/02

  97. Crystal growth of Cu metal single crystal by CZ method

    Kumagai Tsuyoshi, Ando Hiroyuki, Watanabe Kiyokazu, Takahashi Kazuya, Fujii Takashi, Kawamata Toru, Sugiyama Kazumasa, Suzuki Shigeru, Fukuda Tsuguo

    JSAP Annual Meetings Extended Abstracts 2021/02/26

  98. Growth conditions and defects of ScAlMgO4 single crystal.

    Shiraishi Yuji, Nanto Toki, Fukuda Tsuguo, Fujii Takashi, Sugiyama Kazumasa, Ishiji Kotaro, Inaba Katsuhiko

    JSAP Annual Meetings Extended Abstracts 2021/02/26

  99. The effect of metallic elements for Gallium Nitride crystal growth under a normal pressure nitrogen atmosphere

    Akiyama Shinya, Yagihashi Kazuhiro, Takahashi Yoshimi, Hasegawa Hiroshi, Hayashibe Kazuya, Sugiyama Kazumasa

    JSAP Annual Meetings Extended Abstracts 2021/02/26

  100. Crystal growth of Cu single crystal by CZ technique using partition in the crucible

    高橋和也, 安藤宏孝, 熊谷毅, 藤井高志, 藤井高志, 川又透, 杉山和正, 福田承生

    応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2021

  101. Local structure of Ni and Ni minerals in listvenite in the Nishisonogi unit Nagasaki metamorphic rocks.

    鵜木康平, 西山忠男, 北原銀河, 吉朝朗, 徳田誠, 湯葢邦夫, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2021

  102. Chemical formula, crystal structure and dielectric properties of swedenborgite

    本宮秀朋, 吉朝朗, 吉原茉由, 北原銀河, 鵜木康平, 徳田誠, 杉山和正, 門馬綱一, 宮脇律郎

    日本鉱物科学会年会講演要旨(Web) 2021

  103. Crystal chemistry of Au1-xAgxTe2 minerals: structure analyses krennerite (x=0.13) and sylvanite (x=0.32)

    北原銀河, 吉朝朗, 本宮秀朋, 徳田誠, 杉山和正, 門馬綱一, 宮脇律郎

    日本鉱物科学会年会講演要旨(Web) 2021

  104. Structural Analysis of ilvaite: distribution of Fe2+, Fe3+ and Mn2+.

    井上裕太郎, 川又透, 三河内岳, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2021

  105. Cation distribution in Fe, Co, Ni-bearing Pentlandite

    市村卓視, 徳田誠, 杉山和正, 吉朝朗, 三河内岳

    日本鉱物科学会年会講演要旨(Web) 2021

  106. Synthesis and single crystal structure analysis of pyrite-type PdSb2.

    吉朝朗, 徳田誠, 北原銀河, 鵜木康平, 中塚晃彦, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2021

  107. 高圧下単結晶中性子回折による氷VIIの精密構造解析

    山下恵史朗, 小松一生, KLOTZ Stefan, FABERO Oscar, TERNANDEZ-DIAZ Maria T., 入舩徹男, 杉山和正, 川又透, 鍵裕之

    日本結晶学会年会講演要旨集 2020/11/27

  108. Synthesis, crystal structure, and physical properties of novel strontium iridium oxychloride with a derivative structure of KSbO3-type

    菊地優平, 山本文子, 杉山和正

    日本物理学会講演概要集(CD-ROM) 2020/09/11

  109. Structural Analysis of Nb-Ni Amorphous Alloys by AXS-RMC Method

    竹原直毅, 川又透, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2020/03/13

  110. Site occupancy of Mn2+ and Mn3+ in amphibole determined by x-ray anomalous scattering

    徳田誠, 児玉惟衣, 中村友梨江, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2020/03/13

  111. The location of Fe and Mu in beryl structure

    児玉惟衣, 中村友梨江, 徳田誠, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2020/03/13

  112. Crystal growth of φ6inch Ni single crystal by resistance heating CZ method

    Takahashi Kazuya, Fukuda Tsuguo, Fujii Takashi, Kawamata Toru, Sugiyama Kazumasa, Naritsuka Shigeya

    JSAP Annual Meetings Extended Abstracts 2020/02/28

  113. ハイエントロピー合金における元素間相互作用に起因するナノ構造

    古原忠, 杉山和正, 井上耕治, 荒木秀樹, 水野正隆

    日本金属学会講演大会(Web) 2020

  114. Crystal growth of 8inch diameter Ni single crystal for GaN substrate

    高橋和也, 安藤宏孝, 熊谷毅, 藤井高志, 川又透, 杉山和正, 松岡隆志, 福田承生

    応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2020

  115. Crystal growth of Fe-Ga magnetostrictive single crystal alloy ingot and evaluation of the magnetostrictive properties

    熊谷毅, 安藤宏孝, 南都十輝, 藤井高志, 志村玲子, 川又透, 杉山和正, 田口收, 鈴木茂, 福田承生

    応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2020

  116. Behavior of carbonate ions in Ba-doped calcite

    丸形詩歩, 鍵裕之, 小松一生, 斉藤綾花, XUE X., 杉山和正

    日本地球化学会年会要旨集(Web) 2020

  117. Effect of element substitution on thermophysical properties of langasite-type crystal

    臼井晴紀, 徳田誠, 保科拓也, 鶴見敬章, 杉山和正, LEBBOU Kheirreddine, 武田博明

    日本セラミックス協会年会講演予稿集(CD-ROM) 2020

  118. Extra-framework sites of labuntsovite-Mn from Aris Quarries, Aris, Windhoek, Khomas, Namibia

    中村友梨江, 杉山和正, 長瀬敏郎

    日本鉱物科学会年会講演要旨(Web) 2019/09/20

  119. Crystal chemistry of loparite (Na, REE, Ca)(Ti, Nb)O3: on the average and local structures

    北原銀河, 吉朝朗, 鳥羽瀬翼, 徳田誠, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2019/09/20

  120. Thermally treatment on metamict minerals: case of fergusonite

    徳田誠, 吉朝朗, 上原誠一郎, 宮脇律郎, 門馬綱一, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2019/09/20

  121. Synthesis Condition and Iron Valence in Vivianite

    千葉康平, 大嶋江利子, 高橋美咲, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2019/09/20

  122. 多成分カルシウムフェライト(SFCA)相の構造的研究

    杉山 和正

    日本鉄鋼協会(第178回秋季後援会) 2019/09/11

  123. Middle Range Ordering of Zr-based Amorphous Alloys International-presentation

    SUGIYAMA Kazumasa, KAWAMATA Toru

    2019/08/18

  124. Structural analysis of amorphous alloys with composition dominated by single element.

    OSHIDATeturo, KAWAMATA Toru, SUGIYAMA Kazumasa

    2019/03/12

  125. The local structure of Ce in rare eather phosphates

    SIMURA Rayko. NIIYAMA Shintaro, SUGIYAMA Kazumasa, ARIMA Hiroshi, MIKOUCHI Takashi

    2019/03/12

  126. Structure of natural minerals with Mn and Fe

    KITAHARA Daitaro, TANAKA Keita, KAWAMATA Toru, SUGIYAMA Kazumasa

    2019/03/12

  127. Crystal chemistry of pyrite-type compounds and single crystal structure analyses of MnTe2, MnSe2, MnS2 and FeS2

    YOSHIASA Akira, TOKUDA Makoto, HONGU Hideaki, MASHIMO Shigeru, NAKATSUKA Akihiko, ARIMA Hiroshi, Sugiyama Kazumasa

    2019/03/12

  128. Local structure in ScRh3B0.6 compound

    湯葢邦夫, 野村明子, 菅原孝昌, 吉川彰, 杉山和正, 宍戸統悦, 神津薫, 山崎貴, 岡田繁, 森孝雄

    Journal of Flux Growth 2019

  129. CZ法ScAlMgO4(SCAM)結晶のX線トポグラフ観察と光学特性評価

    藤井高志, 藤井高志, 福田承生, 荒木努, 杉山和正, 石地耕太朗, 杉江隆一

    応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2019

  130. 3種のSrIrO3多形の合成,結晶構造および物性

    菊地優平, 杉山和正, 山本文子

    高圧討論会講演要旨集 2019

  131. 一本鎖β-グルカンによるケルセチンの分散安定性改善

    堂脇晶有, 内山博雅, 門田和紀, 有馬寛, 杉山和正, 戸塚裕一

    日本食品化学学会総会・学術大会講演要旨集 2019

  132. CZ法による直径100mm径金属Ni単結晶の育成・加工と評価

    藤井高志, 藤井高志, 渡邊清和, 高橋和也, 熊谷毅, 福田承生, 松岡隆志, 川又透, 杉山和正

    応用物理学会春季学術講演会講演予稿集(CD-ROM) 2019

  133. Synthesis and luminescence of Ce-doped merrillite

    新山慎太郎, 志村玲子, 杉山和正

    日本鉱物科学会年会講演要旨(Web) 2019

  134. 天然産(Na,REE,Ca)(Ti,Nb)O3ペロブスカイト型結晶の構造精密化とXAFS法による微量元素の局所構造

    北原銀河, 吉朝朗, 徳田誠, 杉山和正

    日本地球惑星科学連合大会予稿集(Web) 2019

  135. Al-M-P-O-IM(M=Co,Zn)系LAU(laumontite)の精密構造解析

    田中啓大, 徳田誠, 杉山和正

    日本結晶学会年会講演要旨集 2019

  136. 四成分系ランガサイト型結晶の構造と物性

    武田博明, 臼井晴紀, 保科拓也, 鶴見敬章, 杉山和正, 徳田誠

    日本結晶学会年会講演要旨集 2019

  137. AXS-RMC法を用いたNb-Ni系非晶質合金の中距離構造解析

    竹原直毅, 川又透, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2019

  138. CaTiO3-NaCeTi2O6系ペロブスカイト型結晶の合成

    児玉惟衣, 徳田誠, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2019

  139. 層状構造を有するRE-Rh-B化合物の結晶構造解析

    森秀太, 湯葢邦夫, 杉山和正, 宍戸統悦

    日本金属学会東北支部研究発表大会予稿集 2019

  140. Crystal chemistry of pyrite-type compounds and single crystal structure analyses of MnTe2, MnSe2,MnS2, and FeS2

    吉朝朗, 徳田誠, 本宮秀朋, 真下茂, 中塚晃彦, 有馬寛, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2019

  141. Structural analysis of amorphous alloys with composition dominated by single element

    大志田達郎, 川又透, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2019

  142. The local structure of Ce in rare earth phosphates

    志村玲子, 新山慎太郎, 杉山和正, 有馬寛, 三河内岳

    量子ビームサイエンスフェスタ(Web) 2019

  143. MnおよびFeを含むaxiniteの精密構造解析

    北原大太朗, 杉山和正, 有馬寛, 三河内岳

    日本結晶学会年会講演要旨集 2018/11/01

  144. MnS2(hauerite),MnSe2,MnTe2の構造解析と黄鉄鉱型化合物の結晶化学

    YOSHIASA Akira, TOKUDA Makoto, HONGU Hideaki, TOBASE Tsubasa, NAKATSUKA Akihiko, ARIMA Hiroshi, SUGIYAMA Kazumasa

    日本鉱物科学会2018年会 2018/09/19

  145. 新規高圧Srケルマン酸塩SrGe2O5の結晶構造

    NAKATUKA Akihiko, SUGIYAMA Kazumasa, OHKAWA Makio, OHTAKA Osamu, FUJIWAARA Keiko, YOSHIASA Akira

    日本鉱物科学会2018年会 2018/09/19

  146. MnおよびFeを含むaxiniteの精密構造解析

    KITAHARA Daitaro, SUGIYAMA Kazumasa, ARIMA Hiroahi

    日本鉱物科学会2018年会 2018/09/19

  147. X線異常散乱法を用いた非晶質合金の中距離秩序構造解析

    川又透, 杉山和正

    日本分析化学会年会講演要旨集 2018/08/29

  148. 水熱処理β‐グルカンを用いたルチンの分散性改善に関する研究

    田中舜, 内山博雅, 門田和紀, 有馬寛, 杉山和正, 戸塚裕一

    日本食品化学学会総会・学術大会講演要旨集 2018/05/17

  149. 常圧窒素中で成長した窒化ガリウム結晶の結晶配向性

    秋山晋也, 八木橋和弘, 林部和弥, 杉山和正, 宮嶋孝夫

    応用物理学会春季学術講演会講演予稿集(CD-ROM) 2018/03/05

  150. 福岡県田川市磁石山スカルン産Scheelite-Powellite固溶体の産状及び固溶体単結晶合成・構造解析

    山下紅弓, 吉朝朗, 徳田誠, 鳥羽瀬翼, 宮崎晴菜, 西山忠男, 杉山和正, 宮脇律郎, 上原誠一郎

    日本地球惑星科学連合大会予稿集(Web) 2018

  151. Ce-perovskiteとNb-perovskiteの単結晶構造解析とXAFS法による局所構造解析

    北原銀河, 吉朝朗, 徳田誠, 鳥羽瀬翼, 本宮秀朋, 有馬寛, 杉山和正

    日本地球惑星科学連合大会予稿集(Web) 2018

  152. Site occupancy analysis of cations in Fe2.69Ti0.31O4 by X-ray anomalous scattering

    奥部真樹, 鴛海太郎, 長瀬敏郎, 佐々木聡, 佐々木聡, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2018

  153. Atom and ion transport mechanism in NaAlH4-Ti compounds

    大友季哉, 大友季哉, 大友季哉, 藤崎布美佳, 本田孝志, 本田孝志, 大下英敏, 池田一貴, 中尾裕則, 中尾裕則, 阿部仁, 阿部仁, 有馬寛, 杉山和正, 佐藤豊人, 折茂慎一, 榊浩司, KIM Hyunjeong, 中村優美子

    量子ビームサイエンスフェスタ(Web) 2018

  154. Crystal structure refinements of mantle origin spinel type minerals and unique cation site occupancies

    吉朝朗, 徳田誠, 西山忠男, 真下茂, 中塚晃彦, 有馬寛, 奥部真樹, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2018

  155. Structural study of Mg-stabilized amorphous calcium carbonate

    脇本聡, 有馬寛, 杉山和正

    量子ビームサイエンスフェスタ(Web) 2018

  156. Crystal structure analyses of MnS2 (hauerite), MnSe2 and MnTe2 and crystal chemistry of pyrite type compounds

    Yoshiasa Akira, Tokuda Makoto, Hongu Hidetomo, Tobase Tsubasa, Nakatsuka Akihikp, Arima Hiroshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2018

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    The crystal structure of MnS2 [hauerite a=6.1013(1)Å; u-parameter 0.40105(4) from Osorezan, Aomori], MnSe2 [a = 6.4275(2) Å; u-parameter 0.39358(2)], MnTe2 [a = 6.9513(1)Å; u-parameter 0.38554(2); space group Pa-3; Z=4] and FeS2 [pyrite a=5.4190(1)Å; u-parameter 0.38484(5) from Nagasaki] have been analysed by the single-crystal X-ray diffraction and refined yielding the R1 values of 0.0113, 0.0160, 0.0189 and 0.0181 using 354, 278, 318 and 165 unique reflections with Fo>2σ(Fo).

  157. Crystal structure of new high-pressure strontium germanate SrGe2O5

    Nakatsuka Akihiko, Sugiyama Kazumasa, Ohkawa Makio, Ohtaka Osamu, Fujiwara Keiko, Yoshiasa Akira

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2018

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    Single crystals of new high-pressure strontium germanate SrGe2O5 have successfully been grown at high-pressure and high-temperature. The single-crystal X-ray diffraction analysis of this compound was conducted at room temperature (296 K). The determined crystal structure consists of germanium-oxygen framework layers stacked along [001] with Sr atoms located at 12-fold coordinated cuboctahedral site; the layers are formed by the corner-linkages between GeO6 octahedra and between GeO6 octahedra and GeO4 tetrahedra.

  158. Ce‐perovskiteとNb‐perovskiteの単結晶構造解析とXAFS法による局所構造解析

    北原銀河, 吉朝朗, 徳田誠, 鳥羽瀬翼, 本宮秀朋, 有馬寛, 杉山和正

    日本地球惑星科学連合大会予稿集(Web) 2018

  159. 福岡県田川市磁石山スカルン産Scheelite‐Powellite固溶体の産状及び固溶体単結晶合成・構造解析

    山下紅弓, 吉朝朗, 徳田誠, 鳥羽瀬翼, 宮崎晴菜, 西山忠男, 杉山和正, 宮脇律郎, 上原誠一郎

    日本地球惑星科学連合大会予稿集(Web) 2018

  160. 小角X線散乱法による葉酸ナノ製剤の再分散性と構造評価

    仙波久実, 仙波久実, 有馬寛, 内山博雅, 門田和紀, 杉山和正, 戸塚裕一

    日本薬剤学会年会講演要旨集(Web) 2018

  161. Mg添加非晶質炭酸カルシウムの結晶化観察

    脇本聡, 有馬寛, 杉山和正

    日本金属学会東北支部研究発表大会予稿集 2018

  162. XAFS法による元素の局所構造解析と濃集過程の推定:白亜紀‐第三紀境界粘土層中のSb,Asについて

    本宮秀朋, 鳥羽瀬翼, 吉朝朗, 磯部博志, 奥部真樹, 有馬寛, 杉山和正, 宮脇律郎

    日本結晶学会年会講演要旨集 2017/11/23

  163. 宮崎県大崩山産フェルグソン石の構造精密化とYNbO4‐YTaO4固溶体の構造について

    中山咲希, 徳田誠, 上原誠一郎, 山下紅弓, 鳥羽瀬翼, 本宮秀朋, 吉朝朗, 杉山和正, 門馬綱一, 宮脇律郎

    日本結晶学会年会講演要旨集 2017/11/23

  164. 天然産Ce‐perovskiteとNb‐perovskiteの構造精密化とパラ誘電性の探査

    北原銀河, 吉朝朗, 徳田誠, 鳥羽瀬翼, 本宮秀朋, 杉山和正, 有馬寛, 中塚晃彦

    日本結晶学会年会講演要旨集 2017/11/23

  165. Tissint産Shergottite隕石のガラス部中心‐表面におけるZr局所構造のXAFS法による解析

    鳥羽瀬翼, 鳥羽瀬翼, 吉朝朗, ネスポロ マッシモ, 本宮秀朋, 磯部博志, 有馬寛, 杉山和正

    日本結晶学会年会講演要旨集 2017/11/23

  166. 異常分散法を用いたチタノマグネタイトの陽イオン価数分布解析

    奥部真樹, 鴛海太郎, 長瀬敏郎, 佐々木聡, 佐々木聡, 杉山和正

    日本結晶学会年会講演要旨集 2017/11/23

  167. 小角X線散乱法による糖転移ルチンとItraconazoleの非晶質複合体評価

    門田和紀, 赤土了介, 内山博雅, 有馬寛, 杉山和正, 戸塚裕一

    日本薬学会 第137年会 2017/03/24

  168. 常圧窒素雰囲気中で成長した窒化ガリウム結晶の貫通転位密度

    秋山晋也, 渡辺誠, 林部和弥, 杉山和正, 宮嶋孝夫

    第64回応用物理学会春季学術講演会 2017/03/14

  169. X線異常散乱法をもちいたviridineの結晶構造

    谷祐樹, 有馬寛, 杉山和正, 吉朝朗

    2016年度量子ビームサイエンスフェスタ 2017/03/14

  170. X線異常散乱法を用いたNi-Nb系非晶質合金の構造解析

    黒田燎, 有馬寛, 杉山和正, 川又透

    2016年度量子ビームサイエンスフェスタ 2017/03/14

  171. プロトン伝導性鉱物藍鉄鉱と亜砒酸鉄鉱の精密構造と鉄イオン酸化に伴う構造変化

    吉朝朗, 本宮秀明, 杉山和正, 奥部真樹, 有馬寛, 中塚晃彦, 門馬鋼一, 宮脇律郎

    2016年度量子ビームサイエンスフェスタ 2017/03/14

  172. Threading dislocation density of Gallium Nitride crystal, grown under atmospheric pressure Nitrogen

    Akiyama Shinya, Watanabe Makoto, Hayashibe Kazuya, Sugiyama Kazumasa, Miyajima Takao

    JSAP Annual Meetings Extended Abstracts 2017

  173. Ni-Nb系非晶質合金の局所構造単位

    黒田燎, 有馬寛, 川又透, 杉山和正

    日本金属学会講演概要(CD-ROM) 2017

  174. シャルゴッタイトの溶融ガラス部に見られるCa,Ti,Fe局所構造特性

    鳥羽瀬翼, 鳥羽瀬翼, 吉朝朗朗, NESPOLO Massimo, 本宮秀朋, 磯部博志, 奥部真樹, 有馬寛, 杉山和正

    日本地球惑星科学連合大会予稿集(Web) 2017

  175. Structure refinements and structure changes of natural proton-conductor vivianite and parasymplesite

    吉朝朗, 本宮秀朋, 杉山和正, 奥部真樹, 有馬寛, 中塚晃彦, 門馬綱一, 宮脇律郎

    量子ビームサイエンスフェスタ(Web) 2017

  176. Atom and ion transport mechanism in NaAlH4-Ti compounds

    大友季哉, 大友季哉, 大友季哉, 藤崎布美佳, 本田孝志, 本田孝志, 大下英敏, 池田一貴, 中尾裕則, 中尾裕則, 阿部仁, 阿部仁, 有馬寛, 杉山和正, 佐藤豊人, 折茂慎一, 榊浩司, KIM Hyunjeong, 中村優美子

    量子ビームサイエンスフェスタ(Web) 2017

  177. Single crystal structure analyses of Scheelite-Powellite solid solution

    Yamashita Koyumi, Yoshiasa Akira, Miyazaki Haruna, Tokuda Makoto, Tobase Tsubasa, Isobe Hiroshi, Nishiyama Tadao, Sugiyama Kazumasa, Miyawaki Ritsuro

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2017

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    In Mt. Jisyakuyama, Tagawa-machi, Fukuchi-gun, Fukuoka Prefecture, there are skarns that formed a unique production state. In this skarn, Scheelite end component, Powellite end component and solid solutions of intermediate composition are produced close to each other as aggregates. We conducted structure analysis and synthesis experiment of solid solutions and discussed the cause of its unique production state. For it, SEM / EDS was used, and precise structural analysis was carried out. We can expect that will give restrictive conditions to elucidate the mineralization process.

  178. Local structures of Sb and As in K-T boundary clays by the XAFS method and the estimation of concentration processes of those elements

    Hongu Hidetomo, Tobase Tubasa, Yoshiasa Akira, Isobe Hiroshi, Okube Maki, Arima Hiroshi, Sugiyama Kazumasa, Miyawaki Ritsuro

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2017

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    The K-T boundary clay is also enriched in some elements such as As and Sb. We have already clarified about the local structure around Sb atoms in K-T boundary clay by XAFS analyses. In this study, in addition to As XAFS analyses, Sb XAFS measurements were performed again with additional reference materials to determine the concentration phase. From the XANES spectra, the oxidation state of Sb of K-T clays is estimated Sb(+5) and Sb exists as antimony oxides. The XANES spectrum and RSF for Sb of K-T clays agree well with those of schwertmannite.

  179. Structural analysis of viridine by anomalous X-ray scattering

    Tani Yuki, arima hirosi, sugiyama kazumasa, yoshiasa akira

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2017

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    andalusites containing Mn and Fe (viridine) shows grass green colour. We investigated the relations between the existence of transition metals and optical properties by X-ray anomalous scattering(AXS) and XAFS methods.

  180. Determination of chirality of minerals with screw symmetry using X-ray anomalous scattering effects

    Oshiumi Taro, Okube Maki, Arima Hiroshi, Nagase Toshiro, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2017

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    Quartz has two different types of crystal structures, either in P3121 or P3221 space group,which are enantiomorphic to each other. Since conventional X-ray structure analysis can't distinguish these two structures, we applied X-ray anomalous scattering method in our chirality detemination analysis. Levoratory and dextrorotary quartz crystals were proved as in P3121 and P3221 space group, respectively. In addition, we discuss chirality discriomination of Cyrilovite which has 4 fold screw axis.

  181. Local structure of Zr in core- and fusion glass- of Tissint meteorite

    Tobase Tsubasa Tobase, Yoshiasa Akira, Nespolo Massimo, Hongu Hidetomo, Isobe Hiroshi, Arima Hiroshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2017

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    Local structure analysis of Zr in core- and surface- part of Tissint were performed by XAFS method. The formation conditions of both part of Tissint were estimated by comparison between reference materials. The local structures of Zr in core- and surface-part are similar to those in baddeleyite and fulgurite, and suevite, respectively. According to the local structure of Zr, we successed to add the restriction condition to the formation condition of core and surface of Tissint.

  182. Thermal decomposition of kaolinite and chlorite as a proxy for earthquake slip along an imbricate thrust fault in an accretionary prism

    Masumoto Hirokazu, Kameda Jun, Nagai Takaya, Arima Hiroshi, Sugiyama Kazumasa, Yamamoto Yuzuru

    Annual Meeting of the Geological Society of Japan 2017

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    [Program canceled for typhoon] Program canceled for typhoon. However, This abstract is quotable and viewable on PDF.

  183. Local structures of Ca, Ti, Fe in shergottite fusion glass

    Tsubasa Tobase, Massimo Nespolo, Akira Yoshiasa, Hidetomo Hongu, Hiroshi Isobe, Maki Okube, Hiroshi Arima, Kazumasa Sugiyama

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 2017

  184. Precursor phenomenon before phase transitions in PbTiO3 and BaTiO3

    Akira Yoshiasa, Tomotaka Nakatani, Akihiko Nakatsuka, Maki Okube, Hiroshi Arima, Kazumasa Sugiyama

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 2017

  185. ロード石の構造解析とその関連鉱物の結晶化学

    羽田峻輔, 吉朝朗, 磯部博志, 宮野優美子, 本宮秀明, 奥部真樹, 有馬寛, 杉山和正

    日本結晶学会 2016/11/17

  186. ペロブスカイト型PbTiO3の単結晶構造解析:正方相にみられる立方相への転移前駆現象

    吉朝朗, 中塚晃彦, 本宮秀明, 有馬寛, 奥部真樹, 杉山和正

    日本結晶学会 2016/11/17

  187. 木浦鉱山亜ヒ酸藍鉄鉱と奈良登美ヶ丘産藍鉄鉱の構造精密化と水素原子位置に関して

    范華玲, 宮野優美子, 本宮秀明, 吉朝朗, 杉山和正, 奥部真樹, 有馬寛, 中塚晃彦, 門馬鋼一, 宮脇律郎

    日本結晶学会 2016/11/17

  188. 金・白金系鉱物のAu, Pt,Te,Sb,Se,Asの局所構造解析と化学都合性:陽イオン陰イオン双方からのXAFS法による検証

    本宮秀明, 鳥羽瀬翼, 吉朝朗, 杉山和正, 奥部真樹, 有馬寛, 門馬鋼一, 宮脇律郎

    日本結晶学会 2016/11/17

  189. XAFS法によるデボン紀―石炭紀および白亜紀―古第三紀境界層粘土中のTiとZrの局所構造解析:隕石衝突と大量絶滅の検証方法

    鳥羽瀬翼, マッシモネスポロ, 吉朝朗, 本宮秀明, 小松俊文, 前川匠, 奥部真樹, 有馬寛, 杉山和正

    日本結晶学会 2016/11/17

  190. ポストペロブスカイト型(CaIrO3)の結晶構造の温度依存性と原子変位挙動

    中塚晃彦, 谷地史幸, 米田明, 吉朝朗, 藤原恵子, 佐々木聡, 杉山和正

    日本結晶学会 2016/11/17

  191. 広島県生口島産斜開銅鉱Cu3AsO4(OH)3の構造精密化

    馬屋原明寛, 本宮秀明, 吉朝朗, 杉山和正, 奥部真樹, 有馬寛, 中塚晃彦, 門馬鋼一, 宮脇律郎

    日本結晶学会 2016/11/17

  192. 木浦鉱山亜砒藍鉄鉱の構造精密化と水素原子位置について

    范華玲, 宮野優美子, 本宮秀明, 吉朝朗, 杉山和正, 奥部真樹, 有馬寛, 中塚晃彦, 門馬鋼一, 宮脇律郎

    日本鉱物科学会 2016/09/23

  193. アルカリゲルマン酸塩ガラスの局所構造

    有馬寛, 杉山和正

    日本鉱物科学会 2016/09/23

  194. XAFS法によるK-RG境界層年度のTi局所構造解析:新たな巨大隕石衝突の痕跡の可能性

    鳥羽瀬翼, 吉朝朗, ネスポロ マッシモ, 本宮秀明, 磯部博志, 奥部真樹, 有馬寛, 杉山和正

    日本鉱物科学会 2016/09/23

  195. 正方・立方相ペロブスカイト型PbTiO3の相転移機構

    吉朝朗, 本宮秀明, 中塚晃彦, 有馬寛, 杉山和正

    日本鉱物科学会 2016/09/23

  196. 広島県生口島産斜開銅鉱Cu3AsO4(OH)3の構造精密化と水素位置に関して

    馬屋原明寛, 本宮秀明, 吉朝朗, 杉山和正, 奥部真樹, 有馬寛, 中塚晃彦, 門馬鋼一, 宮脇律郎

    日本鉱物科学会 2016/09/23

  197. ダイアスポアの熱膨張に伴う結晶構造変化

    杉浦晃希, 永井隆哉, 有馬寛, 杉山和正

    日本鉱物科学会 2016/09/23

  198. 元素置換に伴うアパタイトの構造変化

    木田祐輔, 志村玲子, 杉山和正, 三河内岳

    日本鉱物科学会 2016/09/23

  199. 非晶質炭酸カルシウムの合成と構造の評価

    磯部佑太, 有馬寛, 杉山和正, 鍵裕之

    日本鉱物科学会 2016/09/23

  200. Crystalline approximants in the Al-rich part of the Al-Ru-Ni system International-presentation

    Shota Suzuki, Rayko Simura, Kazumasa Sugiyama, Akira Yoshiasa

    13th International Conference on Quasicrystals (ICQ13) 2016/09/18

  201. Middle range ordering realized in Zr-Pt amorphous alloy and quasicrystalline approximants International-presentation

    Kazumasa Sugiyama, Toru Kawamata, H.Arima

    13th International Conference on Quasicrystals (ICQ13) 2016/09/18

  202. 常圧窒素雰囲気下ににおける金属ガリウム原料からの窒化ガリウム微粒子結晶の析出

    秋山晋也, 渡辺誠, 高橋芳美, 有馬寛, 杉山和正

    第77回応用物理学会秋季学術講演会 2016/09/13

  203. 窒化ガリウム単結晶の常圧窒素中LPE結晶成長

    秋山晋也, 渡辺誠, 高橋芳美, 杉山和正

    第77回応用物理学会秋季学術講演会 2016/09/13

  204. 糖転移ルチンを粉砕媒体として利用したItraconazoleの非晶質化促進

    赤土 了介, 門田 和紀, 有馬 寛, 杉山 和正, 戸塚 裕一

    日本薬剤学会第31年会 2016/05/19

  205. Zr80Pt20非晶質合金の中距離秩序構造

    杉山和正, 有馬寛, 川又透

    2015年度量子ビームサイエンスフェスタ 2016/03/15

  206. アルカリゲルマン酸塩ガラスの局所構造

    有馬寛, 杉山和正, 川又透

    2015年度量子ビームサイエンスフェスタ 2016/03/15

  207. ペロブスカイト型PbTiO3、BaTiO3強誘電体の結晶構造と温度依存性

    吉朝朗, 仲谷友孝, 中塚晃彦, 奥部真樹, 杉山和正, 真下茂

    2015年度量子ビームサイエンスフェスタ 2016/03/15

  208. Synthesis of Gallium Nitride particle from Gallium metal under atmospheric pressure Nitrogen

    Akiyama Shinya, Watanabe Makoto, Takahashi Yoshimi, Arima Hiroshi, Sugiyama Kazumasa

    JSAP Annual Meetings Extended Abstracts 2016

  209. Middle Range Ordering Structure of Zr80Pt20 Amorphous Alloy

    杉山和正, 有馬寛, 川又透

    量子ビームサイエンスフェスタ(Web) 2016

  210. Structure refinements and temperature dependences on perovskite-type ferroelectric PbTiO3 and BaTiO3

    吉朝朗, 仲谷友孝, 中塚晃彦, 奥部真樹, 杉山和正, 真下茂

    量子ビームサイエンスフェスタ(Web) 2016

  211. The crystal structure refinement and hydrogen atom positions of parasymplesite from Kiura mine, Ohita

    Han Karin, Miyawaki Ritsurou, Miyano Yumiko, Hongu Hidetomo, Yoshiasa Akira, Sugiyama Kazumasa, Okube Maki, Arima Hiroshi, Nakatsuka Akihiko, Momma Koichi

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2016

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    The crystal structure refinement of parasymplesite from Kiura mine, Ohita, Fe3(AsO4)28H2O converged into R = 0.0304 and S = 1.154 for 722 independent reflections of single-crystal XRD data. The hydrogen bonds were described based on hydrogen atom positions on the difference Fourier maps in reference to the bond valence calculations. The bond distance of M2-O5, where O5 is the oxygen of H2O groups, is shorter than that of M2-O2, the oxygen atoms of edge-sharing M22O6(H2O)4 double octahedra.&nbsp;

  212. Local environments of Ti in K-Pg boundary clays probed by XAFS: possible marker of large meteorite impact

    Tsubasa Tobase, Yoshiasa Akira, Nespolo Massimo, Hongu Hidetomo, Isobe Hiroshi, Okube Maki, Arima Hiroshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2016

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    The coordination environments of Ti in K-Pg boundary clays were studied by K-edge XAFS. The XANES spectra and Ti-O distance of K-Pg clays are similar to those of suevite. The formation information at meteorite impact is preserved in the coordination environments of Ti in K-Pg clays. The similarity between Ti coordination environment in K-Pg clays and that in impact glasses suggests that Ti coordination environment investigation may be exploited as a marker of large meteorite impact.&nbsp;

  213. Transition mechanism of tetragonal and cubic perovskite-type PbTiO3

    Yoshiasa Akira, Hongu Hidetomo, Nakatsuka Akihiko, Arima Hiroshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2016

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    High temperature single-crystal X-ray diffraction study of a synthetic PbTiO3 perovskite was carried out in the wide temperature range. The Pb contributes sufficiently to polarization as well as Ti because the positions of both cations shift to the opposite direction of O positions. The deviation from the linear changes in Debye Waller factors and bonding distances in the tetragonal phases can be interpreted as a precursor phenomenon before the phase transition.

  214. The crystal structure refinement and hydrogen atom positions of from Clinoclase, Cu3AsO4(OH)3 Ikuchi, Hiroshima

    Umayahara Akihiro, Hongu Hidetomo, Yoshiasa Akira, Sugiyama Kazumasa, Okube Maki, Arima Hiroshi, Nakatsuka Akihiko, Momma Koichi, Miyawaki Ritsurou

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2016

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    The crystal structure refinement of clinoclase from Ikuchi, Hiroshima Cu3AsO4(OH)3 converged into R = 0.0245 and S = 1.158 for 1598 independent reflections of single-crystal XRD data. Space between the respective complex sheets is filled with hydrogen. Two kinds of five coordinate Cu-sites form largely distorted tetragonal pyramids. The four coordinate Cu-site forms square planar. We will discuss the complex structure and largely distorted Cu-sites, Van der Waals bonds and hydrogen bonds.

  215. 浮遊帯域溶融法で作製した不純物添加Ga2O3単結晶の結晶評価

    山崎敬太, 志村玲子, 杉山和正, 有馬寛, 菅原孝昌, 湯蓋邦夫, 吉朝朗

    第51回X線分析討論会 2015/10/29

  216. X線異常散乱法を用いた非晶質金属の構造解析

    杉山和正, 有馬寛, 川又透

    第51回X線分析討論会 2015/10/29

  217. 白亜紀-第三紀境界粘土層中のSbの存在形態と濃農機構

    本宮秀朋, 鳥羽瀬翼, 平床竜也, 磯部博志, 吉朝朗, 奥部真樹, 有馬寛, 杉山和正, 宮脇律郎

    日本結晶学会 2015/10/17

  218. Zn-IM系MOFの合成と結晶構造解析

    長谷川亘, 志村玲子, 有馬寛, 杉山和正

    日本結晶学会 2015/10/17

  219. 2配位子を導入したMOFの合成とその結晶構造

    金翔平, 有馬寛, 杉山和正

    日本結晶学会 2015/10/17

  220. アングライト隕石中の含Siカルシウムリン酸塩の鉱物結晶学

    三河内岳, 杉山和正

    日本鉱物科学会 2015/09/25

  221. 含水量の異なる非晶質炭酸カルシウムの構造解析

    丸山 浩司, 鍵裕之, 有馬寛, 杉山和正

    日本鉱物科学会 2015/09/25

  222. CaGeO3 正方晶ガーネットに由来した低対称ハイドロガーネットの化粧構造と水素結合

    中塚晃彦, 大山玄多, 藤原恵子, 大高理, 奥部真紀, 佐々木聡, 杉山和正

    日本鉱物科学会 2015/09/25

  223. K-T境界粘土層中のSbの形態とその濃集要因

    本宮秀朋, 鳥羽瀬翼, 平床竜矢, 磯部博志, 吉朝朗, 奥部真樹, 有馬寛, 杉山和正, 宮脇律郎

    日本鉱物科学会 2015/09/25

  224. 隕石溶融ガラスのCa、Ti、Fe局所構造のXAFS法による解析

    鳥羽瀬翼, 吉朝朗, 王玲, 本宮秀朋, 磯部博志, 奥部真紀, 有馬寛, 杉山和正

    日本鉱物科学会 2015/09/25

  225. Liイオン伝導性LiMxGe2-x(PO4)3 (M=Al, Ti)の多面的局所構造解析

    山本悠貴友, 藤枝 俊, 篠田弘造, 鈴木 茂, 有馬 寛, 杉山和正

    日本鉄鋼協会第170回秋季講演大会 2015/09/16

  226. High Temperature Structural Change of Pollucite International-presentation

    H.Arima, T.Imai, K.Sugiyama, A.Nakatsuka

    12th International Congress for Applied Mineralogy 2015/08/10

  227. Anomalous X-ray Scattering Study of ZrO2 Powders prepared from ZrOCl2 solution International-presentation

    K.Sugiyama, R.Murao, A.H.Shinohara

    12th International Congress for Applied Mineralogy 2015/08/10

  228. Displacement Corelation Functions and Mean Square Dosplacements in CaGeO3 Perovskitre and Garnet Phase. International-presentation

    A.Yoshiasa, T.Tobase, A,Nakatsuka, M.Okube, H.Arima, K.Sugiyama

    12th International Congress for Applied Mineralogy 2015/08/10

  229. TRANSMISSION ELECTRON MICROSCOPY OF SILICO-APATITE IN D'ORBIGNY.

    T. Mikouchi, K. Sugiyama, A. Yasuhara, T. Mihira

    METEORITICS & PLANETARY SCIENCE 2015/08

  230. XRDを用いたカルシウムフェライトの還元反応過程のその場観察

    村尾玲子, 杉山和正

    日本鉄鋼協会第169回春季講演大会 2015/03/18

  231. 散乱強度プロファイルにプレピークを示す非晶質合金の中距離領域構造

    石井悠嗣, 川又透, 有馬寛, 杉山和正

    2014年度物構研サイエンスフェスタ 2015/03/17

  232. Fe-BおよびNi-B非晶質合金の構造解析

    有馬寛, 川又透, 杉山和正, 大友季哉

    2014年度物構研サイエンスフェスタ 2015/03/17

  233. 強い重力場による酸化物の結晶構造変化

    真下茂, 緒方裕大, Ragum Rabaya, 杉山和正, 杵鞭義明, 奥部真樹, 速水和正, 富永正人, 磯部博志, 吉朝朗

    第62回応用物理学会春季学術講演会 2015/03/11

  234. Pseudo-Mackay clusters realized in the approximant phases for icosahedral quasicrystals International-presentation

    K.Sugiyama

    1st International Forum on the Advanced Materials Processing using Extreme Conditions. 2015/03/06

  235. Crystal-structurue change of some oxides under strong gravitational field

    Mashimo Tsutomu, Ogata Yudai, Bagum Rabaya, Sugiyama Kazumasa, Kinemuchi Yoshiaki, Okube Maki, Hayami kazumasa, Tominaga Masato, Isobe Hiroshi, Yoshiasa Akira

    JSAP Annual Meetings Extended Abstracts 2015/02/26

  236. 結晶表記の基本

    杉山和正

    日本学術振興会第161委員会 第89回研究会 2015/01/07

  237. Local structure of Ca, Ti and Fe in fusion glasses probed by XAFS

    Tobase Tsubasa, Yoshiasa Akira, Wang Ling, Hongu Hidetomo, Isobe Hiroshi, Okube Maki, Arima Hiroshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2015

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    The local structures of meteorite fusion crusts were studied by Ca, Ti and Fe K-edge XANES and EXAFS spectroscopy in order to provide qualitative and quntitative data on coordination environments. This study indicated that meteorite fusion crusts gives unique local structures. The Ca, Ti and Fe XANES spectra for fusion crusts have unique and various shapes. The Ca-O distance in meteorite fusion crusts are 2.61-2.66 A and are extremely longer than the other natural glasses. The fusion crusts have unique local structure since it was experienced extremely high temperature and short quenching time.

  238. Crystal structure and hydrogen bonds of the low-symmetry hydrogarnet derived from CaGeO3 tetragonal garnet

    Nakatsuka Akihiko, Ohyama Genta, Fujiwara Keiko, Ohtaka Osamu, Okube Maki, Sasaki Satoshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2015

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    The tetragonal hydrogarnet derived from CaGeO3 tetragonal garnet was synthesized under high pressure and high temperature. The hydrogen positions were determined and the hydrogen bonding was examined by single-crystal X-ray diffraction. Consequently, the bifurcated hydrogen-bond can be formed between an H atom and its adjacent two acceptor O atoms.

  239. Crystal size distribution obtained by polarization CCD camera system ~ A example from the lower contact of the Nosappumisaki dolerite intrusion, Northern Japan~

    SIMURA Rayko, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2015

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    Size distributions in thinsections of rocks in the lower marginal zone in the Nosappumisaki doleraite intrusion, Northern Japan, were obtained with using the polarization CCD camera system. Mineral types were identified with using the retardation obtained by the system. Analyses of the retardation and primary-axis direction in groundmass of the rocks revealed systematic evolution of size distribution, that corresponded to solidification progression from the contact with host rock toward the inner region of the magma chamber.&nbsp;

  240. Local Structure of Sb in Cretaceous-Tertiary Boundary Clays from Stevns Klint by the XAFS Method International-presentation

    H.Hongo, A.Yoshiasa, T.Tobase, T.Hiratoko, H.Isobe, H.Arima, K.Sugiyama, M.Okube

    American Geophysical Union 2014 Fall Meeting 2014/12/15

  241. Raman Spectroscopy and Structure of MgSiO3 High Temperature C2/c Clinoenstatite International-presentation

    R.Kusu, A.Yoshiasa, T.Nishiyama, N.Akihiko, M.Okube, H.Arima, K.Sugiyama

    American Geophysical Union 2014 Fall Meeting 2014/12/15

  242. W2-AlPdCoの結晶構造

    杉山和正, 湯蓋邦夫, 鈴木将太

    日本結晶学会 2014/11/01

  243. Ca-Ge-O-H系正方晶ハイドロガーネットにおけるOH基の選択性と水素結合

    中塚晃彦, 松富大記, 藤原恵子, 中山則夫, 大高理, 杉山和正

    日本結晶学会 2014/11/01

  244. リチウムゲルマン酸塩ガラスの局所構造

    有馬寛, 川又透, 杉山和正

    日本鉱物科学会 2014/09/17

  245. Prosopite CaAl2F4-x(OH)4+xの構造精密化と水素結合

    手嶋綾, 陣内聡, 磯部博志, 吉朝朗, 杉山和正, 有馬寛, 門馬綱一, 宮脇律郎

    日本鉱物科学会 2014/09/17

  246. Kottigite-symplesite固溶体の結晶構造と水素結合

    宮野優美子, 吉朝朗, 陣内聡, 磯部博志, 杉山和正, 有馬寛, 門馬綱一, 宮脇律郎, 奥部真紀

    日本鉱物科学会 2014/09/17

  247. Cuprian Elbaiteに含まれるCuおよびMn

    杉山和正, 有馬寛, 川又透

    日本鉱物科学会 2014/09/17

  248. レグランド石、アダム石、パラアダム石の構造精密化:結晶化学と水素結合の詳細

    陣内聡, 吉朝朗, 杉山和正, 有馬寛, 志村玲子, 宮脇律郎

    日本鉱物科学会 2014/09/17

  249. Ca-Ge-O-H系正方晶ハイドロガーネットの結晶構造と水素結合

    中塚晃彦, 松富大記, 藤原恵子, 中山則昭, 大高理, 杉山和正

    日本鉱物科学会 2014/09/17

  250. 高温型C 2/c単斜エンスタタイトのラマン測定

    楠 遼介, 吉朝朗, 西山忠男, 奥部真紀, 杉山和正, 有馬寛, 中塚晃彦

    日本鉱物科学会 2014/09/17

  251. AXSおよびHEXD法によるフェリハイドライトの精密構造解析

    針生剛, 有馬寛, 杉山和正

    日本鉱物科学会 2014/09/17

  252. 高温化におけるポルックス石の結晶構造変化

    今井健, 有馬寛, 杉山和正, 中塚晃彦

    日本鉱物科学会 2014/09/17

  253. EXPERIMENTAL CRYSTALLIZATION OF IRON MARTENSITE IN THE ALMAHATA SITTA UREILITE.

    T. Mikouchi, Y. Aoyagi, K. Sugiyama, Y. Yokoyama, C. A. Goodrich, M. E. Zolensky

    METEORITICS & PLANETARY SCIENCE 2014/09

  254. Structure refinement of legrandite and paradamite: crystal chemistry and hydrogen bond International-presentation

    S.Jinnouchi, A.Yoshiasa, K.Sugiyama, R.Miyawaki

    IMA2014 21th Genmaral Meeting of the International Mineralogical Association 2014/09/01

  255. Distribution of Minor Elements in Complex Oxide Structure. International-presentation

    K.Sugiyama

    The 3th Japan-Cjina Crystal Growth and Crystal Technology 2014/08/31

  256. Pseudo-Mackay clusters in the Al-Pd-Co system International-presentation

    K.Sugiyama, S.Suzuki, R.Simura

    23th Congress and General Assembly of the International Union of Crystallography 2014/08/05

  257. Structure refinement of kottigite and symplesite solid-solution. International-presentation

    Y.Miyano, A.Yoshiasa, K.Sugiyama, H.Arima, T.Nakatsuka, M.Okube

    23th Congress and General Assembly of the International Union of Crystallography 2014/08/05

  258. Structure analysis for Fe-based and Ni-based metal-metalloid amorphous alloys. International-presentation

    H.Arima, T.Kawamata, Y.Yokoyama, K.Sugiyama, T.Otomo

    23th Congress and General Assembly of the International Union of Crystallography 2014/08/05

  259. Structure and H position of tetragonal hydrogarnet deived from CaGeO3 garnet. International-presentation

    A.Nakatsuka, H.Matsutomi, K.Fujiwara, N.Nakayama, O.Ohtaka, K.Sugiyama

    23th Congress and General Assembly of the International Union of Crystallography 2014/08/05

  260. The Distribution of Cu in Elbaite International-presentation

    K.Sugiyama, H.Arima, H.Konno, T.Kawamata

    The 6th Asian Conference on Crystal Growth and Crystal Technology 2014/06/11

  261. Thermal Expansion of Sr2SiO4 and Ba2SiO4 International-presentation

    H.Arima, Y.Hirohata, K.Sugiyama, A Nakatsuka

    The 6th Asian Conference on Crystal Growth and Crystal Technology 2014/06/11

  262. 東北放射光施設ビームライン

    杉山和正

    東北大学東北放射光施設推進会議 2014/05/20

  263. Crystallization experiment of alpha-Fe, gamma-Fe and iron compounds found in the Almahata Sitta and Antarctic ureilites.:Almahata Sittaおよび南極産ユレイライトに見られるα鉄,γ鉄,鉄化合物の結晶化実験

    青柳 雄也, 三河内 岳, 杉山 和正, 横山 嘉彦, Goodrich, Cyrena A

    日本地球惑星科学連合 2014/04/28

  264. LegranditeとParadamiteの構造精密化 : 結晶化学と水素結合の詳細:Structure refinement of legrandite and paradamite : crystal chemistry and hydrogen bonds

    陣内 聡, 吉朝 朗, 杉山 和正, 有馬 寛, 志村 玲子, 宮脇 律郎

    日本地球惑星科学連合 2014/04/28

  265. 放射光X線を用いたフェリハイドライトの構造解析

    針生剛, 有馬寛, 杉山和正

    物構研サイエンスフェスタ 2014/03/18

  266. X線異常散乱法を用いたpiemontiteの結晶構造解析

    櫻井謡子, 有馬寛, 杉山和正

    物構研サイエンスフェスタ 2014/03/18

  267. AXS-RMC法を用いた Al 基非晶質合金の中距離構造解析

    石井悠嗣, 川又透, 有馬寛, 横山嘉彦, 杉山和正

    物構研サイエンスフェスタ 2014/03/18

  268. 中性子回折およびエックス線異常散乱法による非晶質金属の構造解析

    有馬寛, 川又透, 横山嘉彦, 杉山和正

    2013年度MLF液体・非晶質材料分科会ユーザーズ・ミーティング 2014/03/17

  269. Structural analysis of O-AlNiRu

    鈴木将太, 志村玲子, 杉山和正

    卓越した大学院研究拠点による日露ワークショップ 2014/03/10

  270. 27pAF-7 Synthesis of Hausmannite-type Fe_3O_4 single crystal by a strong gravitational field

    Mashimo Tsutomu, Bagum Rabaya

    Meeting Abstracts of the Physical Society of Japan 2014

  271. Raman spectroscopy of high-T C2/c clino-enstatite

    Kusu Ryosuke, Yoshiasa Akira, Nishiyama Tadao, Okube Maki, Sugiyama Kazumasa, Arima Hiroshi, Nakatsuka Akihiko

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2014

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    MgSiO3 enstatite is one of the important rock-forming minerals. The high-pressure type is well known C2/c clino-enstatite. However, the high-temperature type was not confirmed about the stability region. Furthermore, the high-temperature phase is doubted even a presence. In this study, we performed the raman spectrometry that the high temperature type C2/c clino-enstatite obtained by rapid cooling and ortho-enstatite. They were compared with previous study for high-temperature phases.

  272. Structure refinement and hydrogen bonds of prosopite CaAl2F4-x(OH)4+x

    Teshima Aya, Jinnouchi Satoshi, Isobe Hiroshi, Yoshiasa Akira, Sugiyama Kazumasa, Arima Hiroshi, Momma Koichi, Miyawaki Ritsuro

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2014

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    As for prosopite expressed with chemical formula&nbsp;CaAl2F4-x(OH)4+x,x=0&sim;1, any unclear points such as hydrogen bonding, an anionic site preference, and the comparison with the related minerals were left. Therefore, in this study,&nbsp;we perform chemical analysis by EPMA and the crystal structure refinement by RAPID(RIGAKU single-crystal structure analysis system).The detailed structure included relation of solid solution of F and OH and a hydrogen position are clarified.

  273. Structure and H position of tetragonal hydrogarnet in the system Ca-Ge-O-H

    Nakatsuka Akihiko, Matsutomi Hiroki, Fujiwara Keiko, Nakayama Noriaki, Ohtaka Osamu, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2014

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    We have successfully synthesized the single crystal of a new low-symmetry hydrogarnet with &nbsp;CaGe0.924O3H0.304 composition (tetragonal; space group I41/a), at 3 GPa and 1273 K. This compound is produced by the partial replacement of (GeO4)4- in CaGeO3 tetragonal garnet by (H4O4)4-. In the present study, we have conducted the single crystal X-ray diffraction study of this tetragonal hydrogarnet at 98 and 298 K to determine the H positions and discuss the H bonding in the crystal structure.

  274. Structures refinement of legrandite, adamite and paradamite : crystal chemistry and hydrogen bonding

    Jinnouchi Satoshi, Yoshiasa Akira, Sugiyama Kazumasa, Arima Hiroshi, Shimura Reiko, Miyawaki Riturou

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2014

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    Legrandite (Zn2AsO4(OH)H2O) and paradamite, adamite (Zn2AsO4(OH)), are zinc arsenate minerals. We performed the structure refinement of legrandite, paradamite and adamite Oujela Mine, Mapimi, Durango, Mexico, by (RAPID) RIGAKU single-crystal structure analysis system. We determined the hydrogen position by difference Fourier method. We revealed the detail hydrogen bonding using bond valence calculation and hydrogen positions and compared crystal structures of these. In adamite, there are weak hydrogen bonds in the same polyhedrons.By contrast, there are standard hydrogen bonds in paradamite. In the structure of legrandite, there are various type hydrogen bonds. In consequently, the structure of legrandite is very complicated.

  275. Local structure of Zr in K-T boundary clays probed by XAFS

    Tobase Tsubasa, Yoshiasa Akira, Wang Ling, Hongu Hidetomo, Sugawara Masahiko, Isobe Hiroshi, Sugiyama Kazumasa, Okube Maki

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2014

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    The local structure of K-T boundary clays was studied by Zr K-edge XAFS in order to provide quantitative data on bonding distance and coordination numbers. The zirconium XANES spectra in K-T boundary clays are similar to rhyolitic volcanic glasses (obsidian and pitch stone) and tektite. It suggested that local structures of Zr in K-T clays remain the thermal quenching history at meteorite impact. The Zr-O distance in K-T boundary clays is 2.164 &Aring; and the coordination number is 6.3. The data suggested that Zr local structure in K-T boundary clays are formed relatively under the condition of higher temperature and lower oxidation state than volcanic glasses and total electric charge of Zr ions is less than 4 and estimated as 3.8.

  276. Structural change of pollucite at high temperature

    Imai Takeru, Arima Hirosi, sugiyama kazumasa, Nakatsuka Akihiko

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2014

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    The variation of unit-cell parameter of pollucite under high temperatures was studied using thermal analysis (TG-DTA) and high-temperature X-ray powder diffraction. The release of the interstitial water molecules is attributed to the shrinkage of a-axis between 300oC and 600oC. The expansion of the cell volume detected below 300oC and over 600oC could be an effect of the rearrangement of the interstitial cations coupled with the tilting T-O-T angles.

  277. Structural study of ferrihydrite using anomalous X-ray scattering and high energy X-ray diffraction methods

    Hariu Tsuyoshi, Arima Hiroshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2014

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    We have investigated short- and medium- range structure of two types of synthesized ferrihydrite sample (2-line and 6-line forms) using AXS and HEXRD methods. There are no significant differences in environmental structures around Fe for both samples. Nevertheless, the difference in the coherent domain size was clearly detected in the obtained pair distribution functions.

  278. Structure and H position of tetragonal hydrogarnet derived from CaGeO3 garnet

    A. Nakatsuka, H. Matsutomi, K. Fujiwara, N. Nakayama, O. Ohtaka, K. Sugiyama

    Acta Crystallographica 2014

  279. ナノ多孔体の微細構造:回折、散乱、像を通じて見えた事、見たい事

    寺崎治, H.S.Cho, MH.Cho, 宮坂慶一, Y.Ma, P.Oleynikov, 朝比奈俊介, 須賀三雄, 大砂哲, 劉崢, 阪本康弘, 富樫望, 杉山和正, H.Deng, OM Yaghi, V.Alfredsson、L.Han, S.Che

    第29回セオライト研究会 2013/11/27

  280. レグランダイト石の構造精密化と水素結合の詳細

    陣内 聡, 吉朝朗, 杉山和正, 有馬寛, 志村玲子, 宮脇律郎

    日本結晶学会 2013/10/12

  281. CaGeO3多形のXAFSによる有効ペアポテンシャル解析

    小金丸 藍, 吉朝朗, 有馬寛, 中谷友孝, 王玲, 奥部真樹, 中塚晃彦, 大高理, 杉山和正

    日本結晶学会 2013/10/12

  282. ペロブスカイト型及びガーネット型cAgEo3高圧相の回折法とxafs方によるDebye-Waller因子の比較研究

    吉朝朗, 小金丸藍, 中塚晃彦, 有馬寛, 杉山和正, 奥部真樹, 大高理

    日本結晶学会 2013/10/12

  283. 白亜紀ー第三紀地質年代境界粘土層中野Sbの局所構造解析

    本宮秀明, 鳥羽瀬翼, 平床竜矢, 王玲, 吉朝朗, 奥部真樹, 有馬寛, 杉山和正, 宮脇律郎

    日本結晶学会 2013/10/12

  284. 周期・非周期系物質に存在するランダム構造の解析

    杉山和正

    日本学術振興会第161委員会 第81回研究会 2013/10/11

  285. AXS-RMC 法を用いたPd基非晶質合金の構造解析

    林良哉, 有馬寛, 川又透, 杉山和正, 春山修身

    日本金属学会 2013/09/17

  286. ガラスおよび結晶状態におけるLiGe2(PO4)3系化合物の構造解析

    小鹿裕希, 藤枝俊, 篠田弘造, 鈴木茂, 柴田浩幸, 早稲田嘉夫, 有馬寛, 川又透, 杉山和正

    日本金属学会 2013/09/17

  287. レグランド石の構造精密化:結晶科学と水素結合

    陣内聡, 吉朝朗, 杉山和正, 有馬寛, 志村玲子, 宮脇律郎

    日本鉱物科学会 2013/09/11

  288. XAFS法によるK-T境界粘土層中のSbの局所構造

    本宮秀朋, 鳥羽瀬翼, 平床竜也, 王玲, 磯部博志, 吉朝朗, 奥部真樹, 有馬寛, 杉山和正, 宮脇律郎

    日本鉱物科学会 2013/09/11

  289. Structure refinement of legrandite : crystal chemistry and hydrogen bonds

    JINNOUCHI S., YOSHIASA A., SUGIYAMA K., ARIMA H., SHIMURA R., MIYAWAKI R.

    日本鉱物科学会年会講演要旨集 2013/09/05

  290. Ce: Gd3(Al,Ga)5O12単結晶におけるGa置換量とシンチレータ特性の関係

    鎌田 圭, 遠藤 貴範, 堤 浩輔, 佐藤 浩樹, 関 真冬, 黒澤 俊介, 横田 有為, 庄子 育宏, 吉川 彰, 杉山 和正

    応用物理学会学術講演会講演予稿集 2013/08/31

  291. Structural Study of Zr-Cu-Ag Bulk Metallic Glasses Using the Anomalous X-ray Scattering Method International-presentation

    T.Kawamata, K.Sugiyama, Y.Yokoyama, T.Fujita

    Light and Particle Beams LPBMS2014 in Material Science 2013/08/29

  292. Site Determination of Sr3YB3O9 Crystals by Anomalous X-ray Scattering International-presentation

    R.Simua, K.Sugiyama

    Light and Particle Beams LPBMS2014 in Material Science 2013/08/29

  293. Transmission electron microscopy of iron metal in Almahata Sitta ureilite International-presentation

    Mikouchi T, Yubuta K, Sugiyama K, Aoyagi Y, Yasuhara A, Mihira T, Zolensky M. E, Goodrich C. A

    The 23th Annual Goldschmidt Conference 2013/08/25

  294. Structure of Al87Y8Ni5 amorphous alloy analyzed by anomalous X-ray scattering International-presentation

    H.Arima, T.Kawamata, Y.Yokoyama, K.Sugiyama

    The 12th Asia Pacific Physics Conference of APPC 2013/08/25

  295. Cooling history of Almahata Sitta ureilite as inferred from transmission electron microscopy of iron metal International-presentation

    Mikouchi T, Aoyagi Y, Goodrich C. A, Yubuta K, Sugiyama K, Zolensky M. E, Goldstein J. I

    The 76th Annual Meeting of The Meteoritical Society 2013/07/29

  296. COOLING HISTORY OF ALMAHATA SITTA UREILITE AS INFERRED FROM TRANSMISSION ELECTRON MICROSCOPY OF IRON METAL

    T. Mikouchi, Y. Aoyagi, C. A. Goodrich, K. Yubuta, K. Sugiyama, M. E. Zolensky, J. I. Goldstein

    METEORITICS & PLANETARY SCIENCE 2013/07

  297. Static measurements for α- and β-relaxation below T<inf>g</inf> in a Zr<inf>55</inf>Cu<inf>30</inf>Ni<inf>5</inf>Al<inf>10</inf> BMG

    Osami Haruyama, Hiroyuki Sawada, Kazuhiro Yoshikawa, Tohru Kawamata, Yoshihiko Yokoyama, Kazumasa Sugiyama

    TMS Annual Meeting 2013/04/25

  298. AXS-RMC 法を用いたPd82Ge18非晶質合金の構造解析

    林良哉, 川又透, 有馬寛, 杉山和正

    日本金属学会 2013/03/27

  299. ポルックス石中での超重力場による陽イオン拡散

    有馬寛, 杉山和正, 真下茂, 吉朝朗

    第60回応用物理学会春季学術講演会 2013/03/27

  300. X線小角散乱法による土壌中のナノ粒子の定量

    月村勝宏, 鈴木正哉, 杉山和正

    微生物-鉱物-水-大気相互作用研究会 2013/03/21

  301. X線異常散乱法を用いたZr基非晶質合金の精密構造解析

    川又透, 横山嘉彦, 杉山和正

    物構研サイエンスフェスタ 2013/03/14

  302. AXS-RMC法を用いたPd系非晶質合金の構造解析

    林 良哉, 川又透, 有馬寛, 杉山和正

    物構研サイエンスフェスタ 2013/03/14

  303. 強い重力場を用いた反ポーリング則構造を持つTiO2の合成

    真下 茂, 緒方 裕大, 奥部 真樹, 杉山 和正, 杵鞭 義明, 磯部 博志, 吉朝 朗

    応用物理学会学術講演会講演予稿集 2013/03/11

  304. ポルックス石中での超重力場による陽イオン拡散

    有馬 寛, 杉山 和正, 真下 茂, 吉朝 朗

    応用物理学会学術講演会講演予稿集 2013/03/11

  305. Structure of ε16-AlPdCo

    鈴木将太, 志村玲子, 杉山和正

    卓越した大学院研究拠点による日露ワークショップ 2013/03/07

  306. Ce:Gd3(Al,Ga)5O12単結晶におけるGa置換量とシンチレータ特性の関係

    鎌田圭, PRUSA Petr, NIKL Martin, 遠藤貴範, 堤浩輔, 関真冬, 黒澤俊介, 横田有為, 庄子育宏, 吉川彰, 吉川彰, 杉山和正

    応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2013

  307. AXS-RMC法を用いたPd基非晶質合金の構造解析

    林良哉, 林良哉, 有馬寛, 川又透, 杉山和正, 春山修身

    日本金属学会講演概要(CD-ROM) 2013

  308. AXS-RMC法を用いたPd82Ge18非晶質合金の構造解析

    林良哉, 川又透, 有馬寛, 杉山和正

    日本金属学会講演概要(CD-ROM) 2013

  309. ガラスおよび結晶状態におけるLiGe2(PO4)3系化合物の構造解析

    小鹿裕希, 藤枝俊, 篠田弘造, 鈴木茂, 柴田浩幸, 早稲田嘉夫, 有馬寛, 川又透, 杉山和正

    日本金属学会講演概要(CD-ROM) 2013

  310. The crystal structure refinement of regrandite

    Jinnouchi Satoshi, Yoshiasa Akira, Sugiyama kazumasa, Arima Hirosi, Shimura Reiko, Miyawaki Riturou

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2013

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    Crystal structural refinement of legrandite was performed using RIGAKU single crystal structure analysis system (RAPID). The hydrogen atom position, distortion around cations, structural relation among arsenate and phosphate minerals were determined. We also made it clear the charge balance in the structure by bond-valence method. We will discuss the details of crystal chemistry of legrandite and one-dimensional proton conduction.

  311. Crystal structure of magnetite single crystal annealed under super strong gravity

    A. Yoshiasa, T. Mashimo, A. Nakatsuka, H. Arima, K. Sugiyama

    Annual Report of the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University 2013

  312. Structure of τ2-Al3Co, a monoclinic approximant of the Al-Co decagonal quasicrystal.

    K.Sugiyama, A.Yasuhara, K.Hiraga

    Aperiodic Crystals, Proceedings of Aperiodic 2012 2013

  313. Effective pair potential for Ca-O bonds in CaGeO3 polymorphs

    A. Koganemaru, A. Yoshiasa, L. Wang, T. Nakatani, A. Nakatsuka, M. Okube, H. Arima, K. Sugiyama

    15TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS15) 2013

  314. 焼結鉱中カルシウムフェライト相の結晶構造と還元による変化

    第5回 製鉄・資源に関するWorkshop(還元研究会) 2012/12/17

  315. 収束電子線回折およびHARRDF-STEMを用いたAl-Ni-Ruデカゴナル準結晶および近似結晶相の構造の研究

    横山大樹, 齋藤晃, 田中信夫, 高倉洋礼, 杉山和正, 鈴木将太

    日本結晶学会 2012/10/25

  316. 小角散乱デバイの剛体球モデルの問題点と改良法

    月村勝宏, 鈴木正哉, 杉山和正

    日本結晶学会 2012/10/25

  317. 近似結晶相e0-AlPdCoの構造解析

    鈴木将太, 志村玲子, 湯蓋邦夫, 杉山和正

    日本結晶学会 2012/10/25

  318. XAFS法を用いた天然産ガラスの局所構造研究と分類

    王 玲, 奥部真樹, 仲谷友孝, 鳥羽瀬 翼, 吉朝 朗, 有馬寛, 磯部博志, 杉山和正

    日本結晶学会 2012/10/25

  319. XAFS法によるCaGeO3多形のCa-O有効二体間ポテンシャル解析

    小金丸 藍, 吉朝 朗, 有馬寛, 仲谷友孝, 王 玲, 奥部真樹, 中塚晃彦, 大高 理, 杉山和正

    日本結晶学会 2012/10/25

  320. XAFS法によるテクタイトと天然ガラス中のCaの局所構造

    鳥羽瀬 翼, 王 玲, 奥部 真樹, 仲谷友孝, 吉朝 朗, 有馬 寛, 磯部 博志, 杉山 和正

    日本結晶学会 2012/10/25

  321. 希土類元素=アルカリ土類金属系の新規ホウ酸塩結晶(Sr3Yb6(BO3)8)の構造解析

    河合 祥平, 志村 玲子, 杉山 和正

    日本結晶学会 2012/10/25

  322. 超強遠心力場下におけるポルックス石中の陽イオン拡散

    有馬 寛, 杉山 和正, 真下 茂

    日本結晶学会 2012/10/25

  323. 東北放射光施設構想について

    東北放射光施設支援協議会

    日本結晶学会 2012/10/25

  324. CuO-SiO2-H2O系珪孔雀石類縁物質の合成と構造解析

    針生 剛, 有馬 寛, 杉山 和正

    日本鉱物科学会 2012/09/19

  325. SiO2系天然ランダム物質のRDF解析

    宮城 寛幸, 志村 玲子, 杉山 和正

    日本鉱物科学会 2012/09/19

  326. X線異常散乱を利用した単結晶X線構造解析による 結晶原子席の特定-アルカリ土類金属=希土類ホウ酸塩結晶の例-

    志村 玲子, 杉山 和正

    日本鉱物科学会 2012/09/19

  327. Pt57.5Cu14.7Ni5.3P22.5バルク金属ガラスの構造緩和課程

    葛西惇, 春山修身, 横山嘉彦, 杉山和正

    日本金属学会 2012/09/17

  328. 強加工したZr55Cu30Ni5Al10バルク金属ガラスにおけるfree volume

    木皿明一, 春山修身, 杉山和正, 横山嘉彦

    日本金属学会 2012/09/17

  329. RDF analysis of the SiO_2 based disordered materials

    MIYAGI H, SIMURA R, SUGIYAMA K

    日本鉱物科学会年会講演要旨集 2012/09/15

  330. Synthesis & structural study of sol-gel materials in CuO-SiO_2-H_2O system comparing with natural chrysocolla

    HARIU T, ARIMA H, SUGIYAMA K

    日本鉱物科学会年会講演要旨集 2012/09/15

  331. Site determination by single crystal X-ray structural analysis with anomalous X-ray scattering : an example of a double borate single crystal with alkali earth metal and rare earth elements

    SIMURA Rayko, SUGIYAMA Kazumasa

    日本鉱物科学会年会講演要旨集 2012/09/15

  332. Structure of τ2-Al3Co, a monoclinic approximant of the Al-Co decagonal qusicrystal. International-presentation

    K.Sugiyama, A.Yasuhara, K.Hiraga

    Aperidic2012 2012/09/02

  333. Structure of ε16 phase in Al-Pd-Co system studied by HREM and X-ray diffraction. International-presentation

    K.Yubuta, S.Suzuki, R.Simura, K.Sugiyama

    Aperidic2012 2012/09/02

  334. Free Volume in a Cold Worked Zr55Cu30Ni5Al10 BGM International-presentation

    O.Haruyama, K.Kisara, K.Kogure, A.Yamashita, Y.Yokoyama, K.Sugiyama

    International Union of Materials Research Societies International Conference in Asia 2012 2012/08/26

  335. 強加工したZr55Cu30Ni5Al10バルク金属ガラスにおけるfree volume

    小暮和正, 小暮和正, 木皿圭一, 山下明希, 山下明希, 春山修身, 杉山和正, 横山嘉彦

    日本金属学会講演概要(CD-ROM) 2012

  336. Pt57.5Cu14.7Ni5.3P22.5バルク金属ガラスの構造緩和過程

    葛西惇, 葛西惇, 春山修身, 横山嘉彦, 杉山和正

    日本金属学会講演概要(CD-ROM) 2012

  337. Site determination by single crystal X-ray structural analysis with X-ray anomalous scattering: an example of a double borate single crystal with alkali earth metal and rare earth elements

    Simura Rayko, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2012

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    X-ray structural analysis with using anomalous scattering can directly determine the atomic sites of atoms having the similar atomic numbers, such as Fe and Co, Cr and Mn, or Sr and Y. We measured a Sr3YB3O9 single crystal by using the 4 circle diffractometer at the BL-10A in Photon Factory, KEK. The energy of incident X-ray was selected by a monochromater of Si(111) to have the appropriate energy. The stricture was refined by SHELX-97 and the sites of Sr and Y were successfully determined with considering the anomalous scattering.

  338. Synthesis & structural study of sol-gel materials in CuO-SiO2-H2O system comparing with natural chrysocolla

    Hariu Tsuyoshi, Arima Hiroshi, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2012

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    Chrysocolla is an amorphous copper silicate which is yielded such as oxide copper deposit. Natural chrysocolla exist as Cu/Si=1. The atomic structure of chrysocolla and its generation process is not clear. In this study, substances related to chrysocolla were synthesized by sol-gel method changing the mol ratio of Cu/Si in starting material. As a result, the syntheses of Cu/Si&ne;1 were succeeded. The local Cu structure of them were smilar to that of natural chrysocolla. These result indicates that the generation process of chrysocolla is revealed through the liquid phase.

  339. RDF analysis of the SiO2 based disordered materials

    Miyagi Hiroyuki, Simura Rayko, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2012

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    In order to clarify the relationship between the structures and their unique properties, radial distribution function (RDF) analysis was carried out by the ordinary X-ray diffraction by using Mo Ka radiation. The features of obtained RDFs agree well with those of the diffraction patterns. The usefulness of the pair function method together with RDF simulation of related crystalline materials will be demonstrated.&nbsp;

  340. Structural features of Al-based approximants of X-AlPdRe and R-AlPdCo and their pseudo Machay clusters International-presentation

    S.Suzuki, R.Simura, K.Sugiyama

    Fourth French Research Organizations- Tohoku University Joint Workshop on Frontier Materials 2011/12/04

  341. Local and Medium range ordering in the binary Zr-Cu amorphous alloys International-presentation

    T.Kawamata, Y.Yokoyama, K.Sugiyama

    Fourth French Research Organizations- Tohoku University Joint Workshop on Frontier Materials 2011/12/04

  342. 4-methlyimidazoleを用いたOH-type ALPO4-34の合成と結晶構造

    千葉悠矢, 杉山和正

    日本結晶学会 2011/11/24

  343. R-AlPdCo近似結晶相の構造解析

    鈴木将太, 志村玲子, 杉山和正

    日本結晶学会 2011/11/24

  344. Mineralogy and crystallography of vein metals in the Almahata Sitta ureilite International-presentation

    T.Mikouchi, C.A.Goodrich, V.H.Hoffmann, W.Satake, M.Kaliwoda, R.Hochleitner, A.M.Gigler, K.Sugiyama, M.E.Zolensky

    34th NIPR Sympos 2011/11/18

  345. AXS-RMC法によるZrCu系非晶質合金の最近接-中距離領域構造

    川又透, 杉山和正, 横山嘉彦

    日本金属学会 2011/11/07

  346. 金属-非金属系非晶質合金NI82P18の構造解析

    松岡耕作, 川又透, 杉山和正, 春山修身

    日本金属学会 2011/11/07

  347. Olivine xenocrysts in quenched angrites: The first "differentiated" materials in the solar system? International-presentation

    T.Mikouchi, G.A.McKay, M.Miyamoto, K.Sugiyama

    Workshop on Formation of the First Solids in the Solar System 2011/11/07

  348. 発光材料応用バリウム希土類複ホウ酸塩(Ba3REB3O9)の結晶構造と相変態

    河合祥平, 志村玲子, 杉山和正

    第41回結晶成長国内会議 2011/11/03

  349. Recent Developement on Crystallography in IMR International-presentation

    The Kumamoto International Symposium on Recent Advancements of Mineralogy and Petrology V and The Fourth Meeting of Research Consortium on High-pressure Research 2011/09/28

  350. 複雑構造を有する物質群の構造解析法の開発研究

    杉山和正

    日本鉱物科学会 2011/09/09

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    日本鉱物科学賞受賞講演

  351. 新潟県糸魚川産ヒスイ輝石岩の希土類、ストロンチウム、チタンを主成分とするケイ酸塩鉱物

    宮島宏, 宮脇律郎, 松原聰, 横山一己, 門馬綱一, 重岡昌子, 杉山和正, 織田宗男

    日本鉱物科学会 2011/09/09

  352. REE-Sr-Ti-dominant silicate in jadeitite from Itoigawa, Niigata Prefecture, Central Japan

    MIYAJIMA Hiroshi, MIYAWAKI Ritsuro, MATSUBARA Satoshi, YOKOYAMA Kazumi, MOMMA Koichi, SHIGEOKA Masako, SUGIYAMA Kazumasa, ODA Muneo

    日本鉱物科学会年会講演要旨集 2011/09/05

  353. Structural study on Zr-based metallic glasses by anomalous X-ray scattering coupled with reverse Monte Carlo simulation International-presentation

    K. Sugiyama, T. Kawamata, T. Muto, Y. Waseda

    IUCr 2011 Madrid 2011/08/22

  354. Structural analysis of metal nano-particles prepared by leaching International-presentation

    R. Murao, K. Sugiyama, S. Kameoka, A.-P. Tsai

    IUCr 2011 Madrid 2011/08/22

  355. Electron back-scatter diffraction study of iron metal in Almahata Sitta ureilite International-presentation

    T.Mikouchi, C.A.Goodrich, V.H.Hoffmann, M.E.Zolensky, K.Sugiyama

    74th Annual Meeting of The Meteoritical Society 2011/08/12

  356. 異常散乱の基礎とFe-Ni系の構造解明の可能性

    杉山和正

    北海道大学・高エネルギー加速器研究機構連携シンポジウム 2011/07/12

  357. ELECTRON BACK-SCATTER DIFFRACTION STUDY OF IRON METAL IN ALMAHATA SITTA UREILITE

    T. Mikouchi, C. A. Goodrich, V. H. Hoffmann, M. E. Zolensky, K. Sugiyama

    METEORITICS & PLANETARY SCIENCE 2011/07

  358. GaN Growth by the Ammonothermal Method using Acidic Mineralizer International-presentation

    Y.Kagamitani, B.Quanxi, S.F.Chichibu, K.Sugiyama, T.Fukuda, T.Ishiguro, C.Yokoyama

    International Conference on materials for Advanced Technologies CGCT5 2011/06/26

  359. Growth and Optical Properties of Ce-doped Strontium Yttorium Double Borate International-presentation

    R.Simura, S.Kawai, T.Yanagida, T.Sugawara, K.Sugiyama, A.Yoshikawa, T.Shishido

    International Conference on materials for Advanced Technologies CGCT5 2011/06/26

  360. Growth and Optical Properties of Ce-doped (Ba, or Sr)3Gd(BO3)3 International-presentation

    R.Simura, T.Yagi, K.Sugiyama, T.Yanagida, Y.Kagamitani, A.Yoshikawa

    International Conference on materials for Advanced Technologies CGCT5 2011/06/26

  361. Ce添加Sr3Y(BO3)3の結晶成長と発光特性

    河合祥平, 志村玲子, 杉山和正, 柳田健之, 吉川彰, 菅原孝昌, 宍戸統悦

    第58回応用物理学会関係連合講演会 2011/03/24

  362. Ce添加Sr3Y(BO3)3の結晶成長と発光特性

    河合 祥平, 志村 玲子, 杉山 和正, 柳田 健之, 吉川 彰, 菅原 孝昌, 宍戸 統悦

    応用物理学会学術講演会講演予稿集 2011/03/09

  363. Mineralogy and Crystallography of Calcium Silico-Phosphate in Northwest Africa 4590 Angrite International-presentation

    T.Mikouchi, K.Sugiyama, W.Satake, Y.Amelin

    42nd Lunar and Planetary Science Conference 2011/03/07

  364. Advanced Diversity of Mineralogical Crystallography ; Recent Development and Challenge

    SUGIYAMA Kazumasa, OKUDERA Hiroki, YOSHIASA Akira

    Nihon Kessho Gakkaishi 2011/02/28

  365. Crystal Chemistry of Amphibole Minerals in Extraterrestrial Materials and Implications for Their Formation History

    MIKOUCHI Takashi, MONKAWA Akira, SUGIYAMA Kazumasa

    Nihon Kessho Gakkaishi 2011/02/28

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    Although amphibole is one of the most common rock-forming minerals on the earth, it rarely occurs in meteorites. This is due to anhydrous and low-pressure environment of most meteorite parent bodies. In this paper we report two different occurrences of amphibole from extraterrestrial materials. One is hornblende from an R chondrite, and the other is kaersutite from Martian meteorites. Both amphiboles bear unique crystal chemistry different from terrestrial ones and provide important information about their thermal history especially related to the water in extraterrestrial environment.

  366. Crystal Chemistry of MgAl_2O_4 Spinel Solid Solution : Peculiar Site Preference of Cation Observed Under Substitution and Pressure

    YOSHIASA Akira, MAEKAWA Hidemi, SUGIYAMA Kazumasa

    Nihon Kessho Gakkaishi 2011/02/28

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    Considerable efforts have been devoted to the structural studies of spinel group minerals or type compounds because of their importance as constituents of the Earth&rsquo;s crust and mantle. Despite their simple structures, many spinel type compounds exhibit complex disordering phenomena involving the mixing of cation on two sites, which have important consequences for both thermodynamic and physical properties. The cation distributions and the structural variation in MgAl2-xGaxO4 solid-solution have been clarified using 27Al MAS NMR measurements and single crystal X-ray diffraction. The determined local distance in the solid solution corresponds with the bond distance expected from the effective ionic radii except Al-O distance in the tetrahedral site. We have revealed that the Al-O distance in the tetrahedral site in spinel solid solution is about 0.15 &Aring; longer than the expected value. Boron is the same group element as Al and Ga and its ionic radius is considerably small. Single crystals of MgAl2-xBxO4 spinel were synthesized under high pressure and high temperature. The maximum content of boron was about x = 0.13 at 1273 K and 11 GPa. The smallest B ion occupies the octahedral site in top priority in the spinel solid solution of the Mg-Al-B systems. The B3+ ions can replace considerably bigger Al3+ ion under pressure. These spinel solid-solutions are largely disordered crystals. Only the positional shifts of oxygen ion have been relaxing the disorder in the solid solution.

  367. 地球外試料角閃石の結晶化学と形成過程について

    Takashi Mikouchi, Akira Monkawa, Kazumasa Sugiyama

    日本結晶学会誌 2011/02

  368. 巨大ひずみ加工による異種金属の混合を通じた非平衡ナノ材料の形成

    宮崎達也, 寺田大将, 宮嶋陽司, SURYANARAYANA C., 村尾玲子, 横山嘉彦, 杉山和正, 梅本実, 戸高義一, 辻伸泰

    東北大学金属材料研究所金属ガラス総合研究センター共同利用研究報告書 2011

  369. 金属-非金属系非晶質合金Ni82P18の構造解析

    松岡耕作, 川又透, 杉山和正, 春山修身

    日本金属学会講演概要(CD-ROM) 2011

  370. AXS-RMC法によるZrCu系非晶質合金の最近接-中距離領域構造解析

    川又透, 杉山和正, 横山嘉彦

    日本金属学会講演概要(CD-ROM) 2011

  371. REE-Sr-Ti-dominant silicate in jadeitite from Itoigawa, Niigata, Central Japan

    Miyajima Hiroshi, Miyawaki Ritsuro, Matsubara Satoshi, Yokoyama Kazumi, Momma Koichi, Shigeoka Masako, Sugiyama Kazumasa, Oda Muneo

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2011

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    A REE-Sr-Ti-dominant silicate mineral occurs as reddish brown aggregate (5 mm) in jadeitite at Itoigawa, Niigata Prefecture, Japan. The aggregate are composed of tiny rhombohedral crystals (max 0.1 mm) closely coexisted with REE-bearing matsubaraite, REE-Sr-bearing clinozoisite and natrolite. The mean of 11 electron microprobe analyses (WDS) gave SiO2 24.96, Al2O3 0.47, P2O5 0.10, TiO2 2.96, FeO 0.18, MgO 0.19, SrO 21.26, CaO 0.43, La2O3 13.94, Ce2O3 22.79, Pr2O3 2.23, Nd2O3 6.56, Sm2O3 0.30, ThO2 1.49, F 0.54, -O = F2 -0.23, total 98.16 wt.%. This leads an empirical formula (O = 27.5); (Sr3.59Ca0.13Ce2.43La1.50Nd0.68Pr0.24Th0.10Sm0.03) &Sigma; 8.70(Ti0.65Al0.16Mg0.08Fe0.05) &Sigma; 0.94 [SiO3 F0.50(OH)0.50](SiO3.83)6.27. Single-crystal XRD investigation showed it is hexagonal, s.p., a = 10.793(8), c = 19.31(3) &Aring;;, V = 1958(4) &Aring;3. This mineral is isostructural with synthetic RE9Fe(AlO3OH)(SiO4)6, and is independent from any known mineral species.

  372. KLiYF5, KLiLuF5およびNd添加KLiLuF5の作製と真空紫外領域におけるシンチレーション特性評価

    古谷優貴, 田中秀彦, 河口範明, 福田健太郎, 横田有為, 柳田健之, 杉山和正, 吉川彰

    第21回光物性研究会 2010/12/10

  373. New Technology for Gypsum Plaster Production International-presentation

    K.Sugiyama

    First International Workshop on New Technologies for Plaster Production and Development of New Materials 2010/11/25

  374. Bulk GaN Substlate Technology International-presentation

    K.Sugiyama

    Symposium Brazil-Japan on Energy, Environment and Advanced Materials 2010/11/22

  375. 鉄製造プロセスの中で利用する鉱物の構造

    杉山和正

    材料工学のための先端X線構造解析 2010/10/29

  376. 11nmトバモライトにおけるCa含有量の影響

    大嶋江利子, 阿藤敏行, 菊池昌枝, 杉山和正

    日本化学会東北支部 2010/09/25

  377. Nb-Zr異種金属対のHPT加工に伴う非平衡相の形成

    宮崎達也, 寺田大将, 辻伸泰, 村尾玲子, 横山嘉彦, 杉山和正, 戸高義一, 梅本実

    日本金属学会 2010/09/25

  378. AXS-RMC法によるZr70X30(X=Cu,Ni,Pd)非晶質合金の構造解析

    川又透, 杉山和正, 横山嘉彦

    日本金属学会 2010/09/25

  379. chrysocollaと微晶質spertiniiteの中距離領域構造

    村尾玲子, 杉山和正

    日本鉱物科学会 2010/09/23

  380. 山口県長門市川尻産offretite

    松原聰, 宮脇律郎, 重岡昌子, 杉山和正, 毛利孝明, 中原理栄, 岡井隆

    日本鉱物科学会 2010/09/23

  381. X線異常散乱法による非晶質材料の構造評価

    第71回応用物理学会学術講演会 2010/09/14

  382. MgO添加により化学量論組成と調和融解組成を一致させたニオブ酸リチウムバルク単結晶のSHG特性

    木村博充, 小泉晴比古, 杉山和正, 谷内哲夫, 宇田聡

    第71回応用物理学会学術講演会 2010/09/14

  383. Nd添加KLiLuF5単結晶の作製と光学特性評価

    古谷優貴, 田中秀彦, 河口範明, 柳田健之, 横田有為, 杉山和正, 吉川彰

    第71回応用物理学会学術講演会 2010/09/14

  384. ヨウ化アンモニウムを鉱化剤に用いたアモノサーマル法によるGaN育成

    鏡谷勇二, 栗林岳人, 羽豆耕治, 尾沼猛儀, 冨田大輔, 志村玲子, 秩父重英, 杉山和正, 横山千昭, 石黒徹, 福田承生

    第71回応用物理学会学術講演会 2010/09/14

  385. ヨウ化アンモニウムを鉱化剤に用いたアモノサーマル法によるGaN育成

    鏡谷 勇二, 栗林 岳人, 羽豆 耕治, 尾沼 猛儀, 冨田 大輔, 志村 玲子, 秩父 重英, 杉山 和正, 横山 千昭, 石黒 徹, 福田 承生

    応用物理学会学術講演会講演予稿集 2010/08/30

  386. 「講演奨励賞受賞記念講演」MgO添加により化学量論組成と調和融解組成を一致させたニオブ酸リチウムバルク単結晶のSHG特性

    木村 博充, 小泉 晴比古, 杉山 和正, 谷内 哲夫, 宇田 聡

    応用物理学会学術講演会講演予稿集 2010/08/30

  387. Nd添加KLiLuF5単結晶の作製と光学特性評価

    古谷優貴, 田中秀彦, 河口範明, 柳田健之, 横田有為, 杉山和正, 吉川彰

    応用物理学会学術講演会講演予稿集(CD-ROM) 2010/08/30

  388. 鏡笵面の金属鋳込みに伴う皮殻形成の研究 その4 塗型材の分析

    田賀井篤平, 白雲翔, 三船温尚, 韓偉東, 清水康二, 三河内岳, 杉山和正

    アジア鋳造技術史学会研究発表概要集 2010/08/28

  389. Anomalous X-ray Scattering Study on Chrysocolla International-presentation

    K.Sugiyama, R.Murao

    IMA2010 20th Genmaral Meeting of the International Mineralogical Association 2010/08/21

  390. Structure of Nagelschmidtite Ca7Si2P2O16 International-presentation

    K.Sugiyama, Y.Kato, T.Mikouchi

    IMA2010 20th Genmaral Meeting of the International Mineralogical Association 2010/08/21

  391. Crystallographic Orientation Relationship between SFCA and Hematite International-presentation

    A.Monkawa, T.Mikouchi, K.Sugiyama

    IMA2010 20th Genmaral Meeting of the International Mineralogical Association 2010/08/21

  392. Boron Occupation of Aluminium Site in Spinel and Olivine-related Structures under High-Pressure International-presentation

    A.Yoshiasa, S.Sakai, K.Sugiyama, M.Okube, L.Wang, A.Nakatsuka

    IMA2010 20th Genmaral Meeting of the International Mineralogical Association 2010/08/21

  393. Fabriation of Non-equilibrium Phase in Mechanically Mixed Metals by High Pressure Torsion International-presentation

    T.Miyazaki, D.Terada, Y.Miyajima, R.Murao, Y.Yokoyama, K.Sugiyama, M.Umemoto, Y.Todaka, N.Tsuji

    XIII International Conference on Intergranular and Interphase Boundaries in Materials 2010/06/27

  394. Structural analysis of amorphous Zr70Pd30 alloy by anomalous X-ray scattering coupled with reverse Monte Carlo simulation International-presentation

    K.Sugiyama, T.Muto, Y.Yokoyama

    11th International Conference on Quasicrystals (ICQ11) 2010/06/13

  395. Crystal structure of new orthorhombic approximant phase Al72Pd18Mn5Si5 International-presentation

    R.Simura, N.Kaji, K.Sugiyama, K.Hiraga

    11th International Conference on Quasicrystals (ICQ11) 2010/06/13

  396. Crystal structure of kai-AlPdRe International-presentation

    S.Suzuki, R.Simura, K.Sugiyama

    11th International Conference on Quasicrystals (ICQ11) 2010/06/13

  397. Radial distribution function analysis of Raney Pd and Rh fine particles International-presentation

    R.Murao, K.Sugiyama, Y.Kashiwagi, S.Kameoka, A.P.Tsai

    11th International Conference on Quasicrystals (ICQ11) 2010/06/13

  398. Cesium position in morganite from Sakrdu, Pakistan

    SIMURA Rayko, SUGIYAMA Kazumasa

    日本鉱物科学会年会講演要旨集 2010/04/07

  399. Structure of naegite

    SUGIYAMA Kazumasa, MURAO Reiko, SAKAI Syunsuke, YUBUTA Kunio

    日本鉱物科学会年会講演要旨集 2010/04/07

  400. Analysis of aluminoceladonite included in green heulandite

    MURAO R, YUBUTA K, MIYAWAKI R, SUGIYAMA K

    日本鉱物科学会年会講演要旨集 2010/04/07

  401. X線異常散乱法およびRMC法を用いたZr基二元系非晶質合金の構造解析

    川又 透, 杉山和正, 横山嘉彦

    日本金属学会 2010/03/28

  402. 蛍石構造をもつ稀土類添加Na0.4Lu0.6F2.2単結晶の作製と光学特性評価

    古谷優貴, 田中秀彦, 福田健太郎, 河口範明, 阿部直人, 柳田健之, 横田有為, 杉山和正, 吉川彰

    応用物理学関連連合講演会 2010/03/17

  403. Ce:A3RE(BO3)3(A=Ba/Sr, RE=Y/Gd)結晶の作製と結晶構造解析

    八木立志, 志村玲子, 杉山和正, 菅原孝昌, 宍戸統悦, 鏡谷勇二, 吉川彰

    応用物理学関連連合講演会 2010/03/17

  404. MgO添加により化学量論組成と調和融解組成を一致させたニオブ酸リチウムのSHG特性

    木村博充, 小泉晴比古, 杉山和正, 谷内哲夫, 宇田聡

    応用物理学関連連合講演会 2010/03/17

  405. Ce:A3RE(BO3)3(A=Ba/Sr,RE=Y/Gd)結晶の作製と結晶構造解析

    八木 立志, 志村 玲子, 杉山 和正, 菅原 孝昌, 宍戸 統悦, 鏡谷 勇二, 吉川 彰

    応用物理学会学術講演会講演予稿集 2010/03/03

  406. MgO添加により化学量論組成と調和融解組成を一致させたニオブ酸リチウムのSHG特性

    木村 博充, 小泉 晴比古, 杉山 和正, 谷内 哲夫, 宇田 聡

    応用物理学会学術講演会講演予稿集 2010/03/03

  407. 蛍石型構造をもつ希土類添加Na0.4Lu0.6F2.2単結晶の作製と光学特性評価

    古谷優貴, 田中秀彦, 福田健太郎, 河口範明, 阿部直人, 柳田健之, 横田有為, 杉山和正, 吉川彰

    応用物理学関係連合講演会講演予稿集(CD-ROM) 2010/03/03

  408. Mineralogy of Calcium Silico-phosphates in Angrites Compared with Related Phases in Heated Eucrite and Synthetic Analog International-presentation

    T.Mikouchi, K.Sugiyama, Y.Kato, A.Yamaguchi, E.Koizumi, K.Kaneda

    41st Lunar and Planetary Science Conference 2010/03/01

  409. Middle range ordering in chrysocolla and nano-crystalline spertiniite

    Murao Reiko, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2010

    More details Close

    Structures of chrysocolla from Congo and synthesized Cu(OH)2 nano-crystallite were analyzed by the anomalous X-ray scattering techniques. Environmental RDFs around Cu clarify Cu-O correlations corresponding to nearer four oxygen out of the distorted octahedral coordination. Although Cu-K edge EXAFS spectrum of chrysocolla is quite similar to that of nano-crystalline Cu(OH)2, the Cu-Cu correlation around 3.3 &Aring; observed in environmental-RDF showed different features. This result may indicate the unique structure of chrysocolla composed of local structural units of SiO4 and Cu(O,OH)6.

  410. KLiYF5,KLiLuF5およびNd添加KLiLuF5の作製と真空紫外領域におけるシンチレーション特性評価

    古谷優貴, 田中秀彦, 河口範明, 福田健太郎, 横田有為, 柳田健之, 杉山和正, 吉川彰

    光物性研究会論文集 2010

  411. 環境構造RMC法によるランダム系物質の構造解析

    杉山和正, 川又透, 武藤卓

    金研ワークショップ 2009/12/21

  412. X線回折法も用いた原始レベルの解析技術の進歩と鉄鋼製錬プロセス

    製銑第54委員会 第175回研究会 2009/12/02

  413. Valence State Analysis of Fe-containig Inclusions in Zeolite International-presentation

    R.Murao, K.Yubuta, R.Miyawaki, K.Sugiyama

    Second French Research Organizations- Tohoku University Joint Workshop on Frontier Materials 2009/11/29

  414. Medium Range ordering of Zr-based amorphous alloys analyzed by the anomalous X-ray Scttering coupled with reverse Monte Carlo simulation International-presentation

    T.Kawamata, T.Muto, Y.Yokoyama, K.Sugiyama

    Second French Research Organizations- Tohoku University Joint Workshop on Frontier Materials 2009/11/29

  415. MgO添加により化学量論組成と調和融解組成を一致させたニオブ酸リチウムのSHG特性

    木村博充, 小泉晴比古, 杉山和正, 谷内哲夫, 宇田聡

    第39回結晶成長国内会議 2009/11/12

  416. 鉄鋼製錬プロセスの中で利用できるX線回折の情報

    製鋼計測化学研究会 2009/10/09

  417. リン酸成分を固溶したCa2SiO4の結晶構造

    加藤 裕介, 杉山和正

    日本鉄鋼協会第158回秋季講演大会 2009/09/15

  418. Zr80Pt20非晶質合金の中距離領域構造解析

    武藤卓, 横山嘉彦, 杉山和正

    日本金属学会 2009/09/15

  419. X線異常散乱法を用いたZr基二元系非晶質金属合金の構造解析

    川又透, 横山嘉彦, 杉山和正

    日本金属学会 2009/09/15

  420. パキスタン産モルガナイト中のセシウムの位置

    志村玲子, 杉山和正

    日本鉱物科学会 2009/09/08

  421. グリーン輝沸石に含まれるアルミノセラドン石の解析

    村尾玲子, 湯蓋邦夫, 宮脇律郎, 杉山和正

    日本鉱物科学会 2009/09/08

  422. 苗木石の構造

    杉山和正, 村尾玲子, 酒井俊輔, 湯蓋邦夫

    日本鉱物科学会 2009/09/08

  423. 中性子シンチレータ用Ce添加Ba3Y(BO3)3結晶の育成と結晶構造解析

    八木立志, 志村玲子, 杉山和正, 鏡谷勇二, 吉川彰

    第70回応用物理学会学術講演会 2009/09/08

  424. 鏡笵面の金属鋳込みに伴う化学変化の研究 その3鏡笵面の黒色皮殻の構成物質

    田賀井篤平, 白雲翔, 三浦温尚, 韓偉東, 清水康二, 杉山和正

    アジア鋳造技術史学会 2009/08/29

  425. Superconduction phase prepared from Ta3Si under high pressure International-presentation

    R.Murao, M.Kikuchi, T.Atou, K.Kusaba, K.Fukuoka, K.Sugiyama, Y.Syono

    International; Conference on High Pressure Science and Technology 2009/07/26

  426. CALCIUM SILICO-PHOSPHATE IN ANGRITE REVISITED

    T. Mikouchi, K. Sugiyama, Y. Kato, A. Yamaguchi, K. Kaneda

    METEORITICS & PLANETARY SCIENCE 2009/07

  427. Growth and Characterization of Sc3Y(BO3)3 International-presentation

    Y. Fujimoto, Y. Yokota, T.Yanagida, J.Pejchal, H.Konno, K.Sugiyama, M.Nikl, A.Yoshikawa

    The 10th Internaional Conference on Onorganic Scintillators and their Applications 2009/06/08

  428. Developement and Evaluation of Apatite Crystal Scintillators International-presentation

    T. Yanagida, Y.Fujimoto, Y.Ohgi, Y Yokota, A Yoshikawa, H.Kagi, K.Sugiyama

    The 10th Internaional Conference on Onorganic Scintillators and their Applications 2009/06/08

  429. "Ca1+e"Co4B4 and "Ca1+e"Ru4B4: New Borides with One-dimensional Channel Structures International-presentation

    Y.Katsura, H.Ogino, Y.Matsumura, K.Sugiyama, T.Shishido, S.Horii, J.Shimoyama, K.Kishio

    American Physical Soceity March Meeting (APS2009) 2009/03/16

  430. 鏡笵面の金属鋳込みにともなう化学変化の研究その3鏡笵面の黒色皮殻の構成物質

    田賀井 篤平, 白 雲翔, 三船 温尚, 韓 偉東, 清水 康二, 杉山 和正

    アジア鋳造技術史学会研究発表概要集 3号 2009

  431. Structural Study on the Al-based Approximants for the Quasicrystalline Phase International-presentation

    K.Sugiyama

    Symposium Brazil-Japan on Energy, Environment and Advanced Materials 2008/12/09

  432. 高延性Zr基バルク金属ガラスの引張塑性変形挙動

    横山嘉彦, 井上明久, 川又透, 杉山和正, A.R.Yavari, 藤田和彦, 徳永仁夫

    日本金属学会 2008/09/23

  433. 高延性Zr基バルク金属ガラスの原子構造の特徴と組成依存性

    川又 透, 杉山和正, 横山嘉彦, 井上明久

    日本金属学会 2008/09/23

  434. 焼結鉱の中の多成分カルシウムフェライト相

    杉山和正, 扇嘉史

    日本鉄鋼協会第156回秋季講演大会 2008/09/23

  435. メタミクト化したAllaniteの構造的研究

    酒井俊輔, 湯葢邦夫, 杉山和正

    日本鉱物科学会 2008/09/20

  436. Elbaiteに含まれる微量Mnの局所構造

    金野隼人, 杉山和正, 篠田弘造, 三河内岳

    日本鉱物科学会 2008/09/20

  437. Ce:Gd9.33(SiO4)6O2単結晶の合成,構造特性および光学特性

    扇嘉史, 鍵裕之, 鎌田圭, 柳田健之, 太田充恒, 有馬寛, 吉川彰, 杉山和正

    日本鉱物科学会 2008/09/20

  438. Approximant structures for the AlCo decagonal phases. International-presentation

    K.Sugiyama, K.Yubuta, K.Hiraga

    IUCr 2008 Osaka 2008/08/23

  439. (8)Crystal structure and site occupancy of boron in synthetic high-pressure spinelMgAl2-xBxO4 International-presentation

    S.Sakai, K.Sugiyama, A.Yoshiasa, A.Nakatsuma, M.Okube, S.Sasaki, E.Ito

    IUCr 2008 Osaka 2008/08/23

  440. Peculiar site preference of B and Ga in MgAl2O4 spinel solid solutions. International-presentation

    A.Yoshiasa, S.Sakai, H.Maekawa, K.Sugiyama, A.Nakatsuka, E.Ito

    IUCr 2008 Osaka 2008/08/23

  441. Crystal Growth of Fluoride Garnet Na3Al2Li3F12 by Movcro-pulling Down Method International-presentation

    H.Konnno, K.J.Kim, A.Yoshikawa, K.Sugiyama

    The 4th Asian Conference on Crystal Growth and Crystal Technology 2008/05/21

  442. Structural Study of Liquid LiNbO3 by the High Temperature Energy Dispersive X-ray Diffraction Coupled with Reverse Monte Carlo Simulation International-presentation

    K.Sugiyama, M.Saito, Y.Waseda

    The 4th Asian Conference on Crystal Growth and Crystal Technology 2008/05/21

  443. Growth and Low Dislocation Synthetic Quartz Crystals from Cylindrical Seeds International-presentation

    A.H.Shinohara, P.L.Guzzo, K.Sugiyama

    The 4th Asian Conference on Crystal Growth and Crystal Technology 2008/05/21

  444. (3)Synthesis of Single Crystal (Mg,Fe)1-dO Solid-Solution and Electrical Conduction Mechanism at High Temperature International-presentation

    A.Yoshiasa, K.Sugiyama, H.Isobe, D.Sakamoto, K.Ota, H.Arima, H.Takei

    The 4th Asian Conference on Crystal Growth and Crystal Technology. 2008/05/21

  445. (4)High Resolution Stress Mapping of Al2O3/cubic ZrO2(Y2O3) Etectics Using Scanning Near-Field Optical Microscopy International-presentation

    S.Fukura, H.Kagi, M.Nakai, K.Sugiyama, T.Fukuda

    The 4th Asian Conference on Crystal Growth and Crystal Technology 2008/05/21

  446. (6)CrystalGrowth, Structural and Optical Characterizations of Ce-doped Gd9.33(SiO4)6O2 Single Crystals International-presentation

    Y.Ohgi, H.Kagi, K.Kamada, T.Yanagida, A.Yoshikawa, K.Sugiyama

    The 4th Asian Conference on Crystal Growth and Crystal Technology 2008/05/21

  447. Peculiar site preferences of B and Ga in MgAl2O4 spinel solid solutions

    A. Yoshiasa, S. Sakai, H. Maekawa, K. Sugiyama, A. Nakatsuka, E. Ito

    Acta Crystallographica 2008

  448. Structual investigation of metamicted Allanite

    Sakai Shunsuke, Yubuta Kunio, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2008

    More details Close

    Allanite is a member of the epidote group minerals with the general formula (Ca,RE)(Fe2+,Fe3+,Al)3(Si2O7)(SiO4)O(OH). Allanite incorporates radioactive elements like U and Th and indicates metamicitization. We demonstrate the structure of the metamicted allanite from Teofilo, Otoni, Brazil by using the results of radial distribution function and transmission electron microscopy techniques.

  449. Crystal growth, structural and optical characterizations of Ce-doped Gd9.33(SiO4)6O2 single crystals

    Ohgi Yoshifumi, Kagi Hiroyuki, Kamada Kei, Yanagida Takayuki, Ohta Atsuyuki, Arima Hiroshi, Yoshikawa Akira, Sugiyama Kazumasa

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2008

    More details Close

    (Cex,Gd1-x)9.33(SiO4)6O2 single crystals were grown by the &micro;-PD method. From the structural analysis, the lattice constants increased with increasing Ce concentration. Two nonequivalent crystallographic sites were found for Gd (Ce), 6h and 4f sites. It was revealed that most of Ce locate at Gd(6h) site. XANES analysis revealed while almost all Ce exist as Ce3+ in the crystals, a trace amount of Ce exist as Ce4+. The X-ray excited luminescence spectra of the crystals showed a peak around 400 nm originating from the Ce3+ 5d-4f transition. The corresponding decay time is about 25 ns.

  450. Approximant structures for the AlCo based decagonal phases

    Kazumasa Sugiyama, Kunio Yubuta, Kenji Hiraga

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 2008

  451. Crystal structure and site occupancy of boron in synthetic high-pressure spinet MgAl2-xBxO4

    Shunsuke Sakai, Kazumasa Sugiyama, Akira Yoshiasa, Akihiko Nakatsuka, Maki Okube, Satoshi Sasaki, Eiji Ito

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 2008

  452. Peculiar site preferences of B and Ga in MgAl2O4 spinet solid solutions

    Akira Yoshiasa, Syunsuke Sakai, Hideki Maekawa, Kazumasa Sugiyama, Akihiko Nakatsuka, Eiji Ito

    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES 2008

  453. Al-Co-Si系準結晶近傍に存在する結晶構造

    佐藤広教, 杉山和正

    日本結晶学会 2007/12/01

  454. t2-AlCo相の結晶構造

    杉山和正, 平賀贒二

    日本結晶学会 2007/12/01

  455. Unusual site preference of boron in synthetic MgAl2-xBxO4 spinel (x=0.11 and 0.13) under high pressure. International-presentation

    S.Sakai, A.Yoshiasa, T.Hashimoto, A.Nakatsuka, K.Sugiyama, M.Okube, E.Ito

    The 8th Conference of the Asian Crystallographic Association 2007/11/03

  456. Mineralogy of a hornblende in R-chondrite LAP04840

    OTA K., MIKOUCHI T., SUGIYAMA K.

    Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences 2007/09/22

  457. RコンドライトLAP04840に含まれるhornblende

    織田公平, 三河内岳, 杉山和正

    日本鉱物科学会 2007/09/22

    More details Close

    隕石の母天体の多くは、無水・低圧の環境にあるため、角閃石を含有する隕石は特定のタイプに限られる。本研究では、普通角閃石hornblendeを多く含むRコンドライトLAP04840を題材に、含有されるhornblendeの結晶学的情報を整理し、隕石の形成環境に関して議論した。分析の結果LAP04840はほぼ典型的なRコンドライトだと分かったが、Hornblendeの存在から母天体、恐らくその深部で含水・高圧力の環境下での変成が起こったことが示唆される。Fe-XANESによりhornblendeのFe3+/&Sigma;Feは約0.6と求められ、EPMAの分析を考慮することで構造組成(Na0.40K0.04)(Ca1.46Fe2+0.08Na0.46)(Al0.06Fe2+0.43Fe3+0.77Cr0.08Mn0.03Mg3.6)(Si7.01Al0.99)O22(OH)2を導出することができた。

  458. マンガンを含む角閃石の結晶構造解析およびXANESによるMnの酸化状態の決定

    織田公平, 三河内岳, 杉山和正

    日本鉱物科学会 2007/09/22

  459. 多成分フェライトSFCA-I相の結晶構造と還元変化

    扇 嘉史, 杉山 和正

    日本鉱物科学会 2007/09

  460. 溶液攪拌の導入による耐レーザー損傷閾値の高いDAST結晶の開発

    高橋義典, 隠塚信次, 杉山和正, 笹井謙一, Srinivasan, Brahadeeswaran, 吉村政志, 森勇介, 佐々木孝友

    応用物理学関連連合講演会 2007/03

  461. 高レーザー損傷耐性を有するテラヘルツ波発生用DAST結晶の開発

    高橋義典, 隠塚信次, 杉山和正, Srinivasan, Brahadeeswaran, 吉村政志, 森勇介, 佐々木孝友

    レーザー学会 2007/01

  462. 02aA11 Development of DAST crystals with high laser tolerance(NCCG-36)

    Takahashi Y, Onzuka S, Sugiyama K, Brahadeeswaran S, Yoshimura M, Mori Y, Sasaki T

    JJACG 2006

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    We carried out the damage test of 4-dimethylamino-N-methyl-4-stilbazolium tosylate (DAST) crystals. Nearly defect-free crystal with smooth surfaces had high damage tolerance with the peak power density of 2.8 GW/cm^2. Stirring the solution and using the relatively low-supersaturated solution with high-purity solvent were effective to improve the laser tolerance of DAST crystals.

  463. Environmental structural study of chrysocolla by anomalous X-ray scattering (AXS)

    Takemaru Yasutaka, Sugiyama Kazumasa

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2005

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    The structure of a chrysocolla sample from Cupiapo, Chile has been studied by the conventional X-ray diffraction and the anomalous X-ray scattering (AXS). The X-ray scattering profiles were measured at the Cu K-absorption edge and the obtained energy dependence in scattering intensities allowed us to obtain the environmental radial distribution function around Cu. The fundamental structural image with local SiO4 and CuO4 coordinations was confirmed by the present analysis. The medium range structure is discussed by using the reverse Monte Carlo (RMC) simulation method.

  464. Structural analysis of non-crystalline materials by X-ray scattering coupled with reverse Monte Carlo simulation

    Sugiyama kazumasa, Saito Masatoshi

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2005

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    The structure of disordered materials such as glasses and liquids is usually analyzed by the X-ray diffraction and obtained pair distribution functions are used in the structural discussion. This function corresponds to the probability of finding another atom at a distance r from the origin atom and careful analysis allows us to obtain the local structural image by estimating inter-atomic distances and corresponding coordination numbers at near neighbor region. However, recent structural studies of non-crystalline materials require the information covering middle range structure so as to discuss physico-chemical properties such as crystallization procedure. The reverse Monte Carlo (RMC) simulation technique is one way to obtain such middle range structure and present paper demonstrates a couple of structural studies analyzed by X-ray scattering coupled with RMC simulation method.

  465. Two-dimensional stress mapping in the Al2O3/ZrO2 eutectics using Scanning Near-field Optical Microscopy

    Fukura Satoshi, Kagi Hiroyuki, Nakai Munenori, Sugiyama Kazumasa, Nakagawa Tatsuo

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2005

  466. Characterization of synthetic quartz crystals grown on cylindrical seeds long in X, Y and Z directions by the X-ray topography

    SHINOHARA A. H, SUGIYAMA K

    日本鉱物学会・学術講演会,日本岩石鉱物鉱床学会学術講演会講演要旨集 2004/09/22

  467. Calcium ferrites with the aenigmatite structure

    SUGIYAMA K, MONKAWA A, SUGIYAMA T

    日本鉱物学会・学術講演会,日本岩石鉱物鉱床学会学術講演会講演要旨集 2004/09/22

  468. Microstructure and crystallographic orientation in an eutectic Al_2O_3/Y_3Al_5O_<12> fiber modified by the substitution of Sc_2O_3

    NAKAI M, SUGIYAMA K, YOSHIKAWA A, FUKUDA T

    日本鉱物学会・学術講演会,日本岩石鉱物鉱床学会学術講演会講演要旨集 2004/09/22

  469. Structure of the calcium ferrite phase (SFCAM)

    SUGIYAMA Kazumasa

    材料とプロセス : 日本鉄鋼協会講演論文集 = Current advances in materials and processes : report of the ISIJ meeting 2004/09/01

  470. Iron micro-xanes analysis of Martian kaersutites

    A Monkawa, T Mikouchi, E Koizumi, J Chokai, K Sugiyama, M Miyamoto

    METEORITICS & PLANETARY SCIENCE 2004/08

  471. Microstructure and crystallographic orientation in an eutectic Al2O3/Y3Al5O12 fiber modified by the substitution of Sc2O3

    NAKAI MUNENORI, SUGIYAMA KAZUMASA, YOSHIKAWA AKIRA, FUKUDA TSUGUO

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2004

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    A corundum&frasl;YAG eutectic fiber sample was produced by the micro-pulling-down method with the substitution of Sc2O3 for 3,5 & 10% of total Al2O3 in the binary Al2O3&frasl;Y3Al5O12 eutectic system. In the 3%- & 5%-substituted samples, typical "Chinese script structure" was modified into colony structure, but the basic crystallographic relationship of <001>corundum&frasl;&frasl;<112>YAG&perp; solidification direction was maintained. In the 10%-substituted sample, primary garnet single crystalline rods were formed in the eutectic matrix and the different crystallographic relationship of <001>corundum&frasl;&frasl;<100>YAG&frasl;&frasl;solidification direction was specified.

  472. 30pXF-4 Ionic conductivity and structure in AgI-AgBr-Ag_2B_2O_4 glass system

    Kusakabe M, Saito M, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 2004

  473. Structural study of calcium ferrite with the aenigmatite structure

    SUGIYAMA Kazumasa

    材料とプロセス : 日本鉄鋼協会講演論文集 = Current advances in materials and processes : report of the ISIJ meeting 2003/03/01

  474. Synthesis and structure of hureaulite [(Fe,Mn)5(HOPO3)(PO4)2(H2O)4]

    Kimiyama Makoto, Sugiyama Kazumasa

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2003

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    Hureaulite is one of the most persistent low temperature transition metal phosphate hydrates derived usually from hydrothermal attack of the primary phosphate triphylite-lithiophilite series. A single crystal of Mn-hureaulite[Mn5(HOPO3)(PO4)2(H2O)4] has been readily synthesized hydro-thermally in reaction mixture of 4H3PO4:3(CH3COO)2Mn4H2O:100H2O at 180oC for 3 days. Similar hydro-thermal technique was applied in order to produce a single crystal Fe-hureaulite [Fe5(HOPO3)(PO4)2(H2O)4], however obtained compounds were Fe3(PO4)2H2O and NH4Fe4(PO4)3 phases, only. This result agrees with the previous reports that the substisution of Mn by Fe in the hureaulite structure is limited to a maximum of about 40%. Structural features for a variety of transition series phosphates prepared in this study are also discussed.

  475. Microstructure and rystallographic orientation relationship in eutectic fibers of Al2O3/Y3Al5O12 and related compounds produced by micro-pulling down method

    NAKAI MUNENORI, Lee Jong Ho, KAIDEN HIROSHI, YOSHIKAWA AKIRA, SUGIYAMA KAZUMASA, WAKU YOSHIHARU, HUKUDA TSUGUO

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2003

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    The directionally solidified Al2O3/Y3Al5O12 eutectics indicates a fundamental feature, where the crystals of corundum and YAG are finely entangled without grain boundary. This characteristic Chinese script microstructure is suggested to be one of the important factors for providing its useful mechanical performance. Eutectic fiber samples were prepared by the mu-PD method where a fiber sample is pulled down through a capillary hole at the bottom of a conical Ir crucible. The mu-PD apparatus was equipped in a tight SiO2 glass tube and the atmosphere was controlled by the flowing of Ar gas. The ordinary chemical composition for a corundum/YAG eutectic fiber sample is 81mol% Al2O3/19mol%Y2O3. The present study also investigate a variety of eutectic samples by exchanging 3 or 5mol% of Al2O3 in the parent eutectic fiber sample by the corresponding amount of Fe2O3, Cr2O3 or Sc2O3. The microstructure was studied by the scanning electron microscope(SEM). The crystallographic orientation relationship between corundum and YAG phases was studied by using Precession and Laue photographs. Electron backscattered pattern (EBSP) method was also applied. The non-substituted sample showed the Chinese script microstructure and the present X-ray diffraction study clearly revealed the crystallographic orientation relationship; (1) (001)corundum // (112)YAG perpendicular to the solidified direction and (2) (210)corundum//(432)YAG parallel to the solidified direction. The change in the crystallographic orientation of the corundum phase was also demonstrated in a non-substituted fiber sample prepared by using a corundum (001) seed crystal. The analysis of a series of Precession photographs indicates that the crystallographic orientation of the corundum phase in the eutectic fiber is almost identical to that of the seed crystal at the initial stage of the fiber growth. Nevertheless, the c-axis of the corundum phase lay down perpendicular to the solidified direction, finally. On the other hand, the substitution for Al2O3 appears fundamentally to enhance the formation of colony area in the typical Chinese Script microstructure. The Cr2O3 is distributed in corundum and garnet structures. On the other hand, Sc2O3 prefers the garnet structure. The reduced FeO component produces another phase of hercynite FeAl2O4. The fundamental crystallographic orientation relationship of (001)corundum //(112)YAG, appears to be maintained within an individual colony texture.

  476. Electron Density Distribution in Liquid Ga Estimated from the AXS Measuremnets

    Saito M, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 2003

  477. Synthesis and Crystal Structure of Zn-Al-P-O materials with the Zeolite-type Framework

    Kimiyama Makoto, Sugiyama Kazumasa

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2002

  478. Structural analysis of piemontite by means of anomalous X-ray scattering

    Genba Michiyo, Sugiyama Kazumasa

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2002

  479. Determination of Fe distribution in kaersutite by anomalous X-ray scattering (AXS)

    Nakai Munenori, Monkawa Ryo, Sugiyama Kazumasa

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2002

  480. Synthesis of Al-P-O materials including protonated 4-methylimidazole

    Takashima Junya, Sugiyama Kazumasa, Tagai Tokuhei

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2002

  481. Structure of quantarandorite (andorite IV;PbAgSb3S6)

    KAWASAKI Yusuke, SUGIYAMA Kazumasa, OZAWA Tohru

    Abstracts for Annual Meeting of the Mineralogical Society of Japan 2002

  482. Specimen Preparation of Rock Forming Minerals by Using Ion Beam for TEM Observation

    YOSHIASA A., MIYAWAKI R., SUGIYAMA K., AKAOGI M.

    1999/02/01

  483. 31a-XA-7 Structure Analysis of Selenium Clusters in Zeolite MOR

    Togashi N, Ito Y, Sugiyama K, J Yu, S Qiu, Terasaki O

    Meeting Abstracts of the Physical Society of Japan 1999

  484. 31a-XA-6 Structure of Se Clusters in Zeolite LTA II

    Ito Y, Togashi N, Sakamoto Y, Sugiyama K, Nozue Y, Terasaki O

    Meeting Abstracts of the Physical Society of Japan 1999

  485. STM Tip Current Measurement Excited by Synchrotron Radiation.

    TSUJI KOICHI, WAGATSUMA KAZUAKI, SUGIYAMA KAZUMASA

    X線分析討論会講演要旨集 1998

  486. High Field Magnetization of R_2Cu_2O_5(R=In,Sc)

    MATSUOKA Y, NISHIMURA Y, MITSUDO S, SUGIYAMA K, KIKUCHI M, KOMATSU H, MOTOKAWA H

    Meeting Abstracts of the Physical Society of Japan 1998

  487. The structure of crystalline appoximants of decagonal quasicrystals with four layers

    HIRAGA K, SUGIYAMA K, OHSUNA T, OBATA T

    Meeting Abstracts of the Physical Society of Japan 1998

  488. 5p-R-7 Partial Structural Functions of Liquid Bi-Ga Alloy Estimated from the Anomalous X-ray Scattering Measurement with Synchrotron Radiation

    Saito M, Park C, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 1997

  489. 7p-X-11 Structure of Se clusters in Zeolite LTA

    Ito Y, Togashi N, Sakamoto Y, Sugiyama K, Nozue Y, Terasaki O

    Meeting Abstracts of the Physical Society of Japan 1997

  490. Partial Structure Factors of Molten CuBr Determined by the Anomalous X-ray Scattering Method

    Saito M, Omote K, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 1996

  491. 高温融液の構造 : 回折法に基づく原子レベルの構造解析のねらい : バルク成長シンポジウムI

    杉山 和正, 早稲田 嘉夫

    日本結晶成長学会誌 1994

  492. 31a-K-14 Structural Study of CuI-Cu_2MoO_4 Superionic Glass by the Anomalous X-ray Scattering Method.

    Saito M, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 1994

  493. 3p-YC-11 Structural Study of Liquid V_2O_5

    Takeda S, Inui M, Kawakita Y, Maruyama K, Tamaki S, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 1994

  494. 粉砕処理による原料変質のカオリナイト化反応への影響

    宮脇律郎, 渡村 信治, 岡崎 正治, 里川 重夫, 杉山 和正

    粘土科学 1993/12/30

  495. 製鉄水砕スラグからのカオリナイトの水熱合成 (第2報)

    渡村 信治, 宮脇 律郎, 犬飼 恵一, 岡崎 正治, 杉山 和正, 里川 重夫

    粘土科学 1993/12/30

  496. P13 粉砕処理による原料変質のカオリナイト化反応への影響

    宮脇 律郎, 渡村 信治, 岡崎 正治, 里川 重夫, 杉山 和正

    討論会発表抄録 1993

  497. P12 製鉄水砕スラグからのカオリナイトの水熱合成(第2報)

    渡村 信治, 宮脇 律郎, 犬飼 恵一, 岡崎 正治, 杉山 和正, 里川 重夫

    討論会発表抄録 1993

  498. 13p-A-4 Electron-Ion Correlation in Liquid Magnesium

    Inui M, Takeda S, Maruyama K, Tamaki S, Waseda Y, Sugiyama K

    Meeting Abstracts of the Physical Society of Japan 1993

  499. 12p-A-8 Neutron Diffraction Experiments of Molten Cuprous Halied Mixtures.

    Shirakawa Y, Tamaki S, Usuki T, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 1993

  500. 29aA12 CNGG単結晶における各種不純物の偏析(融液成長V)

    島村 清史, 大岡 知幸, 杉山 和正, 福田 承生, Timoshechkin M

    日本結晶成長学会誌 1993

  501. Work Index and Physical Properties of Slage Produced in Non-ferrous Metallurgical Processes.

    SHINOHARA Armando H., SUGIYAMA Kazumasa, SAITO Fumio, WASEDA Yoshio, TOGURI James M.

    Shigen-to-Sozai 1992

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    The slag samples from various non-ferrous metallurgical smelters have been characterized by determining Bond's work index, density and Vickers hardness coupled with X-ray powder diffraction and optical microscopic observation. Bond's work index for a slag consisting almost of glassy phase shows relatively higher index value than that of the crystalline slags and brittle minerals like quartz and feldspar, although a consistent index for zinc slag could not be obtained due to a large amount of co-existing metallic phase.<BR>The following empirical equation for crystalline brittle materials has been developed to describe the correlation between work index; Wi [kWh/t] and the product of Mohs' hardness; HM and density;&rho;[Mg/m3]. Wi=0.42 (HM&middot;&rho;) +6.56<BR>This equation is suitable for the range up to 30&times;103 in the values of HM&middot;&rho; with corresponding correlation coefficient of 0.83. Using this equation, the work index for the brittle portion of zinc slag, which is mainly constituted of oxide and silicate minerals, was estimated to be 16 kWh/t.

  502. Quantitative X-ray Diffraction Analysis of Quartz and Anatase in Kaolin by Applying the Prolonged Grinding Technique.

    SUGIYAMA Kazumasa, RYU Hojin, SAITO Fumio, WASEDA Yoshio, MIYAWAKI Ritsuro

    Shigen-to-Sozai 1992

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    X-ray powder diffraction method coupled with the prolonged grinding technique has been used for analyzing quartz and anatase in several kaolin samples. Kaolin minerals easily change from crystalline state to amorphous one by the prolonged dry grinding. This contrasts to the behavior of quartz and anatase. Because of this selective feature, Bragg reflections of quartz and anatase can readily be identified in the X-ray diffraction profiles of ground kaolin samples. The internal standard method was applied to the ground kaolin samples and quantitative analysis of constituent quartz and anatase was carried out. Gibbsite is known to become amorphous state by the prolonged dry grinding. Thus, present technique was also applied to the analysis of natural bauxite samples. The results clearly indicate that the present technique is promising for the analysis of quartz and anatase in kaolin and bauxite samples by reducing the difficulties unsolved in the conventional X-ray powder diffraction method.

  503. 28a-ZP-13 Neutron Diffraction Study of Liquid Bi-Se alloys

    Usuki T, Shirakawa Y, Tamaki S, Inui M, Takeda S, Sugiyama K, Waseda Y

    Meeting Abstracts of the Physical Society of Japan 1992

  504. 21.製鉄水砕スラグからのカオリナイトの水熱合成(第35回粘土科学討論会発表論文抄録)

    宮脇 律郎, 渡村 信治, 犬飼 恵一, 芝崎 靖雄, 杉山 和正, 里川 重夫

    粘土科学 1991/02/25

  505. X線異常散乱法を応用した、非晶質ジルコニアの構造解析

    杉山 和正, 早稲田 嘉夫

    日本結晶学会誌 1991

  506. 21 製鉄水砕スラグからのカオリナイトの水熱合成

    宮脇 律郎, 渡村 信治, 犬飼 恵一, 芝崎 靖雄, 杉山 和正, 里川 重夫

    討論会発表抄録 1991

  507. X線異常散乱法を用いた、非晶質系物質の構造解析

    杉山 和正, 早稲田 嘉夫

    日本結晶学会誌 1990

  508. B10 上部マントルにおける希土類元素の担体鉱物

    村山 恭平, 床次 正安, 熊沢 峰夫, 杉山 和正

    日本火山学会講演予稿集 1990

  509. Sr3 (PO4) 2-Ba3 (PO4) 2固溶体の陽イオン席占有率について

    杉山 和正, 床次 正安

    日本結晶学会誌 1986

  510. 放射光によるGeO2の構造相転移の研究―ダイアモンドアンビルを用いた高圧高温下の白色粉末X線回折実験

    山中 高光, 尾形 潔, 杉山 和正, 床次 正安, 末野 重穂, 中井 泉

    日本結晶学会誌 1985

  511. 放射光によるGcO2 (α-quartz type) の粉末X線回折パターンのRietveld解析

    尾形 潔, 山中 高光, 杉山 和正, 床次 正安, 森川 日出貴, 泉 富士夫

    日本結晶学会誌 1985

  512. 放射光によるGeO2の構造相転移の研究:―ダイアモンドアンビルを用いた高圧高温下の白色粉末X線回折実験

    山中 高光, 尾形 潔, 杉山 和正, 床次 正安, 末野 重穂, 中井 泉

    日本結晶学会誌 1985

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Industrial Property Rights 1

  1. 有機光学結晶、差周波発生素子、テラヘルツ波発生装置、有機光学結晶の直線状欠陥発生防止方法および有機光学結晶の製造方法

    高橋 義典, 吉村 政志, 森 勇介, 佐々木 孝友, 中西 八郎, 谷内 哲夫, 岡田 修司, 杉山 和正

    Property Type: Patent

Research Projects 25

  1. 天然鉱物に内在する不均一特異構造の解明とミメシス素材創生プログラム

    杉山 和正, 吉朝 朗, 湯葢 邦夫, 川又 透

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 基盤研究(A)

    Category: 基盤研究(A)

    Institution: 東北大学

    2020/04/01 - 2025/03/31

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    本研究は,最新鋭の散乱強度マッピング装置と波長選択性や偏光性を積極的に利用できる高輝度放射光X線源をドッキングすることによって,ブラッグピークの隙間空間に表現される鉱物の特異構造を解明することを目的とする.令和2年度は,合金の複雑構造の解明にデザインされている既設装置に,惑星活動の履歴を記録するケイ酸塩鉱物や燐酸塩鉱物の特異構造の解析に不可欠な散漫散乱や長周期構造の高分解能解析に有効なCu線源を導入した.そして準結晶に関連する分野では,Al-Mn-Co系において元素の秩序化配列にともなう新しい近似結晶相の構造を解明することができた.また硫化鉱物に関しては,放射光源を併用することによって,スピネル構造およびペントランダイト構造に記録される特異な元素秩序化とその温度依存性に関しての解析を進めることに成功した.とくに放射光異常散乱の研究成果は,令和3年度挿入する最新鋭の特異構造解析システムの設計との関連性が深く,現状のシステムの精度と実験的に改善できるポイントの精査を進める基礎データとなった.またペントランダイト構造から読み取れる鉱物の受けた温度履歴に関しては,令和3年度に”りゅうぐう(ハヤブサプロジェクト)”より回収された鉱物試料の解析に展開する計画である.本研究グループが令和2年度に発展させた方法論は,”りゅうくう”の生成環境を解明できる強力な解析方法であることは明らかであり,令和2年度の目標”生成環境が特異構造の相違点として観測可能かどうかの検証”は達成できた.また,鉄隕隕石から採取できるkamaciteおよびtaenite,急冷法で作製した Fe-Ni合金など様々な冷却条件で準備した合金の規則度を解明もおこなった.しかし予想に反して,現在のところ隕石に存在するFe-Ni系合金の秩序化配列は明瞭に観測できなかった.令和3年度は,研究されていない隕鉄合金に研究展開をしたい.

  2. Development of new geothermometer and cooling speed-meter for extraterrestrial materials based upon phase transitions of silica minerals

    Mikouchi Takashi

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Challenging Research (Exploratory)

    Category: Grant-in-Aid for Challenging Research (Exploratory)

    Institution: The University of Tokyo

    2021/07/09 - 2023/03/31

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    We have analyzed silica minerals in diverse extraterrestrial materials. Among them, we especially analyzed lunar meteorites in particular. As with Martian meteorites, many silica phases were amorphous, suggesting that they were affected by strong shock metamorphism. In fact, many of the samples we analyzed were brecciated, further indicating the strong influence of shock metamorphism. Heating and cooling experiments using an electric furnace are continuing under various conditions, and it will take some more time to obtain comprehensive results. The results of X-ray diffraction experiments on tridymite in both terrestrial and extraterrestrial samples did not reveal any differences between "terrestrial" and "meteoritic" types, as has been suggested, but suggested that it may be only a matter of differences in crystallinity.

  3. ハイエントロピー合金に内在する元素間相互作用と相安定性原理の実験的解明

    古原 忠, 荒木 秀樹, 杉山 和正, 井上 耕治

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 新学術領域研究(研究領域提案型)

    Category: 新学術領域研究(研究領域提案型)

    Institution: 東北大学

    2018/06/29 - 2023/03/31

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    本年度は,以下の項目についての研究を行った. (1)fccおよびbcc基の規則相を有するFe-Ni-AlおよびFe-Ni-Mn合金に注目して時効硬化挙動を幅広い時効条件で評価した.Fe-Ni-Al合金の微細組織をTEMおよび3DAPを用いて調査することで,時効硬化の初期段階でAl-Niの引力相互作用が関係する規則化を伴う相分離が生じていることが示唆される結果が得られた. (2)ハイエントロピー合金に内在する構成元素間の短距離秩序(SRO)および中距離秩序(MRO)の構造詳細を,X線回折法およびX線分光学的手法を用いて解明することを目指した。その中で,非晶質合金に内在するSROおよびMROの構造解明,Fe-Ni-Mn合金粗大結晶材の時効処理に対応する散漫散乱の直接観測,Fe-Ni系合金の各元素の秩序化配列の評価などを試みた. (3)CoCrFeMnNiハイエントロピー合金における積層欠陥への偏析の有無を調べたが,積層欠陥が存在する領域の元素マップからは,明瞭な積層欠陥への偏析は確認できなかった.一方,CrCoNiの[111]および[100]方向のSpatial Distribution Mapの測定から,[111]方向では濃度変調は見られないが、[100]では1原子面おきに濃度変調が観測され,形成初期段階のL12やL10が存在する可能性が示唆された. (4)典型的な高エントロピー合金であるCoCrFeMnNiについて原子空孔の形成エンタルピーを評価した。陽電子寿命法により求めたCoCrFeMnNi合金の空孔形成エンタルピーは構成元素の純金属と比較しても顕著な差は見られなかった.第一原理計算による結果では空孔形成エンタルピーは約0.8 eVの分布幅を示すが、各原子種の平均値は約2.0 eVと一定の値となり、原子種による大きな差は見られなかった.

  4. The Medium Range Ordering of Amorphous Alloys: Chemical Short Range Ordring and Bernal Polyhedra

    Sugiyama Kazumasa, KAWAMATA TORU

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: Tohoku University

    2016/04/01 - 2019/03/31

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    In this study, we used the advanced AXS-RMC method to evaluate the medium-range ordering structure of an amorphous alloy that shows a pre-peak signal in the diffraction profile. It was clarified that the clear short-range ordering structures such as icosahedral cluster (TSRO) and/or the strongly binding solute-center model (CSRO), which have been regarded as the origin of pre-peaks in the past, are not essential elements for the appearance of pre-peak signals. And, according to the newly developed CA-Bernal analysis, the identity of pre-peak signal is suggested to be formed by the harmony of the strongly binding Bernal-typed high density domain structure (CMRO) and the non-Bernal-typed low density domain structure (TMRO) inherent in composition and density non-uniformity.

  5. Formation process and local structure of amorphous aluminosilicates in fault zone

    Kameda Jun, SUGIYAMA Kazumasa, TSUTSUMI Akito, TAKESHITA Toru

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: Hokkaido University

    2015/04/01 - 2018/03/31

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    Thermal and mechanical activations on hydrous clay minerals in fault zones are examined. High-temperature XRD experiments demonstrated that kaolinite and chlorite, typical clay components in crustal faults, dehydroxylate in a different manner, which can be utilized as a new temperature proxy for seismogenic faults in subduction zones. In addition, we showed that mechanical action can facilitate mineral dehydroxylation reaction due to selective degradation of clay interlayers connected by hydrogen bondings. We also investigated smectite/illite mixed layers around a slip zone of the mega-branching fault of the Nankai Trough, and showed that mechanochemical processes possibly associated with seismogenic faulting can activate its transfrormation reaction by reducing the activation energy of the reaction.

  6. Structural Analysis of Maskelynite and Genesis of Martian Meteorites

    Sugiyama Kazumasa

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Challenging Exploratory Research

    Category: Grant-in-Aid for Challenging Exploratory Research

    Institution: Tohoku University

    2015/04/01 - 2018/03/31

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    In order to analyze the amorphous structure, a solar-slit system and a sample stage was prepared for the X-ray diffractometer installed at IMSS. The structural analysis of maskelynite in ASCA881757, was performed by the developed analytical system. As for the synthesis of artificial maskelynite, present trial by the impact compression test did not succeed to obtain a sample with fully amorphous state. The similar test of parent olivine could not serve the black one with nano-meter sized iron. These observations suggest that the formation of maskelynite and black olivine in Martian meteorites require the high impact compression together with the following high temperature heating. This project also studied the structure of materials produced by the meteorite impact. As an example, the local structural analysis of the trace elements in the clay of K-Pg boundary was conducted and succeeded to discuss the genesis of such interesting materials.

  7. Characterization of role of constituent ions in complicated solid electrolytes by combination of element-selective structural analysis methods

    Waseda Yoshio

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: Tohoku University

    2014/04/01 - 2017/03/31

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    The element-selective structural analysis methods were used to characterize the local structures in several phosphate compounds with the NASICON-type structure. They are promising materials for lithium ion batteries, as they reveal superior charge-discharge characteristics. The chemical state in Li2NaV2(PO4)3 samples of a candidate cathode during the charge-discharge was analyzed by using X-ray absorption spectroscopy. X-ray anomalous scattering was used to analyze the middle-range order structure in NASICON-type glass-ceramics, which are utilized as electrolytes in solid state batteries. Influences of foreign elements on the local structure around aluminum and phosphorus in these samples were also analyzed by NMR. These results were discussed coupled with their electrochemical properties.

  8. The medium range ordering and environmental reclamation function of ferrihydrite

    Kawamata Toru, Sugiyama Kazumasa

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)

    Category: Grant-in-Aid for Scientific Research (C)

    Institution: Tohoku University

    2014/04/01 - 2017/03/31

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    Ferrihydrite as hydrous ferric oxyhydroxide (Fe2O3・0.5H2O) is widespread mineral in environment of the earth’s surface, and can be regarded as important absorbent for trace elements and heavy metals in ground water and soil. However, the medium range order of atomic arrangement in ferrihydrite which is closely related to the physicochemical properties has not been revealed yet. In this study, we demonstrate the structural study of ferrihydrite by state of art AXS-RMC method, coupling of anomalous X-ray scattering and reverse Monte-Carlo simulation.

  9. Investigation of atomic and ionic transportation mechanism in complex hydrides

    OTOMO Toshiya, SAKAKI Kouji, IKEDA Kazutaka, ORIMO Shinichi, NAKAMURA Yumiko, ABE Hitoshi, SUGIYAMA Kazumasa, ARIMA Hiroshi, KITAJIMA Yoshinori, SATO Toyoto

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)

    Category: Grant-in-Aid for Scientific Research (A)

    Institution: High Energy Accelerator Research Organization

    2012/04/01 - 2015/03/31

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    NaAlH4 is light weight and high hydrogen density material but the hydrogen desorption speed is very slow in the solid state. Ti-additives improves the speed 10 times. It is important to reveal the mechanism of the kinetics improvement by the Ti-additives to make NaAlH4 practical hydrogen storage material. The purpose of this study is to reveal the improvement mechanism of Ti-additives with neutron scattering, X-ray absorption, X-ray anomalous scattering and positron annihilation. It was found that the chemical state of Al is changed by Ti-additives. Also, existing of two type of Ti position was found: one is the Al site of NaAlH4 and the other is Ti-Al allow outside of NaAlH4.

  10. The structutal study of dicalcium-silicates for the dephosphorization process and the application for functional materials.

    SUGIYAMA Kazumasa, MIKOUCHI Takeshi

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: Tohoku University

    2011/04/01 - 2015/03/31

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    The mechanism of the Ca2SiO4-Ca3(PO4)2 solid solutions with respect to the dephosphorization reaction in the steal making process was studied. Thanks to the high temperature X-ray studies, the relationship between nagelschmidtite and silico-carnotite was realized and this leads to remove the inconvenience in the reported phase diagram. The single crystal structural analysis of both minerals can provide the reliable structural images and the structural information allows us to discuss the mechanism of dephosphorization, which is closely associated with the vacant Ca sites together with the random distribution of SiO4 and PO4. This research project succeeded to characterize the unique Ca-silico-phospahte in angrite. The SAED patterns of Ca silico-phosphates in D’Orbigny are consistent with those of the apatite structure. The further single crystal structural analysis of Ca-phosphate in NWA4590 demonstrates the common structural features of Ca silico-phosphates in angrites.

  11. Structural characterization of complex metallic glasses and structural relationship with their approximants

    SUGIYAMA Kazumasa, SIMURA Rayko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Challenging Exploratory Research

    Category: Grant-in-Aid for Challenging Exploratory Research

    Institution: Tohoku University

    2010 - 2012

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    In order to understand the interesting physico-chemical properties of Zr-based glassy metals, the combinatorial analysis of single crystal XRD for crystalline approximants and AXS-RMC of glassy metals is strongly required. This research project succeeded to demonstrate the structural features of a variety Mackay clusters around transition metal elements and the local structural features for Zr-based and Pd-based glassy metals. A series of AXS-RMC analysis revealed that the stability of glassy metals has no significant relationship with the probability of icosahedral structural units in thesamples.

  12. Chemical analyses of the Chinese mirror-molds of the Han-Period and restoration experiments of the high-Sn bronze mirror

    TAGAI Tokuhei, MIFUNE Haruhisa, SHIMIZU Yasuji, SUGIYAMA Kazumasa, BAI Yunxiang, HANG Weidong

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: The University of Tokyo

    2008 - 2010

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    A black crust is often observed on the surface of the mirror-mold. As a result of the chemical analyses, the elements such as Cu, Sn, Pb, and Zn originated in the casting metals were confirmed to exist in the black crust The black crust is, therefore, thought to be a reaction product of mirror-mold and the metal in the course of the casting process. In addition, S and C were found and it indicates that they might be originated in the coating- or release-agents for the mold. Then, the casting experiments were carried out by the mixture of Cu, Sn, and Pb using several kinds of oil and fat as the coating- or separating-agents. A black crust was well reproduced by using a fat as release-agent. As a result of chemical analyses of the reproduced black crust, the existence of metallic elements and S were confirmed to be in the crust on the surface of the mirror mold. The element of C was not analyzed but C was thought to be a kind of soot caused from burned fats in the course of casting.

  13. Characterization of natural minerals with the mezoscopic scale structure by means of reverse Monte Carlo simulation analysis.

    SUGIYAMA Kazumasa, YOKOYAMA Yoshihiko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: Tohoku University

    2008 - 2010

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    In the field of structural mineralogy, much attention has been paid to the nano-meter sized middle range ordering with a mezzo-scopic structure. Present study focuses on AXS-RMC analyses of natural chrysocolla and synthetic naegite, and discusses the relationship between their middle range ordering structures and unique crystallization procedures. Additionally, the structures of Zr-Pd and ZrPt amorphous metals with their unique crystallization process of an icosahedral phase, have been studied by means of AXS-RMC technique. The results of this study can be obtained only by the unique and advanced AXS-RMC method by the high energy X-ray diffraction and anomalous X-ray scattering together with reverse Monte Carlo simulation.

  14. Interaction between the transition metals and organic molecules in the framework structure of zeolite.

    SUGIYAMA Kazumasa, TANAKA Masahiko

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: The University of Tokyo

    2002 - 2004

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    The purpose of this study is to characterize the interaction between transition metals and organic molecules in zeolites with the porous framework structure. For this purpose a special experimental facility which allows us to perform the single crystal anomalous X-ray scattering measurement was newly built at the Photon Factory at the Institute of Materials Structure Research. Anomalous x-ray scattering method is powerful technique and the environmental structure around a specific element can be obtained from the analysis of the energy dependence of the scattering data. This relatively new method was applied to the analysis of Se@mordenite and the chain like Se molecule in the mordenite channel was quantitatively obtained by suggesting the electron transfer from Se molecules. The solvo-thermal technique in the Zn-Al-P-O and Co-Al-P-O system allowed us to serve the laumontite framework structure. Laumontite in the Zn(Co)-Al-P-O system indicates the ordering of transition metals and incorporated organic molecule and 1,2-aminoethypiperazine@laumontite, in particular, showed the non-centered space group symmetry of Cc. The measurement of the SHG signal for this new material supported the attractive performance and further application of such materials for the optic-electrical will be realized in near future.

  15. 天然ゼオライトに学んだ,細孔構造を有するアンチモン硫化物の合成

    杉山 和正

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 萌芽研究

    Category: 萌芽研究

    Institution: 東京大学

    2002 - 2003

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    本年度は,昨年度のandohriteシリーズ鉱物群の解析結果に基づき、Na_2Sを添加したSb_2S_3系を基本に、IM(imidazole)、TEA(triethylenamine)、MOR(morphorine)など、各種有機鋳型物質を添加した系で、マイクロポーラスアンチモン化合物の合成を試みた。これまでの研究成果をまとめると、AEP(1,2-aminoethylpiperadine1)およびEDA(ethylenediamine)など,立体的占有体積のほぼ同じ2価の有機アミン鋳型の存在で,天然のandohriteシリーズ類似の骨格構造を有するアンチモン硫化物鎖状構造が育成できるが、一方、IM、MORなどの環状有機鋳型分子の場合は、重合反応が進まず、夫然andhrite類似のSBUは導入できないことが判明した。しかし、今回の研究で新たに合成できたアンチモン系硫化物には、天然に見られるSb_2S_4-SBUが存在しないこと、また天然で観察されないSbS_3ピラミッドが3つ結合したSBUがあることなどの相違点もある。天然の硫塩鉱物に含まれる鉛や銀成分がこのSBUの相違点を生じる主因と考えられるが、このような元素を添加した系では、良質な単結晶の合成に成功しなかったため、アンチモン系硫化物のSBUを決定する主因を特定することはできなかった。しかし、本研究の目的である天然硫塩鉱物類似のマイクロポーラスアンチモン化合物を合成することには成功し、今後目的とするSBUを選択的に合成できる技術の端緒を得ることができ左と考えている。

  16. Structural study on quasicrystals and their approximants in the Al-Ni-Co alloy system, by means of anomalous X-ray scattering

    SUGIYAMA Kazumasa, HIRAGA Kenji

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)

    Category: Grant-in-Aid for Scientific Research (B)

    Institution: The University of Tokyo

    2000 - 2001

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    The Al-Ni-Co decagonal phase has received much attention, because, of several modulations of decagonal quasicrystals, showing highly-ordered diffraction patterns or several different type of diffraction patterns with super-lattice reflections, and some crystalline approximants. In order to reveal the structures of these decagonal quasicrystals, many studies have been made by electron diffraction analysis, high-resolution transmission electron microscopy (HRTEM) and high-angle annular detector dark-field scanning transmission electron microscopy (HAERDF-STEM). However, previous studies have been made on individual decagonal quasicrystals, and no systematic interpretation on the structures of all the Al-Ni-Co decagonal quasicrystals has been performed. This research project has performed precise structural analysis of a crystalline approximant, which is found in alloy around Al_<72.5>Ni_<17>Co_<20.5>, annealed at 950℃. The structure of this W-(AlCoNi) phase, enables us to discuss the structures of the Al-Ni-Co decagonal quasicrystals in detail. These research results can be referred as one of the most important structural information considering the quasicrystals and related approximant crystals and the head investigator was invited to International Conference of Quasicrystals 2001. The present research project developed the relatively new technique of single crystal anomalous X-ray scattering technique, which prompts us to know fine structure around a specific element in an alloy sample. This, new analytical tool succeeded to characterize the distribution of Cu in the Al-Cu-Fe approximant phase and allowed us to understand the structural role for Cu for the formation of approximant phase related to quasicrystals. The present research group has also performed the systematic research with respect to structures of cubic approximant phase with large icosahedarl atom clusters. The obtained results were demonstrated in the International Workshop for Quasicrystals as a key lecture.

  17. Study on mesoscopic physical phenomenon in many particle systems by electron holography

    HIRAGA Kenji, OHSUNA Tetsu, SUGIYAMA Kazumasa

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B).

    Category: Grant-in-Aid for Scientific Research (B).

    Institution: Tohoku University

    1999 - 2000

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    1) We determined site occupancy of Zn atoms in (Al, Zn)_<49>Mg_<32>-type Mg_<40>Al_<60-x>Zn_x (x=14=51) alloys by single crystal X-ray diffractometry. We also demonstrated that they have no atom at the center of Bergman-type atom cluster, on the contrary to the previously proposed models. 2) We succeeded in fabricating a single crystal of 2/1 cubic approximant, which were found in (Al, Zn)-Mg alloys, and determined sophisticated structure of Bergman clusters by X-ray diffractometry. 3)Single crystal diffractometry allowed us to determine the structure of the following 1/0 crystalline approximants : Al_<66.8>Pd_<21.2>Ru_<12.0> (Fms ; a=1.56058nm), Al_<63.6>Pd_<30.2>Fe_<6.2> (Fms ; a=1.55187nm), and Al_<68.9>Pd_<17.1>Fe_<13.9> (Fms ; a=1.53755nm). Surrounding the 1/4, 1/4, 1/4 position, Al assumes icosahedral coordination, which were also surrounded by pentagonally-coordinated clusters that share edges and forms a simple cubic arrangement. 4) We showed, using single crystal X-ray diffractometry, that Al_<57.3>Cu_<31.4>Ru_<11.3> 1/1 crystalline approximant belongs to the cubic system with Pm3 and a=1.23773, in which truncated dodecahedron clusters arrange themselves in a cubic manner, sharing octahedrons. 5)We also showed that 1/0, 1/1, 2/1 crystalline approximants are grouped into the simple cubic and body-centered cubic systems when viewed via arrangements of icosahedral atom clusters.

  18. Structural Analysis on Quasicrystals and their Approximants.

    HIRAGA Kenji, YAMAMOTO Akiji, LI Shinzun, SUGIYAMA Kazumasa

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)

    Category: Grant-in-Aid for Scientific Research (A)

    Institution: Tohoku University

    1996 - 1997

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    Since the first finding of a quasicrystal in Al-Mn system by Schetman, a number of structural studies have been carried out in order to understand the physico-chemical properties of this new materials. The conventional high-resolution electron microscope is known to be one of the most powerful methods to analyze the structures of quasicrystals and their approximants. However, detailed structural information such as transition metal distribution cannot be obtained from the results of the electron microscope only. On the other hand, X-ray diffraction allows us to determine the precise atomic coordinates for individual constituents and such information is strongly required for discussing a variety of physical properties of quasicrystals. In these contexts, the main purpose of this research project is to characterize the structures of quasicrystals and their approximants by the combination of high-resolution electron microscope and X-ray diffraction. It may be added that the projection method including high dimensional space group theory is intensively used for elucidate the obtained structural results. For the intensity measurement of X-ray diffraction, we developed a new type of weissenberg camera equipped with imaging plates and the intensity reader for them. The rotating anode type X-ray generator with a maximum load of 18kW is employed as a X-ray source, the graphite monochromator is set in the incident beam pass for selecting MoKalpha radiation. Two imaging plates are installed and the measuring time is extensively reduced in comparison with a conventional four-circle diffractometer. It should be added that the mu-axis controlling system is also introduced for the intensity measurement with no special blind region. By using this weissenberg camera, we foundan dodecahedral atom clusters with 1.2nm and 2.0nm in diameter in Al-Pd-Mn system. These atom cluster are classified as essential structural units for the corresponding icosahedral phase, by indicating tau-inflation rule in their sizes. The structural model by using these atom clusters coupled with the projection method allows us to demonstrate a feasible structural model of Al-Pd-Mn icosahedral quasicrystals. These results were appreciated by many material scientists and we are invited to talk these fruitful results at the international conference of quasicrystals in 1997. These atom clusters with dodecahedral symmetry together with a projection method are suggested to shed light upon the real understanding of icosahedral quasicrystals.

  19. X線異常小角散乱装置の試作および巨大磁気抵抗効果の解明

    早稲田 嘉夫, 表 和彦, 杉山 和正, 齋藤 正敏

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 試験研究(B)

    Category: 試験研究(B)

    Institution: 東北大学

    1995 - 1995

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    本研究のキ-ポイントは、たとえ原子番号が近接する元素が共存する場合でも夫々の元素を的確に識別し、数十ナノメートルの微細構造を解明するX線異常小角散乱装置を世界に先駆け試作し、Co/Cu合金からなる巨大磁気抵抗効果の解明をすることにある。 当初の研究計画に基づき、まず本研究補助金を持ちいて入射X線のエネルギーを自由に選択できるヨハン型あるいは2結晶モノクロメータを搭載する分光部、角度分解能の優れた小角ゴニオメータおよび位置敏感型検出器を装備した計測部を設計・製作し、既設の高輝度X線源と組み合わせたX線異常小角散乱装置を試作した。また本年度は、原子番号が近接するCoおよびCuから構成される多層膜の構造解析を実施した。X線異常小角散乱を応用した結果、CoおよびCu元素の原子番号が5番近く離れている場合に相当する小角散乱強度が測定できた。フーリエ変換法によって解析した結果、本実験で解析した多層膜は2.05nm周期であり、Cuが0.46nm,Coが0.50nm堆積し境界界面構1.09nmであることが判明した。この解析結果は、X線異常小角散乱法を用いて初めて得られた結果であり、今後はこの新しい手法を用いた各種機能性素材の系統的かつ精密な微細構造の解明が十分期待できる。

  20. エネルギー分散型X線回折法による珪酸塩融体の構造解析

    早稲田 嘉夫, 杉山 和正

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 重点領域研究

    Category: 重点領域研究

    Institution: 東北大学

    1994 - 1994

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    半導体検出器(SSD)を用いたエネルギー分散型X線回折(EDXD)法は、高温および高圧などの特殊条件下における構造解析の有力な手段の一つである。例えば、20〜40keVの白色X線を用いて強度測定を行なえば、回折角70°でも200nm^<-1>越える波数ベクトル領域(Q=4πEsinθ/1.24(nm^<-1>)、2θ(°)=回折角、E(keV)=X線のエネルギー)の情報に基づいた解析が可能となり、解析精度が大幅に増大する。 本研究は、高温融体の高分解能動径分布関数を得る目的のため、融体用エネルギー分散型X線回折法解析システムを開発し、水銀(Hg)、ニオブ酸リチウム(LiNbO_3)、曹長石(NaAlSi_3O_8)融体などの構造解析を行なった。Ptセル中で溶融したLiNbO_3融体(1280℃)の解析結果では、波数ベクトルの大きな領域までフーリエ変換した動径分布関数は、最近接Nb-O原子相関に対応する約0.2nmのピークをはじめとして0.3〜0.5nm付近の原子相関の分解能に優れ、EDXD法が高分解能の動径分布関数を得るために効果的な手段であることが判明した。融体の最近接Nb-0原子相関にLiNbO_3結晶と同様な2種類の相関距離(約0.19nmおよび0.21nm)が存在することは、融体中のNbO_6局所構造要素が結晶に極めて類似した立体構造を構成していることを強く示唆していると考えられる。 このように、高分解能動径分布解析は、融体構造中の基本構造単位である局所構造のみならず局所構造の立体的構成に関する議論を可能にすることが判明した。

  21. エネルギー分散型X線解析法による珪酸塩融体の構造解析

    早稲田 嘉夫, 杉山 和正

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 重点領域研究

    Category: 重点領域研究

    Institution: 東北大学

    1993 - 1993

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    半導体検出器(SSD)を用いたエネルギー分散型X線回折(EDXD)法は、高温および高圧などの特殊条件下における構造解析の有力な手段の一つである。白色X線を用いて回折角を固定し強度測定を行なうEDXD法は、(1)広い波数ベクトル領域(Q=4πEsinθ/1.24(nm^<-1>)、2θ(^0)=回折角、E(kev)=X線のエネルギー)の強度測定に基づいた解析を可能とする。たとえば、20〜40keVのX線を使用して測定を行なえば、200nm^<-1>を越える波数ベクトル領域の構造情報を得ることができ、MoKα線(17.447keV)を用いた通常の回折(ADXD)法で解析可能な波数ベクトルの領域が高々150nm^<-1>であることを考慮すると、構造情報が大幅に増大する。(2)異なるエネルギーを持つX線の計測を同時に行なうため、広範囲の波数ベクトル領域の情報を一括して得ることが可能である。したがって、X線源の強度変動は結果に全く影響せず、実験室系の測定において高い再現性が期待できる。などの特徴を持ち、特に非晶質系物質の構造解析に極めて有効な手段と考えられる。しかし、主として解析プロセスが複雑であることに起因し現在のところ汎用されているとは言い難い。 本研究では、構造解析手段としてEDXD法を確立し、さらに酸化物系非晶質物質の高分解能動径分布関数を得る目的のため、新たにエネルギー分散型X線回折装置を製作した。本システムを用いて、SiO_2ガラスおよび(Ca,Sr,Ba)P_2O_6ガラスの構造解析を行なった。干渉関数には、波数ベクトルの大きい領域まで強度の強い振幅が明瞭に観測される。これは、結合力の強い局所構造単位の存在を示唆しており、本試料の場合、SiO_4およびPO_4四面体がこの構造単位に相当する。フーリエ変換を行なって得られた動径分布関数には、通常の角度分散型X線解析法によって得られた分布関数に比べて、0.3〜0.5nm付近の相関の分解能が格段に向上した。これは、EDXD法が高分解能の動径分布関数を得るために効果的な手段であることを示唆している。

  22. Li_2O-B_2O_3系融体の構造決定

    杉山 和正

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 奨励研究(A)

    Category: 奨励研究(A)

    Institution: 東北大学

    1992 - 1992

  23. Structural study for hydrolytic condensed amorphous(Y,Zr)O_x.

    WASEDA Yoshio, SUGIYAMA Kazumasa

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for General Scientific Research (C)

    Category: Grant-in-Aid for General Scientific Research (C)

    Institution: Tohoku University

    1991 - 1992

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    The sol-gel technique using metal alkoxides and other metal organic compounds as master materials has been developed for making various advanced materials and ZrO_2 is known to be included in this category. Thermal decomposition of amorphous-ZrO_2(a-ZrO_2) obtained by this sol-gel method produces a metastable tetragonal-ZrO_2(t-ZrO_2) in addition to monoclinic-ZrO_2(m-ZrO_2). In order to clarify this crystallization behavior, we analyzed the structure of a- ZrO_2 systematically. Two kinds of a-ZrO_2 were prepared by the hydrolytic condensation of Zr(OC_4H_9)_4 and the aqueous solution of ZrOCl_2+8H_2O. The anomalous X-ray scattering technique has been applied to obtain the environmental radial distribution function around a zirconium. Zirconium is quantitatively confirmed to be coordinated by six oxygens at a distance of 0.214nm and this Zr-octahedron is surrounded by other four octahedra at a distance of 0.341nm. This typical local ordering is suggested to be similar to that in the structure of m-ZrO_2 rather than that of t-ZrO_2. The structure of REE(Y or Er) substituted a-ZrO_2 have been analyzed in similar way. The typical local structure was not changed by the addition of REE elements to the a-ZrO_2, although cubic-ZrO_2 is produced by the crystallization of REE substituted a-ZrO_2. Therefore, it is rather suggested that the crystallization behavior is independent of the structural feature of a-ZrO_2 in this system. The research by using X-ray small-angle diffraction is strongly required for discussing the structural inhomogeneity in a-ZrO_2, which is one of the characteristic natures of the materials produced by sol-gel technique.

  24. Development of a System for Measuring Thermal Diffusivity of Thin Films by Laser Flash Method Based on a New Principle.

    WASEDA Yoshio, OHTA Hiromichi, SUGIYAMA Kazumasa

    Offer Organization: Japan Society for the Promotion of Science

    System: Grants-in-Aid for Scientific Research Grant-in-Aid for Developmental Scientific Research (B).

    Category: Grant-in-Aid for Developmental Scientific Research (B).

    Institution: Tohoku University

    1989 - 1990

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    A laser flash method for measuring thermal diffusivity in the direction parallel or perpendicular to the sample surface of film has been developed. On measurement of parallel direction of a sample, a pulsed laser beam which has narrow line-shaped cross section is flashed onto the front surface of the sample. The temperature response at the back surface at a certain distance away fro the line-shaped illuminated area of a laser beam is measured by the infrared detector and the thermal diffusivity value can be dete mined by comparing measured temperature response curve with theoretical one. On the other hand, the measurement of thermal diffusivity in the direction perpendicular to the sample surface of a film, a pulsed laser beam whose diameter is about 10 mm, is flashed onto the front surface of the sample. The temperature response at the back surface is measured by the infrared detector. The thermal diffusivity value can be determined by comparing with the theoretical solution including a pulse duration. The usefulness the present method has been demonstrated by measuring successfully thermal diffusivities of metallic foil samples of platinum (25 mum copper (18 mum), SUS304 stainles s steel (50 mum) and nickel (130 mum). Ruby lasers usually employed in the laser flash method for measuring thermal diffusivity of various inorganic substances a known to have the inhomogeneous energy distribution and their particular spatial intensity structure significantly effects the quantitative accuracy of the resultant thermal diffusivity data in some cases. Random packed fiber bundle made of plastic optical fiber wi plastic optical guiding rod has been developed for homogenizing the energy distribution in a laser beam on the specimen surface. T usefulness of this new device has been well approved by measuring the energy distribution and the thermal diffusivity of nickel disc. A simple cell and easy data processing have been proposed for measuring the thermal diffusivity of a liquid sample at high temperatures using the laser flash method. A cell consists of a liquid sample sandwiched by two metallic plates. The front surface one metallic plate is exposed to a single pulse of beam laser and the resulting temperature rise of the back surface of the other metal plate is measured. The logarithmic analysis proposed by James using the initial time region of the temperature response curve of a two layered cell system has been extended to apply to the present three layered cell system in order to estimate the thermal diffusivity value of a liquid sample. Measurements of distilled water and methanol were made first and the results were found to be in good agreement with the reference data. Then, the thermal diffusivities of molten NaNO_3 at 593-660 K and of molten KNO_3 at 621-694 were determined and the results also appear to agree reasonably well with those reported in the literature.

  25. 異常分散法を用いたメタミクト鉱物の構造キャラクタリゼーション

    杉山 和正

    Offer Organization: 日本学術振興会

    System: 科学研究費助成事業 奨励研究(A)

    Category: 奨励研究(A)

    Institution: 東北大学

    1988 - 1988

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Social Activities 7

  1. 大学見学訪問 仙台市上杉山中学校

    2013/10/23 -

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    金属材料研究所の案内および研究内容紹介

  2. 2014世界結晶年記念公開講座

    2013/10/14 -

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    高校生に2014世界結晶年の企画として講演を行った。

  3. 大学見学訪問 真室川町立真室川北部小学校

    2013/09/27 -

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    金属材料研究所の案内および研究内容紹介

  4. 大学見学訪問 仙台市上杉山中学校

    2012/10 -

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    金属材料研究所の案内および研究内容紹介

  5. 大学見学訪問 仙台市上杉山中学校

    2011/11 -

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    金属材料研究所の案内および研究内容紹介

  6. 大学見学訪問 仙台市上杉山中学校

    2010/11 -

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    金属材料研究所の案内および研究内容紹介

  7. 1日総合大学「模擬講義」 山形県立山形東高校

    2008/10/08 -

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    山形東高等学校において、結晶学の基礎の模擬講義を行った。

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    物質構造科学研究所放射光実験施設を用いた共同研究(2011G666 )

  2. 異常散乱法を利用した複硼酸塩結晶の構造解析

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    物質構造科学研究所放射光実験施設を用いた東北大学志村助教との共同研究(2012G680)

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    物質構造科学研究所放射光実験施設を用いたX線異常散乱法によるAgBr系超イオン導電ガラスの構造解析(2010G167、東北大学 志村玲子助教との共同研究)

  4. FeとMn含有角閃石中の酸化還元状態と結晶席選択性

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    物質構造科学研究所放射光実験施設を用いた共同研究(2010G117、東北大学 志村玲子助教との共同研究)

  5. リーチングによって作製したPd系合金触媒の構造

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    物質構造科学研究所放射光実験施設を用いた共同研究(2010G034)

  6. Pd-Cu-P金属ガラスのGFAと局所構造変化

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    物質構造科学研究所放射光実験施設を用いたPd-Cu-P金属ガラスの構造解析(2009G575、東京理科大学 春山修身教授との共同研究)

  7. Zr-PtおよびZr- Pd金属ガラスの構造ユニット

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    物質構造科学研究所放射光実験施設を用いたZr-PtおよびZr-Pd系非晶質金属構造解析(2009G091)

  8. LED照明の高効率・高品質化に係る基盤技術開発 (1)窒化物等結晶成長手法の高度化に関する基盤技術開発 高温成長アモノサーマル法によるバルク窒化ガリウム単結晶の製造技術開発

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    LED照明の高効率・高品質化に係る基盤技術開発の一環として、窒化物等結晶成長手法の高度化に関する基盤技術開発 高温成長アモノサーマル法によるバルク窒化ガリウム単結晶の製造技術開発をおこなった。

  9. バルクPd40Ni40P20金属ガラスの熱誘起CSRO過程に伴うアモルファス構造変化の研究

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    物質構造科学研究所放射光実験施設を用いた非晶質金属ガラスの構造解析(2008G573、東京理科大学 春山修身教授との共同研究)

  10. バルクZr-Cu基金属ガラスの中距離領域構造の解明と強靭性の発現メカニズム

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    物質構造科学研究所放射光実験施設を用いたZr-Cu系ガラスの構造解析(2008G695)

  11. XANESを用いた隕石中スピネル及び玄武岩ガラスのVの酸化比決定

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    物質構造科学研究所放射光実験施設を用いたPd-Cu-P金属ガラスの構造解析(2008G658、東京大学 三河内 岳助教との共同研究)

  12. 電気石に含まれる微量遷移元素元素の局所構造と発色原因の解明

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    物質構造科学研究所放射光実験施設を用いた共同利用研究(2009G207)

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